| Preface |
| Nomenclature |
| Part I Systematic Framing of Thermodynamics 1 |
| Chapter 1 Thermodynamics for Creation of a New Process 3 |
| 1.1 What Does Thermodynamics Offer You? 3 |
| 1.2 Targets of Thermodynamics 4 |
| 1.3 Thermodynamics as Basic Science 4 |
| Chapter 2 Thermodynamics of a Substance 7 |
| 2.1 Thermodynamics Comprises Three Kinds of Thermodynamics 7 |
| 2.2 What is Substance? 8 |
| 2.3 Energy H and Entropy S of a Substance 9 |
| Chapter 3 Thermodynamics of a Process 13 |
| 3.1 What is a Process? 13 |
| 3.2 Energy Change ΔH and Entropy Change ΔS 13 |
| 3.3 Intermediary Energy 16 |
| 3.4 Common Processes without Specification of Substances 19 |
| Chapter 4 Thermodynamics of a System 23 |
| 4.1 What is a System in Thermodynamics ? 23 |
| 4.2 The First and Second Laws of Thermodynamics 25 |
| 4.3 Interpretation of the First and Second Laws by ‘Water Model' 27 |
| Chapter 5 The First-Step Applications of Thermodynamics 33 |
| 5.1 Relationship between Energy Change ΔH and Heat of Reaction Qr 33 |
| 5.2 Calculation of ΔH for a Reaction as Combination of ΔH for Other Reactions 35 |
| 5.3 Thermodynamic Analysis of Exothermic and Endothermic Reactions 36 |
| 5.4 Thermodynamic Analysis of Electrolysis 40 |
| 5.5 Thermodynamic Analysis of a Loop 43 |
| Part II Properties of Substances and Chemical Equilibrium 51 |
| Chapter 6 Equations for Thermodynamics of Substances 53 |
| 6.1 Differential Forms of Energy h and Entropy s for 1 mol of Pure Substance 53 |
| 6.2 Calculation of Energy H and Entropy S for Gas 54 |
| 6.3 Calculation of Energy H and Entropy S for Liquid 59 |
| 6.4 Calculation of Energy H and Entropy S for Solid 60 |
| 6.5 Calculation of H and S for Substances with Multiple Phases 60 |
| Chapter 7 Chemical Equilibrium 61 |
| 7.1 Limit for Proceeding of a Process 61 |
| 7.2 Equilibrium Condition for a Gas-Phase Reaction 62 |
| 7.3 Equilibrium Condition for a Reaction with Multiple Phases 67 |
| 7.4 The Second-Step Applications - Applications of Equilibrium Constant Kp - 68 |
| 7.5 The Second-Step Applications - Application of Temperature Dependence of Kp - 75 |
| Part III Application of Thermodynamics to System Synthesis 83 |
| Chapter 8 Introduction to Exergy Change and Graphical Presentation by Vectors 85 |
| 8.1 Exergy Change Δε 85 |
| 8.2 Thermodynamics on a Two-Dimensional Space 87 |
| 8.3 Energy Level, A 89 |
| 8.4 Heat Source, Heat Sink, Work Source and Work Sink 93 |
| 8.5 Classification of Processes and System Synthesis on the Thermodynamic Compass 96 |
| 8.6 Exergy Loss 100 |
| 8.7 Representation of Processes on the Thermodynamic Compass 103 |
| Chapter 9 Process System Synthesis - The Third-Step Applications - 117 |
| 9.1 Equilibrium Viewpoint 117 |
| 9.2 Energy Transformation Viewpoint - Selection of Coupled Process - 119 |
| 9.3 Energy Transformation Viewpoint - Decomposition of Coupled Process - 122 |
| 9.4 Energy Transformation Viewpoint - Decomposition of a Target Process - 123 |
| Chapter 10 Toward Wider Applications 127 |
| 10.1 Chemical Cells and Fuel Cells 127 |
| 10.2 Behavior of Real Gas and Real Liquid 132 |
| 10.3 Partial Molar Quantities and Chemical Potential μ 133 |
| 10.4 Synthesis of an Entire System 133 |
| 10.5 Relationship to the Previous Thermodynamics 133 |
| 10.6 Characteristic Features of this Book - Closing Remarks - 138 |
| Appendix 139 |
| Index 145 |
| Preface |
| Nomenclature |
| Part I Systematic Framing of Thermodynamics 1 |
図書
