The theory of atomic spectra

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The theory of atomic spectra / by E.U. Condon and G.H. Shortley

資料種別:

図書

出版情報:

Cambridge : Cambridge University Press, 1951

形態:

xiv, 441 p. ; ill. ; 24 cm

著者名:

ISBN:

9780521092098 [0521092094] (: pbk)

書誌ID:

BA02863249

子書誌情報

フルテキスト

所蔵情報

他の版・巻

書誌詳細

注記:

"1st printed 1935, reprinted with corrections 1951, reprinted 1953,1957,1959,1963,1964,1967,1970"--T.p. verso
Includes indexes

主題:

Quantum theory; Spectrum analysis

言語:

英語

目次情報:

Preface to the 1963 impression

Preface

Introduction / Chapter I：

The Quantum Mechanical Method / Chapter II：

Symbolic algebra of states and observables / Section 1：

Representations of states and observables / Section 2：

Continuous eigenvalues and the Schrodinger representation / Section 3：

The statistical interpretation / Section 4：

The laws of quantum mechanics / Section 5：

Schrodinger's equation / Section 6：

Matrix mechanics / Section 7：

Perturbation theory / Section 8：

Resume of the perturbation theory / Section 9：

Remarks on the perturbation theory / Section 10：

Perturbation caused by a single state / Section 11：

The analysis of non-commuting vectors / Section 12：

Angular Momentum / Chapter III：

Definition of angular momentum

Allowed values of angular momentum

The matrices of angular momentum

Orbital angular momentum

Spin angular momentum

Vector addition of angular momenta

The matrix of [characters not reproducible]

Matrix of T in the j m scheme. Selection rule on j

Dependence of the matrix of T on m

The matrices of J[subscript 1] and J[subscript 2], where J[subscript 1] + J[subscript 2] = J

Matrix of a vector P which commutes with J[subscript 1]

Matrix of P.Q

Sum rules / Section 13：

Transformation amplitudes for vector addition / Section 14：

The Theory of Radiation / Chapter IV：

Transition probabilities

Classical electromagnetic theory

Expansion of the retarded potential

The correspondence principle for emission

The dipole-radiation field

The quadrupole-radiation field

Spectral lines in natural excitation

Induced emission and absorption

Dispersion theory. Scattering. Raman effect

Natural shape of absorption lines

One-Electron Spectra / Chapter V：

Central-force problem

Radial functions for hydrogen

The relativity correction

Spin-orbit interaction

Sketch of the relativistic theory

Intensities in hydrogen

Experimental results for hydrogenic spectra

General structure of the alkali spectra

Intensities in alkali spectra

Zeeman effect

The Central-Field Approximation / Chapter VI：

The Hamiltonian for many-electron atoms

Equivalence degeneracy

The dynamical equivalence of the electrons

The Pauli exclusion principle

Conventions concerning quantum numbers. Closed shells

Matrix components for [Sigma subscript i]f(i)

Matrix components for [Sigma subscript i,j]g(i, j)

Matrix components of electrostatic interaction

Specialization for closed shells

One electron outside closed shells

Odd and even states

The Russell-Saunders Case: Energy Levels / Chapter VII：

The LS-coupling scheme

Term energies

The Lande interval rule

Absolute term intervals

Formulas and experimental comparison

Terms in the nl[superscript x] configurations

The triplet terms of helium

The Russell-Saunders Case: Eigenfunctions / Chapter VIII：

Vector coupling in antisymmetric states

Genealogical characterization of LS-coupling terms

Lande intervals for terms of coupled groups

Calculation of eigenfunctions by direct diagonalization

Calculation of eigenfunctions using angular-momentum operators

Calculation of eigenfunctions from vector-coupling formulas

Separation of the [superscript 2]D's of d[superscript 3]

The Russell-Saunders Case: Line Strengths / Chapter IX：

Configuration selection rules

Line strengths in Russell-Saunders multiplets

Multiplet strengths in a transition array

Multiplet strengths obtained from spectroscopic stability

Quadrupole multiplets

jj Coupling / Chapter X：

The jj-coupling scheme and the spin-orbit interaction

The addition of a weak electrostatic interaction

Eigenfunctions

Line strengths

Intermediate Coupling / Chapter XI：

Matrix of spin-orbit interaction for configurations consisting of coupled groups

Matrix of spin-orbit interaction obtained from the eigenfunctions

Illustrations of the transition from LS to jj coupling

Line strengths in intermediate coupling

The forbidden lines of astrophysical interest

Transformations in the Theory of Complex Spectra / Chapter XII：

Configurations containing almost closed shells

The transformation to LS coupling

The transformation to jj coupling

The transformation between zero-order states

The transformation nlm[subscript s]m[subscript i] [left harpoon over right] nljm

The transformation jjJM [left harpoon over right] SLJM

Configurations Containing Almost Closed Shells. X-Rays / Chapter XIII：

The electrostatic energy in LS coupling

The spin-orbit interaction

Pure almost-closed-shell configurations

The rare-gas spectra

The configurations p[superscript 5]s and d[superscript 9]s

The configuration p[superscript 5]p in the rare gases

The configuration p[superscript 5]d in the rare gases

X-ray spectra

Line strengths in X-ray spectra

X-ray satellites

Central Fields / Chapter XIV：

The periodic system

The statistical method of Fermi-Thomas

The Wentzel-Brillouin-Kramers approximation

Numerical integration of the radial equation

Normal state of helium

Excited levels in helium

Normal states of first-row atoms

Hartree's self-consistent fields

Survey of consistent-field results

Self-consistent fields for oxygen

Configuration Interaction / Chapter XV：

Interaction of sd and p[superscript 2] in magnesium

Perturbed series

Auto-ionization

Many-electron jumps

Spin-orbit perturbation of doublet intensities

The Zeeman Effect / Chapter XVI：

The 'normal' Zeeman effect

The weak-field case: Russell-Saunders terms

Weak fields: general case

Intensities in the Zeeman pattern: weak fields

The Paschen-Back effect

The Paschen-Back effect: illustrative examples

Quadrupole lines

The Stark Effect / Chapter XVII：

Hydrogen

Stark effect at the series limit

General theory for non-hydrogenic atoms

Helium

Alkali metals

The Nucleus in Atomic Spectra / Chapter XVIII：

Effect of finite mass

Local nuclear fields

Nuclear spin in one-electron spectra

The hyperfine structure of two-electron spectra

Zeeman effect of hyperfine structure

Universal Constants and Natural Atomic Units / Appendix：

List of Principal Tables

Index of Subjects

Index of Names

Preface to the 1963 impression

Preface

Introduction / Chapter I：

The Quantum Mechanical Method / Chapter II：

Symbolic algebra of states and observables / Section 1：

Representations of states and observables / Section 2：

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