Multiple bonds between metal atoms

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Multiple bonds between metal atoms / F. Albert Cotton, Richard A. Walton

資料種別:

図書

出版情報:

New York : Wiley, c1982

形態:

xiv, 466 p. ; 24 cm

著者名:

ISBN:

9780471046868 [0471046868]

書誌ID:

BA0990162X

子書誌情報

フルテキスト

所蔵情報

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書誌詳細

注記:

"A Wiley-Interscience publication."
Includes bibliographical references and index

主題:

Metal-metal bonds

言語:

英語

目次情報:

Introduction and Survey

Prolog / 1.1：

From Werner to the new transition metal chemistry / 1.1.1：

Prior to about 1963 / 1.1.2：

How It All Began / 1.2：

Rhenium chemistry from 1963 to 1965 / 1.2.1：

The recognition of the quadruple bond / 1.2.2：

Initial work on other elements / 1.2.3：

An Overview of the Multiple Bonds / 1.3：

A qualitative picture of the quadruple bond / 1.3.1：

Bond orders less than four / 1.3.2：

Oxidation states / 1.3.3：

Growth of the Field / 1.4：

Going Beyond Two / 1.5：

Complexes of the Group 5 Elements

General Remarks / 2.1：

Divanadium Compounds / 2.2：

Triply-bonded divanadium compounds / 2.2.1：

Metal-metal vs metal-ligand bonding / 2.2.2：

Divanadium compounds with the highly reduced V₂³⁺ core / 2.2.3：

Diniobium Compounds / 2.3：

Diniobium paddlewheel complexes / 2.3.1：

Diniobium compounds with calix[4]arene ligands and related species / 2.3.2：

Tantalum / 2.4：

Chromium Compounds

Dichromium Tetracarboxylates / 3.1：

History and preparation / 3.1.1：

Properties of carboxylate compounds / 3.1.2：

Unsolvated Cr₂(O₂CR)₄ compounds / 3.1.3：

Other Paddlewheel Compounds / 3.2：

The first 'supershort' bonds / 3.2.1：

2-Oxopyridinate and related compounds / 3.2.2：

Carboxamidate compounds / 3.2.3：

Amidinate compounds / 3.2.4：

Guanidinate compounds / 3.2.5：

Miscellaneous Dichromium Compounds / 3.3：

Compounds with intramolecular axial interactions / 3.3.1：

Compounds with Cr-C bonds / 3.3.2：

Other pertinent results / 3.3.3：

Concluding Remarks / 3.4：

Molybdenum Compounds

Dimolybdenum Bridged by Carboxylates or Other O,O Ligands / 4.1：

General remarks / 4.1.1：

Mo₂(O₂CR)₄ compounds / 4.1.2：

Other compounds with bridging carboxyl groups / 4.1.3：

Paddlewheels with other O,O anion bridges / 4.1.4：

Paddlewheel Compounds with O,N, N,N and Other Bridging Ligands / 4.2：

Compounds with anionic O,N bridging ligands / 4.2.1：

Compounds with anionic N,N bridging ligands / 4.2.2：

Compounds with miscellaneous other anionic bridging ligands / 4.2.3：

Non-Paddlewheel Mo₂⁴⁺ Compounds / 4.3：

Mo₂X₈^4- and Mo₂X₆(H₂O)₂^2- compounds / 4.3.1：

[Mo₂X₈H]^3- compounds / 4.3.2：

Other aspects of dimolybdenum halogen compounds / 4.3.3：

M₂X₄L₄ and Mo₂X₄(LL)₂ compounds / 4.3.4：

Cationic complexes of Mo₂⁴⁺ / 4.3.5：

Complexes of Mo₂⁴⁺ with macrocyclic, polydentate and chelate ligands / 4.3.6：

Alkoxide compounds of the types Mo₂(OR)₄L₄ and Mo₂(OR)₄(LL)₂ / 4.3.7：

Other Aspects of Mo₂⁴⁺ Chemistry / 4.4：

Cleavage of Mo₂⁴⁺ compounds / 4.4.1：

Redox behavior of Mo₂⁴⁺ compounds / 4.4.2：

Hydrides and organometallics / 4.4.3：

Heteronuclear Mo-M compounds / 4.4.4：

An overview of Mo-Mo bond lengths in Mo₂⁴⁺ compounds / 4.4.5：

Higher-order Arrays of Dimolybdenum Units / 4.5：

General concepts / 4.5.1：

Two linked pairs with carboxylate spectator ligands / 4.5.2：

Two linked pairs with nonlabile spectator ligands / 4.5.3：

Squares: four linked pairs / 4.5.4：

Loops: two pairs doubly linked / 4.5.5：

Rectangular cyclic quartets / 4.5.6：

Other structural types / 4.5.7：

Tungsten Compounds

Multiple Bonds in Ditungsten Compounds / 5.1：

The W₂⁴⁺ Tetracarboxylates / 5.2：

W₂⁴⁺ Complexes Containing Anionic Bridging Ligands Other Than Carboxylate / 5.3：

W₂⁴⁺ Complexes without Bridging Ligands / 5.4：

Compounds coordinated by only anionic ligands / 5.4.1：

Compounds coordinated by four anionic ligands and four neutral ligands / 5.4.2：

Multiple Bonds in Heteronuclear Dimetal Compounds of Molybdenum and Tungsten / 5.5：

Paddlewheel Compounds with W₂⁵⁺ or W₂⁶⁺ Cores / 5.6：

X₃ M ≡ MX₃ Compounds of Molybdenum and Tungsten

Introduction / 6.1：

Homoleptic X₃M ≡ MX₃ Compounds / 6.2：

Synthesis and characterization of homoleptic M₂X₆ compounds / 6.2.1：

Bonding in M₂X₆ compounds / 6.2.2：

X₃M ≡ MX₃ Compounds as Molecular Precursors to Extended Solids / 6.2.3：

M₂X₂(NMe₂)₄ and M₂X₄(NMe₂)₂ Compounds / 6.3：

Other M₂X₂Y₄, M₂X_6-n Y_n and Related Compounds / 6.4：

Mo₂X₂(CH₂SiMe₃)₄ compounds / 6.4.1：

1,2-M₂R₂(NMe₂)₄ compounds and their derivatives / 6.4.2：

M₄ Complexes: Clusters or Dimers? / 6.5：

Molybdenum and tungsten twelve-electron clusters M₄(OR)₁₂ / 6.5.1：

M₄X₄(OPrⁱ)₈ (X = Cl, Br) and Mo₄Br₃(OPrⁱ)₉ / 6.5.2：

W₄ (p-tolyl)₂ (OPrⁱ)₁₀ / 6.5.3：

W₄O(X)(OPrⁱ)₉, (X = Cl or OPrⁱ) / 6.5.4：

K(18-crown-6)₂Mo₄(μ₄-H)(OCH₂Bu^t)₁₂ / 6.5.5：

Linked M₄ units containing localized MM triple bonds / 6.5.6：

M₂X₆L, M₂X₆L₂ and Related Compounds / 6.6：

Mo₂(CH₂Ph)₂(OPrⁱ)₄(PMe₃) and [Mo₂(OR)₇]^- / 6.6.1：

M₂(OR)₆L₂ compounds and their congeners / 6.6.2：

Amido-containing compounds / 6.6.3：

Mo₂Br₂(CHSiMe₃)₂(PMe₃)₄ / 6.6.4：

Calix[4]arene complexes / 6.6.5：

Triple Bonds Uniting Five- and Six-Coordinate Metal Atoms / 6.7：

Redox Reactions at the M₂⁶⁺ Unit / 6.8：

Organometallic Chemistry of M₂(OR)₆ and Related Compounds / 6.9：

Carbonyl adducts and their products / 6.9.1：

Isocyanide complexes / 6.9.2：

Reactions with alkynes / 6.9.3：

Reactions with C≡N bonds / 6.9.4：

Reactions with C=C bonds / 6.9.5：

Reactions with H₂ / 6.9.6：

Reactions with organometallic compounds / 6.9.7：

(η-C₅H₄R)₂W₂X₄ compounds where R = Me, Prⁱ and X = Cl, Br / 6.9.8：

Conclusion / 6.10：

Technetium Compounds

Synthesis and Properties of Technetium / 7.1：

Preparation of Dinuclear and Polynuclear Technetium Compounds / 7.2：

Bonds of Order 4 and 3.5 / 7.3：

Tc₂⁶⁺ and Tc₂⁵⁺ Carboxylates and Related Species with Bridging Ligands / 7.4：

Bonds of Order 3 / 7.5：

Hexanuclear and Octanuclear Technetium Clusters / 7.6：

Rhenium Compounds

The Last Naturally Occurring Element to Be Discovered / 8.1：

Synthesis and Structure of the Octachlorodirhenate(III) Anion / 8.2：

Synthesis and Structure of the Other Octahalodirhenate(III) Anions / 8.3：

Substitution Reactions of the Octahalodirhenate(III) Anions that Proceed with Retention of the Re₂⁶⁺ Core / 8.4：

Monodentate anionic ligands / 8.4.1：

The dirhenium(III) carboxylates / 8.4.2：

Other anionic ligands / 8.4.3：

Neutral ligands / 8.4.4：

Dirhenium Compounds with Bonds of Order 3.5 and 3 / 8.5：

The first metal-metal triple bond: Re₂Cl₅(CH₃SCH₂CH₂SCH₃)₂ and related species / 8.5.1：

Simple electron-transfer chemistry involving the octahalodirhenate(III) anions and related species that contain quadruple bonds / 8.5.2：

Oxidation of [Re₂X₈]^2- to the nonahalodirhenate anions [Re₂X₉]^n- (n = 1 or 2) / 8.5.3：

Re₂⁵⁺ and Re₂⁴⁺ halide complexes that contain phosphine ligands / 8.5.4：

Other Re₂⁵⁺ and Re₂⁴⁺ complexes / 8.5.5：

Other dirhenium compounds with triple bonds / 8.5.6：

Dirhenium Compounds with Bonds of Order Less than 3 / 8.6：

Cleavage of Re-Re Multiple Bonds by o-donor and π-acceptor Ligands / 8.7：

σ-Donor ligands / 8.7.1：

Jπ-Acceptor ligands / 8.7.2：

Other Types of Multiply Bonded Dirhenium Compounds / 8.8：

Postscript on Recent Developments / 8.9：

Ruthenium Compounds

Ru₂⁵⁺ Compounds / 9.1：

Ru₂⁵⁺ compounds with O,O′-donor bridging ligands / 9.2.1：

Ru₂⁵⁺ compounds with N,O-donor bridging ligands / 9.2.2：

Ru₂⁵⁺ compounds with N,N′-donor bridging ligands / 9.2.3：

Ru₂⁴⁺ Compounds / 9.3：

Ru₂⁴⁺ compounds with O,O′-donor bridging ligands / 9.3.1：

Ru₂⁴⁺ compounds with N,O-donor bridging ligands / 9.3.2：

Ru₂⁴⁺ compounds with N,N′-donor bridging ligands / 9.3.3：

Ru₂⁶⁺ Compounds / 9.4：

Ru₂⁶⁺ compounds with O,O′-donor bridging ligands / 9.4.1：

Ru₂⁶⁺ compounds with N,N′-donor bridging ligands / 9.4.2：

Compounds with Macrocyclic Ligands / 9.5：

Applications / 9.6：

Catalytic activity / 9.6.1：

Biological importance / 9.6.2：

Osmium Compounds

Syntheses, Structures and Reactivity of Os₂⁶⁺ Compounds / 10.1：

Syntheses and Structures of Os₂⁵⁺ Compounds / 10.2：

Syntheses and Structures of Other Os₂ Compounds / 10.3：

Magnetism, Electronic Structures, and Spectroscopy / 10.4：

Iron, Cobalt and Iridium Compounds / 10.5：

Di-iron Compounds / 11.1：

Dicobalt Compounds / 11.3：

Tetragonal paddlewheel compounds / 11.3.1：

Trigonal paddlewheel compounds / 11.3.2：

Dicobalt compounds with unsupported bonds / 11.3.3：

Compounds with chains of cobalt atoms / 11.3.4：

Di-iridium Compounds / 11.4：

Paddlewheel compounds and related species / 11.4.1：

Unsupported Ir-Ir bonds / 11.4.2：

Other species with Ir-Ir bonds / 11.4.3：

Iridium blues / 11.4.4：

Rhodium Compounds

Dirhodium Tetracarboxylato Compounds / 12.1：

Preparative methods and classification / 12.2.1：

Structural studies / 12.2.2：

Other Dirhodium Compounds Containing Bridging Ligands / 12.3：

Complexes with fewer than four carboxylate bridging groups / 12.3.1：

Complexes supported by hydroxypyridinato, carboxamidato and other (N, O) donor monoanionic bridging groups / 12.3.2：

Complexes supported by amidinato and other (N, N) donor bridging groups / 12.3.3：

Complexes supported by sulfur donor bridging ligands / 12.3.4：

Complexes supported by phosphine and (P, N) donor bridging ligands / 12.3.5：

Complexes supported by carbonate, sulfate and phosphate bridging groups / 12.3.6：

Dirhodium Compounds with Unsupported Rh-Rh Bonds / 12.4：

The dirhodium(II) aquo ion / 12.4.1：

The [Rh₂(NCR)₁₀]⁴⁺ cations / 12.4.2：

Complexes with chelating and macrocyclic nitrogen ligands / 12.4.3：

Other Dirhodium Compounds / 12.5：

Complexes with isocyanide ligands / 12.5.1：

Rhodium blues / 12.5.2：

Reactions of Rh₂⁴⁺ Compounds / 12.6：

Oxidation to Rh₂⁵⁺ and Rh₂⁶⁺ species / 12.6.1：

Cleavage of the Rh-Rh bond / 12.6.2：

Applications of Dirhodium Compounds / 12.7：

Catalysis / 12.7.1：

Supramolecular arrays based on dirhodium building blocks / 12.7.2：

Biological applications of dirhodium compounds / 12.7.3：

Photocatalytic reactions / 12.7.4：

Other applications / 12.7.5：

Chiral Dirhodium(II) Catalysts and Their Applications

Synthetic and Structural Aspects of Chiral Dirhodium(II) Carboxamidates / 13.1：

Synthetic and Structural Aspects of Dirhodium(II) Complexes Bearing Orthometalated Phosphines / 13.3：

Dirhodium(II) Compounds as Catalysts / 13.4：

Catalysis of Diazo Decomposition / 13.5：

Chiral Dirhodium(II) Carboxylates / 13.6：

Chiral Dirhodium(II) Carboxamidates / 13.7：

Catalytic Asymmetric Cyclopropanation and Cyclopropenation / 13.8：

Intramolecular reactions / 13.8.1：

Intermolecular reactions / 13.8.2：

Cyclopropenation / 13.8.3：

Macrocyclization / 13.8.4：

Metal Carbene Carbon-Hydrogen Insertion / 13.9：

Catalytic Ylide Formation and Reactions / 13.9.1：

Additional Transformations of Diazo Compounds Catalyzed by Dirhodium(II) / 13.11：

Silicon-Hydrogen Insertion / 13.12：

Nickel, Palladium and Platinum Compounds

Dinickel Compounds / 14.1：

Dipalladium Compounds / 14.3：

A singly bonded Pd₂⁶⁺ species / 14.3.1：

Chemistry of Pd₂⁵⁺ and similar species / 14.3.2：

Other compounds with Pd-Pd interactions / 14.3.3：

Diplatinum Compounds / 14.4：

Complexes with sulfate and phosphate bridges / 14.4.1：

Complexes with pyrophosphite and related ligands / 14.4.2：

Complexes with carboxylate, formamidinate and related ligands / 14.4.3：

Complexes containing monoanionic bridging ligands with N,O and N,S donor sets / 14.4.4：

Unsupported Pt-Pt bonds / 14.4.5：

Dinuclear Pt₂⁵⁺ species / 14.4.6：

The platinum blues / 14.4.7：

Other compounds

Extended Metal Atom Chains

Overview / 15.1：

EMACs of Chromium / 15.2：

EMACs of Cobalt / 15.3：

EMACs of Nickel and Copper / 15.4：

EMACs of Ruthenium and Rhodium / 15.5：

Other Metal Atom Chains / 15.6：

Physical, Spectroscopic and Theoretical Results

Structural Correlations / 16.1：

Bond orders and bond lengths / 16.1.1：

Internal rotation / 16.1.2：

Axial ligands / 16.1.3：

Comparison of second and third transition series homologs / 16.1.4：

Disorder in crystals / 16.1.5：

Rearrangements of M₂X₈ type molecules / 16.1.6：

Diamagnetic anisotropy of M-M multiple bonds / 16.1.7：

Thermodynamics / 16.2：

Thermochemical data / 16.2.1：

Bond energies / 16.2.2：

Electronic Structure Calculations / 16.3：

Background / 16.3.1：

[M₂X₈]^n- and M₂X₄(PR₃)₄ species / 16.3.2：

The M₂(O₂CR)₄ (M = Cr, Mo, W) molecules / 16.3.3：

M₂(O₂CR)₄R′₂ (M = Mo, W) compounds / 16.3.4：

Dirhodium species / 16.3.5：

Diruthenium compounds / 16.3.6：

M₂X₆ molecules (M = Mo, W) / 16.3.7：

Other calculations / 16.3.8：

Electronic Spectra / 16.4：

Details of the δ manifold of states / 16.4.1：

Observed δ → δ* transitions / 16.4.2：

Other electronic absorption bands of Mo₂, W₂, Tc₂ and Re₂ species / 16.4.3：

Spectra of Rh₂, Pt₂, Ru₂ and Os₂ compounds / 16.4.4：

CD and ORD spectra / 16.4.5：

Excited state distortions inferred from vibronic structure / 16.4.6：

Emission spectra and photochemistry / 16.4.7：

Photoelectron Spectra / 16.5：

Paddlewheel molecules / 16.5.1：

Other tetragonal molecules / 16.5.2：

M₂X₆ molecules / 16.5.3：

Miscellaneous other PES results / 16.5.4：

Vibrational Spectra / 16.6：

M-M stretching vibrations / 16.6.1：

M-L stretching vibrations / 16.6.2：

Other types of Spectra / 16.7：

Electron Paramagnetic Resonance / 16.7.1：

X-Ray spectra, EXAFS, and XPS / 16.7.2：

Abbreviations

Index

Introduction and Survey

Prolog / 1.1：

From Werner to the new transition metal chemistry / 1.1.1：

Prior to about 1963 / 1.1.2：

How It All Began / 1.2：

Rhenium chemistry from 1963 to 1965 / 1.2.1：

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