Dendrimer chemistry

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Dendrimer chemistry / authors, Fritz Vögtle, Gabriele Richardt, Nicole Werner ; translator, Anthony J. Rackstraw

資料種別:

図書

出版情報:

Weinheim : Wiley-VCH, c2009

形態:

xi, 342 p. ; 24 cm

著者名:

ISBN:

9783527320660 [3527320660] (: pbk)

書誌ID:

BA89225128

子書誌情報

フルテキスト

所蔵情報

他の版・巻

書誌詳細

その他の標題:

Dendrimer chemistry : concepts, syntheses, properties, applications
Dendritische Moleküle

注記:

Includes bibliographical references and index

主題:

Dendrimers

言語:

英語

目次情報:

Preface

Introduction / 1：

Historical - Cascade molecules and dendrimers / 1.1：

Dendritic architectures / 1.2：

Perfection, defects, dispersity / 1.3：

Definition and classification of dendritic molecules / 1.4：

Nomenclature of dendritic molecules / 1.5：

Newkome nomenclature / 1.5.1：

Cascadane nomenclature / 1.5.2：

Bibliography and Notes for Chapter 1 "Introduction"

Synthetic methods for dendritic molecules / 2：

Divergent synthesis / 2.1：

Convergent synthesis / 2.2：

Recent synthetic methods / 2.3：

Orthogonal synthesis / 2.3.1：

Double-stage convergent method / 2.3.2：

Double-exponential method / 2.3.3：

Hypermonomer method / 2.3.4：

Click chemistry / 2.3.5：

Solid phase synthesis / 2.4：

Coordination-chemical synthesis / 2.5：

Metal complex as core unit / 2.5.1：

Metal complex as branching unit / 2.5.2：

Supramolecular synthesis / 2.6：

Hyperbranched polymers / 2.7：

Dendronised linear polymers / 2.8：

Polymer-analogous method / 2.8.1：

Macromonomer method / 2.8.2：

Dendro-Isomers / 2.9：

Bibliography and Notes for Chapter 2 "Synthetic methods for dendritic molecules"

Functional dendrimers / 3：

Monofunctional dendrimers / 3.1：

Functional core / 3.1.1：

Functional periphery / 3.1.2：

Functionalisation of terminal groups / 3.1.2.1：

Introduction of peripheral groups prior to dendrimer growth / 3.1.2.2：

Functional units in the dendrimer scaffold / 3.1.3：

Modification prior to dendrimer growth / 3.1.3.1：

Internal modification on conclusion of dendrimer growth / 3.1.3.2：

Multifunctional dendrimers

Bifunctionalised molecular periphery / 3.2.1：

Two different functional units in different parts of the molecule / 3.2.2：

More than two different functional units / 3.2.3：

Overview of functional dendrimers and their synthesis / 3.2.4：

Bibliography and Notes for Chapter 3 "Functional dendrimers"

Types of dendrimers and their syntheses / 4：

Achiral dendrimers / 4.1：

POPAM / 4.1.1：

PAMAM / 4.1.2：

POMAM / 4.1.3：

Polylysine dendrimers / 4.1.4：

Dendritic hydrocarbons / 4.1.5：

Condensed arene components - Iptyceness / 4.1.5.1：

Dendrimers from arene and multiply bonded building blocks / 4.1.5.2：

Stilbenoid dendrimers / 4.1.5.3：

Hyperbranched polybenzenes / 4.1.5.4：

Carbon/oxygen-based (and FrÃ©chet) dendrimers / 4.1.6：

Polyether dendrimers / 4.1.6.1：

Polyester dendrimers / 4.1.6.2：

Carbohydrate dendrimers (glycodendrimers) / 4.1.6.3：

Porphyrin-based dendrimers / 4.1.7：

Ionic dendrimers / 4.1.8：

Polyanionic dendrimers / 4.1.8.1：

Silicon-based dendrimers / 4.1.8.2：

Silane dendrimers / 4.1.9.1：

Carbosilane dendrimers / 4.1.9.2：

Carbosiloxane dendrimers / 4.1.9.3：

Siloxane dendrimers / 4.1.9.4：

Hyperbranched silicon-based polymers / 4.1.9.5：

Phosphorus-based dendrimers / 4.1.10：

Metallodendrimers (and Newkome dendrimers) / 4.1.11：

Bibliography and Notes for Section 4.1 "Achiral dendrimers"

Chiral dendrimers / 4.2：

Classification of chiral dendrimers / 4.2.1：

Studies on the chirality of dendritic molecules / 4.2.2：

Chiroptical studies / 4.2.2.1：

Possible applications of chiral dendrimers / 4.2.2.2：

Dendrimers with chiral core and achiral branching scaffold / 4.2.3：

Chiroptical studies on dendrimers with chiral cores / 4.2.3.1：

Possible applications of chiral-core dendrimers / 4.2.3.2：

Dendrimers with chiral building blocks as spacers or branching units / 4.2.4：

Chiroptical studies on dendrimers with chiral dendrimer scaffold / 4.2.4.1：

Possible applications of dendrimers with chiral branching scaffold / 4.2.4.2：

Chirality in the periphery / 4.2.5：

Chiroptical studies on dendrimers with peripheral chiral units / 4.2.5.1：

Possible applications of dendrimers with peripheral chiral units / 4.2.5.2：

Chiral dendrimers for asymmetric catalysis / 4.2.6：

Interpretation of the chirality of dendritic molecules / 4.2.7：

Bibliography and Notes for Section 4.2 "Chiral Dendrimers"

Photophysical properties of dendirtic molecules / 5：

Luminescence and energy transfer / 5.1：

Luminescence / 5.1.1：

Energy transfer / 5.1.2：

Dexter mechanism: Energy transfer by radiative emission / 5.1.2.1：

FÃ¶rster mechanism: Energy transfer by dipole-dipole interactions / 5.1.2.2：

Examples from the field of dendritic molecules / 5.1.2.3：

Antenna effect and photoisomerisation of dendrimers / 5.2：

Antenna effect / 5.2.1：

Photoisomerisation / 5.2.2：

Bibliography and Notes for Chapter 5 "Photophysical properties of dendritic molecules"

(Special) chemical reactions of dendritic molecules / 6：

Covalent chemical reactions / 6.1：

Metathesis / 6.1.1：

Molecular imprinting / 6.1.2：

Covalent introduction of functionalities in the interior of dendritic molecules / 6.1.3：

Supramolecular (host/guest) interactions / 6.2：

Non-covalent modification of a dendrimer periphery / 6.2.1：

Self-assembly of dendrimers / 6.2.2：

Inclusion of guest species in dendritic host molecules / 6.2.3：

Dendrimers with multiple receptor units / 6.2.3.1：

Guest inclusion by steric compression / 6.2.3.2：

Guest inclusion by dynamic processes (diffusion) / 6.2.3.3：

Dendritic stopper groups (in rotaxanes) / 6.2.4：

Dendritic effects / 6.3：

Dendritic effects in inclusion of guests / 6.3.1：

Dendritic effects in catalysis / 6.3.2：

Metal-containing dendritic catalysts / 6.3.2.1：

Metal-free dendritic catalysts / 6.3.2.2：

Dendritic effects on electrochemical properties / 6.3.3：

Redox gradients / 6.3.3.1：

Redox sensors / 6.3.3.3：

Redox potential and redox transfer kinetics / 6.3.3.4：

Charge-separation processes / 6.3.3.5：

Summary of the dendritic effect / 6.3.4：

Bibliography and Notes for Chapter 6 "(Special) chemical reactions of dendritic molecules"

Characterisation and analysis / 7：

Chromatography / 7.1：

Liquid chromatography / 7.1.1：

Preparative liquid chromatography / 7.1.1.1：

High-performance liquid chromatography / 7.1.1.2：

Gel permeation chromatography / 7.1.2：

Gel electrophoresis / 7.2：

NMR spectroscopy / 7.3：

(1D)-NMR spectroscopic studies / 7.3.1：

Multidimensional NMR spectroscopy in dendrimer research / 7.3.2：

Diffusion NMR spectroscopy / 7.3.3：

Dynamic NMR spectroscopy / 7.3.4：

Mass spectrometry / 7.4：

Gentle ionisation methods: MALDI and ESI / 7.4.1：

Study of dendrimers by MALDI and ESI-MS / 7.4.1.1：

X-ray crystal structure analysis / 7.5：

Small-angle scattering / 7.6：

Principle of small-angle scattering / 7.6.1：

Capability of small-angle scattering / 7.6.2：

Structural analysis of dissolved dendrimers with SANS and SAXS / 7.6.3：

Radial segment density distribution of flexible dendrimers / 7.6.3.1：

Distribution of end groups / 7.6.3.2：

Intermolecular interactions of flexible dendrimers in solution / 7.6.3.3：

Scanning probe microscopy / 7.7：

STM and AFM / 7.7.1：

AFM images of dendrimers / 7.7.1.1：

STM images of dendrimers / 7.7.1.2：

Transmission electron microscopy / 7.8：

TEM / 7.8.1：

TEM images of dendrimers / 7.8.1.1：

Chiroptical methods / 7.9：

Optical rotatory dispersion and circular dichroism / 7.9.1：

Chiroptical studies on chiral dendritic structures / 7.9.2：

Summary / 7.10：

Bibliography and Notes for Chapter 7 "Characterization and analysis"

Special properties and potential applications / 8：

Catalysis, membrane technology / 8.1：

Dendrimers as catalyst supports / 8.2.1：

Catalytic dendrimers for membrane reactors / 8.2.2：

Dendrimers in enantioselective catalysis / 8.2.3：

Dendrimers as phase transfer catalysts / 8.2.4：

Pigments, adhesives, additives in chemical materials / 8.3：

Dendrimers as additives / 8.3.1：

Dendritic polymers for printing inks / 8.3.2：

Dendritic polymers for paints / 8.3.3：

Dendritic polymers as additives in foam formulation / 8.3.4：

Network precursors for plastics / 8.3.5：

Dendrimers as nanocapsules for dyes and for molecular imprinting / 8.3.6：

Dendrimers for displays and (opto)electronics / 8.4：

Liquid-crystalline dendrimers / 8.4.1：

Biomimetics, sensor technology, diagnostics (fluorescence) / 8.5：

Protein dendrimers / 8.5.1：

Glycomimetics / 8.5.2：

Dendrimers in sensor technology / 8.5.3：

Quartz micro balance with dendritic sensor layers / 8.5.3.1：

Luminescent dendrimers as sensor materials / 8.5.3.2：

Fluorescing PET sensors / 8.5.3.3：

Dendrimers in medical diagnostics / 8.6：

Magnetic resonance imaging (MRI) processes / 8.6.1：

DNA dendrimers as biosensors for DNA hybridisation / 8.6.2：

Medical applications / 8.7：

Dendrimers as carriers for cytostatic agents / 8.7.1：

Gene therapy / 8.7.2：

Photodynamic therapy / 8.7.3：

Dendrimers in prevention against HIV / 8.7.4：

Culture of organs and tissue / 8.7.5：

Wound healing / 8.7.5.1：

Boron neutron capture therapy / 8.7.6：

Dendrimers in nanotechnology / 8.8：

Photoswitchable dendrimers / 8.8.1：

Dendrimers as impellers / 8.8.2：

Dendrimers as nanotubes / 8.8.3：

Dendritic polymers as templates / 8.8.4：

Bibliography and Notes for Chapter 8 "Special properties and potential applications"

Outlook

Subject Index

Preface

Introduction / 1：

Historical - Cascade molecules and dendrimers / 1.1：

Dendritic architectures / 1.2：

Perfection, defects, dispersity / 1.3：

Definition and classification of dendritic molecules / 1.4：

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