Introduction / 1: |
The Laws of Thermodynamics / 1.1: |
Definitions / 1.2: |
Exothermic and Endothermic Processes / 1.3: |
The First Law / 2: |
Internal Energy / 2.1: |
Heat / 2.2: |
Work / 2.3: |
Heat Capacity, Enthalpy and Thermochemistry / 3: |
Heat Capacity, C / 3.1: |
Enthalpy / 3.2: |
Thermochemistry / 3.3: |
Reaction Enthalpy and Hess's Law / 3.4: |
Temperature Dependence of Enthalpy Changes / 3.5: |
The Second and Third Laws: Entropy / 4: |
Spontaneous Processes / 4.1: |
The Clausius Inequality / 4.2: |
Temperature Dependence of the Entropy, S / 4.3: |
Free Energy / 5: |
Gibbs and Helmholtz Free Energy / 5.1: |
Maximum Work / 5.2: |
Pressure and Temperature Dependence of G / 5.3: |
Phase Transitions / 6: |
Stability of Phases / 6.1: |
Effect of Pressure on the Boiling Point / 6.2: |
Phase Diagrams / 6.3: |
Clapeyron Equation / 6.4: |
Clausius-Clapeyron Equation / 6.5: |
Gibbs Free Energy and Chemical Potential / 6.6: |
Chemical Equilibrium / 7: |
Extent of Reaction and the Reaction Gibbs Free Energy / 7.1: |
The Equilibrium Constant / 7.2: |
Temperature Dependence of the Equilibrium Constant / 7.3: |
Effect of Pressure on Equilibrium / 7.4: |
Le Chatelier's Principle / 7.5: |
The Statistical Definition of Entropy / 8: |
Statistical Entropy / 8.1: |
Microstates / 8.2: |
Calculating the Entropy / 8.3: |
Connecting Microscopic and Macroscopic Properties / 9: |
Ensembles / 9.1: |
Ensemble Averages / 9.2: |
What is the Preferred State of a System? / 9.3: |
The Boltzmann Distribution / 9.4: |
The Partition Function / 10: |
Definition of the Partition Function / 10.1: |
The Internal Energy / 10.2: |
The Helmholtz Free Energy / 10.3: |
The Entropy / 10.4: |
The Pressure / 10.5: |
The Isochoric Heat Capacity / 10.6: |
An Ideal Gas of Atoms / 11: |
The Ideal Gas / 11.1: |
The Molecular Partition Function / 11.2: |
The Translational Partition Function / 11.3: |
The Internal Energy of a Monatomic Ideal Gas / 11.4: |
The Heat Capacity of a Monatomic Ideal Gas / 11.5: |
The Pressure of a Monatomic Ideal Gas / 11.6: |
The Entropy of a Monatomic Ideal Gas / 11.7: |
An Ideal Gas of Diatomic Molecules / 12: |
The Rotational Partition Function / 12.1: |
Rotation and Symmetry / 12.2: |
The Properties of a Rigid Rotor / 12.3: |
The Harmonic Oscillator / 12.4: |
Thermodynamic Properties of the Harmonic Oscillator / 12.5: |
The Electronic Partition Function / 12.6: |
Statistical Mechanics and Equilibrium / 13: |
Thermodynamics of Gaseous Molecules / 13.1: |
The Gibbs Free Energy / 13.2: |
The Standard Gibbs Free Energy / 13.3: |
The Equilibrium Constant, K[subscript p] / 13.4: |
Glossary |
Answers to Problems |
Subject Index |
Introduction / 1: |
The Laws of Thermodynamics / 1.1: |
Definitions / 1.2: |
Exothermic and Endothermic Processes / 1.3: |
The First Law / 2: |
Internal Energy / 2.1: |