Photochemical Methods |
Photochemistry and Organic Synthesis |
Irradiation Apparatus |
Further Experimental Parameters |
Photochemical Steps in Synthesis |
Carbon-Carbon Bond Formation by Photoelimination of Small Molecules In Solution and In Crystals |
Introduction |
Photochemical C-C Bond Formation in Solution |
Reactions in the Solid State |
Conclusions |
Intermolecular Addition Reactions Onto C-C Multiple Bonds |
Addition to C-C Double Bonds |
Addition to C-C Triple Bonds |
Formation Of A 3-Membered Ring |
Di-Pi-Methane Rearrangement |
Oxa-Di-Pi-Methane Rearrangement and Related Rearrangements |
[2+1] Cycloaddition of Alkenes with Carbenes |
Formation of a Cyclopropane Via Intramolecular Hydrogen Abstraction |
[3+2] Cycloaddition of Arenes with Alkenes |
Photochemical Synthesis of Three-Membered Heterocycles |
Formation Of A 4-Membered Ring I |
[2+2]-Photocycloaddition of Non Conjugated Alkenes |
[2+2]-Photocycloaddition of Aromatic Compounds |
Photochemical Electrocyclic Reactions |
Intramolecular Gamma-Hydrogen Abstraction / Yang Reaction |
Metal Catalyzed Reactions |
Various Methods |
Formation Of A 4-Membered Ring II |
[2+2]-Photocycloaddition of Enones (Substrate Type A1) |
[2+2]-Photocycloaddition of Vinylogous Amides and Esters (Substrate Clases A2 and A3) |
[2+2]-Photocycloaddition of Alpha, Beta-Unsaturated Carboxylic Acid Derivatives (Substrate Classes A4, A5 and A6) |
Conclusions and Perspectives |
Formation Of A 4-Membered Ring III (Oxetanes) |
Generally Accepted Mechanisms of the Paterno-Buchi Reaction |
Regio- and Siteselective Synthesis of Oxetanes |
Stereoselective Syntheses of Oxetanes |
Conclusive Remarks |
Formation Of A 5-Membered Ring |
Formation of Five-Membered Ring: Intramolecular Delta-H Abstraction |
Formation of Five-Membered Rings Via [3+2]-Cycloadditions |
Photochemical Electrocyclization Reactions: Synthesis of Fused Five-Membered Ring Compounds |
Photoinduced Electron Transfer Radical Cation Mediated Cyclizations: Synthesis of Five-Membered Carbocyclic as well as Heterocyclic Ring Systems |
Formation Of 6-Membered Ring (And Larger Rings) |
Photoelectron Transfer Initiated Cyclizations |
Photoinduced 6Pi-Electrocyclization |
Photocycloaddition Reactions |
Remote Intramolecular Hydrogen Abstraction |
Ring Contraction and Ring Enlargement |
Other Reactions |
Summary |
Aromatic And Heteroaromatic Substitution by SRN1 and SN1 Reactions |
General Mechanistic Features |
Carbon-Carbon Bond Formation |
Carbon-Heteroatom Bond Formation |
Synthesis of Bi, Tri, and Poliaryls |
Synthesis of Carbocycles and Heterocycles |
Singlet Oxygen As a Reagent in Organic Synthesis |
Dioxetanes |
Endoperoxides |
Allylic Hydroperoxides |
Tandem Singlet Oxygen Reactions |
Conclusion |
Synthesis of Heteroaromatics Via Rearrangement Reactions |
Synthesis of Five-Membered Rings with One Heteroatom |
Synthesis of Five-Membered Rings with Two Heteroatoms |
Synthesis of Five-Membered Rings with Three Heteroatoms |
Synthesis of Six-Membered Rings |
Synthesis of Seven-Membered Rings |
Concluding Remarks |
Photolabile Protecting Groups In Organic Synthesis |
Photolabile Protecting Groups |
Chromatic Orthogonality |
Two-Photons Absorption |
Perspectives and Conclusion |
Photochemical Methods |
Photochemistry and Organic Synthesis |
Irradiation Apparatus |
Further Experimental Parameters |
Photochemical Steps in Synthesis |
Carbon-Carbon Bond Formation by Photoelimination of Small Molecules In Solution and In Crystals |