Three-Dimensional Free-Radical Polymerization. Cross-Linked Polymers / Part I: |
Microheterogeneous Mechanism of Three-Dimensional Free-Radical Polymerization / 1: |
Microheterogeneous Model of Polymerization Process / 1.1: |
Polymerization Process: Stages of Formation of the Microheterogeneous Structure for Cross-Linked Polymers / 1.2: |
Formation of Polymer Grains at the Initial Stage of Polymerization / 1.2.1: |
Growth of Polymer Grains During Polymerization / 1.2.2: |
Accretion of Polymer Grains at the Final Stages of Polymerization / 1.2.3: |
Structural and Physical Processes Taking Place During Three-Dimensional Free-Radical Polymerization / 1.3: |
Microsyneresis of Liquid Components in Reaction Medium / 1.3.1: |
Microredistribution of Substances Dissolved in Liquid Components / 1.3.2: |
Local Glass Transition of Highly Cross-Linked Micro-Volumes of Polymer / 1.3.3: |
Microheterogeneous Structure of Cross-Linked Polymers / 1.4: |
Interlayers Between Polymer Grains / 1.4.1: |
Polymer Grains / 1.4.2: |
References |
Kinetic Features of Three-Dimensional Free-Radical Polymerization / 2: |
Kinetic Features of Individual Stages of Polymerization / 2.1: |
Initial Stage of Polymerization / 2.1.1: |
Stages of Auto-Acceleration and Auto-Deceleration / 2.1.2: |
Inhibited Polymerization / 2.2: |
Polymerization in Solutions / 2.3: |
Polymerization in Films Under the Conditions of Oxygen Diffusion / 2.4: |
Vinyl Compounds / 2.4.1: |
Allyl Compounds / 2.4.2: |
Three-Dimensional Free-Radical Polymerization as a Tool for Macromolecular Design of Cross-Linked Polymers / 2.5: |
Living Chain Three-Dimensional Radical Polymerization / 3: |
Living Chains in Free-Radical Polymerization / 3.1: |
Implementation of Living Chains Conditions in Three-Dimensional Free-Radical Polymerization / 3.2: |
Copolymerization of Styrene with Dimethacrylates in the Presence of Alkoxyamines / 3.2.1: |
Polymerization of Dimethacrylates of Poly(Ethylene Glycol)s in the Presence of Complex CuBr with Organic Ligands / 3.2.2: |
Living Chain Three-Dimensional Free-Radical Polymerization as a Tool for Macromolecular Design of Cross-Linked Polymers / 3.3: |
Kinetic Features of Three-Dimensional Free-Radical Copolymerization / 4: |
Kinetic Features of Three-Dimensional Copolymerization of Oligomer and Vinyl Monomers / 4.1: |
Variation of Copolymer Composition During Three-Dimensional Free-Radical Copolymerization of Oligomers and Vinyl Monomer / 4.2: |
Critical Conversion (Gel Point) in Three-Dimensional Free-Radical Polymerization / 5: |
Inapplicability of Known Critical Conversion Calculation Methods to Three-Dimensional Free-Radical Polymerization / 5.1: |
Novel Approach to Calculating Critical Conversion in Three-Dimensional Free-Radical Polymerization / 5.2: |
Results of Critical Conversion Calculation for Different Cases of Three-Dimensional Free-Radical Polymerization / 5.3: |
Living Chains Three-Dimensional Polymerization and Copolymerization (Without Chain Termination) / 5.3.1: |
Three-Dimensional Polymerization and Copolymerization with Quadratic or Linear Chain Termination / 5.3.2: |
Three-Dimensional Polymerization with "Pendent" Double Bonds Taken into Account (Chain Termination by Disproportionation) / 5.3.3: |
Summary of Results of Theoretical Calculations for Critical Conversion / 5.3.4: |
Comparison of Results of Theoretical Calculations for Critical Conversion with Experimental Data / 5.4: |
Inhibited Polymerization of Dimethacrylates / 5.4.1: |
Copolymerization of Divinyl Benzene (m-DVB) with Styrene / 5.4.2: |
Properties of Cross-Linked Polymers and Copolymers / 6: |
Cross-Linked Poly(acrylates). Physical and Mechanical Properties / 6.1: |
Influence of Chemical Structure of Oligomers upon Physical and Mechanical Properties of Cross-Linked Poly(acrylates) / 6.1.1: |
Influence of Physical Network Density upon Physical and Mechanical Properties of Cross-Linked Poly(acrylates) / 6.1.2: |
Cross-Linked Copolymers. Physical and Mechanical Properties / 6.2: |
Mechanism of Copolymers Transition into Forced-Elastic State / 6.2.1: |
Influence of Cyclization on Physical and Mechanical Properties of Copolymers / 6.2.2: |
Cross-Linked Copolymers. Thermo-Mechanical Properties / 6.3: |
Mechanism of Copolymers Transition into High-Elastic State / 6.3.1: |
Comparison of Transitions into High-Elastic State with those into Forced-Elastic State / 6.3.2: |
Diffusion-Sorption Properties of Copolymers / 6.4: |
Three-Dimensional Free-Radical Polymerization. Hyper-Branched Polymers / Part II: |
Synthesis of Hyper-Branched Polymers / 7: |
Classification of Reactions for Hyper-Branched Polymer Synthesis / 7.1: |
Synthesis of Hyper-Branched Polymers Via Three-Dimensional Free-Radical (Co)polymerization with Regulation of Polymer Chain Length / 7.2: |
Regulation of Chain Length Through Initiation Rate Variation / 7.2.1: |
Regulation of Chain Length by Chain Transfer Agents and Chain Transfer Catalysts / 7.2.2: |
Regulation of Chain Length Through the Use of Intrachain Reactions of Chain Carrier Radicals / 7.2.3: |
Regulation of Chain Length Through the Use of Molecular Oxygen as an Inhibitor / 7.2.4: |
Synthesis of Hyper-Branched Polymers Via Living Chains Free-Radical Three-Dimensional Polymerization / 7.3: |
Living Chains Free-Radical Three-Dimensional Polymerization as Reaction for Hyper-Branched Polymers Synthesis / 7.3.1: |
Living Chains Polymerization of Vinyl Monomers with Diethyldithiocarbamate Groups / 7.3.2: |
Properties and Application of Hyper-Branched Polymers / 8: |
"Structure-Property" Relationship and Purposeful Generation of Hyper-Branched Polymer Properties That Are in Demand in Practice / 8.1: |
Hyper-Branched Polymers as Modifiers of Polymeric Materials / 8.2: |
Major Fields for Hyper-Branched Polymers Application / 8.3: |
HBP: Main Achievements and Problems to Be Solved Without Delay / 8.4: |
Methods for Studying Three-Dimensional Free-Radical Polymerization and Cross-Linked Polymers / 9: |
Calorimetry / 9.1: |
IR Spectroscopy / 9.2: |
Other Methods of Kinetic Measurements / 9.3: |
Light Scattering / 9.4: |
EPR / 9.5: |
Studying the Kinetics of Free-Radical Accumulation in Nonstationary Mode / 9.5.1: |
Studying the Kinetics of Decay of Accumulated Free Radicals / 9.5.2: |
Structural and Physical Studies Using EPR / 9.5.3: |
NMR / 9.6: |
Physicomechanical and Thermo-Mechanical Methods / 9.7: |
Volumetric Method / 9.8: |
Complex Methods / 9.9: |
Index |
Three-Dimensional Free-Radical Polymerization. Cross-Linked Polymers / Part I: |
Microheterogeneous Mechanism of Three-Dimensional Free-Radical Polymerization / 1: |
Microheterogeneous Model of Polymerization Process / 1.1: |
Polymerization Process: Stages of Formation of the Microheterogeneous Structure for Cross-Linked Polymers / 1.2: |
Formation of Polymer Grains at the Initial Stage of Polymerization / 1.2.1: |
Growth of Polymer Grains During Polymerization / 1.2.2: |