Hydrolysis, oxidation and reduction

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Hydrolysis, oxidation and reduction / edited by Stan M. Robert and Geraldine Poignant

資料種別:

図書

出版情報:

Chichester : J. Wiley & Sons, c2002

形態:

xviii, 225 p. ; 24 cm

シリーズ名:

Catalysts for fine chemical synthesis ; v. 1 <BA5862286X>

著者名:

ISBN:

9780471981237 [0471981230]

書誌ID:

BA58622881

子書誌情報

フルテキスト

所蔵情報

他の版・巻

書誌詳細

注記:

Includes bibliographical references and index

主題:

触媒反応．触媒化学

言語:

英語

目次情報:

Series Preface

Preface to Volume 1

Abbreviations

Review / Part I：

The Integration of Biotransformations into the Catalyst Portfolio / 1：

Hydrolysis of esters, amides, nitriles and oxiranes / 1.1：

Reduction reactions / 1.2：

Reduction of carbonyl compounds / 1.2.1：

Reduction of alkenes / 1.2.2：

Oxidative transformations / 1.3：

Carbon-carbon bond-forming reactions / 1.4：

Conclusions / 1.5：

References

Procedures / Part II：

General Information / 2：

Asymmetric Epoxidation / 3：

Introduction / 3.1：

Epoxidation of [alpha], [beta]-Unsaturated Carbonyl Compounds / 4：

Non-asymmetric epoxidation / 4.1：

Asymmetric epoxidation using poly-d-leucine / 4.2：

Synthesis of leucine N-carboxyanhydride / 4.2.1：

Synthesis of immobilized poly-d-leucine / 4.2.2：

Asymmetric epoxidation of (E)-benzylideneacetophenone / 4.2.3：

Conclusion / 4.2.4：

Asymmetric epoxidation using chiral modified diethylzinc / 4.3：

Epoxidation of 2-isobutylidene-1-tetralone / 4.3.1：

Asymmetric epoxidation of (E)-benzylideneacetophenone using the La-(R)-BINOL-Ph[subscript 3]PO/cumene hydroperoxide system / K. Daikai ; M. Kamaura ; J. Inanaga4.3.2：

Merits of the system / 4.4.1：

Epoxidation of Allylic Alcohols / 5：

Asymmetric epoxidation using a chiral titanium complex / 5.1：

Epoxidation of cinnamyl alcohol / 5.2.1：

Epoxidation of (E)-2-methyl-3-phenyl-2-propenol / 5.2.2：

Epoxidation of (E)-2-hexen-1-ol / 5.2.3：

Asymmetric epoxidation of (E)-undec-2-en-1-ol using poly(octamethylene tartrate) / D.C. Sherrington ; J.K. Karjalainen ; O.E.O. Hormi5.2.4：

Synthesis of branched poly (octamethylene-L-(+)-tartrate) / 5.3.1：

Asymmetric epoxidation of (E)-undec-2-en-1-ol / 5.3.2：

Epoxidation of Unfunctionalized Alkenes and [alpha], [beta]-Unsaturated Esters / 6：

Asymmetric epoxidation of disubstituted Z-alkenes using a chiral salen-manganese complex / 6.1：

Epoxidation of (Z)-methyl styrene / 6.1.1：

Epoxidation of (Z)-ethyl cinnamate / 6.1.2：

Asymmetric epoxidation of disubstituted E-alkanes using a D-fructose based catalyst / 6.1.3：

Epoxidation of (E)-stilbene / 6.2.1：

Enantioselective epoxidation of (E)-[beta]-methylstyrene by D[subscript 2]-symmetric chiral trans-dioxoruthenium (VI) porphyrins / Rui Zhang ; Wing-Yiu Yu ; Chi-Ming Che6.2.2：

Preparation of the trans-dioxoruthenium (VI) complexes with D[subscript 2]-symmetric porphyrins (H[subscript 2]L[superscript 1-3]) / 6.3.1：

Enantioselective epoxidation of (E)-[beta]-methylstyrene / 6.3.2：

Asymmetric Hydroxylation and Aminohydroxylation / 6.3.3：

Asymmetric aminohydroxylation of 4-methoxystyrene / P.O'Brien ; S.A. Osborne ; D.D. Parker7.1：

Asymmetric dihydroxylation of (1-cyclohexenyl)acetonitrile / Jean-Michel Vatele7.1.1：

(R,R)-(1,2-Dihydroxycyclohexyl)acetonitrile acetonide / 7.2.1：

Asymmetric Sulfoxidation / 7.2.2：

Asymmetric oxidation of sulfides and kinetic resolution of sulfoxides / Laura Palombi ; Arrigo Scettri8.1：

Asymmetric oxidation of 4-bromothioanisole / 8.1.1：

Kinetic resolution of racemic 4-bromophenyl methyl sulfoxide / 8.1.2：

Asymmetric Reduction of Ketones Using Organometallic Catalysts / 9：

Asymmetric hydrogenation using a metal catalyst: [Ru((S)-BiNAP)] / 9.1：

Asymmetric transfer hydrogenation of [beta]-ketoesters / Kathelyne Everaere ; Jean-Francois Carpentier ; Andre Mortreux ; Michel Bulliard9.3：

(S,S)-1,2-bis(tert-Butylmethylphosphino)ethane (BisP*): Synthesis and use as a ligand / T. Imamoto9.4：

Synthesis of BisP* / 9.4.1：

Synthesis of 1,2-bis(tert-butylmethylphosphino) ethaneruthenium bromide (BisP*-Ru) / 9.4.2：

Synthesis of (R)-(-)-methyl 3-hydroxypentanoate using (BisP*-Ru) / 9.4.3：

(1S,3R,4R)-2-Azanorbornylmethanol, an efficient ligand for ruthenium-catalysed asymmetric transfer hydrogenation of aromatic ketones / Diego A. Alonso ; Pher G. Andersson9.5：

Synthesis of ethyl(1S,3R,4R)-2-[(S)-1-phenylethylamino]-2-azabicyclo[2.2.1] hept-5-ene-3-carboxylate / 9.5.1：

Synthesis of (1S,3R,4R)-3-hydroxymethyl-2-azabicyclo[2.2.1]heptane / 9.5.2：

Ruthenium-catalysed asymmetric transfer hydrogenation of acetophenone / 9.5.3：

Asymmetric Reduction of Ketones Using Bakers' Yeast / 10：

Bakers' yeast reduction of ethyl acetoacetate / 10.1：

Enantioselective synthesis of cis-N-carbobenzyloxy-3-hydroxyproline ethyl ester / Mukund P. Sibi ; James W. Christensen10.2：

Immobilization of bakers' yeast / 10.2.1：

Bakers' yeast reduction of cis-N-carbobenzyloxy-3-ketoproline ethyl ester / 10.2.2：

Asymmetric Reduction of Ketones Using Nonmetallic Catalysts / 11：

Oxazaborolidine borane reduction of acetophenone / 11.1：

Oxazaphosphinamide borane reduction of chloroacetophenone / 11.3：

Asymmetric reduction of chloroacetophenone using a sulfoximine catalyst / 11.4：

Preparation of [beta]-hydroxysulfoximine borane / 11.4.1：

Reduction of chloroacetophenone using the sulfoximine borane / 11.4.2：

Summary / 11.4.3：

Asymmetric reduction of bromoketone catalysed by cis-aminoindanol oxazaborolidine / Chris H. Senanayake ; H. Scott Wilkinson ; Gerald J. Tanoury11.5：

Synthesis of aminoindanol oxazaborolidine / 11.5.1：

Asymmetric reduction of 2-bromo-(3-nitro-4-benzyloxy)acetophenone / 11.5.2：

Stereoselective reduction of 2,3-butadione monoxime trityl ether / 11.5.3：

Stereoselective reduction of methyl 3-oxo-2-trityloxyiminostearate / 11.5.5：

Stereoselective reduction of 1-(tert-butyldimethylsilyloxy)-3-oxo-2-trityloxyiminooctadecane / 11.5.6：

Enantioselective reduction of ketones using N-arylsulfonyl oxazaborolidines / Pingrong Liu ; Gregory R. Cook11.6：

Synthesis of N-(2-pyridinesulfonyl)-1-amino-2-indanol / 11.6.1：

Asymmetric reduction of a prochiral ketone (chloroacetophenone) / 11.6.2：

Reduction of ketones using amino acid anions as catalyst and hydrosilane as oxidant / Michael A. Brook11.7：

Asymmetric Hydrogenation of Carbon-Carbon Double Bonds Using Organometallic Catalysts / 12：

Hydrogenation of dimethyl itaconate using [Rh((S,S)-Me-BPE)] / 12.1：

Hydrogenation of an [alpha]-amidoacrylate using [Rh((R,R)-Me-DuPHOS)] / 12.3：

Hydrogenation of an [alpha]-amidoacrylate using [Rh(B[3.2.0]DPO)] complexes / 12.4：

Preparation of (COD)[subscript 2] Rh[superscript +]BF[subscript 4 superscript -] / 12.4.1：

Preparation of the bisphosphinite ligand / 12.4.2：

Asymmetric reduction of [alpha]-acetamido cinnamic acid / 12.4.3：

Hydrogenation of enol carbonates and 4-methylene-N-acyloxazolidinone using [Rh((R)-BiNAP)] complexes / P.H. Dixneuf ; C. Bruneau ; P. Le Gendre12.5：

Synthesis of (S)-4,4,5-trimethyl-1, 3-dioxolane-2-one / 12.5.1：

Synthesis of (S)-2-methyl-2,3-butanediol / 12.5.2：

Preparation of optically active N-acyloxazolidinones / 12.5.3：

Synthesis of (R)-N-propionyl-4,5,5-trimethyl-1, 3-oxazolidin-2-one / 12.5.4：

Enantioselective ruthenium-catalyzed hydrogenation of vinylphosphonic acids / Virginie Ratovelomanana-Vidal ; Jean-Pierre Genet12.6：

Synthesis of chiral Ru(II) catalysts / 12.6.1：

Asymmetric hydrogenation of vinylphosphonic acids carrying a phenyl substituent at C[subscript 2] / 12.6.2：

Asymmetric reduction of a vinylphosphonic acid carrying a naphthyl substituent at C[superscript 2] / 12.6.3：

Scope of the hydrogenation reaction / 12.6.4：

Synthesis of a cylindrically chiral diphosphine and asymmetric hydrogenation of dehydroamino acids / Jahyo Kang ; Jun Hee Lee12.7：

Preparation of (R,R)-1,1'-bis([alpha]-hydroxypropyl) ferrocene / 12.7.1：

Preparation of (R,R)-1,1'-bis [alpha-(dimethylamino)propyl]ferrocene / 12.7.2：

Preparation of (R,R,[subscript p]S,[subscript p]S)-1,1'-bis [alpha-(dimethylamino)propyl]-2,2'-bis (diphenyl-phosphino)ferrocene / 12.7.3：

Preparation of (R,R,[subscript p]S,[subscript p]S)-1,1'-bis [alpha-acetoxypropyl)-2,2'-bis(diphenyl-phosphino)ferrocene / 12.7.4：

Preparation of ([subscript p]S,[subscript p]S)-1, 1'-bis (diphenylphosphino)-2,2'-bis(1-ethylpropyl) ferrocene [(S,S)-3-Pt-FerroPHOS] / 12.7.5：

Preparation of [(COD)Rh(([subscript p]S, [subscript p]S)-1, 1'-bis(diphenylphosphino)-2,2'-bis (1-ethylpropyl)ferrocene superscript +]BF[superscript - subscript 4] / 12.7.6：

Asymmetric hydrogenation of [alpha]-acetamido cinnamic acid / 12.7.7：

Synthesis and application of diamino FERRIPHOS as ligand for enantioselective Rh-catalysed preparation of chiral [alpha]-amino acids / Matthias Lotz ; Juan J. Almena Perea ; Paul Knochel12.8：

Synthesis of 1,1'-di(benzoyl)ferrocene / 12.8.1：

Synthesis of (S,S)-1,1'-bis ([alpha]-hydroxyphenylmethyl)ferrocene / 12.8.2：

Synthesis of (S,S)-1,1'-bis ([alpha]-acetoxyphenylmethyl)ferrocene / 12.8.3：

Synthesis of (S,S)-1,1'-bis([alpha]-N,N-dimethylaminophenylmethyl)ferrocene / 12.8.4：

Synthesis of ([alpha]S, [alpha]'S)-1,1'-bis([alpha]-N, N-dimethylaminophenylmethyl)-(R,R)-1,1'bis(diphenylphosphino)ferrocene / 12.8.5：

Asymmetric hydrogenation of methyl-(Z)-3-phenyl-2-methyl-carboxamido-2-propenoate using (S)-(R)-diamino FERRIPHOS as chiral ligand / 12.8.6：

Employment of Catalysts Working in Tandem / 13：

A one-pot sequential asymmetric hydrogenation utilizing Rh(I)- and Ru(II)-catalysts / Takayuki Doi ; Takashi Takahashi13.1：

Synthesis of ethyl (Z)-4-acetamido-3-oxo-5-phenyl-4-pentenoate / 13.1.1：

Asymmetric hydrogenation of ethyl 4-acetamido-3-oxo-5-phenyl-4-pentenoate / 13.1.2：

Index

Series Preface

Preface to Volume 1

Abbreviations

Review / Part I：

The Integration of Biotransformations into the Catalyst Portfolio / 1：

Hydrolysis of esters, amides, nitriles and oxiranes / 1.1：

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