Polymer Dynamics and Relaxation

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Polymer Dynamics and Relaxation / Richard Hays Boyd, Richard Boyd, Grant Smith, Grant D. Smith

資料種別:

電子ブック

出版情報:

Cambridge University Press Online Books
Cambridge : Cambridge University Press, 2007

著者名:

ISBN:

9780521152914 [0521152917]
9780521814195 [0521814197]
9781107316096 [110731609X]

書誌ID:

OB00232231

子書誌情報

フルテキスト

所蔵情報

書誌詳細

主題:

Engineering - General and Others

言語:

英語

目次情報:

Preface

Methodology / Part I：

Mechanical relaxation / 1：

Regimes of behavior / 1.1：

Superposition principle / 1.2：

Relaxation modulus / 1.3：

Simple stress relaxation / 1.4：

Dynamic modulus / 1.5：

Interconversion of stress relaxation and dynamic modulus / 1.6：

Representation of the relaxation function: single relaxation time (SRT) / 1.7：

Relaxations in polymeric materials tend to be "broad" / 1.8：

Distribution of relaxation times / 1.9：

Relaxation spectrum from E[subscript R](t) / 1.10：

Creep compliance / 1.11：

Dynamic compliance / 1.12：

Representation of the retardation function / 1.13：

Summary of the data transformations illustrated / 1.14：

A brief summary of elasticity / Appendix A1：

References

Dielectric relaxation / 2：

Dielectric permittivity / 2.1：

Measurement of dielectric permittivity / 2.2：

Time dependence of polarization: reorientation of permanent dipoles / 2.3：

Polarization and permittivity in time dependent electric fields / 2.4：

Empirical representations of the dielectric permittivity / 2.5：

NMR spectroscopy / 3：

NMR basics / 3.1：

The pulsed NMR method / 3.2：

NMR relaxation measurements / 3.3：

NMR exchange spectroscopy / 3.4：

Dynamic neutron scattering / 4：

Neutron scattering basics / 4.1：

Time-of-flight (TOF) and backscattering QENS / 4.2：

Neutron spin echo (NSE) spectroscopy / 4.3：

Molecular dynamics (MD) simulations of amorphous polymers / 5：

A brief history of atomistic MD simulations of amorphous polymers / 5.1：

The mechanics of MD simulations / 5.2：

Studying relaxation processes using atomistic MD simulations / 5.3：

Classical atomistic force fields / 5.4：

Amorphous polymers / Part II：

The primary transition region / 6：

Mechanical vs. dielectric relaxation / 6.1：

NMR relaxation / 6.4：

Neutron scattering / 6.5：

Secondary (subglass) relaxations / 7：

Occurrence of mechanical and dielectric secondary processes / 7.1：

Complexity and multiplicity of secondary processes / 7.2：

Flexible side group motion as a source of secondary relaxation / 7.3：

NMR spectroscopy studies of flexible side group motion / 7.4：

The transition from melt to glass and its molecular basis / 8：

Experimental description / 8.1：

Molecular basis / 8.2：

Complex systems / Part III：

Semi-crystalline polymers / 9：

Phase assignment / 9.1：

Effect of crystal phase presence on amorphous fraction relaxation / 9.2：

Relaxations in semi-crystalline polymers with a crystal phase relaxation / 9.3：

NMR insights / 9.4：

Miscible polymer blends / 10：

Poly(isoprene)/poly(vinyl ethylene) (PI/PVE) blends / 10.1：

Models for miscible blend dynamics / 10.2：

MD simulations of model miscible blends / 10.3：

PI/PVE blends revisited / 10.4：

The Rouse model / Appendix AI：

Formulation and normal modes / AI.1：

Establishment of Rouse parameters for a real polymer / AI.2：

The viscoelastic response of a Rouse chain / AI.3：

Bead displacements and the coherent single-chain structure factor / AI.4：

Site models for localized relaxation / Appendix AII：

Dipolar relaxation in terms of site models / AII.1：

Mechanical relaxation in terms of site models / AII.2：

Index

Amorphous Polymers

Complex Systems

The Rouse Model / Appendix 1：

Preface

Methodology / Part I：

Mechanical relaxation / 1：

Regimes of behavior / 1.1：

Superposition principle / 1.2：

Relaxation modulus / 1.3：

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