Preface |
Acknowledgments |
Introduction / 1: |
The Role of Chemistry in Engineering / 1.1: |
Green Engineering / 1.2: |
Measurement and Calculations / 1.3: |
The Physical States of Matter / 1.4: |
Classification of Matter / 1.5: |
Separation of Mixtures / 1.6: |
Important Terms |
Study Questions |
Problems |
The Periodic Table of the Elements / 2: |
Atomic Structure / 2.1: |
The Shell Model of the Atom / 2.2: |
Electron Assignments / 2.3: |
Periodic Trends / 2.4: |
Chemical Bonding-The Formation of Materials / 3: |
Atoms and Ions / 3.1: |
Ionic Bonding / 3.2: |
Covalent Bonding / 3.3: |
Mixed Covalent/Ionic Bonding / 3.4: |
Molecular Orbitals / 3.5: |
Molecular Geometry / 3.6: |
Molecular Polarity / 3.7: |
Intermolecular Forces / 3.8: |
Chemical Equations and Mass Balance / 4: |
The Mole / 4.1: |
The Empirical Formula / 4.2: |
Chemical Equations / 4.3: |
Stoichiometry / 4.4: |
Limiting Reactant and Percent Yield / 4.5: |
Aqueous Solubility of Ionic Compounds / 4.6: |
Precipitation Reactions in Aqueous Solution / 4.7: |
Concentrations in Aqueous Solution / 4.8: |
Acids and Bases / 5: |
Defining Acids and Bases / 5.1: |
Acids and Bases in Aqueous Solution / 5.2: |
The pH Scale / 5.3: |
Other "p" Functions / 5.4: |
Buffer Solutions / 5.5: |
The Titration / 5.6: |
Properties of Gases / 6: |
A Historical Perspective / 6.1: |
Boyle's Law / 6.2: |
Charles' Law / 6.3: |
Gay-Lussac's Law / 6.4: |
The Ideal Gas Law / 6.5: |
Nonideal Gas Behavior / 6.6: |
Partial Pressures / 6.7: |
Chemical Reactions With Gases / 6.8: |
Chemical Equilibrium / 7: |
Reversible Reactions / 7.1: |
The Equilibrium Constant / 7.2: |
Relationships Between Equilibrium Constants / 7.3: |
Le Chatelier's Principle: Disturbing a Chemical Equilibrium / 7.4: |
The Reaction Quotient / 7.5: |
Thermodynamics and Energy Balance / 8: |
Chemical Thermodynamics / 8.1: |
The First Law of Thermodynamics: Heat and Work / 8.2: |
Enthalpy / 8.3: |
Standard Enthalpies / 8.4: |
Bond Enthalpy / 8.5: |
The Second Law of Thermodynamics: Entropy / 8.6: |
The Third Law of Thermodynamics: Entropy and Temperature / 8.7: |
Gibbs Free Energy / 8.8: |
Standard Gibb Free Energies and Chemical Equilibrium / 8.9: |
Kinetics and the Rate of Chemical Reactions / 9: |
Reaction Rate / 9.1: |
Rate Laws / 9.2: |
Integrated Rate Laws / 9.3: |
Half-Life / 9.4: |
Collision Theory / 9.5: |
Reaction Mechanisms / 9.6: |
Chain Reaction Mechanisms / 9.7: |
Oxidation-Reduction Reactions Electrochemistry / 10: |
Oxidation-Reduction Reactions / 10.1: |
The Galvanic Cell / 10.2: |
Balancing Oxidation-Reduction Equations / 10.3: |
Standard Cell Potentials / 10.4: |
Reactions at Nonstandard Conditions: The Nernst Equation / 10.5: |
Electrolysis / 10.6: |
Batteries / 10.7: |
Fuel Cells / 10.8: |
Solids / 11: |
Crystalline Solids / 11.1: |
Ionic Solids / 11.2: |
Molecular Solids / 11.3: |
Atomic Solids / 11.4: |
Metallic Solids / 11.5: |
Amorphous Solids / 11.6: |
Solution Chemistry / 12: |
Solution Composition / 12.1: |
Dissolution / 12.2: |
The Effect of Pressure on Solubility / 12.3: |
The Effects of Temperature on Solubility / 12.4: |
Solubility of Ionic Solids / 12.5: |
Complexing Agents / 12.6: |
Surfactants / 12.7: |
Colligative Properties / 12.8: |
The Chemistry of Carbon / 13: |
Carbon Bonding and Hybridization / 13.1: |
Organic Hydrocarbons: Alkanes, Alkynes, Alkenes, and Aromatics / 13.2: |
Organic Functional Groups / 13.3: |
Organic Reaction Mechanisms / 13.4: |
Polymer Chemistry / 13.5: |
Nuclear and Radiochemistry / 14: |
Isotopes and Radioactive Decay / 14.1: |
Radioactive Decay Rates and Half Lives / 14.2: |
Natural Radioisotopes / 14.3: |
Detecting Radioisotopes and Radioactivity / 14.4: |
Fission and Fusion / 14.5: |
Nuclear Energy / 14.6: |
Radiation Safety / 14.7: |
Applications of Radioisotopes / 14.8: |
Chemical Measurements and Instrumentation / 15: |
Chromatography / 15.1: |
Atomic Spectroscopy / 15.2: |
UV-Visible Absorption Spectroscopy / 15.3: |
Infrared Spectroscopy / 15.4: |
Luminescence Spectroscopy / 15.5: |
Mass Spectrometry / 15.6: |
Nuclear Magnetic Resonance Spectroscopy / 15.7: |
Glossary |
Answers to Study Questions and Problems |
Working with Units / Appendix I: |
Using Spreadsheets / Appendix II: |
Some Standard Half-Cell Potential at 298.15K (25°C) / Appendix III: |
Index |
Preface |
Acknowledgments |
Introduction / 1: |
The Role of Chemistry in Engineering / 1.1: |
Green Engineering / 1.2: |
Measurement and Calculations / 1.3: |