Titanium and zirconium in organic synthesis

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Titanium and zirconium in organic synthesis / edited by Ilan Marek

資料種別:: 図書
出版情報:: Weinheim : Wiley-VCH, c2002
形態:: xxv, 512 p. ; 25 cm
著者名:: Marek, Ilan
ISBN:: 9783527304288 [3527304282]
書誌ID:: BA57682039

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注記:

Includes bibliographical references and index
"with a foreword by Victor Snieckus" -- Cover

主題:

Organic compounds--Synthesis; Organotitanium compounds

言語:

英語

目次情報:

Foreword

Preface

List of Contributors

Synthesis and Reactivity of Zirconocene Derivatives / Ei-ichi Negishi ; Shouquan Huo1：

Introduction and Historical Background / 1.1：

Fundamental Patterns of Transformations of Zirconocene Derivatives / 1.2：

Synthesis of Organic Derivatives of ZrCp[subscript 2] / 1.3：

Reactivity of Organylzirconocene Compounds / 1.4：

References

Zirconacyclopentadienes in Organic Synthesis / Tamotsu Takahashi ; Yanzhong Li2：

Introduction / 2.1：

Preparation and Reaction of Zirconacyclopentadienes / 2.2：

Carbon--Carbon Bond Formation / 2.3：

Conclusion / 2.4：

Elaboration of Organozirconium Species by Insertion of Carbenoids / Sally Dixon ; Richard J. Whitby3：

Carbonylation and Isonitrile Insertion / 3.1：

Insertion of 1-Halo-1-lithio Species into Organozirconocenes / 3.3：

References and Notes / 3.4：

Hydrozirconation and Further Transmetalation Reactions / Bruce H. Lipshutz ; Steven S. Pfeiffer ; Kevin Noson ; Takashi Tomioka4：

Hydrozirconation/Quenching / 4.1：

Hydrozirconation: Ring-Forming and Ring-Opening Reactions / 4.3：

Acyl Zirconocenes / 4.4：

Allylic Zirconocenes / 4.5：

Cross-Coupling Reactions / 4.6：

Zirconium to Copper / 4.7：

Zirconium to Zinc / 4.8：

Zirconium to Boron / 4.9：

Zirconium to Nickel / 4.10：

Summary and Outlook / 4.11：

Acylzirconocenes in Organic Synthesis / Yuji Hanzawa5：

Synthesis and Stability of Acylzirconocene Complexes / 5.1：

Reactions of Acylzirconocene Complexes / 5.3：

Reactions of Acylzirconocene Chlorides as "Unmasked" Acyl Group Donors / 5.4：

Reactivity of [alpha],[beta]-Unsaturated Acylzirconocene Chlorides toward Nucleophiles / 5.5：

Chiral Zirconium Catalysts for Enantioselective Synthesis / Amir H. Hoveyda5.6：

Zr-Catalyzed Enantioselective C-C Bond-Forming Reactions / 6.1：

Zr-Catalyzed Enantioselective C-N Bond-Forming Reactions / 6.3：

Zr-Catalyzed Enantioselective C-H Bond-Forming Reactions / 6.4：

gem-Metallozirconocenes in Organic Synthesis / Valery M. Dembitsky ; Morris Srebnik6.5：

1,1-Aluminiozirconocene Complexes / 7.1：

1,1-Boriozirconocene Complexes / 7.3：

1,1-Lithiozirconocene Reagents / 7.4：

1,1-Stanniozirconocene Reagents / 7.5：

1,1-Galliozirconocene Complexes / 7.6：

1,1-Germaniozirconocene Complexes / 7.7：

1,1-Zinciozirconocene Reagents / 7.8：

1,1-Dizirconocene Complexes / 7.9：

Cationic Zirconocene Species in Organic Synthesis / Keisuke Suzuki ; Lukas Hintermann ; Shigeo Yamanoi7.10：

General Introduction / 8.1：

Glycosylations with Cp[subscript 2]ZrCl[subscript 2]/Silver Salt Activators / 8.2：

Nucleophilic Additions to Aldehydes and Epoxides / 8.3：

Carbometalation of Alkynes and Alkenes / 8.4：

Cationic Zirconocene Complexes as Lewis Acid Catalysts / 8.5：

Miscellaneous Reactions / 8.6：

Titanium(II) Alkoxides in Organic Synthesis / Fumie Sato ; Hirokazu Urabe8.7：

Generation of ([eta superscript 2]-alkyne)Ti(OiPr)[subscript 2] and its Utilization in Organic Synthesis / 9.1：

Preparation of Allyl- and Allenyltitanium Reagents and their Synthetic Utility / 9.3：

Intramolecular Nucleophilic Acyl Substitution (INAS) Mediated by 1 / 9.4：

Intramolecular Coupling of Alkenes and Acetylenes / 9.5：

Concluding Remarks / 9.6：

Organometallic Chemistry of Titanocene and Zirconocene Complexes with Bis(trimethylsilyl)acetylene as the Basis for Applications in Organic Synthesis / Uwe Rosenthal ; Vladimir V. Burlakov10：

Reactions of Titanocene and Zirconocene Sources / 10.1：

Alkenes >C=C< / 10.3：

Diacetylenes / 10.4：

Dialkenes / 10.5：

Double Bonds to Heteroatoms >C=X(-) / 10.6：

Selected Combinations of Functional Groups / 10.7：

Miscellaneous / 10.8：

Titanium-Mediated Syntheses of Cyclopropanols and Cyclopropylamines / Armin de Meijere ; Sergei I. Kozhushkov ; Andrei I. Savchenko10.9：

Reaction Modes of Titanium Alkyl Derivatives Possessing [beta]-Hydrogen Atoms / 11.1：

Preparation of Cyclopropanols / 11.3：

Preparation of Cyclopropylamines / 11.4：

Applications in Natural Product Syntheses and Syntheses of Compounds with Potentially Useful Properties / 11.5：

Titanocene-Catalyzed Epoxide Opening / Andreas Gansauer ; Bjorn Rinker11.6：

Stoichiometric Opening of Epoxides by Electron Transfer / 12.1：

Synthesis and Reactivity of Allyltitanium Derivatives / Jan Szymoniak ; Claude Moise12.3：

Allyl Bis(cyclopentadienyl)titanium Reagents / 13.1：

Allyl Mono(cyclopentadienyl)titanium Reagents / 13.3：

Allyltitanium Reagents without Cyclopentadienyl Groups / 13.4：

Titanium-Based Olefin Metathesis and Related Reactions / Takeshi Takeda13.5：

Reactions of Titanium Carbene Complexes with Carbon--Carbon Double Bonds / 14.1：

Reactions of Titanium Carbene Complexes with Carbon--Oxygen Double Bonds / 14.3：

Reactions of Titanium Carbene Complexes with Triple Bonds / 14.4：

Index / 14.5：

Foreword

Preface

List of Contributors

Synthesis and Reactivity of Zirconocene Derivatives / Ei-ichi Negishi ; Shouquan Huo1：

Introduction and Historical Background / 1.1：

Fundamental Patterns of Transformations of Zirconocene Derivatives / 1.2：

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