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図書

図書
edited by Hisashi Yamamoto, Takashi Kato
出版情報: Weinheim : Wiley-VCH, c2018  xvii, 381 p. ; 25 cm
シリーズ名: Molecular technology ; v. 2
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Foreword / Dr Hamaguchi
Preface / Dr Noyori
Control of DNA Packaging by Block Catiomers for Systemic Gene Delivery System / Kensuke Osada1:
Introduction / 1.1:
Packaging of pDNA by Block Catiomers / 1.2:
Rod-Shaped Packaging of pDNA / 1.2.1:
Rod Shape or Globular Shape / 1.2.2:
Polyplex Micelles as a Systemic Gene Delivery System / 1.3:
Stable Encapsulation of pDNA Within Polyplex Micelles for Systemic Delivery / 1.3.1:
Polyplex Micelles for Efficient Cellular Entry / 1.3.2:
Polyplex Micelles for Safe Endosome Escape / 1.3.3:
Polyplex Micelles for Nuclear Translocation / 1.3.4:
Polyplex Micelles for Efficient Transcription / 1.3.5:
Design Criteria of Block Catiomers Toward Systemic Gene Therapy / 1.4:
Rod Shape or Toroid Shape / 1.5:
Summary / 1.6:
References
Manipulation of Molecular Architecture with DNA / Akinori Kuzuya2:
Molecular Structure of DNA / 2.1:
Immobile DNA Junctions / 2.3:
Topologically Unique DNA Molecules / 2.4:
DNA Tiles and Their Assemblies / 2.5:
DNA Origami / 2.6:
DNA Origami as a Molecular Peg Board / 2.7:
Molecular Machines Made of DNA Origami / 2.8:
DNA Origami Pinching Devices / 2.9:
Novel Design Principles / 2.10:
DNA-PAINT: An Application of DNA Devices / 2.11:
Prospects / 2.12:
Chemical Assembly Lines for Skeletally Diverse Indole Alkaloids / Hiroki Oguri3:
Macmillan's Collective Total Synthesis by Means of Organocascade Catalysis / 3.1:
Systematic Synthesis of Indole Alkaloids Employing Cyclopentene Intermediates by the Zhu Group / 3.3:
Biogenetically Inspired Synthesis Employing a Multipotent Intermediate by the Oguri Group / 3.4:
Molecular Technology for Injured Brain Regeneration / Itsuki Ajioka4:
Biology of Angiogenesis / 4.1:
Angiogenesis for Injured Brain Regeneration / 4.3:
Molecular Technology to Promote Angiogenesis / 4.4:
Biology of Cell Cycle / 4.5:
Biology of Neurogenesis / 4.6:
Molecular Technology to Promote Neuron Regeneration / 4.7:
Conclusion / 4.8:
Engineering the Ribosomal Translation System to Introduce Non-proteinogenic Amino Acids into Peptides / Takayuki Katoh5:
Decoding the Genetic Code / 5.1:
Aminoacylation of tRNA by Aminoacyl-tRNA Synthetases / 5.3:
Methods for Preparing Noncanonical Aminoacyl-tRNAs / 5.4:
Ligation of Aminoacyl-pdCpA Dinucleotide with tRNA Lacking the 3'-Terminal CA / 5.4.1:
Post-aminoacylation Modification of Aminoacyl-tRNA / 5.4.2:
Misacylation of Non-proteinogenic Amino Acids by ARSs / 5.4.3:
Flexizyme, an Aminoacylation Ribozyme / 5.4.4:
Methods for Assigning Non-proteinogenic Amino Acids to the Genetic Code / 5.5:
The Nonsense Codon Method / 5.5.1:
Genetic Code Reprogramming / 5.5.2:
The Four-base Codon Method / 5.5.3:
The Nonstandard Base Method / 5.5.4:
Limitation of the Incorporation of Noncanonical Amino Acids: Substrate Scope / 5.6:
Improvement of the Substrate Tolerance of Ribosomal Translation / 5.7:
Ribosomally Synthesized Noncanonical Peptides as Drug Discovery Platforms / 5.8:
Summary and Outlook / 5.9:
Development of Functional Nanoparticles and Their Systems Capable of Accumulating to Tumors / Sotoru Karasawa6:
Accumulation Based on Aberrant Morphology and Size / 6.1:
Accumulation Based on Aberrant pH Microenvironment / 6.3:
Accumulation Based on Temperature of Tumor Microenvironment / 6.4:
Perspective / 6.5:
Glycan Molecular Technology for Highly Selective In Vivo Recognition / Katsunori Tanaka7:
Molecular Technology for Chemical Glycan Conjugation / 7.1:
Conjugation to Lysine / 7.1.1:
Conjugation to Cysteine / 7.1.2:
Bioorthogonal Conjugation / 7.1.3:
Enzymatic Glycosylation / 7.1.4:
In Vivo Kinetic Studies of Monosaccharide-Modified Proteins / 7.2:
Dissection-Based Kinetic and Bio distribution Studies: Effects of Protein Modification by Galactose, Mannose, and Fucose / 7.2.1:
Noninvasive imaging of In Vivo Kinetic and Organ-Specific Accumulation of Monosaccharide-Modified Proteins / 7.2.2:
In Vivo Kinetic Studies of Oligosaccharide-Modified Proteins / 7.3:
In Vivo Kinetics of Proteins Modified by a Few Molecules of N-glycans / 7.3.1:
In Vivo Kinetics of Proteins Modified by Many AT-glycans: Homogeneous N-glycoalbumins / 7.3.2:
In Vivo Kinetics of Proteins Modified by Many N-glycans: Heterogeneous N-glycoalbumins / 7.3.3:
Tumor Targeting by JV-glycoalbumins / 7.3.4:
Glycan Molecular Technology on Live Cells: Tumor Targeting by N-glycas-Engineered Lymphocytes / 7.3.5:
Glycan Molecular Technology Adapted as Metal Carriers: In Vivo Metal-Catalyzed Reactions within Live Animals / 7.4:
Concluding Remarks / 7.5:
Acknowledgments
Molecular Technology Toward Expansion of Nucleic Acid Functionality / Michiko Kimoto and Kiyohiko Kawai8:
Molecular Technologies that Enable Genetic Alphabet Expansion / 8.1:
Nucleotide Modification / 8.2.1:
Unnatural Base Pairs (UBPs) as Third Base Pairs Toward Expansion of Nucleic Acid Functionality / 8.2.2:
High-Affinity DNA Aptamer Generation Using the Expanded Genetic Alphabet / 8.2.3:
Molecular Technologies that Enable Fluorescence Blinking Control / 8.3:
Single Molecule Detection Based on Blinking Observations / 8.3.1:
Blinking Kinetics / 8.3.2:
Control of Fluorescence Blinking by DNA Structure / 8.3.3:
Triplet Blinking / 8.3.3.1:
Redox Blinking / 8.3.3.2:
Isomerization Blinking / 8.3.3.3:
Conclusions / 8.4:
Molecular Technology for Membrane Functionalization / Michio Murakoshi and Takahiro Muraoka9:
Synthetic Approach for Membrane Functionalization / 9.1:
Formation of Multipass Transmembrane Structure / 9.2.1:
Formation of Supramolecular Ion Channels / 9.2.2:
Demonstration of Ligand-Gated Ion Transportation / 9.2.3:
Light-Triggered Membrane Budding / 9.2.4:
Semi-biological Approach for Membrane Functionalization / 9.3:
Mechanical Analysis of the Transmembrane Structure of Membrane Proteins / 9.3.1:
Development of the Nanobiodevice Using a Membrane Protein Expressing in the Inner Ear / 9.3.2:
Improvement of Protein Performance by Genetic Engineering / 9.3.3:
Molecular Technology for Degradable Synthetic Hydrogels for Biomaterials / Hiroharu Ajiro and Takamasa Sakai10:
Scope of the Chapter
Degradation Behavior of Hydrogels / 10.1:
Polylactide Copolymer / 10.2:
Trimethylene Carbonate Derivatives / 10.3:
Polyurethane / 10.4:
Molecular Technology for Epigenetics Toward Drug Discovery / Takayoshi Suzuki11:
Epigenetics / 11.1:
Isozyme-Selective Histone Deacetylase (HDAC) Inhibitors / 11.3:
Identification of HDAC3-Selective Inhibitors by Click Chemistry Approach / 11.3.1:
Identification of HDAC8-Selective Inhibitors by Click Chemistry Approach and Structure-Based Drug Design / 11.3.2:
Identification of HDAC6-Insensitive Inhibitors Using C-H Activation Reaction / 11.3.3:
Identification of HDAC6-Selective Inhibitors by Substrate-Based Drug Design / 11.3.4:
Identification of SIRT1-Selective Inhibitors by Target-Guided Synthesis / 11.3.5:
Identification of SIRT2-Selective Inhibitors by Structure-Based Drug Design and Click Chemistry Approach / 11.3.6:
Histone Lysine Demethylase (KDM) Inhibitors / 11.4:
Identification of KDM4C Inhibitors by Structure-Based Drug Design / 11.4.1:
Identification of KDM5A Inhibitors by Structure-Based Drug Design / 11.4.2:
Identification of KDM7B Inhibitors by Structure-Based Drug Design / 11.4.3:
Identification of LSD1 Inhibitors by Target-Guided Synthesis / 11.4.4:
Small-Molecule-Based Drug Delivery System Using LSD1 and its Inhibitor / 11.4.5:
Molecular Technology for Highly Efficient Gene Silencing: DNA/RNA Heteroduplex Oligonucleotides / Kotaro Yoshioka and Kazutaka Nishina and Tetsuya Nagata and Takanori Yokota11.5:
Therapeutic Oligonucleotides / 12.1:
siRNA / 12.2.1:
ASO / 12.2.2:
Chemical Modifications of Therapeutic Oligonucleotide / 12.3:
Modifications of Inter nucleotide Linkage / 12.3.1:
Modifications of Sugar Moiety / 12.3.2:
Ligand Conjugation for DDS / 12.4:
Development of Ligand Molecules for Therapeutic Oligonucleotides / 12.4.1:
Vitamin E for Ligand Molecule / 12.4.2:
siRNA Conjugated with Tocopherol / 12.4.3:
ASO Conjugated with Tocopherol / 12.4.4:
DNA/RNA Heteroduplex Oligonucleotide / 12.5:
Basic Concept of Heteroduplex Oligonucleotide / 12.5.1:
HDO Conjugated with Tocopherol (Toc-HDO) / 12.5.2:
Design of Toc-HDO / 12.5.2.1:
Potency of Toc-HDO / 12.5.2.2:
Adverse Effect of Toc-HDO / 12.5.2.3:
Mechanism of Toc-HDO / 12.5.2.4:
Future Prospects / 12.6:
Molecular Technology for Highly Sensitive Biomolecular Analysis: Hyperpolarized NMR/MRI Probes / Shinsuke Sando and Hiroshi Nonaka13:
HyperpoJarization / 13.1:
Requirements for HP Molecular Imaging Probes / 13.2:
HP 13C Molecular Probes for Analysis of Enzymatic Activity / 13.3:
[1-13C] Pyruvate / 13.3.1:
HP 13C Probes for Analysis of Glycolysis and Tricarboxylic Acid Cycle / 13.3.2:
¿-Glutamyl-[l-13C]glycine: HP 13C Probe for Analysis of ¿-glutamyl Transpeptidase / 13.3.3:
[1-13C]Alanine-NH2: HP 13C Probes for Analysis of Aminopeptidase N / 13.3.4:
HP 13C Molecular Probes for Analysis of the Chemical Environment / 13.4:
[1-13C] Bicarbonate / 13.4.1:
[l-13C]Ascorbate and Dehydroascorbate / 13.4.2:
[13C]Benzoylformic Acid for Sensing H202 / 13.4.3:
[13C,D3]-p-Anisidine for Sensing of HOCl / 13.4.4:
[13C,D]EDTA for Sensing of Metal Ions / 13.4.5:
HP 15N Molecular Probes / 13.5:
A Strategy for Designing HP Molecular Probes / 13.6:
Scaffold Structure for Design of 15N HP Probes: [15N,D9]TMPA / 13.6.1:
[15N,D14]TMPA / 13.6.1.1:
Scaffold Structure for Designing 13C Hyperpolarized Probes / 13.6.2:
Molecular Technologies in Life Innovation: Novel Molecular Technologies for Labeling and Functional Control of Proteins Under Live Cell Conditions / Itaru Homochi and Shigeki Kiyonaka and Tomonori Tamura and Ryou Kubota13.7:
General Introduction / 14.1:
Ligand-Directed Chemistry for Neurotransmitter Receptor Proteins Under Live Cell Condition and its Application / 14.2:
Affinity-Guided DMAP Reaction for Analysis of Live Cell Surface Proteins / 14.3:
Coordination Chemistry-Based Chemogenetic Approach to Switch the Activity of Glutamate Receptors in Live Cells / 14.4:
Molecular Technologies for Pseudo-natural Peptide Synthesis and Discovery of Bioactive Compounds Against Undruggable Targets / Joseph M. Rogers and Hiroaki Suga14.5:
Peptides Could Target Undruggable Targets / 15.1:
Druggable Proteins / 15.2.1:
Undruggable Proteins / 15.2.2:
Natural Peptides as Drugs / 15.2.3:
Modification to Peptides can Improve Their Drug-Like Characteristics / 15.2.4:
Macro cyclization / 15.2.4.1:
Amino Acids with Unnatural Side Chains / 15.2.4.2:
Backbone Modifications Including N-Methylation / 15.2.4.3:
Cyclosporin - A Membrane-Permeable Anomaly / 15.2.4.4:
Membrane Permeability Cannot be Calculated from Amino Acid Content / 15.2.4.5:
Cyclosporin - The Inspiration for the Cyclic Peptide Approach to Undruggable Targets / 15.2.5:
Molecular Technologies to Discover Functional Peptides / 15.3:
Ribosomal Synthesis of Peptides / 15.3.1:
Natural Peptide Synthesis is an Efficient Method to Generate Huge Libraries / 15.3.2:
Selection Methods / 15.3.3:
Intracellular Peptide Selection / 15.3.3.1:
Phage Display / 15.3.3.2:
A Cell-Free Display, mRNA Display / 15.3.3.3:
Other Methods of Selection / 15.3.4:
Molecular Technology for Pseudo-natural Peptide Synthesis and Its Use in Peptide Drug Discovery / 15.4:
The Need for Pseudo-natural Synthesis - The Limitations of SPPS / 15.4.1:
Intein Cyclization and SICLOPPS / 15.4.2:
Post-translation Modification / 15.4.3:
Genetic Code Expansion / 15.4.4:
Replacing Amino Acids in Translation / 15.4.5:
Flexizymes / 15.4.6:
RaPID System / 15.4.6.2:
Acknowledgment / 15.5:
Index
Foreword / Dr Hamaguchi
Preface / Dr Noyori
Control of DNA Packaging by Block Catiomers for Systemic Gene Delivery System / Kensuke Osada1:
2.

図書

図書
edited by Hisashi Yamamoto and Takashi Kato
出版情報: Weinheim : Wiley-VCH, c2018  xvii, 314 p. ; 25 cm
シリーズ名: Molecular technology ; v. 1
所蔵情報: loading…
目次情報: 続きを見る
Foreword / Dr Hamaguchi
Preface / Dr Noyori
Charge Transport Simulations for Organic Semiconductors / Hiroyuki Ishii1:
Introduction / 1.1:
Historical Approach to Organic Semiconductors / 1.1.1:
Recent Progress and Requirements to Computational "Molecular Technology" / 1.1.2:
Theoretical Description of Charge Transport in Organic Semiconductors / 1.2:
Incoherent Hopping Transport Model / 1.2.1:
Coherent Band Transport Model / 1.2.2:
Coherent Polaron Transport Model / 1.2.3:
Trap Potentials / 1.2.4:
Wave-packet Dynamics Approach Based on Density Functional Theory / 1.2.5:
Charge Transport Properties of Organic Semiconductors / 1.3:
Comparison of Polaron Formation Energy with Dynamic Disorder of Transfer Integrals due to Molecular Vibrations / 1.3.1:
Temperature Dependence of Mobility / 1.3.2:
Evaluation of Intrinsic Mobilities for Various Organic Semiconductors / 1.3.3:
Summary / 1.4:
Forthcoming Challenges in Theoretical Studies / 1.4.1:
Acknowledgments
References
Liquid-Phase Interfacial Synthesis of Highly Oriented Crystalline Molecular Nanosheets / Rie Makiura2:
Molecular Nanosheet Formation with Traditional Surfactants at Air/Liquid Interfaces / 2.1:
History of Langmuir-Blodgett Film / 2.2.1:
Basics of Molecular Nanosheet Formation at Air/Liquid Interfaces / 2.2.2:
Application of Functional Organic Molecules for Nanosheet Formation at Air/Liquid Interfaces / 2.3:
Functional Organic Molecules with Long Alkyl Chains / 2.3.1:
Functional Organic Molecules without Long Alkyl Chains / 2.3.2:
Application of Functional Porphyrins on Metal Ion Solutions / 2.3.3:
Porphyrin-Based Metal-Organic Framework (MOF) Nanosheet Crystals Assembled at Air/Liquid Interfaces / 2.4:
Metal-Organic Frameworks / 2.4.1:
Method of MOF Nanosheet Creation at Air/Liquid Interfaces / 2.4.2:
Study of the Formation Process of MOF Nanosheets by In Situ X-Ray Diffraction and Brewster Angle Microscopy at Air/Liquid Interfaces / 2.4.3:
Application of a Postinjection Method Leading to Enlargement of the Uniform MOF Nanosheet Domain Size / 2.4.4:
Layer-by-Layer Sequential Growth of Nanosheets - Toward Three-Dimensionally Stacked Crystalline MOF Thin Films / 2.4.5:
Manipulation of the Layer Stacking Motif in MOF Nanosheets / 2.4.6:
Manipulation of In-Plane Molecular Arrangement in MOF Nanosheets / 2.4.7:
Molecular Technology for Organic Semiconductors Toward Printed and Flexible Electronics / Toshihiro Okamoto3:
Molecular Design and Favorable Aggregated Structure for Effective Charge Transport of Organic Semiconductors / 3.1:
Molecular Design of Linearly Fused Acene-Type Molecules / 3.3:
Molecular Technology of ¿-Conjugated Cores for p-Type Organic Semiconductors / 3.4:
Molecular Technology of Substituents for Organic Semiconductors / 3.5:
Bulky-Type Substituents / 3.5.1:
Linear Alkyl Chain Substituents / 3.5.2:
Molecular Technology of Conceptually-new Bent-shaped ¿-Conjugated Cores for p-Type Organic Semiconductors / 3.6:
Bent-Shaped Heteroacenes / 3.6.1:
Molecular Technology for n-Type Organic Semiconductors / 3.7:
Naphthalene Diimide and Perylene Diimide / 3.7.1:
Design of Multiproton-Responsive Metal Complexes as Molecular Technology for Transformation of Small Molecules / Shigeki Kuwata4:
Cooperation of Metal and Functional Groups in Metalloenzymes / 4.1:
[FeFe] Hydrogenase / 4.2.1:
Peroxidase / 4.2.2:
Nitrogenase / 4.2.3:
Proton-Responsive Metal Complexes with Two Appended Protic Groups / 4.3:
Pincer-Type Bis(azole) Complexes / 4.3.1:
Bis(2-hydroxypyridine) Chelate Complexes / 4.3.2:
Proton-Responsive Metal Complexes with Three Appended Protic Groups on Tripodal Scaffolds / 4.4:
Summary and Outlook / 4.5:
Photo-Control of Molecular Alignment for Photonic and Mechanical Applications / Miho Aizawa and Christopher J. Barrett and Atsushi Shishido5:
Photo-Chemical Alignment / 5.1:
Photo-Physical Alignment / 5.3:
Photo-Physico-Chemical Alignment / 5.4:
Application as Photo-Actuators / 5.5:
Conclusions and Perspectives / 5.6:
Molecular Technology for Chirality Control: From Structure to Circular Polarization / Yoshiaki Uchida and Tetsuya Narushima and Junpei Yuasa6:
Chiral Lanthanide(III) Complexes as Circularly Polarized Luminescence Materials / 6.1:
Circularly Polarized Luminescence (CPL) / 6.1.1:
Theoretical Explanation for Large CPL Activity of Chiral Lanthanide(III) Complexes / 6.1.2:
Optical Activity of Chiral Lanthanide(III) Complexes / 6.1.3:
CPL of Chiral Lanthanide(III) Complexes for Frontier Applications / 6.1.4:
Magnetic Circular Dichroism and Magnetic Circularly Polarized Luminescence / 6.2:
Magnetic-Field-induced Symmetry Breaking on Light Absorption and Emission / 6.2.1:
Molecular Materials Showing MCD and MCPL and Applications / 6.2.2:
Molecular Self-assembled Helical Structures as Source of Circularly Polarized Light / 6.3:
Chiral Liquid Crystalline Phases with Self-assembled Helical Structures / 6.3.1:
Strong CPL of CLC Laser Action / 6.3.2:
Optical Activity Caused by Mesoscopic Chiral Structures and Microscopic Analysis of the Chiroptical Properties / 6.4:
Microscopic CD Measurements via Far-field Detection / 6.4.1:
Optical Activity Measurement Based on Improvement of a PEM Technique / 6.4.2:
Discrete Illumination of Pure Circularly Polarized Light / 6.4.3:
Complete Analysis of Contribution From All Polarization Components / 6.4.4:
Near-field CD Imaging / 6.4.5:
Conclusions / 6.5:
Molecular Technology of Excited Triplet State / Yuki Kurashige and Nobuhiro Yanai and Yong-Jin Pu and So Kawata7:
Properties of the Triplet Exciton and Associated Phenomena for Molecular Technology / 7.1:
Introduction: The Triplet Exciton / 7.1.1:
Molecular Design for Long Diffusion Length / 7.1.2:
Theoretical Analysis for the Electronic Transition Processes Associated with Triplet / 7.1.3:
Near-infrared-to-visible Photon Upconversion: Chromophore Development and Triplet Energy Migration / 7.2:
Evaluation of TTA-UC Properties / 7.2.1:
NIR-to-visible TTA-UC Sensitized by Metalated Macrocyclic Molecules / 7.2.3:
TTA-UC Sensitized by Metal Complexes with S-T Absorption / 7.2.4:
Conclusion and Outlook / 7.2.5:
Singlet Exciton Fission Molecules and Their Application to Organic Photovoltaics / 7.3:
Polycyclic ¿-Conjugated Compounds / 7.3.1:
Pentacene / 7.3.2.1:
Tetracene / 7.3.2.2:
Hexacene / 7.3.2.3:
A Heteroacene
Perylene and Terrylene / 7.3.2.5:
Nonpolycyclic ¿-Conjugated Compounds / 7.3.3:
Polymers / 7.3.4:
Perspectives / 7.3.5:
Material Transfer and Spontaneous Motion in Mesoscopic Scale with Molecular Technology / Yoshiyuki Kageyama and Yoshiko Takenaka and Kenji Higashiguchi8:
Introduction of Chemical Actuators / 8.1:
Composition of This Chapter / 8.1.2:
Mechanism to Originate Mesoscale Motion / 8.2:
Motion Generated by Molecular Power / 8.2.1:
Gliding Motion of a Mesoscopic Object by the Gradient of Environmental Factors / 8.2.2:
Mesoscopic Motion of an Object by Mechanical Motion of Molecules / 8.2.3:
Toward the Implementation of a One-Dimensional Actuator: Artificial Muscle / 8.2.4:
Generation of "Molecular Power" by a Stimuli-Responsive Molecule / 8.3:
Structural Changes of Molecules and Supramolecular Structures / 8.3.1:
Structural Changes of Photo chromic Molecules / 8.3.2:
Fundamentals of Kinetics of Photochromic Reaction / 8.3.3:
Photoisomerization and Actuation / 8.3.4:
Mesoscale Motion Generated by Cooperation of "Molecular Power" / 8.4:
Motion in Gradient Fields / 8.4.1:
Movement Triggered by Mobile Molecules / 8.4.2:
Autonomous Motion with Self-Organization / 8.4.3:
Molecular Technologies for Photocatalytic CO2 Reduction / Yusuke Tamaki and Hiroyuki Takeda and Osamu Ishitani8.5:
Photocatalytic Systems Consisting of Mononuclear Metal Complexes / 9.1:
Rhenium(I) Complexes / 9.2.1:
Reaction Mechanism / 9.2.2:
Multicomponent Systems / 9.2.3:
Photocatalytic CO2 Reduction Using Earth-Abundant Elements as the Central Metal of Metal Complexes / 9.2.4:
Supramolecular Photocatalysts: Multinuclear Complexes / 9.3:
Ru(II)-Re(I) Systems / 9.3.1:
Ru(II)-Ru(II) Systems / 9.3.2:
Ir(III)-Re(I) and Os(II)-Re(I) Systems / 9.3.3:
Photocatalytic Reduction of Low Concentration of CO2 / 9.4:
Hybrid Systems Consisting of the Supramolecular Photocatalyst and Semiconductor Photocatalysts / 9.5:
Conclusion / 9.6:
Acknowledgements
Molecular Design of Photocathode Materials for Hydrogen Evolution and Carbon Dioxide Reduction / Christopher D. Windle and Soundarrajan Chandrasekaran and Hiromu Kumagai and Go Sahara and Keiji Nagai and Toshiyuki Abe and Murielle Chavarot-Kerlidou and Osamu Ishitani and Vincent Artero10:
Photocathode Materials for H2 Evolution / 10.1:
Molecular Photocathodes for H2 Evolution Based on Low Bandgap Semiconductors / 10.2.1:
Molecular Catalysts Physisorbed on a Semiconductor Surface / 10.2.1.1:
Covalent Attachment of the Catalyst to the Surface of the Semiconductor / 10.2.1.2:
Covalent Attachment of the Catalyst Within an Oligomeric or Polymeric Material Coating the Semiconductor Surface / 10.2.1.3:
H2-evolving Photocathodes Based on Organic Semiconductors / 10.2.2:
Dye-sensitised Photocathodes for H2 Production / 10.2.3:
Dye-sensitised Photocathodes with Physisorbed or Diffusing Catalysts / 10.2.3.1:
Dye-sensitised Photocathodes Based on Covalent or Supramolecular Dye-Catalyst Assemblies / 10.2.3.2:
Dye-sensitised Photocathodes Based on Co-grafted Dyes and Catalysts / 10.2.3.3:
Photocathodes for CO2 Reduction Based on Molecular Catalysts / 10.3:
Photocatalytic Systems Consisting of a Molecular Catalyst and a Semiconductor Photo electrode / 10.3.1:
Dye-sensitised Photocathodes Based on Molecular Photocatalysts / 10.3.2:
Molecular Design of Glucose Biofuel Cell Electrodes / Michael Holzinger and Yuta Nishina and Alan Le Goff and Masato Tominaga and Serge Cosnier and Seiya Tsujimura11:
Molecular Approaches for Enzymatic Electrocatalytic Oxidation of Glucose / 11.1:
Molecular Designs for Enhanced Electron Transfers with Oxygen-Reducing Enzymes / 11.3:
Conclusion and Future Perspectives / 11.4:
Index
Foreword / Dr Hamaguchi
Preface / Dr Noyori
Charge Transport Simulations for Organic Semiconductors / Hiroyuki Ishii1:
3.

図書

図書
Jeffrey S. Gaffney, Nancy A. Marley
出版情報: Amsterdam : Elsevier, c2018  xiii, 622 p. ; 24 cm
所蔵情報: loading…
目次情報: 続きを見る
Preface
Acknowledgments
Introduction / 1:
The Role of Chemistry in Engineering / 1.1:
Green Engineering / 1.2:
Measurement and Calculations / 1.3:
The Physical States of Matter / 1.4:
Classification of Matter / 1.5:
Separation of Mixtures / 1.6:
Important Terms
Study Questions
Problems
The Periodic Table of the Elements / 2:
Atomic Structure / 2.1:
The Shell Model of the Atom / 2.2:
Electron Assignments / 2.3:
Periodic Trends / 2.4:
Chemical Bonding-The Formation of Materials / 3:
Atoms and Ions / 3.1:
Ionic Bonding / 3.2:
Covalent Bonding / 3.3:
Mixed Covalent/Ionic Bonding / 3.4:
Molecular Orbitals / 3.5:
Molecular Geometry / 3.6:
Molecular Polarity / 3.7:
Intermolecular Forces / 3.8:
Chemical Equations and Mass Balance / 4:
The Mole / 4.1:
The Empirical Formula / 4.2:
Chemical Equations / 4.3:
Stoichiometry / 4.4:
Limiting Reactant and Percent Yield / 4.5:
Aqueous Solubility of Ionic Compounds / 4.6:
Precipitation Reactions in Aqueous Solution / 4.7:
Concentrations in Aqueous Solution / 4.8:
Acids and Bases / 5:
Defining Acids and Bases / 5.1:
Acids and Bases in Aqueous Solution / 5.2:
The pH Scale / 5.3:
Other "p" Functions / 5.4:
Buffer Solutions / 5.5:
The Titration / 5.6:
Properties of Gases / 6:
A Historical Perspective / 6.1:
Boyle's Law / 6.2:
Charles' Law / 6.3:
Gay-Lussac's Law / 6.4:
The Ideal Gas Law / 6.5:
Nonideal Gas Behavior / 6.6:
Partial Pressures / 6.7:
Chemical Reactions With Gases / 6.8:
Chemical Equilibrium / 7:
Reversible Reactions / 7.1:
The Equilibrium Constant / 7.2:
Relationships Between Equilibrium Constants / 7.3:
Le Chatelier's Principle: Disturbing a Chemical Equilibrium / 7.4:
The Reaction Quotient / 7.5:
Thermodynamics and Energy Balance / 8:
Chemical Thermodynamics / 8.1:
The First Law of Thermodynamics: Heat and Work / 8.2:
Enthalpy / 8.3:
Standard Enthalpies / 8.4:
Bond Enthalpy / 8.5:
The Second Law of Thermodynamics: Entropy / 8.6:
The Third Law of Thermodynamics: Entropy and Temperature / 8.7:
Gibbs Free Energy / 8.8:
Standard Gibb Free Energies and Chemical Equilibrium / 8.9:
Kinetics and the Rate of Chemical Reactions / 9:
Reaction Rate / 9.1:
Rate Laws / 9.2:
Integrated Rate Laws / 9.3:
Half-Life / 9.4:
Collision Theory / 9.5:
Reaction Mechanisms / 9.6:
Chain Reaction Mechanisms / 9.7:
Oxidation-Reduction Reactions Electrochemistry / 10:
Oxidation-Reduction Reactions / 10.1:
The Galvanic Cell / 10.2:
Balancing Oxidation-Reduction Equations / 10.3:
Standard Cell Potentials / 10.4:
Reactions at Nonstandard Conditions: The Nernst Equation / 10.5:
Electrolysis / 10.6:
Batteries / 10.7:
Fuel Cells / 10.8:
Solids / 11:
Crystalline Solids / 11.1:
Ionic Solids / 11.2:
Molecular Solids / 11.3:
Atomic Solids / 11.4:
Metallic Solids / 11.5:
Amorphous Solids / 11.6:
Solution Chemistry / 12:
Solution Composition / 12.1:
Dissolution / 12.2:
The Effect of Pressure on Solubility / 12.3:
The Effects of Temperature on Solubility / 12.4:
Solubility of Ionic Solids / 12.5:
Complexing Agents / 12.6:
Surfactants / 12.7:
Colligative Properties / 12.8:
The Chemistry of Carbon / 13:
Carbon Bonding and Hybridization / 13.1:
Organic Hydrocarbons: Alkanes, Alkynes, Alkenes, and Aromatics / 13.2:
Organic Functional Groups / 13.3:
Organic Reaction Mechanisms / 13.4:
Polymer Chemistry / 13.5:
Nuclear and Radiochemistry / 14:
Isotopes and Radioactive Decay / 14.1:
Radioactive Decay Rates and Half Lives / 14.2:
Natural Radioisotopes / 14.3:
Detecting Radioisotopes and Radioactivity / 14.4:
Fission and Fusion / 14.5:
Nuclear Energy / 14.6:
Radiation Safety / 14.7:
Applications of Radioisotopes / 14.8:
Chemical Measurements and Instrumentation / 15:
Chromatography / 15.1:
Atomic Spectroscopy / 15.2:
UV-Visible Absorption Spectroscopy / 15.3:
Infrared Spectroscopy / 15.4:
Luminescence Spectroscopy / 15.5:
Mass Spectrometry / 15.6:
Nuclear Magnetic Resonance Spectroscopy / 15.7:
Glossary
Answers to Study Questions and Problems
Working with Units / Appendix I:
Using Spreadsheets / Appendix II:
Some Standard Half-Cell Potential at 298.15K (25°C) / Appendix III:
Index
Preface
Acknowledgments
Introduction / 1:
4.

図書

図書
by Ian Guch
出版情報: New York : Alpha, a member of Penguin Random House LLC, c2011  xviii, 396 p. ; 24 cm
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5.

図書

図書
Peter Atkins, Loretta Jones, Leroy Laverman
出版情報: New York : W.H. Freeman, c2016  xxvi, 106, 830, 26, 29, 57, 12 p. ; 29 cm
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6.

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図書
David W. Oxtoby, H. P. Gillis, Laurie J. Butler
出版情報: Boston : Cengage Learning, c2016  xxvii, 993, A1-A71, I1-I36 p. ; 29 cm
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7.

図書

図書
edited by Xin-bo Zhang
出版情報: Weinheim : Wiley-VCH, c2018  xiv, 417 p. ; 25 cm
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目次情報: 続きを見る
Preface
Introduction to Metal-Air Batteries: Theory and Basic Principles / Zhiwen Chang and Xin-bo Zhang1:
Li-O2 Battery / 1.1:
Sodium-O2 Battery / 1.2:
References
Stabilization of Lithium-Metal Anode in Rechargeable Lithium-Air Batteries / Bin Liu and Wu Xu and Ji-Guang Zhang2:
Introduction / 2.1:
Recent Progresses in Li Metal Protection for Li-O2 Batteries / 2.2:
Design of Composite Protective Layers / 2.2.1:
New Insights on the Use of Electrolyte / 2.2.2:
Functional Separators / 2.2.3:
Solid-State Electrolytes / 2.2.4:
Alternative Anodes / 2.2.5:
Challenges and Perspectives / 2.3:
Acknowledgment
Li-Air Batteries: Discharge Products / Xuanxuan Bi and Rongyue Wang and Jun Lu3:
Discharge Products in Aprotic Li-O2 Batteries / 3.1:
Peroxide-based Li-O2 Batteries / 3.2.1:
Electrochemical Reactions / 3.2.1.1:
Crystalline and Electronic Band Structure of Li2O2 / 3.2.1.2:
Reaction Mechanism and the Coexistence of Li2O2 and LiO2 / 3.2.1.3:
Super oxide-based Li-02 Batteries / 3.2.2:
Problems and Challenges in Aprotic Li-O2 Batteries / 3.2.3:
Decomposition of the Electrolyte / 3.2.3.1:
Degradation of the Carbon Cathode / 3.2.3.2:
Discharge Products in Li-Air Batteries / 3.3:
Challenges to Exchanging O2 to Air / 3.3.1:
Effect of Water on Discharge Products / 3.3.2:
Effect of Small Amount of Water / 3.3.2.1:
Aqueous Li-O2 Batteries / 3.3.2.2:
Effect of C02 on Discharge Products / 3.3.3:
Current Li-Air Batteries and Perspectives / 3.3.4:
Electrolytes for Li-O2 Batteries / Alex R. Neale and Peter Goodrich and Christopher Hardacre and Johan Jacquemin4:
General Li-O2 Battery Electrolyte Requirements and Considerations / 4.1:
Electrolyte Salts / 4.1.1:
Ethers and Glymes / 4.1.2:
Dimethyl Sulfoxide (DMSO) and Sulfones / 4.1.3:
Nitriles / 4.1.4:
Amides / 4.1.5:
Ionic Liquids / 4.1.6:
Future Outlook / 4.1.7:
Li-Oxygen Battery: Parasitic Reactions / Xiahui Yao and Qi Dong and Qingmei Cheng and Dunwei Wang5:
The Desired and Parasitic Chemical Reactions for Li-Oxygen Batteries / 5.1:
Parasitic Reactions of the Electrolyte / 5.2:
Nucleophilic Attack / 5.2.1:
Autoxidation Reaction / 5.2.2:
Acid-Base Reaction / 5.2.3:
Proton-mediated Parasitic Reaction / 5.2.4:
Additional Parasitic Chemical Reactions of the Electrolyte: Reduction Reaction / 5.2.5:
Parasitic Reactions at the Cathode / 5.3:
The Corrosion of Carbon in the Discharge Process / 5.3.1:
The Corrosion of Carbon in the Recharge Process / 5.3.2:
Catalyst-induced Parasitic Chemical Reactions / 5.3.3:
Alternative Cathode Materials and Corresponding Parasitic Chemistries / 5.3.4:
Additives and Binders / 5.3.5:
Contaminations / 5.3.6:
Parasitic Reactions on the Anode / 5.4:
Corrosion of the Li Metal / 5.4.1:
SEI in the Oxygenated Atmosphere / 5.4.2:
Alternative Anodes and Associated Parasitic Chemistries / 5.4.3:
New Opportunities from the Parasitic Reactions / 5.5:
Summary and Outlook / 5.6:
Li-Air Battery: Electrocatalysts / 6:
Types of ELectrocatalyst / 6.1:
Carbonaceous Materials / 6.2.1:
Commercial Carbon Powders / 6.2.1.1:
Carbon Nanotubes (CNTs) / 6.2.1.2:
Graphene / 6.2.1.3:
Doped Carbonaceous Material / 6.2.1.4:
Noble Metal and Metal Oxides / 6.2.2:
Transition Metal Oxides / 6.2.3:
Perovskite Catalyst / 6.2.3.1:
Redox Mediator / 6.2.3.2:
Research of Catalyst / 6.3:
Reaction Mechanism / 6.4:
Summary / 6.5:
Lithium-Air Battery Mediator / Zhuojion Liang and Guangtao Cong and Yu Wang and Yi-Chun Lu7:
Redox Mediators in Lithium Batteries / 7.1:
Redox Mediators in Li-Air Batteries / 7.1.1:
Redox Mediators in Li-ion and Lithium-flow Batteries / 7.1.2:
Overcharge Protection in Li-ion Batteries / 7.1.2.1:
Redox Targeting Reactions in Lithium-flow Batteries / 7.1.2.2:
Selection Criteria and Evaluation of Redox Mediators for Li-O2 Batteries / 7.2:
Redox Potential / 7.2.1:
Stability / 7.2.2:
Reaction Kinetics and Mass Transport Properties / 7.2.3:
Catalytic Shuttle vs Parasitic Shuttle / 7.2.4:
Charge Mediators / 7.3:
Lil (Lithium Iodide) / 7.3.1:
LiBr (Lithium Bromide) / 7.3.2:
Nitroxides: TEMPO (2,2,6,6-TetramethyIpiperidinyioxyl) and Others / 7.3.3:
TTF (Tetrathiafulvalene) / 7.3.4:
Tris[4-(diethylamino)phenyl]amine (TDPA) / 7.3.5:
Comparison of the Reported Charge Mediators / 7.3.6:
Discharge Mediator / 7.4:
Iron Phthalocyanine (FePc) / 7.4.1:
2,5-Di-tert'butyl-l,4-benzoquinone (DBBQ) / 7.4.2:
Conclusion and Perspective / 7.5:
Spatiotemporal Operando X-ray Diffraction Study on Li-Air Battery / Di-Jia Liu and Jiang-Lan Shui8:
Microfocused X-ray Diffraction (¿-XRD) and Li-O2 Cell Experimental Setup / 8.1:
Study on Anode: Limited Reversibility of Lithium in Rechargeable LAB / 8.2:
Study on Separator: Impact of Precipitates to LAB Performance / 8.3:
Study on Cathode: Spatiotemporal Growth of Li2O2 During Redox Reaction / 8.4:
Metal-Air Battery: In Situ Spectroelectrochemical Techniquesx / lain M. Aldous and Laurence J. Hardwick and Richard J. Nichols and J. Padmanabhan Vivek9:
Raman Spectroscopy / 9.1:
In Situ Raman Spectroscopy for Metal-O2 Batteries / 9.1.1:
Background Theory / 9.1.2:
Practical Considerations / 9.1.3:
Electrochemical Roughening / 9.1.3.1:
Addressing Inhomogeneous SERS Enhancement / 9.1.3.2:
In Situ Raman Setup / 9.1.4:
Determination of Oxygen Reduction and Evolution Reaction Mechanisms Within Metal-O2 Batteries / 9.1.5:
Infrared Spectroscopy / 9.2:
Background / 9.2.1:
IR Studies of Electrochemical Interfaces / 9.2.2:
Infrared Spectroscopy for Metal-O2 Battery Studies / 9.2.3:
UV/Visible Spectroscopic Studies / 9.3:
UV/Vis Spectroscopy / 9.3.1:
UV/Vis Spectroscopy for Metal-O2 Battery Studies / 9.3.2:
Electron Spin Resonance / 9.4:
Cell Setup / 9.4.1:
Deployment of Electrochemical ESR in Battery Research / 9.4.2:
Zn-Air Batteries / Tong wen Yu and Rui Cai and Zhongwei Chen9.5:
Zinc Electrode / 10.1:
Electrolyte / 10.3:
Separator / 10.4:
Air Electrode / 10.5:
Structure of Air Electrode / 10.5.1:
Oxygen Reduction Reaction / 10.5.2:
Oxygen Evolution Reaction / 10.5.3:
Electrocatalyst / 10.5.4:
Noble Metals and Alloys / 10.5.4.1:
Inorganic-Organic Hybrid Materials / 10.5.4.2:
Meta-free Materials / 10.5.4.4:
Conclusions and Outlook / 10.6:
Experimental and Computational investigation of Nonaqueous Mg/O2 Batteries / Jeffrey G. Smith and Güiin Vardar and Charles W. Monroe and Donald J. Siegel11:
Experimental Studies of Magnesium/Air Batteries and Electrolytes / 11.1:
Ionic Liquids as Candidate Electrolytes for Mg/O2 Batteries / 11.2.1:
Modified Grignard Electrolytes for Mg/O2 Batteries / 11.2.2:
All-inorganic Electrolytes for Mg/O2 Batteries / 11.2.3:
Electrochemical Impedance Spectroscopy / 11.2.4:
Computational Studies of Mg/O2 Batteries / 11.3:
Calculation of Thermodynamic Overpotentials / 11.3.1:
Charge Transport in Mg/O2 Discharge Products / 11.3.2:
Concluding Remarks / 11.4:
Novel Methodologies to Model Charge Transport In Metal-Air Batteries / Nicoiai Rask Mathiesen and Marko Melander and Mikael Kuisma and Pablo García-Fernandez and Juan Maria García Lastra12:
Modeling Electrochemical Systems with GPAW / 12.1:
Density Functional Theory / 12.2.1:
Conductivity from DFT Data / 12.2.2:
The GPAW Code / 12.2.3:
Charge Transfer Rates with Constrained DFT / 12.2.4:
Marcus Theory of Charge Transfer / 12.2.4.1:
Constrained DFT / 12.2.4.2:
Polaronic Charge Transport at the Cathode / 12.2.4.3:
Electrochemistry at Solid-Liquid Interfaces / 12.2.5:
Modeling the Electrochemical Interface / 12.2.5.1:
Implicit Solvation at the Electrochemical Interface / 12.2.5.2:
Generalized Poisson-Boltzmann Equation for the Electric Double Layer / 12.2.5.3:
A Electrode Potential Within the Poisson-Boltzmann Model
Calculations at Constant Electrode Potential / 12.2.6:
The Need for a Constant Potential Presentation / 12.2.6.1:
Grand Canonical Ensemble for Electrons / 12.2.6.2:
Fictitious Charge Dynamics / 12.2.6.3:
Model in Practice / 12.2.6.4:
Conclusions / 12.2.7:
Second Principles for Material Modeling / 12.3:
The Energy in SP-DET / 12.3.1:
The Lattice Term (E(0)) / 12.3.2:
Electronic Degrees of Freedom / 12.3.3:
Model Construction / 12.3.4:
Perspectives on SP-DFT / 12.3.5:
Acknowledgments
Flexible Metal-Air Batteries / Huisheng Peng and Yifan Xu and Jian Pan and Yang Zhao and Lie Wang and Xiang Shi13:
Flexible Electrolytes / 13.1:
Aqueous Electrolytes / 13.2.1:
PAA-based Gel Polymer Electrolyte / 13.2.1.1:
PEO-based Gel Polymer Electrolyte / 13.2.1.2:
PVA-based Gel Polymer Electrolyte / 13.2.1.3:
Nonaqueous Electrolytes / 13.2.2:
PEO-based Polymer Electrolyte / 13.2.2.1:
PVDF-HFP-based Polymer Electrolyte / 13.2.2.2:
Ionic Liquid Electrolyte / 13.2.2.3:
Flexible Anodes / 13.3:
Flexible Cathodes / 13.4:
Modified Stainless Steel Mesh / 13.4.1:
Modified Carbon Textile / 13.4.2:
Carbon Nanotube / 13.4.3:
Graphene-based Cathode / 13.4.4:
Other Composite Electrode / 13.4.5:
Prototype Devices / 13.5:
Sandwich Structure / 13.5.1:
Fiber Structure / 13.5.2:
Perspectives on the Development of Metal-Air Batteries / 13.6:
Lithium Anode / 14.1:
Cathode / 14.1.2:
The Reaction Mechanisms / 14.1.4:
The Development of Solid-state Li-O2 Battery / 14.1.5:
The Development of Flexible Li-O2 Battery / 14.1.6:
Na-O2 Battery / 14.2:
Zn-air Battery / 14.3:
Index
Preface
Introduction to Metal-Air Batteries: Theory and Basic Principles / Zhiwen Chang and Xin-bo Zhang1:
Li-O2 Battery / 1.1:
8.

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図書
Mihai V. Putz, Fanica Cimpoesu, Marilena Ferbinteanu
出版情報: Cham : Springer, c2018  xxx, 802 p. ; 25 cm
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図書
Jinlong Zhang ... [et al.]
出版情報: Singapore : Springer, c2018  xii, 409 p. ; 25 cm
シリーズ名: Lecture notes in chemistry ; 100
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図書
Peter Atkins
出版情報: Oxford : Oxford University Press, 2015  xvi, 107 p. ; 18 cm
シリーズ名: Very short introductions ; 417
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