Preface |
Solid Oxide Fuel Cell with Ionic Conducting Electrolyte / Part I: |
Introduction / Bin Zhu and Peter D. Lund1: |
An Introduction to the Principles of Fuel Cells / 1.1: |
Materials and Technologies / 1.2: |
New Electrolyte Developments on LTSOFC / 1.3: |
Beyond the State of the Art: The Electrolyte-Free Fuel Cell (EFFC) / 1.4: |
Fundamental Issues / 1.4.1: |
Beyond the SOFC / 1.5: |
References |
Solid-state Electrolytes for SOFC / Liangdong Fan2: |
Single-Phase SOFC Electrolytes / 2.1: |
Oxygen Ionic Conducting Electrolyte / 2.2.1: |
Stabilized Zirconia / 2.2.1.1: |
Doped Ceria / 2.2.1.2: |
SrO- and MgO-Doped Lanthanum Gallates (LSGM) / 2.2.1.3: |
Proton-Conducting Electrolyte and Mixed Ionic Conducting Electrolyte / 2.2.2: |
Alternative New Electrolytes and Research Interests / 2.2.3: |
Ion Conduction/Transportation in Electrolytes / 2.3: |
Composite Electrolytes / 2.4: |
Oxide-Oxide Electrolyte / 2.4.1: |
Oxide-Carbonate Composite / 2.4.2: |
Materials Fabrication / 2.4.2.1: |
Performance and Stability Optimization / 2.4.2.2: |
Other Oxide-Salt Composite Electrolytes / 2.4.3: |
Ionic Conduction Mechanism Studies of Ceria-Carbonate Composite / 2.4.4: |
NANOCOFC and Material Design Principle / 2.5: |
Concluding Remarks / 2.6: |
Acknowledgments |
Cathodes for Solid Oxide Fuel Cell / Tianmin He and Qingjun Zhou and Fangjun Jin3: |
Overview of Cathode Reaction Mechanism / 3.1: |
Development of Cathode Materials / 3.3: |
Perovskite Cathode Materials / 3.3.1: |
Mn-Based Perovskite Cathodes / 3.3.1.1: |
Co-Based Perovskite Cathodes / 3.3.1.2: |
Fe-Based Perovskite Cathodes / 3.3.1.3: |
Ni-Based Perovskite Cathodes / 3.3.1.4: |
Double Perovskite Cathode Materials / 3.3.2: |
Microstructure Optimization of Cathode Materials / 3.4: |
Nanostructured Cathodes / 3.4.1: |
Composite Cathodes / 3.4.2: |
Summary / 3.5: |
Anodes for Solid Oxide Fuel Cell / Chunwen Sun4: |
Overview of Anode Reaction Mechanism / 4.1: |
Basic Operating Principles of a SOFC / 4.2.1: |
The Anode Three-Phase Boundary / 4.2.1.1: |
Development of Anode Materials / 4.3: |
Ni-YSZ Cermet Anode Materials / 4.3.1: |
Alternative Anode Materials / 4.3.2: |
Fluorite Anode Materials / 4.3.2.1: |
Perovskite Anode Materials / 4.3.2.2: |
Sulfur-Tolerant Anode Materials / 4.3.3: |
Development of Kinetics, Reaction Mechanism, and Model of the Anode / 4.4: |
Summary and Outlook / 4.5: |
Design and Development of SOFC Stacks / Wanting Guan5: |
Change of Cell Output Performance Under 2D Interface Contact / 5.1: |
Design of 2D Interface Contact Mode / 5.2.1: |
Variations of Cell Output Performance Under 2D Contact Mode / 5.2.2: |
2D Interface Structure Improvements and Enhancement of Cell Output Performance / 5.2.3: |
Contributions of 3D Contact in 2D Interface Contact / 5.2.4: |
Mechanism of Performance Enhancement After the Transition from 2D to 3D Interface / 5.2.5: |
Control Design of Transition from 2D to 3D Interface Contact and Their Quantitative Contribution Differentiation / 5.3: |
Control Design of 2D and 3D Interface Contact / 5.3.1: |
Quantitative Effects of 2D Contact on the Transient Output Performance of a Cell / 5.3.2: |
Quantitative Effects of 2D Contact on the Steady-State Output Performance of the Cell / 5.3.3: |
Quantitative Effects of 3D Contact on Cell Transient Performance / 5.3.4: |
Quantitative Effects of 3D Contact on the Steady-State Performance of a Cell / 5.3.5: |
Differences Between 2D and 3D Interface Contacts / 5.3.6: |
Conclusions / 5.4: |
Electrolyte-Free Fuel Cells: Materials, Technologies, and Working Principles / Part II: |
Electrolyte-Free SOFCs: Materials, Technologies, and Working Principles / Bin Zhu and Liangdong Fan and Jung-Sik Kim and Peter D. Lund6: |
Concept of the Electrolyte-Free Fuel Cell / 6.1: |
SLFC Using the Ionic Conductor-based Electrolyte / 6.2: |
Developments on Advanced SLFC / 6.3: |
From SLFCs to Semiconductor-Ionic Fuel Cells (SIFCs) / 6.4: |
The SLFC Working Principle / 6.5: |
Remarks / 6.6: |
Ceria Fluorite Electrolytes from Ionic to Mixed Electronic and Ionic Membranes / Baoyuan Wang and Liangdong Fan and Yanyan Liu and Bin Zhu7: |
Doped Ceria as the Electrolyte for Intermediate Temperature SOFCs / 7.1: |
Surface Doping for Low Temperature SOFCs / 7.3: |
Non-doped Ceria for Advanced Low Temperature SOFCs / 7.4: |
Charge Transfer in Oxide Solid Fuel Cells / Jing Shi and Sining Yun8: |
Oxygen Diffusion in Perovskite Oxides / 8.1: |
Oxygen Vacancy Formation / 8.1.1: |
Oxygen Diffusion Mechanisms / 8.1.2: |
Anisotropy Oxygen Transport in Layered Perovskites / 8.1.3: |
Oxygen Transport in Ruddlesden-Popper (RP) Perovskites / 8.1.3.1: |
Oxygen Transport in A-Site Ordered Double Perovskites / 8.1.3.2: |
Oxygen Ion Diffusion at Grain Boundary / 8.1.4: |
Factors Controlling Oxygen Migration Barriers in Perovskites / 8.1.5: |
Proton Diffusion in Perovskite-Type Oxides / 8.2: |
Proton Diffusion Mechanisms / 8.2.1: |
Proton-Dopant Interaction / 8.2.2: |
Influence of Dopants in A-site / 8.2.2.1: |
Influence of Dopants in B-Stte / 8.2.2.2: |
Long-range Proton Conduction Pathways in Perovskites / 8.2.3: |
Hydrogen-Induced Insulation |
Enhanced Ion Conductivity in Oxide Heterostructures / 8.3: |
Enhanced Ionic Conduction by Strain / 8.3.1: |
Enhanced Ionic Conductivity by Band Bending / 8.3.2: |
Surface State-induced Band Bending / 8.3.2.1: |
Band Bending in p-n Heterojunctions / 8.3.2.2: |
p-n Hetero junction Structures in SOFC / 8.3.2.3: |
Material Development II: Natural Material-based Composites for Electrolyte Layer-free Fuel Cells / Chen Xia and Yanyan Liu8.4: |
Materials Development for EFFCs / 9.1: |
Natural Materials as Potential Electrolytes / 9.1.2: |
Industrial-grade Rare Earth for EFFCs / 9.2: |
Rare-earth Oxide LCP / 9.2.1: |
Semiconducting-Ionic Composite Based on LCP / 9.2.2: |
LCP-LSCF / 9.2.2.1: |
LCP-ZnO / 9.2.2.2: |
Stability Operation and Schottky Junction of EFFC / 9.2.3: |
Performance Stability / 9.2.3.1: |
In Situ Schottky Junction Effect / 9.2.3.2: |
Natural Hematite for EFFCs / 9.2.4: |
Natural Hematite / 9.3.1: |
Semiconducting-Ionic Composite Based on Hematite / 9.3.2: |
Hematite-LSCF / 9.3.2.1: |
Hematite/LCP-LSCF / 9.3.2.2: |
Natural CuFe Oxide Minerals for EFFCs / 9.3.3: |
Natural CuFe2O4 Mineral for EFFC / 9.4.1: |
Natural Delafossite CuFeO2 for EFFC / 9.4.2: |
Bio-derived Calcite for EFFC / 9.4.3: |
Charge Transfer, Transportation, and Simulation / Muhammad Afzal and Mustafa Anwar and Muhammad I. Asghar and Peter D. Lund and Naveed Jhamat and Rizwan Raza and Bin Zhu9.5.1: |
Physical Aspects / 10.1: |
Electrochemical Aspects / 10.2: |
Ionic Conduction Enhancement in Heterostructure Composites / 10.3: |
Charge Transportation Mechanism and Coupling Effects / 10.4: |
Surface and Interfacial State-Induced Superionic Conduction and Transportation / 10.5: |
Ionic Transport Number Measurements / 10.6: |
Determination of Electron and Ionic Conductivities in EFFCs / 10.7: |
EIS Analysis / 10.8: |
Semiconductor Band Effects on the Ionic Conduction Device Performance / 10.9: |
Simulations / 10.10: |
Electrolyte-Free Fuel Cell: Principles and Crosslink Research / Yan Wu and Liangdong Fan and Naveed Mushtaq and Bin Zhu and Muhammad Afzal and Muhammad Sajid and Rizwan Raza and Jung-Sik Kim and Wen-Feng Lin and Peter D. Lund11: |
Fundamental Considerations of Fuel Cell Semiconductor Electrochemistry / 11.1: |
Physics and Electrochemistry at Interfaces / 11.2.1: |
Electrochemistry vs. Semiconductor Physics / 11.2.2: |
Working Principle of Semiconductor-Based Fuel Cells and Crossing Link Sciences / 11.3: |
Extending Applications by Coupling Devices / 11.4: |
Final Remarks / 11.5: |
Fuel Cells: From Technology to Applications / Part III: |
Scaling Up Materials and Technology for SLFC / Kang Yuan and Zhigang Zhu and Muhammad Afzal and Bin Zhu12: |
Single-Layer Fuel Cell (SLFC) Engineering Materials / 12.1: |
Scaling Up Single-Layer Fuel Cell Devices: Tape Casting and Hot Pressing / 12.2: |
Scaling Up Single-Layer Fuel Cell Devices: Thermal Spray Coating Technology / 12.3: |
Traditional Plasma Spray Coating Technology / 12.3.1: |
New Developed Low-Pressure Plasma Spray (LPPS) Coating Technology / 12.3.2: |
Short Stack / 12.4: |
SLFC Cells / 12.4.1: |
Bipolar Plate Design / 12.4.2: |
Sealing and Sealant-Free Short Stack / 12.4.3: |
Tests and Evaluations / 12.5: |
Durability Testing / 12.6: |
A Case Study for the Cell Degradation Mechanism / 12.7: |
Continuous Efforts and Future Developments / 12.8: |
Planar SOFC Stack Design and Development / Shaorong Wang and Yixiang Shi and Naveed Mushtaq and Bin Zhu12.9: |
Internal Manifold and External Manifold / 13.1: |
Interface Between an Interconnect Plate and a Single Cell / 13.2: |
Antioxidation Coating of the Interconnect Plate / 13.3: |
Design the Flow Field of Interconnect Plate / 13.4: |
Mathematical Simulation / 13.4.1: |
Effect of Co-flow, Crossflow, and Counterflow / 13.4.2: |
Air Flow Distribution Between Layers in a Stack / 13.4.3: |
The Importance of Sealing / 13.5: |
Thermal Cycling of the Sealing / 13.5.1: |
Durability of Sealing / 13.5.2: |
The Life of the Stack: The Chemical Problems on the Interface / 13.6: |
Toward Market Products / 13.7: |
Energy System Integration and Future Perspectives / Ghazanfar Abbas and Muhammad Ali Babar and Fida Hussain and Rizwan Raza13.8: |
Solar Cell and Fuel Cell / 14.1: |
Fuel Cell-Solar Cell Integration / 14.2: |
Solar Electrolysis-Fuel Cell Integration / 14.3: |
Fuel Cell-Biomass Integration / 14.4: |
The Fuel Cell System Modeling Using Biogas / 14.5: |
Activation Loss / 14.5.1: |
Ohmic Loss / 14.5.2: |
Concentration Voltage Loss / 14.5.3: |
The Fuel Cell System Efficiency (Heating and Electrical) / 14.6: |
The Effect of Different Temperatures on System Efficiency / 14.6.1: |
The Fuel Utilization Factor and Efficiencies of the System / 14.6.2: |
The System Efficiencies and Operating Pressure / 14.6.3: |
Integrated New Clean Energy System / 14.7: |
Index / 14.8: |