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1.

図書

図書
Wan-Hui Wang, Xiujuan Feng, Ming Bao
出版情報: Singapore : Springer, c2018  vi, 123 p. ; 24 cm
シリーズ名: Springer briefs in molecular science / series editor, Seth C. Rasmussen ; . Green chemistry for sustainability
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2.

図書

図書
edited by Stanley M. Roberts ... [et al.]
出版情報: Chichester : John Wiley, c2004  xvii, 256 p. ; 24 cm
シリーズ名: Catalysts for fine chemical synthesis ; v. 3
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3.

図書

図書
by Charles Kemball
出版情報: London : The Chemical Society, [c1977-]  v. ; 23 cm
シリーズ名: A Specialist periodical report
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4.

図書

図書
by Charles N. Satterfield and Thomas K. Sherwood
出版情報: Reading, Mass. : Addison-Wesley, c1963  vii, 118 p.
シリーズ名: Addison-Wesley series in chemical engineering
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5.

図書

図書
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6.

図書

図書
Ivan Kozhevnikov
出版情報: Chichester : J. Wiley & Sons, c2002  xiv, 201 p. ; 24 cm
シリーズ名: Catalysts for fine chemical synthesis ; v. 2
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Series Preface
Preface to Volume 2
Introduction / 1:
Scope and definitions / 1.1:
Nomenclature / 1.2:
Historical background / 1.3:
Introduction to catalysis by polyoxometalates / 1.4:
References
Properties of Polyoxometalates / 2:
Structures of polyoxometalates / 2.1:
General principles / 2.1.1:
The Keggin structure / 2.1.2:
The Wells-Dawson structure / 2.1.3:
The Anderson-Evans structure / 2.1.4:
The Dexter-Silverton structure / 2.1.5:
Crystal structure of heteropoly compounds / 2.2:
Thermal stability / 2.3:
Solubility / 2.4:
Formation and state in solution / 2.5:
Stability of polyoxometalates in solution / 2.5.1:
Polyoxometalates as ligands / 2.5.2:
Isotope exchange / 2.5.3:
Kinetics and mechanism of substitution in polyoxmetalates / 2.5.4:
Acid properties / 2.6:
Proton structure / 2.6.1:
Heteropoly acids in solutions / 2.6.2:
Acidity of solid heteropoly acids / 2.6.3:
Redox properties / 2.7:
Synthesis of Polyoxometalates / 3:
General methods of synthesis / 3.1:
Keggin polyoxometalates / 3.2:
12-Molybdosilicic acid, [alpha]-H[subscript 4 SiMo[subscript 12]O[subscript 40] / 3.2.1:
12-Tungstosilicic acid, [alpha]-H[subscript 4 SiW[subscript 12]O[subscript 40] / 3.2.2:
12-Tungstophosphoric acid, [alpha]-H[subscript 3 PW[subscript 12]O[subscript 40] / 3.2.3:
12-Molybdophosphoric acid, [alpha]-H[subscript 3 PMo[subscript 12]O[subscript 40] / 3.2.4:
12-Tungstogermanic acid, [alpha]-[H[subscript 4 GeW[subscript 12]O[subscript 40] / 3.2.5:
11-Molybdo-1-vanadophosphoric acid, H[subscript 4 PMo[subscript 11] VO[subscript 40] / 3.2.6:
10-Molybdo-2-vanadophosphoric acid, H[subscript 5 PMo[subscript 10]V[subscript 2]O[subscript 40] / 3.2.7:
9-Molybdo-3-vanadophosphoric acid, H[subscript 6 PMo[subscript 9] V[subscript 3]O[subscript 40] / 3.2.8:
Transition-metal-substituted tungstophosphates, {PW[subscript 11]MO[subscript 39]} / 3.2.9:
Wells-Dawson polyoxometalates / 3.3:
18-Tungstodiphosphoric acid, H[subscript 6 P[subscript 2]W[subscript 18]O[subscript 62] / 3.3.1:
Sandwich-type polyoxometalates / 3.4:
Na[subscript 12 WZn[subscript 3](H[subscript 2]O)[subscript 2](ZnW[subscript 9]O[subscript 34])[subscript 2] / 3.4.1:
Na[subscript 12 WCo[subscript 3 superscript II](H[subscript 2]O)[subscript 2] (Co[superscript II]W[subscript 9]O[subscript 34])[subscript 2] / 3.4.2:
K[subscript 11 WZnRu[subscript 2 superscript III](OH)(H[subscript 2]O) (ZnW[subscript 9]O[subscript 34])[subscript 2] / 3.4.3:
K[subscript 10 WZnRh[superscript III subscript 2](H[subscript 2]O)(ZnW[subscript 9]O[subscript 34])[subscript 2] / 3.4.4:
Peroxo polyoxometalates / 3.5:
Venturello complex, {PO[subscript 4 WO(O[subscript 2])[subscript 2 subscript 4]}[superscript 3-] / 3.5.1:
Polyoxometalate catalysts / 3.6:
Solid acid catalysts / 3.6.1:
Homogeneous catalysts / 3.6.2:
Acid Catalysis by Heteropoly Compounds / 4:
General overview / 4.1:
The scope of applications / 4.1.1:
Mechanistic principles / 4.1.2:
Homogeneous acid catalysis / 4.2:
Acid-catalysed reactions / 4.2.1:
Acid-catalysed reactions in biphasic liquid-liquid systems / 4.3:
Biphasic reactions / 4.3.1:
Heterogeneous acid catalysts / 4.4:
Heteropoly acid catalysts / 4.4.1:
Heterogeneous catalysis in liquid-solid systems / 4.4.2:
Heterogeneous catalysis in gas-solid systems / 4.4.3:
Deactivation and regeneration of solid heteropoly acid catalysts / 4.5:
Polyoxometalates as Catalysts for Selective Oxidation / 5:
Liquid-phase oxidation / 5.1:
Oxidation with dioxygen / 5.1.1:
Oxidation with hydrogen peroxide / 5.1.2:
Oxidation with organic peroxides / 5.1.3:
Miscellaneous oxidations / 5.1.4:
Gas-phase oxidation / 5.2:
Oxidation catalysts / 5.2.1:
Reactions / 5.2.3:
Miscellaneous Catalytic Applications of Polyoxometalates / 6:
Hydrogenation, carbonylation and related reactions / 6.1:
Polyanion-stabilised clusters / 6.2:
Polyoxometalates as catalyst precursors / 6.3:
Catalysis by Polyoxometalates in Industry / 7:
Acid catalysis / 7.1:
Hydration of olefins / 7.1.1:
Synthesis of ethyl acetate from ethylene and acetic acid / 7.1.2:
Selective oxidation / 7.2:
Oxidation of methacrolein in methacrylic acid / 7.2.1:
Oxidation of ethylene to acetic acid / 7.2.2:
Other Applications of Polyoxometalates / 8:
Analytical chemistry / 8.1:
Elemental analysis / 8.1.1:
Analysis of biomaterials / 8.1.2:
Separation / 8.2:
Processing of radioactive waste / 8.2.1:
Sorption of gases / 8.2.2:
Corrosion-resistant coatings / 8.3:
Polyoxometalates as additives to inorganic and organic matrices / 8.4:
Additives in sol-gel matrices / 8.4.1:
Additives in polymer matrices / 8.4.2:
Membranes / 8.5:
Fuel cells / 8.5.1:
Selective electrodes / 8.5.2:
Gas sensors / 8.5.3:
Polyoxometalates in medicine: antiviral and antitumoral activity / 8.6:
Index
Series Preface
Preface to Volume 2
Introduction / 1:
7.

図書

図書
edited by Stan M. Robert and Geraldine Poignant
出版情報: Chichester : J. Wiley & Sons, c2002  xviii, 225 p. ; 24 cm
シリーズ名: Catalysts for fine chemical synthesis ; v. 1
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Series Preface
Preface to Volume 1
Abbreviations
Review / Part I:
The Integration of Biotransformations into the Catalyst Portfolio / 1:
Hydrolysis of esters, amides, nitriles and oxiranes / 1.1:
Reduction reactions / 1.2:
Reduction of carbonyl compounds / 1.2.1:
Reduction of alkenes / 1.2.2:
Oxidative transformations / 1.3:
Carbon-carbon bond-forming reactions / 1.4:
Conclusions / 1.5:
References
Procedures / Part II:
General Information / 2:
Asymmetric Epoxidation / 3:
Introduction / 3.1:
Epoxidation of [alpha], [beta]-Unsaturated Carbonyl Compounds / 4:
Non-asymmetric epoxidation / 4.1:
Asymmetric epoxidation using poly-d-leucine / 4.2:
Synthesis of leucine N-carboxyanhydride / 4.2.1:
Synthesis of immobilized poly-d-leucine / 4.2.2:
Asymmetric epoxidation of (E)-benzylideneacetophenone / 4.2.3:
Conclusion / 4.2.4:
Asymmetric epoxidation using chiral modified diethylzinc / 4.3:
Epoxidation of 2-isobutylidene-1-tetralone / 4.3.1:
Asymmetric epoxidation of (E)-benzylideneacetophenone using the La-(R)-BINOL-Ph[subscript 3]PO/cumene hydroperoxide system / K. Daikai ; M. Kamaura ; J. Inanaga4.3.2:
Merits of the system / 4.4.1:
Epoxidation of Allylic Alcohols / 5:
Asymmetric epoxidation using a chiral titanium complex / 5.1:
Epoxidation of cinnamyl alcohol / 5.2.1:
Epoxidation of (E)-2-methyl-3-phenyl-2-propenol / 5.2.2:
Epoxidation of (E)-2-hexen-1-ol / 5.2.3:
Asymmetric epoxidation of (E)-undec-2-en-1-ol using poly(octamethylene tartrate) / D.C. Sherrington ; J.K. Karjalainen ; O.E.O. Hormi5.2.4:
Synthesis of branched poly (octamethylene-L-(+)-tartrate) / 5.3.1:
Asymmetric epoxidation of (E)-undec-2-en-1-ol / 5.3.2:
Epoxidation of Unfunctionalized Alkenes and [alpha], [beta]-Unsaturated Esters / 6:
Asymmetric epoxidation of disubstituted Z-alkenes using a chiral salen-manganese complex / 6.1:
Epoxidation of (Z)-methyl styrene / 6.1.1:
Epoxidation of (Z)-ethyl cinnamate / 6.1.2:
Asymmetric epoxidation of disubstituted E-alkanes using a D-fructose based catalyst / 6.1.3:
Epoxidation of (E)-stilbene / 6.2.1:
Enantioselective epoxidation of (E)-[beta]-methylstyrene by D[subscript 2]-symmetric chiral trans-dioxoruthenium (VI) porphyrins / Rui Zhang ; Wing-Yiu Yu ; Chi-Ming Che6.2.2:
Preparation of the trans-dioxoruthenium (VI) complexes with D[subscript 2]-symmetric porphyrins (H[subscript 2]L[superscript 1-3]) / 6.3.1:
Enantioselective epoxidation of (E)-[beta]-methylstyrene / 6.3.2:
Asymmetric Hydroxylation and Aminohydroxylation / 6.3.3:
Asymmetric aminohydroxylation of 4-methoxystyrene / P.O'Brien ; S.A. Osborne ; D.D. Parker7.1:
Asymmetric dihydroxylation of (1-cyclohexenyl)acetonitrile / Jean-Michel Vatele7.1.1:
(R,R)-(1,2-Dihydroxycyclohexyl)acetonitrile acetonide / 7.2.1:
Asymmetric Sulfoxidation / 7.2.2:
Asymmetric oxidation of sulfides and kinetic resolution of sulfoxides / Laura Palombi ; Arrigo Scettri8.1:
Asymmetric oxidation of 4-bromothioanisole / 8.1.1:
Kinetic resolution of racemic 4-bromophenyl methyl sulfoxide / 8.1.2:
Asymmetric Reduction of Ketones Using Organometallic Catalysts / 9:
Asymmetric hydrogenation using a metal catalyst: [Ru((S)-BiNAP)] / 9.1:
Asymmetric transfer hydrogenation of [beta]-ketoesters / Kathelyne Everaere ; Jean-Francois Carpentier ; Andre Mortreux ; Michel Bulliard9.3:
(S,S)-1,2-bis(tert-Butylmethylphosphino)ethane (BisP*): Synthesis and use as a ligand / T. Imamoto9.4:
Synthesis of BisP* / 9.4.1:
Synthesis of 1,2-bis(tert-butylmethylphosphino) ethaneruthenium bromide (BisP*-Ru) / 9.4.2:
Synthesis of (R)-(-)-methyl 3-hydroxypentanoate using (BisP*-Ru) / 9.4.3:
(1S,3R,4R)-2-Azanorbornylmethanol, an efficient ligand for ruthenium-catalysed asymmetric transfer hydrogenation of aromatic ketones / Diego A. Alonso ; Pher G. Andersson9.5:
Synthesis of ethyl(1S,3R,4R)-2-[(S)-1-phenylethylamino]-2-azabicyclo[2.2.1] hept-5-ene-3-carboxylate / 9.5.1:
Synthesis of (1S,3R,4R)-3-hydroxymethyl-2-azabicyclo[2.2.1]heptane / 9.5.2:
Ruthenium-catalysed asymmetric transfer hydrogenation of acetophenone / 9.5.3:
Asymmetric Reduction of Ketones Using Bakers' Yeast / 10:
Bakers' yeast reduction of ethyl acetoacetate / 10.1:
Enantioselective synthesis of cis-N-carbobenzyloxy-3-hydroxyproline ethyl ester / Mukund P. Sibi ; James W. Christensen10.2:
Immobilization of bakers' yeast / 10.2.1:
Bakers' yeast reduction of cis-N-carbobenzyloxy-3-ketoproline ethyl ester / 10.2.2:
Asymmetric Reduction of Ketones Using Nonmetallic Catalysts / 11:
Oxazaborolidine borane reduction of acetophenone / 11.1:
Oxazaphosphinamide borane reduction of chloroacetophenone / 11.3:
Asymmetric reduction of chloroacetophenone using a sulfoximine catalyst / 11.4:
Preparation of [beta]-hydroxysulfoximine borane / 11.4.1:
Reduction of chloroacetophenone using the sulfoximine borane / 11.4.2:
Summary / 11.4.3:
Asymmetric reduction of bromoketone catalysed by cis-aminoindanol oxazaborolidine / Chris H. Senanayake ; H. Scott Wilkinson ; Gerald J. Tanoury11.5:
Synthesis of aminoindanol oxazaborolidine / 11.5.1:
Asymmetric reduction of 2-bromo-(3-nitro-4-benzyloxy)acetophenone / 11.5.2:
Stereoselective reduction of 2,3-butadione monoxime trityl ether / 11.5.3:
Stereoselective reduction of methyl 3-oxo-2-trityloxyiminostearate / 11.5.5:
Stereoselective reduction of 1-(tert-butyldimethylsilyloxy)-3-oxo-2-trityloxyiminooctadecane / 11.5.6:
Enantioselective reduction of ketones using N-arylsulfonyl oxazaborolidines / Pingrong Liu ; Gregory R. Cook11.6:
Synthesis of N-(2-pyridinesulfonyl)-1-amino-2-indanol / 11.6.1:
Asymmetric reduction of a prochiral ketone (chloroacetophenone) / 11.6.2:
Reduction of ketones using amino acid anions as catalyst and hydrosilane as oxidant / Michael A. Brook11.7:
Asymmetric Hydrogenation of Carbon-Carbon Double Bonds Using Organometallic Catalysts / 12:
Hydrogenation of dimethyl itaconate using [Rh((S,S)-Me-BPE)] / 12.1:
Hydrogenation of an [alpha]-amidoacrylate using [Rh((R,R)-Me-DuPHOS)] / 12.3:
Hydrogenation of an [alpha]-amidoacrylate using [Rh(B[3.2.0]DPO)] complexes / 12.4:
Preparation of (COD)[subscript 2] Rh[superscript +]BF[subscript 4 superscript -] / 12.4.1:
Preparation of the bisphosphinite ligand / 12.4.2:
Asymmetric reduction of [alpha]-acetamido cinnamic acid / 12.4.3:
Hydrogenation of enol carbonates and 4-methylene-N-acyloxazolidinone using [Rh((R)-BiNAP)] complexes / P.H. Dixneuf ; C. Bruneau ; P. Le Gendre12.5:
Synthesis of (S)-4,4,5-trimethyl-1, 3-dioxolane-2-one / 12.5.1:
Synthesis of (S)-2-methyl-2,3-butanediol / 12.5.2:
Preparation of optically active N-acyloxazolidinones / 12.5.3:
Synthesis of (R)-N-propionyl-4,5,5-trimethyl-1, 3-oxazolidin-2-one / 12.5.4:
Enantioselective ruthenium-catalyzed hydrogenation of vinylphosphonic acids / Virginie Ratovelomanana-Vidal ; Jean-Pierre Genet12.6:
Synthesis of chiral Ru(II) catalysts / 12.6.1:
Asymmetric hydrogenation of vinylphosphonic acids carrying a phenyl substituent at C[subscript 2] / 12.6.2:
Asymmetric reduction of a vinylphosphonic acid carrying a naphthyl substituent at C[superscript 2] / 12.6.3:
Scope of the hydrogenation reaction / 12.6.4:
Synthesis of a cylindrically chiral diphosphine and asymmetric hydrogenation of dehydroamino acids / Jahyo Kang ; Jun Hee Lee12.7:
Preparation of (R,R)-1,1'-bis([alpha]-hydroxypropyl) ferrocene / 12.7.1:
Preparation of (R,R)-1,1'-bis [alpha-(dimethylamino)propyl]ferrocene / 12.7.2:
Preparation of (R,R,[subscript p]S,[subscript p]S)-1,1'-bis [alpha-(dimethylamino)propyl]-2,2'-bis (diphenyl-phosphino)ferrocene / 12.7.3:
Preparation of (R,R,[subscript p]S,[subscript p]S)-1,1'-bis [alpha-acetoxypropyl)-2,2'-bis(diphenyl-phosphino)ferrocene / 12.7.4:
Preparation of ([subscript p]S,[subscript p]S)-1, 1'-bis (diphenylphosphino)-2,2'-bis(1-ethylpropyl) ferrocene [(S,S)-3-Pt-FerroPHOS] / 12.7.5:
Preparation of [(COD)Rh(([subscript p]S, [subscript p]S)-1, 1'-bis(diphenylphosphino)-2,2'-bis (1-ethylpropyl)ferrocene superscript +]BF[superscript - subscript 4] / 12.7.6:
Asymmetric hydrogenation of [alpha]-acetamido cinnamic acid / 12.7.7:
Synthesis and application of diamino FERRIPHOS as ligand for enantioselective Rh-catalysed preparation of chiral [alpha]-amino acids / Matthias Lotz ; Juan J. Almena Perea ; Paul Knochel12.8:
Synthesis of 1,1'-di(benzoyl)ferrocene / 12.8.1:
Synthesis of (S,S)-1,1'-bis ([alpha]-hydroxyphenylmethyl)ferrocene / 12.8.2:
Synthesis of (S,S)-1,1'-bis ([alpha]-acetoxyphenylmethyl)ferrocene / 12.8.3:
Synthesis of (S,S)-1,1'-bis([alpha]-N,N-dimethylaminophenylmethyl)ferrocene / 12.8.4:
Synthesis of ([alpha]S, [alpha]'S)-1,1'-bis([alpha]-N, N-dimethylaminophenylmethyl)-(R,R)-1,1'bis(diphenylphosphino)ferrocene / 12.8.5:
Asymmetric hydrogenation of methyl-(Z)-3-phenyl-2-methyl-carboxamido-2-propenoate using (S)-(R)-diamino FERRIPHOS as chiral ligand / 12.8.6:
Employment of Catalysts Working in Tandem / 13:
A one-pot sequential asymmetric hydrogenation utilizing Rh(I)- and Ru(II)-catalysts / Takayuki Doi ; Takashi Takahashi13.1:
Synthesis of ethyl (Z)-4-acetamido-3-oxo-5-phenyl-4-pentenoate / 13.1.1:
Asymmetric hydrogenation of ethyl 4-acetamido-3-oxo-5-phenyl-4-pentenoate / 13.1.2:
Index
Series Preface
Preface to Volume 1
Abbreviations
8.

図書

図書
[edited by] Roger Arthur Sheldon, Herman van Bekkum
出版情報: Weinheim ; New York : Wiley-VCH, c2001  xxv, 611 p. ; 25 cm
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9.

図書

図書
Hrsg. Gabriele Centi ; Hrsg. Rutger A. van Santen
出版情報: Weinheim : WILEY-VCH, c2007  xxiii, 423 p ; 25 cm
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10.

図書

図書
edited by W.M.H. Sachtler, G.C.A. Schuit, P. Zwietering
出版情報: Amsterdam : North-Holland, 1965  2 v. ; 23 cm
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