Preface to the first edition |
Author's preface to the third edition |
Author's preface to the second edition |
Prologue |
List of principal symbols |
Introduction / 1: |
Chemistry and the climate system / 1.1: |
Air and atmosphere: a multiphase and multicomponent system / 1.2: |
Principles of chemistry in the climate system / 1.3: |
Substances in climate system / 1.4: |
Fundamentals of physics in the climate system / 2: |
Meteorological basics / 2.1: |
Scaling and structure of the atmosphere / 2.1.1: |
Meteorological elements / 2.1.2: |
Air pressure / 2.1.2.1: |
Air temperature / 2.1.2.2: |
Air humidity / 2.1.2.3: |
Hydrometeors / 2.1.3: |
Clouds / 2.1.3.1: |
Fog, mist, and haze / 2.1.3.2: |
Precipitation / 2.1.3.3: |
Dew, frost, rime, and interception / 2.1.4: |
Clirnatologtcai basics / 2.2: |
Climate / 2.2.1: |
Climate system / 2.2.2: |
Chemical climate / 2.2.3: |
Optics of the atmosphere: Radiation / 2.3: |
Solar radiation / 2.3.1: |
The Sun and its radiation output / 2.3.1.1: |
Solar radiation transfer through the atmosphere / 2.3.1.2: |
Absorption and emission of light / 2.3.2: |
Absorption (Lambert-Beer law) / 2.3.2.1: |
Emission (Planck's law and Stefan-Boltzmann law) / 2.3.2.2: |
Terrestrial radiation and radiation budget / 2.3.3: |
Atmospheric dynamics / 2.4: |
Fluid characteristics / 2.4.1: |
Effective atmospheric forces / 2.4.1.1: |
Atmospheric flow: Laminar and turbulent / 2.4.1.2: |
Fluid characteristics: Wind speed and direction / 2.4.1.3: |
Properties of gases: The ideal gas / 2.5: |
Gas laws / 2.5.1: |
Mean free path and number of collisions between molecules / 2.5.2: |
Viscosity / 2.5.3: |
Diffusion / 2.5.4: |
Atmospheric removal: Deposition processes / 2.6: |
Dry deposition / 2.6.1: |
Wet deposition / 2.6.2: |
Characteristic times; Residence time, lifetime, and turnover time / 2.7: |
Fundamentals of physicochemistry in the climate system / 3: |
Chemical thermodynamics / 3.1: |
First law of thermodynamics and its applications / 3.1.1: |
Internal energy / 3.1.1.1: |
Molar heat capacity / 3.1.1.2: |
Thermochemistry: Heat of chemical reaction / 3.1.1.3: |
Second law of thermodynamics and its applications / 3.1.2: |
Entropy and reversibility / 3.1.2.1: |
Thermodynamic potential: Gibbs-Helmholtz equation / 3.1.2.2: |
Chemical potential / 3.1.2.3: |
Chemical potential in real mixtures: Activity / 3.1.2.4: |
Equilibrium / 3.2: |
Chemical equilibrium: The mass action law / 3.2.1: |
Phase equilibrium / 3.2.2: |
Gas-liquid equilibrium: Evaporation and condensation / 3.2.2.1: |
Gas-liquid equilibrium: Special case of droplets (Kelvin equation) / 3.2.2.2: |
Absorption of gases in water: Henry's law / 3.2.2.3: |
Solubility equilibrium: Solid-aqueous equilibrium / 3.2.2.4: |
Adsorption and desorption / 3.2.2.5: |
Steady state / 3.3: |
Water: Physical and chemical properties / 3.4: |
Water structure: Hydrogen bond / 3.4.1: |
Water as solvent / 3.4.2: |
Water vapor / 3.4.3: |
Water properties in relation to the climate system / 3.4.4: |
Properties of solutions and droplets / 3.5: |
Surface tension and surface-active substances / 3.5.1: |
Vapor pressure lowering: Raoult's law / 3.5.2: |
Freezing point depression / 3.5.3: |
Diffusion in solution / 3.5.4: |
Heterogeneous processes: Multiphase chemistry in the climate system / 3.6: |
Aerosols, clouds, and precipitation: The climate multiphase system / 3.6.1: |
Gas-to-particle formation: Homogeneous formation of CCNs / 3.6.2: |
Classical nucleation theory / 3.6.2.1: |
Formation of secondary organic aerosols / 3.6.2.2: |
Atmospheric aerosols and the properties of aerosol particles / 3.6.3: |
Formation of cloud droplets: Heterogeneous nucleation / 3.6.4: |
Scavenging: Acommodation, adsorption, and reaction (mass transfer) / 3.6.5: |
Mass transfer: General remarks / 3.6.5.1: |
Adsorption / 3.6.5.2: |
Surface chemistry: Kinetics of heterogeneous chemical reactions / 3.6.5.3: |
Mass transfer into droplets with chemical reaction / 3.6.5.4: |
Fundamentals of chemistry in the climate system / 4: |
State of matter / 4.1: |
Atoms, elements, molecules, compounds, and substances / 4.1.1: |
Pure substances and mixtures / 4.1.2: |
Radicals, groups, and nomenclature / 4.1.3: |
Units for chemical abundance: Concentrations and mixing ratios / 4.1.4: |
Theory of chemical reactions / 4.2: |
Chemical bonding / 4.2.1: |
Types of chemical reactions / 4.2.2: |
Chemical kinetics: Reaction rate constant / 4.2.3: |
Catalysis / 4.3: |
Electrochemistry / 4.4: |
Electrolytic dissociation / 4.4.1: |
Acids, bases, and the ionic product of water / 4.4.1.1: |
pH value / 4.4.1.2: |
Hydrolysis of salts and oxides / 4.4.1.3: |
Buffer solutions / 4.4.1.4: |
Complex ions / 4.4.1.5: |
The CO2-carbonate system / 4.4.1.6: |
Oxidation-reduction reaction (redox process) / 4.4.2: |
Hydrated electron: A fundamental species / 4.4.3: |
Photochemistry / 4.5: |
Photoexcitation: Electronic states / 4.5.1: |
Photodissociation: Photolysis rate coefficient / 4.5.2: |
Photocatalysis: Photosensitization and autoxidation / 4.5.3: |
Environmental relevance of acidity / 4.6: |
Atmospheric acidity / 4.6.1: |
pH averaging / 4.6.2: |
Isotopes in atmospheric chemistry and geochemistry / 4.7: |
Substaces and chemical reactions in the climate system / 5: |
Hydrogen / 5.1: |
Natural occurrence / 5.1.1: |
Compounds of hydrogen / 5.1.2: |
Chemistry / 5.1.3: |
Oxygen / 5.2: |
Oxygen, dioxygen, and ozone: O, O2, and O3 / 5.2.1: |
Reactive oxygen species I: OH, HO2, and H2O2 (HxOy species) / 5.2.3: |
Atmosphere, free of trace species / 5.2.3.1: |
Atmosphere with trace species / 5.2.3.2: |
Reactive oxygen species II: RO, RO2, and ROOH / 5.2.4: |
Aqueous-phase oxygen chemistry / 5.2.5: |
Water chemistry / 5.2.5.1: |
Dioxygen and superoxide ion chemistry / 5.2.5.2: |
Hydrogen peroxide chemistry / 5.2.5.3: |
Ozone and hydroxyl radical chemistry / 5.2.5.4: |
Hydrogen polyoxides / 5.2.5.5: |
Multiphase oxygen chemistry / 5.2.6: |
Hydrogen peroxide / 5.2.6.1: |
Ozone / 5.2.6.2: |
Stratospheric oxygen chemistry / 5.2.7: |
Nitrogen / 5.3: |
Natural occurrence and sources / 5.3.1: |
Thermal dissociation of dinitrogen (N2) / 5.3.2: |
Ammonia (NH3) / 5.3.3: |
Dinitrogen oxide (N2O) / 5.3.4: |
Inorganic nitrogen oxides and oxoacids (NOy) / 5.3.5: |
Gas-phase chemistry / 5.3.3.1: |
Aqueous and interfacial chemistry / 5.3.5.2: |
Organic nitrogen compounds / 5.3.6: |
Amines, amides, and nitriles / 5.3.6.1: |
Organic NOx compounds / 5.3.6.2: |
Sulfur / 5.4: |
Reduced sulfur: H2S, COS, CS2, and DMS / 5.4.1: |
Oxides and oxoacids: SO2, H2SO3, SO3, and H2SO4 / 5.4.3: |
Gas-phase SO2 oxidation / 5.4.3.1: |
Aqueous-phase sulfur chemistry / 5.4.3.2: |
Multiphase sulfur chemistry / 5.4.4: |
Phosphorus / 5.5: |
Carbon / 5.6: |
Organic carbon and chemistry / 5.6.1: |
Elemental carbon and soot / 5.6.2: |
Inorganic C1 chemistry: CO, CO2, and H2CO3 / 5.6.3: |
Aqueous chemistry / 5.6.3.1: |
Hydrocarbon oxidation and organic radicals / 5.6.4: |
Organic C1 chemistry: CH4, CH3OH, HCHO, HCOOH / 5.6.5: |
C2 chemistry: C2H6, CH3CHO, C2H5OH, CH3COOH, and (COOH)2
|
Alkenes, atkynes, and ketones / 5.6.6.1: |
Aromatic compounds / 5.6.8: |
Is the atmospheric fate of complex organic compounds predictable? / 5.6.9: |
Halogens (Cl, Br, F, and I) / 5.7: |
Chlorine in the environment / 5.7.1: |
Formation of sea salt and chlorine degassing / 5.7.2: |
Metals and metalloids / 5.7.3: |
General remarks / 5.8.1: |
Alkali and alkaline earth metals: Na, K, Mg, and Ca / 5.8.2: |
Iron: Fe / 5.8.3: |
Mercury: Hg / 5.8.4: |
Cadmium: Cd / 5.8.5: |
Lead: Pb / 5.8.6: |
Arsenic: As / 5.8.7: |
Silicon (Si) and aluminum (Al) / 5.8.8: |
Biogeochemistry and global cycling / 6: |
The hydrosphere and the global water cycle / 6.1: |
The hydrological cycle and the climate system / 6.1.1: |
Soil water and groundwater; Chemical weathering / 6.1.2: |
Surface water: Rivers and lakes / 6.1.3: |
The oceans / 6.1.4: |
Atmospheric waters (hydrometeors): Chemical composition / 6.1.5: |
Fog / 6.1.5.1: |
Rain (precipitation) / 6.1.5.3: |
Biogeochemical cycling / 6.2: |
Photosynthesis: Nonequilibrium redox processes / 6.2.1: |
Primary production of carbon / 6.2.2: |
Nitrogen cycling / 6.2.3: |
Sulfur cycling / 6.2.4: |
Natural sources of atmospheric substances / 6.3: |
Source characteristics / 6.3.1: |
Biological processes / 6.3.2: |
Continental / 6.3.2.1: |
Oceanic / 6.3.2.2: |
Geogenic processes / 6.3.3: |
Soil dust / 6.3.3.1: |
Sea salt / 6.3.3.2: |
Volcanism / 6.3.3.3: |
Chemical processes / 6.3.4: |
Lightning / 6.3.4.1: |
Secondary atmospheric processes / 6.3.4.2: |
List of acronyms and abbreviations used in this volume / A: |
Quantities, units, and some useful numerical values / B: |
References |
Name Index |
Subject Index |
Preface to the first edition |
Author's preface to the third edition |
Author's preface to the second edition |
Prologue |
List of principal symbols |
Introduction / 1: |