Catalysis in asymmetric synthesis

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Catalysis in asymmetric synthesis / Vittorio Caprio and Jonathan M.J. Williams

版:

2nd ed

資料種別:

図書

出版情報:

Chichester : Wiley, 2009

形態:

xiii, 393 p. ; 24 cm

シリーズ名:

Postgraduate chemistry series <BA44526890>

著者名:

ISBN:

9781405190916 [1405190914]
9781405175197 [1405175192] (: pbk)

書誌ID:

BA88832340

子書誌情報

フルテキスト

所蔵情報

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書誌詳細

注記:

Includes bibliographical references and index

主題:

Asymmetric synthesis; Catalysis

言語:

英語

目次情報:

Preface to the Second Edition

Preface to the First Edition

Introduction / 1：

Reactions Amenable to Asymmetric Catalysis / 1.1：

Assignment of (R) and (S) Stereochemical Descriptors / 1.2：

Futher Reading

References

Reduction of Alkenes / 2：

Asymmetric Hydrogenation with Rhodium Complexes / 2.1：

Asymmetric Hydrogenation with Ruthenium Catalysts / 2.2：

Alkene Hydrogenation with Titanium and Zirconium Catalysts / 2.3：

Alkene Hydrogenation with Iridium Catalysts / 2.4：

Alkene Hydrogenation with Organocatalysts / 2.5：

Alkene Hydrosilylation / 2.6：

Alkene Hydroboration / 2.7：

Hydroamination / 2.8：

Hydroformylation / 2.9：

Hydroacylation of Alkenes / 2.10：

Hydrocyanation of Alkenes / 2.11：

Reduction of Ketones and Imines / 3：

Hydrogenation of Ketones / 3.1：

Hydrogenation and Transfer Hydrogenation of Imines and Related Compounds / 3.2：

Transfer Hydrogenation of Ketones / 3.3：

Heterogeneous Hydrogenation / 3.4：

Reduction of Ketones Using Enantioselective Borohydride Reagents / 3.5：

Hydrosilylation of Ketones / 3.6：

Hydrosilylation of Imines and Nitrones / 3.7：

Epoxidation / 4：

Epoxidation of Allylic Alcohols / 4.1：

Epoxidation with Metal(salen) Complexes / 4.2：

Epoxidation Using Metal-Porphyrin-Based Catalysts / 4.3：

Other Metal-Catalysed Epoxidations of Unfunctionalised Olefins / 4.4：

Epoxidation of Electron-Deficient Alkenes / 4.5：

Epoxidation with Iminium Salts / 4.6：

Epoxidation with Ketone Catalysts / 4.7：

Epoxidation of Aldehydes / 4.8：

Aziridination of Alkenes / 4.9：

Aziridination of Imines / 4.10：

Further Oxidation Reactions / 5：

Dihydroxylation / 5.1：

Aminohydroxylation / 5.2：

alpha-Heterofunctionalisation of Aldehydes and Ketones / 5.3：

Oxidation of C-H / 5.4：

Baeyer-Villiger Oxidation / 5.5：

Oxidation of Sulfides / 5.6：

Nucleophilic Addition to Carbonyl Compounds / 6：

Addition of Organozincs to Carbonyl Compounds / 6.1：

Addition of Cyanide to Aldehydes and Ketones / 6.2：

Allylation of Aldehydes / 6.3：

Hydrophosphonylation of Aldehydes / 6.4：

Nucleophilic Additions to Imines / 6.5：

The Aldol and Related Reactions / 7：

The Aldol Reaction / 7.1：

Isocyanide and Related Aldol Reactions / 7.2：

The Nitroaldol Reaction / 7.3：

Addition of Enolates to Imines / 7.4：

Darzens Condensation / 7.5：

Morita-Baylis-Hillman Reaction / 7.6：

Carbonyl-Ene Reactions / 7.7：

Cycloadditions / 8：

Diels-Alder Reactions / 8.1：

Inverse Election Demand Diels-Alder Reactions / 8.2：

Hetero-Diels-Alder Reactions / 8.3：

1,3-Dipolar Cycloaddition Reactions / 8.4：

[2+2] Cycloadditions / 8.5：

Pauson-Khand-Type Reactions / 8.6：

Catalytic Reactions Involving Carbenes and Ylides / 9：

Cyclopropanation / 9.1：

Insertion Reactions / 9.2：

Asymmetric Ylide Reactions / 9.3：

Catalytic Carbon-Carbon Bond-Forming Reactions / 10：

Cross-Coupling Reactions / 10.1：

Metal-Catalysed Allylic Substitution / 10.2：

Heck Reactions / 10.3：

Alkylmetalation of Alkenes / 10.4：

Conjugate Addition Reactions / 11：

Conjugate Addition of Enolates / 11.1：

Conjugate Addition of Sulfur Nucleophiles / 11.2：

Conjugate Addition of Nonstabilised Nucleophiles / 11.3：

Conjugate Addition with Nitrogen-Based Nucleophiles and Electrophiles / 11.4：

Further Catalytic Reactions / 12：

Isomerisations and Rearrangements / 12.1：

Deprotonation Reactions / 12.2：

Protonation Reactions / 12.3：

Alkylation and Allylation of Enolates / 12.4：

Formation of Alkenes / 12.5：

Oxyselenylation-Elimination Reactions / 12.6：

The Benzoin Condensation / 12.7：

Ester Formation and Hydrolysis / 12.8：

Ring-Opening of Epoxides / 12.9：

Index

OtherMetal-Catalysed Epoxidations of Unfunctionalised Olefins

+ -Heterofunctionalisation of Aldehydes and Ketones

Inverse Electron Demand Diels-Alder Reactions

Alkylmetalation of Alkenes.#60

Preface to the Second Edition

Preface to the First Edition

Introduction / 1：

Reactions Amenable to Asymmetric Catalysis / 1.1：

Assignment of (R) and (S) Stereochemical Descriptors / 1.2：

Futher Reading

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