Catalysis by polyoxometalates

>> Google Books

所蔵情報QRコード

Catalysis by polyoxometalates / Ivan Kozhevnikov

資料種別:: 図書
出版情報:: Chichester : J. Wiley & Sons, c2002
形態:: xiv, 201 p. ; 24 cm
シリーズ名:: Catalysts for fine chemical synthesis ; v. 2 <BA5862286X>
著者名:: Kozhevnikov, Ivan
ISBN:: 9780471623816 [0471623814]
書誌ID:: BA59158713

子書誌情報

フルテキスト

所蔵情報

他の版・巻

書誌詳細

注記:

Includes bibliographical references and index

主題:

触媒反応．触媒化学

言語:

英語

目次情報:

Series Preface

Preface to Volume 2

Introduction / 1：

Scope and definitions / 1.1：

Nomenclature / 1.2：

Historical background / 1.3：

Introduction to catalysis by polyoxometalates / 1.4：

References

Properties of Polyoxometalates / 2：

Structures of polyoxometalates / 2.1：

General principles / 2.1.1：

The Keggin structure / 2.1.2：

The Wells-Dawson structure / 2.1.3：

The Anderson-Evans structure / 2.1.4：

The Dexter-Silverton structure / 2.1.5：

Crystal structure of heteropoly compounds / 2.2：

Thermal stability / 2.3：

Solubility / 2.4：

Formation and state in solution / 2.5：

Stability of polyoxometalates in solution / 2.5.1：

Polyoxometalates as ligands / 2.5.2：

Isotope exchange / 2.5.3：

Kinetics and mechanism of substitution in polyoxmetalates / 2.5.4：

Acid properties / 2.6：

Proton structure / 2.6.1：

Heteropoly acids in solutions / 2.6.2：

Acidity of solid heteropoly acids / 2.6.3：

Redox properties / 2.7：

Synthesis of Polyoxometalates / 3：

General methods of synthesis / 3.1：

Keggin polyoxometalates / 3.2：

12-Molybdosilicic acid, [alpha]-H[subscript 4 SiMo[subscript 12]O[subscript 40] / 3.2.1：

12-Tungstosilicic acid, [alpha]-H[subscript 4 SiW[subscript 12]O[subscript 40] / 3.2.2：

12-Tungstophosphoric acid, [alpha]-H[subscript 3 PW[subscript 12]O[subscript 40] / 3.2.3：

12-Molybdophosphoric acid, [alpha]-H[subscript 3 PMo[subscript 12]O[subscript 40] / 3.2.4：

12-Tungstogermanic acid, [alpha]-[H[subscript 4 GeW[subscript 12]O[subscript 40] / 3.2.5：

11-Molybdo-1-vanadophosphoric acid, H[subscript 4 PMo[subscript 11] VO[subscript 40] / 3.2.6：

10-Molybdo-2-vanadophosphoric acid, H[subscript 5 PMo[subscript 10]V[subscript 2]O[subscript 40] / 3.2.7：

9-Molybdo-3-vanadophosphoric acid, H[subscript 6 PMo[subscript 9] V[subscript 3]O[subscript 40] / 3.2.8：

Transition-metal-substituted tungstophosphates, {PW[subscript 11]MO[subscript 39]} / 3.2.9：

Wells-Dawson polyoxometalates / 3.3：

18-Tungstodiphosphoric acid, H[subscript 6 P[subscript 2]W[subscript 18]O[subscript 62] / 3.3.1：

Sandwich-type polyoxometalates / 3.4：

Na[subscript 12 WZn[subscript 3](H[subscript 2]O)[subscript 2](ZnW[subscript 9]O[subscript 34])[subscript 2] / 3.4.1：

Na[subscript 12 WCo[subscript 3 superscript II](H[subscript 2]O)[subscript 2] (Co[superscript II]W[subscript 9]O[subscript 34])[subscript 2] / 3.4.2：

K[subscript 11 WZnRu[subscript 2 superscript III](OH)(H[subscript 2]O) (ZnW[subscript 9]O[subscript 34])[subscript 2] / 3.4.3：

K[subscript 10 WZnRh[superscript III subscript 2](H[subscript 2]O)(ZnW[subscript 9]O[subscript 34])[subscript 2] / 3.4.4：

Peroxo polyoxometalates / 3.5：

Venturello complex, {PO[subscript 4 WO(O[subscript 2])[subscript 2 subscript 4]}[superscript 3-] / 3.5.1：

Polyoxometalate catalysts / 3.6：

Solid acid catalysts / 3.6.1：

Homogeneous catalysts / 3.6.2：

Acid Catalysis by Heteropoly Compounds / 4：

General overview / 4.1：

The scope of applications / 4.1.1：

Mechanistic principles / 4.1.2：

Homogeneous acid catalysis / 4.2：

Acid-catalysed reactions / 4.2.1：

Acid-catalysed reactions in biphasic liquid-liquid systems / 4.3：

Biphasic reactions / 4.3.1：

Heterogeneous acid catalysts / 4.4：

Heteropoly acid catalysts / 4.4.1：

Heterogeneous catalysis in liquid-solid systems / 4.4.2：

Heterogeneous catalysis in gas-solid systems / 4.4.3：

Deactivation and regeneration of solid heteropoly acid catalysts / 4.5：

Polyoxometalates as Catalysts for Selective Oxidation / 5：

Liquid-phase oxidation / 5.1：

Oxidation with dioxygen / 5.1.1：

Oxidation with hydrogen peroxide / 5.1.2：

Oxidation with organic peroxides / 5.1.3：

Miscellaneous oxidations / 5.1.4：

Gas-phase oxidation / 5.2：

Oxidation catalysts / 5.2.1：

Reactions / 5.2.3：

Miscellaneous Catalytic Applications of Polyoxometalates / 6：

Hydrogenation, carbonylation and related reactions / 6.1：

Polyanion-stabilised clusters / 6.2：

Polyoxometalates as catalyst precursors / 6.3：

Catalysis by Polyoxometalates in Industry / 7：

Acid catalysis / 7.1：

Hydration of olefins / 7.1.1：

Synthesis of ethyl acetate from ethylene and acetic acid / 7.1.2：

Selective oxidation / 7.2：

Oxidation of methacrolein in methacrylic acid / 7.2.1：

Oxidation of ethylene to acetic acid / 7.2.2：

Other Applications of Polyoxometalates / 8：

Analytical chemistry / 8.1：

Elemental analysis / 8.1.1：

Analysis of biomaterials / 8.1.2：

Separation / 8.2：

Processing of radioactive waste / 8.2.1：

Sorption of gases / 8.2.2：

Corrosion-resistant coatings / 8.3：

Polyoxometalates as additives to inorganic and organic matrices / 8.4：

Additives in sol-gel matrices / 8.4.1：

Additives in polymer matrices / 8.4.2：

Membranes / 8.5：

Fuel cells / 8.5.1：

Selective electrodes / 8.5.2：

Gas sensors / 8.5.3：

Polyoxometalates in medicine: antiviral and antitumoral activity / 8.6：

Index

Series Preface

Preface to Volume 2

Introduction / 1：

Scope and definitions / 1.1：

Nomenclature / 1.2：

Historical background / 1.3：

続きを見る

東工大ブックレビュー

類似資料:

1 図書 Catalysis (Vol. 1 ; Vol. 2) Chemical Society, London., Kemball, Charles The Chemical Society	7 図書 Fine chemicals through heterogeneous catalysis Sheldon, Roger A., Bekkum, Herman van Wiley-VCH
2 図書 Catalysis by metals Bond, G. C. (Geoffrey Colin) Academic Press	8 図書 Catalysis for Renewables : From Feedstock to Energy Production (hdk) Santen, R. A. van (Rutger A.), Centi, G. (Gabriele), 1955- WILEY-VCH
3 図書 Catalysis and inhibition of chemical reactions Ashmore, Philip George Butterworths	9 図書 Proceedings of the Third International Congress on Catalysis. Amsterdam, July, 1964 (v. 1 ; v. 2) International Congress on Catalysis, Sachtler, W. M. H., Schuit, George C. A., Zwietering P. North-Holland
4 図書 Handbook of heterogeneous catalysis (: set - v. 5) Ertl, G., Knözinger, H., Weitkamp, J. VCH	10 図書 Transformation of carbon dioxide to formic acid and methanol (: pbk) Wang, Wan-Hui, Feng, Xiujuan, Bao, Ming Springer
5 図書 The role of diffusion in catalysis Satterfield, Charles N., Sherwood, Thomas Kilgore, 1903-1976 Addison-Wesley	11 図書 Chiral Lewis acids (: softcover) Mikami, Koichi, Brill, M. Springer
6 図書 Catalysis from A to Z : a concise encyclopedia ([set] - Vol. 3. O to Z) Cornils, Boy Wiley-VCH-Verl	12 図書 Metal catalysed carbon-carbon bond-forming reactions Roberts, Stanley M. John Wiley