The organometallic chemistry of the transition metals

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The organometallic chemistry of the transition metals / Robert H. Crabtree

版:: 4th ed
資料種別:: 図書
出版情報:: Hoboken, N.J. : Wiley-Interscience, c2005
形態:: xiii, 546 p. ; 24 cm
著者名:: Crabtree, Robert H., 1948- <DA02181325>
ISBN:: 9780471662563 [0471662569]
書誌ID:: BA7283372X

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注記:

Previous ed.: 2000
Includes bibliographical references and index

主題:

Organotransition metal compounds

言語:

英語

目次情報:

Preface

List of Abbreviations

Introduction / 1：

Werner Complexes / 1.1：

The Trans Effect / 1.2：

Soft Versus Hard Ligands / 1.3：

The Crystal Field / 1.4：

The Ligand Field / 1.5：

Back Bonding / 1.6：

Electroneutrality / 1.7：

Types of Ligand / 1.8：

General Properties of Organometallic Complexes / 2：

The 18-Electron Rule / 2.1：

Limitations of the 18-Electron Rule / 2.2：

Electron Counting in Reactions / 2.3：

Oxidation State / 2.4：

Coordination Number and Geometry / 2.5：

Effects of Complexation / 2.6：

Differences between Metals / 2.7：

Outer-Sphere Coordination / 2.8：

Metal Alkyls, Aryls, and Hydrides and Related ?-Bonded Ligands / 3：

Transition Metal Alkyls and Aryls / 3.1：

Related ?-Bonded Ligands / 3.2：

Metal Hydride Complexes / 3.3：

Complexes / 3.4：

Bond Strengths for Classical ?-Bonding Ligands / 3.5：

Carbonyls, Phosphine Complexes, and Ligand Substitution Reactions / 4：

Metal Complexes of CO, RNC, CS, and NO / 4.1：

Phosphines and Related Ligands / 4.2：

Dissociative Substitution / 4.3：

Associative Mechanism / 4.4：

Redox Effects, the I Mechanism, and Rearrangements in Substitution / 4.5：

Photochemical Substitution / 4.6：

Steric and Solvent Effects in Substitution / 4.7：

Complexes of A-Bound Ligands / 5：

Alkene and Alkyne Complexes / 5.1：

Allyl Complexes / 5.2：

Diene Complexes / 5.3：

Cyclopentadienyl Complexes / 5.4：

Arenes and Other Alicyclic Ligands / 5.5：

Metalacycles and Isoelectronic and Isolobal Replacement / 5.6：

Stability of Polyene and Polyenyl Complexes / 5.7：

Oxidative Addition and Reductive Elimination / 6：

Concerted Additions / 6.1：

SN2 Reactions / 6.2：

Radical Mechanisms / 6.3：

Ionic Mechanisms / 6.4：

Reductive Elimination / 6.5：

?-Bond Metathesis / 6.6：

Oxidative Coupling and Reductive Cleavage / 6.7：

Insertion and Elimination / 7：

Reactions Involving CO / 7.1：

Insertions Involving Alkenes / 7.2：

Other Insertions / 7.3：

?, ?, ?, and ' Elimination / 7.4：

Nucleophilic and Electrophilic Addition and Abstraction / 8：

Nucleophilic Addition to CO / 8.1：

Nucleophilic Addition to Polyene and Polyenyl Ligands / 8.2：

Nucleophilic Abstraction in Hydrides, Alkyls, and Acyls / 8.3：

Electrophilic Addition / 8.4：

Electrophilic Abstraction of Alkyl Groups / 8.5：

Single-Electron Transfer Pathways / 8.6：

Reactions of Organic Free Radicals with Metal Complexes / 8.7：

Homogeneous Catalysis / 9：

Alkene Isomerization / 9.1：

Alkene Hydrogenation / 9.2：

Alkene Hydroformylation / 9.3：

Hydrocyanation of Butadiene / 9.4：

Alkene Hydrosilation and Hydroboration / 9.5：

Coupling Reactions / 9.6：

Surface and Supported Organometallic Catalysis / 9.7：

Physical Methods in Organometallic Chemistry / 10：

Isolation / 10.1：

1H NMR Spectroscopy / 10.2：

13C NMR Spectroscopy / 10.3：

31P NMR Spectroscopy / 10.4：

Dynamic NMR / 10.5：

Spin Saturation Transfer / 10.6：

T1 and the Nuclear Overhauser Effect / 10.7：

Isotopic Perturbation of Resonance / 10.8：

IR Spectroscopy / 10.9：

Crystallography / 10.10：

Other Methods / 10.11：

Metal-Ligand Multiple Bonds / 11：

Carbenes / 11.1：

Carbynes / 11.2：

Bridging Carbenes and Carbynes / 11.3：

N-Heterocyclic Carbenes / 11.4：

Multiple Bonds to Heteroatoms / 11.5：

Applications of Organometallic Chemistry / 12：

Alkene Metathesis / 12.1：

Dimerization, Oligomerization, and Polymerization of Alkenes / 12.2：

Activation of CO and CO2 / 12.3：

CH Activation / 12.4：

Organometallic Materials and Polymers / 12.5：

Preface

List of Abbreviations

Introduction / 1：

Werner Complexes / 1.1：

The Trans Effect / 1.2：

Soft Versus Hard Ligands / 1.3：

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