Spectra of atoms and molecules

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Spectra of atoms and molecules / Peter F. Bernath

版:: 2nd ed
資料種別:: 図書
出版情報:: New York : Oxford University Press, c2005
形態:: xiv, 439 p. ; 27 cm
著者名:: Bernath, Peter F. <DA0910871X>
ISBN:: 9780195177596 [0195177592]
書誌ID:: BA73869449

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Spectra of atoms and molecules
Peter F. Bernath , Oxford University Press , 1995

書誌詳細

注記:

Includes bibliographical references and index

主題:

Atomic spectroscopy--Textbooks; Molecular spectroscopy--Textbooks; Spectrum analysis--Textbooks

言語:

英語

目次情報:

Introduction / 1：

Waves, Particles, and Units / 1.1：

The Electromagnetic Spectrum / 1.2：

Interaction of Radiation with Matter / 1.3：

Blackbody Radiation

Einstein A and B Coefficients

Absorption and Emission of Radiation

Beer's Law

Lineshape Functions

Natural Lifetime Broadening

Pressure Broadening

Doppler Broadening

Transit-Time Broadening

Power Broadening

Molecular Symmetry / 2：

Symmetry Operations / 2.1：

Operator Algebra

Symmetry Operator Algebra

Groups / 2.2：

Point Groups

Classes

Subgroups

Notation for Point Groups / 2.3：

Matrix Representation of Groups / 3：

Vectors and Matrices / 3.1：

Matrix Eigenvalue Problem

Similarity Transformations

Symmetry Operations and Position Vectors / 3.2：

Reflection

Rotation

Inversion

Rotation-Reflection

Identity

Symmetry Operators and Basis Vectors / 3.3：

Symmetry Operators and Basis Functions / 3.4：

Function Spaces

Gram-Schmidt Procedure

Transformation Operators

Equivalent, Reducible, and Irreducible Representations / 3.5：

Equivalent Representations

Unitary Representations

Reducible and Irreducible Representations

Great Orthogonality Theorem / 3.6：

Characters

Character Tables / 3.7：

Mulliken Notation

Quantum Mechanics and Group Theory / 4：

Matrix Representation of the Schrodinger Equation / 4.1：

Born-Oppenheimer Approximation / 4.2：

Symmetry of the Hamiltonian Operator / 4.3：

Projection Operators / 4.4：

Direct Product Representations / 4.5：

Integrals and Selection Rules / 4.6：

Atomic Spectroscopy / 5：

Background / 5.1：

Angular Momentum / 5.2：

The Hydrogen Atom and One-Electron Spectra / 5.3：

Vector Model

Spin-Orbit Coupling

Many-Electron Atoms / 5.4：

Selection Rules / 5.5：

Atomic Spectra / 5.6：

Hyperfine Structure

Hydrogen Atom

Intensity of Atomic Lines / 5.7：

Zeeman Effect / 5.8：

Paschen-Back Effect

Stark Effect / 5.9：

Rotational Spectroscopy / 6：

Rotation of Rigid Bodies / 6.1：

Diatomic and Linear Molecules / 6.2：

Centrifugal Distortion

Vibrational Angular Momentum

Line Intensities for Diatomic and Linear Molecules / 6.3：

Symmetric Tops / 6.4：

Molecule and Space-Fixed Angular Momenta

Rotational Spectra

Line Intensity

Asymmetric Tops / 6.5：

Structure Determination / 6.6：

Vibrational Spectroscopy / 7：

Diatomic Molecules / 7.1：

Wavefunctions for Harmonic and Anharmonic Oscillators

Vibrational Selection Rules for Diatomics

Dissociation Energies from Spectroscopic Data

Vibration-Rotation Transitions of Diatomics

Combination Differences

Vibrational Motion of Polyatomic Molecules / 7.2：

Classical Mechanical Description

Quantum Mechanical Description

Internal Coordinates

Symmetry Coordinates

Symmetry of Normal Modes

Selection Rules for Vibrational Transitions

Vibration-Rotation Transitions of Linear Molecules

Nuclear Spin Statistics

Excited Vibrational States of Linear Molecules

Vibrational Spectra of Symmetric Tops / 7.3：

Coriolis Interactions in Molecules

Infrared Transitions of Spherical Tops / 7.4：

Vibrational Spectra of Asymmetric Tops / 7.5：

Vibration-Rotation Line Intensities / 7.6：

Line Intensity Calculations

Fermi and Coriolis Perturbations / 7.7：

Inversion Doubling and Fluxional Behavior / 7.8：

Light Scattering and the Raman Effect / 8：

Classical Model / 8.1：

Quantum Model

Polarization

Rotational Raman Effect / 8.2：

Vibration-Rotation Raman Spectroscopy / 8.3：

Rayleigh and Raman Intensities / 8.4：

Classical Theory

Vibrational Intensity Calculations

Conclusions / 8.5：

Electronic Spectroscopy of Diatomics / 9：

Orbitals and States / 9.1：

Vibrational Structure / 9.2：

Rotational Structure of Diatomic Molecules / 9.3：

Singlet-Singlet Transitions

Nonsinglet Transitions

The Symmetry of Diatomic Energy Levels: Parity / 9.4：

Total (+/-) Parity

Rotationless (e/f) Parity

Gerade/Ungerade (g/u) Parity

Symmetric/Antisymmetric (s/a) Parity

Rotational Line Intensities / 9.5：

Dissociation, Photodissociation, and Predissociation / 9.6：

Electronic Spectroscopy of Polyatomics / 10：

Walsh's Rules: Qualitative Molecular Orbital Theory / 10.1：

Huckel Molecular Orbital Theory

Vibrational Structure of Electronic Transitions / 10.2：

Vibronic Coupling: The Herzberg-Teller Effect / 10.3：

Jahn-Teller Effect / 10.4：

Renner-Teller Effect / 10.5：

Nonradiative Transitions: Jablonski Diagram / 10.6：

Photoelectron Spectroscopy / 10.7：

Rotational Structure: H[subscript 2]CO and HCN / 10.8：

Intensity of Transitions / 10.9：

Units, Conversions, and Physical Constants / A：

Direct Product Tables / B：

Introductory Textbooks / D：

Figure Acknowledgments

Index

Introduction / 1：

Waves, Particles, and Units / 1.1：

The Electromagnetic Spectrum / 1.2：

Interaction of Radiation with Matter / 1.3：

Blackbody Radiation

Einstein A and B Coefficients

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