Catalysis without precious metals /

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Catalysis without precious metals / / edited by R. Morris Bullock

資料種別:: 電子ブック
出版情報:: Weinheim : Wiley-VCH, 〓2010
形態:: 1 online resource (xviii, 290 pages)
著者名:: Bullock, R. Morris.
ISBN:: 9783527631582 [3527631585]
9783527631599 [3527631593]
9783527323548 [3527323546]
書誌ID:: EB00000506

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Includes bibliographical references and index.
Written for chemists in industry and academia, this ready reference and handbook summarizes recent progress in the development of new catalysts that do not require precious metals. The research thus presented points the way to how new catalysts may ultimately supplant the use of precious metals in some types of reactions, while highlighting the remaining challenges. An essential companion for organic and catalytic chemists, as well as those working with/on organometallics, and graduate students.

主題:

Catalysis; Catalysts; SCIENCE--Chemistry Physical & Theoretical

目次情報:

Preface

List of Contributors

Catalysis Involving the H* Transfer Reactions of First-Row Transition Metals / John Hartung ; Jack R. Norton1：

H* Transfer Between M-H Bonds and Organic Radicals / 1.1：

H* Transfer Between Ligands and Organic Radicals / 1.2：

H* Transfer Between M-H and C-C Bonds / 1.3：

Chain Transfer Catalysis / 1.4：

Catalysis of Radical Cydizations / 1.5：

Competing Methods for the Cyclization of Dienes / 1.6：

Summary and Conclusions / 1.7：

References

Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum / Richard R. Schrock2：

Some Characteristics of Triamidoamine Complexes / 2.1Introduction：

Possible [HIPTN₃N]Mo Intermediates in a Catalytic Reduction of Molecular Nitrogen / 2.3：

MoN₂ and MoN₂^- / 2.3.1：

Mo-N=NH / 2.3.2：

Conversion of Mo(N₂) into Mo-N=NH / 2.3.3：

[Mo=N-NH₂]⁺ / 2.3.4：

Mo=N and [Mo=NH]⁺ / 2.3.5：

Mo(NH₃) and [Mo(NH₃)⁺ / 2.3.6：

Interconversion of Mo(NH₃) and Mo(N₂) / 2.4：

Catalytic Reduction of Dinitrogen / 2.5：

MoH and Mo(H₂) / 2.6：

Ligand and Metal Variations / 2.7：

Comments / 2.8：

Acknowledgements

Molybdenum and Tungsten Catalysts for Hydrogenation, Hydrosilylation and Hydrolysis / R. Morris Bullock3：

Introduction / 3.1：

Proton Transfer Reactions of Metal Hydrides / 3.2：

Hydride Transfer Reactions of Metal Hydrides / 3.3：

Stoichiometric Hydride Transfer Reactivity of Anionic Metal Hydride Complexes / 3.4：

Catalytic Hydrogenation of Ketones with Anionic Metal Hydrides / 3.5：

Ionic Hydrogenation of Ketones Using Metal Hydrides and Added Acid / 3.6：

Ionic Hydrogenations from Dihydrides: Delivery of the Proton and Hydride from One Metal / 3.7：

Catalytic Ionic Hydrogenations With Mo and W Catalysts / 3.8：

Mo Phosphine Catalysts With Improved lifetimes / 3.9：

Tungsten Hydrogenation Catalysts with N-Heterocyclic Carbene Ligands / 3.10：

Catalysts for Hydrosilylation of Ketones / 3.11：

Cp₂Mo Catalysts for Hydrolysis, Hydrogenations and Hydrations / 3.12：

Conclusion / 3.13：

Modern Alchemy: Replacing Precious Metals with Iron in Catalytic Alkene and Carbonyl Hydrogenation Reactions / Paul J. Chink4：

Alkene Hydrogenation / 4.1：

Iron Carbonyl Complexes / 4.2.1：

Iron Phosphine Compounds / 4.2.2：

Bis(imino)pyridine Iron Complexes / 4.2.3：

α-Diimine Iron Complexes / 4.2.4：

Carbonyl Hydrogenation / 4.3：

Hydrosilylation / 4.3.1：

Bifunctional Complexes / 4.3.2：

Outlook / 4.4：

Olefin Oligomerizations and Polymerizations Catalyzed by Iron and Cobalt Complexes Bearing Bis(imino)pyridine Ligands / Vernon C. Gibson ; Gregory A. Solan5：

Precatalyst Synthesis / 5.1：

Ligand Preparation / 5.2.1：

Complexation with MX₂ (M = Fe, Co) / 5.2.2：

Precatalyst Activation and Catalysis / 5.3：

Olefin Polymerization / 5.3.1：

Catalytic Evaluation / 5.3.1.1：

Steric Versus Electronic Effects / 5.3.1.2：

Effect of MAO Concentration / 5.3.1.3：

Effects of Pressure and Temperature / 5.3.1.4：

α-Olefin Monomers / 5.3.1.5：

Olefin Oligomerization / 5.3.2：

Substituent Effects / 5.3.2.1：

Schulz-Flory Distributions / 5.3.2.3：

Poisson Distributions / 5.3.2.4：

The Active Catalyst and Mechanism / 5.3.2.5：

Active Species / 5.4.：

Iron Catalyst / 5.4.1.1：

Cobalt Catalyst / 5.4.1.2：

Propagation and Chain Transfer Pathways/Theoretical Studies / 5.4.2：

Well-Defined Iron and Cobalt Alkyls / 5.4.3：

Other Applications / 5.5：

Immobilization / 5.5.1：

Reactor Blending and Tandem Catalysis / 5.5.2：

Conclusions and Outlook / 5.6：

Cobalt and Nickel Catalyzed Reactions Involving C-H and C-N Activation Reactions / Renee Becker ; William D. Jones6：

Catalysis with Cobal / 6.1：

Catalysis with Nickel / 6.3：

A Modular Approach to the Development of Molecular Electrocatalysts for H₂ Oxidation and Production Based on Inexpensive Metals / M. Rakowski DuBois ; Daniel L. DuBois7：

Concepts in Catalyst Design Based on Structural Studies of Hydrogenase Enzymes / 7.1：

A Layered or Modular Approach to Catalyst Design / 7.3：

Using the First Coordination Sphere to Control the Energies of Catalytic Intermediates / 7.4：

Using the Second Coordination Sphere to Control the Movement of Protons between the Metal and the Exterior of the Molecular Catalyst / 7.5：

Integration of the First and Second Coordination Spheres / 7.6：

Summary / 7.7：

Nickel-Catalyzed Reductive Couplings and Cyclizations / Hasnain A. Malik ; Ryan D. Baxter ; John Montgomery8：

Couplings of Alkynes with α,β-Unsaturated Carbonyls / 8.1：

Three-Component Couplings via Alkyl Group Transfer-Methods Development / 8.2.1：

Reductive Couplings via Hydrogen Atom Transfer-Methods Development / 8.2.2：

Mechanistic Insights / 8.2.3：

Metallacycle-Based Mechanistic Pathway / 8.2.3.1：

Use in Natural Product Synthesis / 8.2.4：

Couplings of Alkynes with Aldehydes / 8.3：

Three-Component Couplings via Alkyl Group Transfer-Method Development / 8.3.1：

Reductive Couplings via Hydrogen Atom Transfer-Method Development / 8.3.2：

Simple Aldehyde and Alkyne Reductive Couplings / 8.3.2.1：

Directed Processes / 8.3.2.2：

Diastereoselective Variants: Transfer of Chirality / 8.3.2.3：

Asymmetric Variants / 8.3.2.4：

Cydocondensations via Hydrogen Gas Extrusion / 8.3.3：

Copper-Catalyzed Ligand Promoted Ullmann-type Coupling Reactions / Yongwen Jiang ; Dawei Ma8.3.5：

C-N Bond Formation / 9.1：

Arylation of Amines / 9.2.1：

Arylation of Aliphatic Primary and Secondary Amines / 9.2.1.1：

Arylation of Aryl Amines / 9.2.1.2：

Arylation of Ammonia / 9.2.1.3：

Arylation and Vinylation of N-Heterocycles / 9.2.2：

Coupling of Aryl Halides and N-Heterocycles / 9.2.2.1：

Coupling of Vinyl Bromides and N-Heterocycles / 9.2.2.2：

Aromatic Amidation / 9.2.3：

Cross-Coupling of aryl Halides with Amides and Carbamates / 9.2.3.1：

Cross-Coupling of Vinyl Halides with Amides or Carbamates / 9.2.3.2：

Cross-Coupling of Alkynl Halides with Amides or Carbamates / 9.2.3.3：

Azidation / 9.2.4：

C-0 Bond Formation / 19.3：

Synthesis of Diaryl Ethers / 9.3.1：

Aryloxylation of Vinyl Halides / 9.3.2：

Cross-Coupling of Aryl Halides with Aliphatic Alcohols / 9.3.3：

C-C Bond Formation / 9.4：

Cross-Coupling with Terminal Acetylene / 9.4.1：

The Arylation of Activated Methylene Compounds / 9.4.2：

Cyanation / 9.4.3：

C-S Bond Formation / 9.5：

The Formation of Bisaryl- and Arylalkyl-Thioethers / 9.5.1：

The Synthesis of Alkenylsulfides / 9.5.2：

Assembly of aryl Sulfones / 9.5.3：

C-P Bond Formation / 9.6：

Copper-Catalyzed Azide-Alkyne Cycloaddition (CuAAC) / M.G. Finn ; Valery V. Fokin9.7：

Azide-Alkyne Cycloaddition: Basics / 10.1：

Copper-Catalyzed Cycloadditions / 10.3：

Catalysts and Ligands / 10.3.1：

CuAAC with In Situ Generated Azides / 10.3.2：

Mechanistic Aspects of the CuAAC / 10.3.3：

Reactions of Sulfonyl Azides / 10.3.4：

Copper-Catalyzed Reactions with Other Dipolar Species / 10.3.5：

Examples of Application of the CuAAC Reaction / 10.3.6：

Synthesis of Compound libraries for Biological Screening / 10.3.6.1：

Copper-Binding Adhesives / 10.3.6.2：

Representative Experimental Procedures / 10.3.7：

"Frustrated Lewis Pairs": A Metal-Free Strategy for Hydrogenation Catalysis / Douglas W. Stephan11：

Phosphine-Borane Activation of H₂ / 11.1：

"Frustrated Lewis Pairs" / 11.2：

Metal-Free Catalytic Hydxogenation / 11.3：

Future Considerations / 11.4：

Index

Preface

List of Contributors

Catalysis Involving the H* Transfer Reactions of First-Row Transition Metals / John Hartung ; Jack R. Norton1：

H* Transfer Between M-H Bonds and Organic Radicals / 1.1：

H* Transfer Between Ligands and Organic Radicals / 1.2：

H* Transfer Between M-H and C-C Bonds / 1.3：

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