Energy innovation

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Energy innovation / edited by Hisashi Yamamoto and Takashi Kato

資料種別:

図書

出版情報:

Weinheim : Wiley-VCH, c2018

形態:

xvii, 314 p. ; 25 cm

シリーズ名:

Molecular technology ; v. 1 <BB27178900>

著者名:

ISBN:

9783527341634 [3527341633] (: print)

書誌ID:

BB27179062

子書誌情報

フルテキスト

所蔵情報

他の版・巻

書誌詳細

注記:

Includes bibliographical references and index

著者名ヨミ:

ヤマモト, ヒサシ
カトウ, タカシ

主題:

Chemistry; Power resources

言語:

英語

目次情報:

Foreword / Dr Hamaguchi

Preface / Dr Noyori

Charge Transport Simulations for Organic Semiconductors / Hiroyuki Ishii1：

Introduction / 1.1：

Historical Approach to Organic Semiconductors / 1.1.1：

Recent Progress and Requirements to Computational "Molecular Technology" / 1.1.2：

Theoretical Description of Charge Transport in Organic Semiconductors / 1.2：

Incoherent Hopping Transport Model / 1.2.1：

Coherent Band Transport Model / 1.2.2：

Coherent Polaron Transport Model / 1.2.3：

Trap Potentials / 1.2.4：

Wave-packet Dynamics Approach Based on Density Functional Theory / 1.2.5：

Charge Transport Properties of Organic Semiconductors / 1.3：

Comparison of Polaron Formation Energy with Dynamic Disorder of Transfer Integrals due to Molecular Vibrations / 1.3.1：

Temperature Dependence of Mobility / 1.3.2：

Evaluation of Intrinsic Mobilities for Various Organic Semiconductors / 1.3.3：

Summary / 1.4：

Forthcoming Challenges in Theoretical Studies / 1.4.1：

Acknowledgments

References

Liquid-Phase Interfacial Synthesis of Highly Oriented Crystalline Molecular Nanosheets / Rie Makiura2：

Molecular Nanosheet Formation with Traditional Surfactants at Air/Liquid Interfaces / 2.1：

History of Langmuir-Blodgett Film / 2.2.1：

Basics of Molecular Nanosheet Formation at Air/Liquid Interfaces / 2.2.2：

Application of Functional Organic Molecules for Nanosheet Formation at Air/Liquid Interfaces / 2.3：

Functional Organic Molecules with Long Alkyl Chains / 2.3.1：

Functional Organic Molecules without Long Alkyl Chains / 2.3.2：

Application of Functional Porphyrins on Metal Ion Solutions / 2.3.3：

Porphyrin-Based Metal-Organic Framework (MOF) Nanosheet Crystals Assembled at Air/Liquid Interfaces / 2.4：

Metal-Organic Frameworks / 2.4.1：

Method of MOF Nanosheet Creation at Air/Liquid Interfaces / 2.4.2：

Study of the Formation Process of MOF Nanosheets by In Situ X-Ray Diffraction and Brewster Angle Microscopy at Air/Liquid Interfaces / 2.4.3：

Application of a Postinjection Method Leading to Enlargement of the Uniform MOF Nanosheet Domain Size / 2.4.4：

Layer-by-Layer Sequential Growth of Nanosheets - Toward Three-Dimensionally Stacked Crystalline MOF Thin Films / 2.4.5：

Manipulation of the Layer Stacking Motif in MOF Nanosheets / 2.4.6：

Manipulation of In-Plane Molecular Arrangement in MOF Nanosheets / 2.4.7：

Molecular Technology for Organic Semiconductors Toward Printed and Flexible Electronics / Toshihiro Okamoto3：

Molecular Design and Favorable Aggregated Structure for Effective Charge Transport of Organic Semiconductors / 3.1：

Molecular Design of Linearly Fused Acene-Type Molecules / 3.3：

Molecular Technology of Â¿-Conjugated Cores for p-Type Organic Semiconductors / 3.4：

Molecular Technology of Substituents for Organic Semiconductors / 3.5：

Bulky-Type Substituents / 3.5.1：

Linear Alkyl Chain Substituents / 3.5.2：

Molecular Technology of Conceptually-new Bent-shaped Â¿-Conjugated Cores for p-Type Organic Semiconductors / 3.6：

Bent-Shaped Heteroacenes / 3.6.1：

Molecular Technology for n-Type Organic Semiconductors / 3.7：

Naphthalene Diimide and Perylene Diimide / 3.7.1：

Design of Multiproton-Responsive Metal Complexes as Molecular Technology for Transformation of Small Molecules / Shigeki Kuwata4：

Cooperation of Metal and Functional Groups in Metalloenzymes / 4.1：

[FeFe] Hydrogenase / 4.2.1：

Peroxidase / 4.2.2：

Nitrogenase / 4.2.3：

Proton-Responsive Metal Complexes with Two Appended Protic Groups / 4.3：

Pincer-Type Bis(azole) Complexes / 4.3.1：

Bis(2-hydroxypyridine) Chelate Complexes / 4.3.2：

Proton-Responsive Metal Complexes with Three Appended Protic Groups on Tripodal Scaffolds / 4.4：

Summary and Outlook / 4.5：

Photo-Control of Molecular Alignment for Photonic and Mechanical Applications / Miho Aizawa and Christopher J. Barrett and Atsushi Shishido5：

Photo-Chemical Alignment / 5.1：

Photo-Physical Alignment / 5.3：

Photo-Physico-Chemical Alignment / 5.4：

Application as Photo-Actuators / 5.5：

Conclusions and Perspectives / 5.6：

Molecular Technology for Chirality Control: From Structure to Circular Polarization / Yoshiaki Uchida and Tetsuya Narushima and Junpei Yuasa6：

Chiral Lanthanide(III) Complexes as Circularly Polarized Luminescence Materials / 6.1：

Circularly Polarized Luminescence (CPL) / 6.1.1：

Theoretical Explanation for Large CPL Activity of Chiral Lanthanide(III) Complexes / 6.1.2：

Optical Activity of Chiral Lanthanide(III) Complexes / 6.1.3：

CPL of Chiral Lanthanide(III) Complexes for Frontier Applications / 6.1.4：

Magnetic Circular Dichroism and Magnetic Circularly Polarized Luminescence / 6.2：

Magnetic-Field-induced Symmetry Breaking on Light Absorption and Emission / 6.2.1：

Molecular Materials Showing MCD and MCPL and Applications / 6.2.2：

Molecular Self-assembled Helical Structures as Source of Circularly Polarized Light / 6.3：

Chiral Liquid Crystalline Phases with Self-assembled Helical Structures / 6.3.1：

Strong CPL of CLC Laser Action / 6.3.2：

Optical Activity Caused by Mesoscopic Chiral Structures and Microscopic Analysis of the Chiroptical Properties / 6.4：

Microscopic CD Measurements via Far-field Detection / 6.4.1：

Optical Activity Measurement Based on Improvement of a PEM Technique / 6.4.2：

Discrete Illumination of Pure Circularly Polarized Light / 6.4.3：

Complete Analysis of Contribution From All Polarization Components / 6.4.4：

Near-field CD Imaging / 6.4.5：

Conclusions / 6.5：

Molecular Technology of Excited Triplet State / Yuki Kurashige and Nobuhiro Yanai and Yong-Jin Pu and So Kawata7：

Properties of the Triplet Exciton and Associated Phenomena for Molecular Technology / 7.1：

Introduction: The Triplet Exciton / 7.1.1：

Molecular Design for Long Diffusion Length / 7.1.2：

Theoretical Analysis for the Electronic Transition Processes Associated with Triplet / 7.1.3：

Near-infrared-to-visible Photon Upconversion: Chromophore Development and Triplet Energy Migration / 7.2：

Evaluation of TTA-UC Properties / 7.2.1：

NIR-to-visible TTA-UC Sensitized by Metalated Macrocyclic Molecules / 7.2.3：

TTA-UC Sensitized by Metal Complexes with S-T Absorption / 7.2.4：

Conclusion and Outlook / 7.2.5：

Singlet Exciton Fission Molecules and Their Application to Organic Photovoltaics / 7.3：

Polycyclic Â¿-Conjugated Compounds / 7.3.1：

Pentacene / 7.3.2.1：

Tetracene / 7.3.2.2：

Hexacene / 7.3.2.3：

A Heteroacene

Perylene and Terrylene / 7.3.2.5：

Nonpolycyclic Â¿-Conjugated Compounds / 7.3.3：

Polymers / 7.3.4：

Perspectives / 7.3.5：

Material Transfer and Spontaneous Motion in Mesoscopic Scale with Molecular Technology / Yoshiyuki Kageyama and Yoshiko Takenaka and Kenji Higashiguchi8：

Introduction of Chemical Actuators / 8.1：

Composition of This Chapter / 8.1.2：

Mechanism to Originate Mesoscale Motion / 8.2：

Motion Generated by Molecular Power / 8.2.1：

Gliding Motion of a Mesoscopic Object by the Gradient of Environmental Factors / 8.2.2：

Mesoscopic Motion of an Object by Mechanical Motion of Molecules / 8.2.3：

Toward the Implementation of a One-Dimensional Actuator: Artificial Muscle / 8.2.4：

Generation of "Molecular Power" by a Stimuli-Responsive Molecule / 8.3：

Structural Changes of Molecules and Supramolecular Structures / 8.3.1：

Structural Changes of Photo chromic Molecules / 8.3.2：

Fundamentals of Kinetics of Photochromic Reaction / 8.3.3：

Photoisomerization and Actuation / 8.3.4：

Mesoscale Motion Generated by Cooperation of "Molecular Power" / 8.4：

Motion in Gradient Fields / 8.4.1：

Movement Triggered by Mobile Molecules / 8.4.2：

Autonomous Motion with Self-Organization / 8.4.3：

Molecular Technologies for Photocatalytic CO₂ Reduction / Yusuke Tamaki and Hiroyuki Takeda and Osamu Ishitani8.5：

Photocatalytic Systems Consisting of Mononuclear Metal Complexes / 9.1：

Rhenium(I) Complexes / 9.2.1：

Reaction Mechanism / 9.2.2：

Multicomponent Systems / 9.2.3：

Photocatalytic CO₂ Reduction Using Earth-Abundant Elements as the Central Metal of Metal Complexes / 9.2.4：

Supramolecular Photocatalysts: Multinuclear Complexes / 9.3：

Ru(II)-Re(I) Systems / 9.3.1：

Ru(II)-Ru(II) Systems / 9.3.2：

Ir(III)-Re(I) and Os(II)-Re(I) Systems / 9.3.3：

Photocatalytic Reduction of Low Concentration of CO₂ / 9.4：

Hybrid Systems Consisting of the Supramolecular Photocatalyst and Semiconductor Photocatalysts / 9.5：

Conclusion / 9.6：

Acknowledgements

Molecular Design of Photocathode Materials for Hydrogen Evolution and Carbon Dioxide Reduction / Christopher D. Windle and Soundarrajan Chandrasekaran and Hiromu Kumagai and Go Sahara and Keiji Nagai and Toshiyuki Abe and Murielle Chavarot-Kerlidou and Osamu Ishitani and Vincent Artero10：

Photocathode Materials for H₂ Evolution / 10.1：

Molecular Photocathodes for H₂ Evolution Based on Low Bandgap Semiconductors / 10.2.1：

Molecular Catalysts Physisorbed on a Semiconductor Surface / 10.2.1.1：

Covalent Attachment of the Catalyst to the Surface of the Semiconductor / 10.2.1.2：

Covalent Attachment of the Catalyst Within an Oligomeric or Polymeric Material Coating the Semiconductor Surface / 10.2.1.3：

H₂-evolving Photocathodes Based on Organic Semiconductors / 10.2.2：

Dye-sensitised Photocathodes for H₂ Production / 10.2.3：

Dye-sensitised Photocathodes with Physisorbed or Diffusing Catalysts / 10.2.3.1：

Dye-sensitised Photocathodes Based on Covalent or Supramolecular Dye-Catalyst Assemblies / 10.2.3.2：

Dye-sensitised Photocathodes Based on Co-grafted Dyes and Catalysts / 10.2.3.3：

Photocathodes for CO₂ Reduction Based on Molecular Catalysts / 10.3：

Photocatalytic Systems Consisting of a Molecular Catalyst and a Semiconductor Photo electrode / 10.3.1：

Dye-sensitised Photocathodes Based on Molecular Photocatalysts / 10.3.2：

Molecular Design of Glucose Biofuel Cell Electrodes / Michael Holzinger and Yuta Nishina and Alan Le Goff and Masato Tominaga and Serge Cosnier and Seiya Tsujimura11：

Molecular Approaches for Enzymatic Electrocatalytic Oxidation of Glucose / 11.1：

Molecular Designs for Enhanced Electron Transfers with Oxygen-Reducing Enzymes / 11.3：

Conclusion and Future Perspectives / 11.4：

Index

Foreword / Dr Hamaguchi

Preface / Dr Noyori

Charge Transport Simulations for Organic Semiconductors / Hiroyuki Ishii1：

Introduction / 1.1：

Historical Approach to Organic Semiconductors / 1.1.1：

Recent Progress and Requirements to Computational "Molecular Technology" / 1.1.2：

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