Preface |
List of contributors |
The zeolite scene / L. MoscouChapter 1: |
Introduction |
What makes zeolites so special? |
Zeolite applications |
Zeolite market volume |
Economic impact |
Zeolite R&D |
Zeolite networks |
Conclusion |
References |
Zeolites and molecular sieves. An historical perspective / E.M. FlanigenChapter 2: |
Early history |
Industrial history |
The 80's |
Review of molecular sieve and zeolite fundamentals |
History of molecular sieve materials |
History of synthesis |
The future |
History of international conferences and organizations |
Historical epilogue |
Structural subunits in silicate and phosphate structures / H. van KoningsveldChapter 3: |
Some basic concepts |
Structural subunits (SSU) |
Description of the structure types |
Conclusions |
The preparation of molecular sieves / Chapter 4: |
Synthesis of zeolites / J.C. JansenA: |
Preparatory |
Zeolite product versus the synthesis mixture |
The low temperature reaction mixture |
The temperature raise of the reaction mixture |
The high temperature reaction process |
Isolation of the zeolite product |
Reaction parameters |
All silica molecular sieves |
Clathrasils |
Examples of systematic research |
Literature sources pertaining zeolite preparation aspects |
Synthesis of AIPO[subscript 4]-based molecular sieves / S.T. WilsonB: |
Historical background |
AlPO[subscript 4]-based molecular sieves |
Synthesis |
Other issues |
Final comments |
Modified zeolites / R. SzostakChapter 5: |
Extraction of aluminum from zeolite frameworks |
Cracking catalyst development: historically a question of stability |
Methods for dealuminating zeolite Y |
Effect of sodium content |
Aluminum extraction: characterization of framework and nonframework components |
Spectroscopic techniques applied to understanding dealumination |
Application of surface spectroscopic techniques |
Does getting there by a different route get you the same place? |
And then there is reality |
Modification of high silica zeolite structures: Differences from zeolite Y |
Reactions of zeolites with fluoride |
Enhancement in activity in ZSM-5 with steam |
Hydrothermal enhancement of activity in metallosilicates |
CVD methods applied to zeolites: SiCl[subscript 4] treatment |
Insertion of silicon into AlPO[subscript 4] structures |
CVD as a method of pore mouth restructuring |
Internal pore modification |
Coming full circle: putting aluminum back into the structure |
Clays from two to three dimensions / R.A. SchoonheydtChapter 6: |
Smectites |
Properties of smectites |
Pillared clays |
Techniques of zeolite characterization / J.H.C. van Hooff ; J.W. RoelofsenChapter 7: |
Zeolite structure and structural defects |
Pore structure of zeolites |
Chemical composition of zeolites |
Determination of the framework Si/Al ratio |
Determination of zeolite acidity |
Zeolite stability |
Zeolite morphology and particle size |
Solid state NMR spectroscopy applied to zeolites / G. EngelhardtChapter 8: |
Basic principles and methods of high-resolution solid-state NMR |
Multinuclear high-resolution solid-state NMR of zeolites |
NMR of aluminophosphate molecular sieves |
Introduction to zeolite theory and modelling / R.A. van Santen ; D.P. de Bruyn ; C.J.J. den Ouden ; B. SmitChapter 9: |
Theory on zeolite lattice stability |
Theory on adsorption and acidity |
Computer modelling techniques |
Computer simulation of adsorption and diffusion |
Future perspectives |
Ion exchange in zeolites / R.P. TownsendChapter 10: |
A picture of the ion-exchange system |
Equilibrium aspects of ion exchange in zeolites |
The kinetics of ion exchange |
Zeolites and detergency |
Other recent developments and trends |
Diffusion in zeolite molecular sieves / M.F.M. PostChapter 11: |
Diffusion in porous zeolite media: general principles |
Experimental measurement of diffusitivities in molecular sieves |
Numerical values of diffusivities |
Diffusion and catalysis |
List of symbols |
Introduction to acid catalysis with zeolites in hydrocarbon reactions / P.A. Jacobs ; J.A. MartensChapter 12: |
Screening of zeolite catalysts at the laboratory scale |
Reaction mechanisms in zeolite catalyzed reactions |
Shape-selective catalysis in acid zeolites |
Preparation of zeolitic catalysts / H.W. Kouwenhoven ; B. de KroesChapter 13: |
Catalyst preparation procedure |
Fluidized catalytic cracking (FCC) catalysts |
Preparation of Ti catalysts for hydroxylation of phenol |
Zeolite supported noble metal catalysts |
Coke formation on zeolites / H.G. KargeChapter 14: |
Methods of coke investigation and results |
Particular phenomena related to coke formation |
Summary and concluding remarks |
Note |
Hydrocarbon processing with zeolites / I.E. Maxwell ; W.H.J. StorkChapter 15: |
Oil-conversion processes |
Gas-conversion processes |
Future developments |
Zeolites in organic syntheses / W.F. Holderich ; H. van BekkumChapter 16: |
General aspects |
Non-catalytic use of zeolites in organic synthesis |
Zeolite-catalyzed isomerizations |
Electrophilic substitution of arenes |
Oxidation reactions |
Zeolite-catalyzed cyclizations |
Nucleophilic substitution and addition |
Zeolite-catalyzed two- and multi-step syntheses |
Final remarks |
Zeolite structures / Appendix I: |
Pore sizes of zeolites / Appendix II: |
Keyword index |
Studies in Surface Science and Catalysis (other volumes in the series) |
Preface |
List of contributors |
The zeolite scene / L. MoscouChapter 1: |
Introduction |
What makes zeolites so special? |
Zeolite applications |