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図書

図書
Kurt Faber
出版情報: Cham : Springer, c2018  xi, 434 p. ; 25 cm
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図書

図書
Yuichi Kobayashi, editor
出版情報: Singapore : Springer, c2019  xxv, 355 p. ; 25 cm
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図書

図書
edited by Stanley M. Roberts, John Whittall
出版情報: Chichester : J. Wiley & Sons, c2007  xxii, 312 p. ; 24 cm
シリーズ名: Catalysts for fine chemical synthesis ; v. 5
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Series Preface
Preface to Volume 5
Abbreviations
Industrial Catalysts for Regio- or Stereo-Selective Oxidations and Reductions A Review of Key Technologies and Targets / John Whittall1:
Introduction / 1.1:
Reduction of Carbon-Carbon Double Bonds / 1.2:
Privileged structures: [alpha]-amino acids and itaconic acids / 1.2.1:
[beta]-Amino acids / 1.2.2:
[alpha]-Alkyl substituted acids / 1.2.3:
[alpha]-Alkoxy substituted acids / 1.2.4:
Unsaturated nitriles / 1.2.5:
Alkenes and allyl alcohols / 1.2.6:
[alpha],[beta]-Unsaturated aldehyde reduction / 1.2.7:
Ketone and Imine Reduction / 1.3:
Catalytic hydrogenation of ketones and imines / 1.3.1:
Asymmetric transfer hydrogenation (ATH) catalysts / 1.3.2:
Modified borane reagents / 1.3.3:
Biocatalysts (alcohol dehydrogenases and ketoreductases) / 1.3.4:
Oxidation / 1.4:
Sharpless chiral epoxidation of allyl alcohols / 1.4.1:
Dioxirane catalyzed epoxidation / 1.4.2:
Amines and iminium salts / 1.4.3:
Phase transfer catalysts / 1.4.4:
The Julia-Colonna method (polyleucine oxidation) / 1.4.5:
Organocatalytic [alpha]-hydroxylation of ketones / 1.4.6:
Baeyer-Villiger oxidation / 1.4.7:
Chiral sulfoxides / 1.4.8:
References
Asymmetric Hydrogenation of Alkenes, Enones, Ene-Esters and Ene-Acids / 2:
(S)-2,2[prime]-Bis{[di(4-methoxyphenyl)phosphinyl]oxy}-5,5[prime],6,6[prime],7,7[prime],8,8[prime]-octahydro-1,1[prime]-binaphthyl as a ligand for rhodium-catalyzed asymmetric hydrogenation / Ildiko Gergely ; Csaba Hegedus ; Jozsef Bakos2.1:
Synthesis of (S)-5,5[prime],6,6[prime],7,7[prime],8,8[prime]-Octahydro-1,1[prime]-bi-2-naphthol / 2.1.1:
Synthesis of (S)-2,2[prime]-Bis{[di(4-methoxyphenyl)phosphinyl]oxy}-5,5[prime],6,6[prime],7,7[prime],8,8[prime]-octahydro-1,1[prime]-binaphthyl / 2.1.2:
Asymmetric hydrogenation of Dimethyl itaconate / 2.1.3:
Conclusion
Synthesis and application of phosphinite oxazoline iridium complexes for the asymmetric hydrogenation of alkenes / Frederik Menges ; Andreas Pfaltz2.2:
Synthesis of (4S,5S)-2-(5-Methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-1,3-diphenyl-propan-2-ol / 2.2.1:
Synthesis of (4S,5S)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenyl-ethyl]-diphenylphosphinite / 2.2.2:
Synthesis of (4S,5S)-[([eta superscript 4]-1,5-Cyclooctadiene)-{2-(2-phenyl-5-methyl-4,5-dihydro-oxazol-4-yl)-1,3-diphenyl-2-diphenylphosphinite-propane}iridium(I)]-tetrakis[3,5-bis(trifluoromethyl)phenyl]borate / 2.2.3:
Asymmetric hydrogenation of trans-[alpha]-Methylstilbene / 2.2.4:
Synthesis and application of heterocyclic phosphine oxazoline (HetPHOX) iridium complexes for the asymmetric hydrogenation of alkenes / Pier Giorgio Cozzi2.3:
Synthesis of (4S)-tert-Butyl-2-(thiophene-2-yl)-4,5-dihydrooxazole / 2.3.1:
Synthesis of (4S)-tert-Butyl-2-(3-diphenylphosphino-thiophene-2-yl)-4,5-dihydrooxazole / 2.3.2:
Synthesis of (4S)-[([eta superscript 4]-1,5-Cyclooctadiene)-{4-tert-butyl-2-(3-diphenylphosphino-thiophene-2-yl)-4,5-dihydrooxazole}iridium(I)]-tetrakis [3,5-bis(trifluoromethyl)phenyl]borate / 2.3.3:
(R)-2,2[prime],6,6[prime]-Tetramethoxy-bis[di(3,5-dimethylphenyl)phosphino]-3,3[prime]-bipyridine [(R)-Xyl-P-Phos] as a ligand for rhodium-catalyzed asymmetric hydrogenation of [alpha]-dehydroamino acids / Jing Wu ; Albert S.C. Chan2.3.4:
Synthesis of 3-Bromo-2,6-dimethoxypyridine / 2.4.1:
Synthesis of Bis(3,5-dimethylphenyl)phosphine chloride / 2.4.2:
Synthesis of 3-Bromo-2,6-dimethoxy-4-di(3,5-dimethylphenyl)phosphinopyridine / 2.4.3:
2,2[prime],6,6[prime]-Tetramethoxy-bis[di(3,5-dimethylphenyl)phosphinoyl]-3,3[prime]-bipyridine / 2.4.4:
Optical resolution of ([plus or minus])-6 with (-) or (+)-2,3-0,0[prime]-Dibenzoyltartaric acid monohydrate [(R)-6 or (S)-6)] / 2.4.6:
(R)-2,2[prime],6,6[prime]-Tetramethoxy-bis[di(3,5-dimethylphenyl)phosphino]-3,3[prime]-bipyridine [(R)-Xyl-P-Phos, (R)-1] / 2.4.7:
Preparation of the stock solution of [Rh(R-Xyl-P-Phos)(COD)]BF[subscript 4] / 2.4.8:
A typical procedure for the asymmetric hydrogenation of methyl (Z)-2-Acetamidocinnamate / 2.4.9:
(R,R)-2,3-Bis(tert-butylmethylphosphino)quinoxaline (QuinoXP) as a ligand for rhodium-catalyzed asymmetric hydrogenation of prochiral amino acid and amine derivatives / Tsuneo Imamoto ; Aya Koide2.5:
Synthesis of (R)-tert-Butyl(hydroxymethyl)methylphosphine-borane / 2.5.1:
Synthesis of (R)-Benzoyloxy(tert-butyl)methylphosphine-borane / 2.5.2:
Synthesis of (S)-tert-Butylmethylphosphine-borane / 2.5.3:
(R,R)-2,3-Bis(tert-butylmethylphosphino)quinoxaline (QuinoxP) / 2.5.4:
Asymmetric hydrogenation of Methyl (E)-3-acetylamino-2-butenoate catalyzed by Rh(I)-(R,R)-2,3-Bis(tert-butylmethylphosphino)quinoxaline / 2.5.5:
Rhodium-catalyzed asymmetric hydrogenation of indoles / Ryoichi Kuwano ; Masaya Sawamura2.6:
Synthesis of (R)-2-[(S)-1-(Dimethylamino)ethyl]-1-iodoferrocene / 2.6.1:
Synthesis of (R)-2-[(S)-1-(Diphenylphosphinyl)ethyl]-1-iodoferrocene / 2.6.2:
Synthesis of (R,R)-2,2[prime]-Bis[(S)-1-(diphenylphosphinyl)ethyl]-1,1[Prime]-biferrocene / 2.6.3:
Synthesis of (R,R)-2,2[Prime]-Bis[(S)-1-(diphenylphosphino)ethyl]-1,1[Prime]-biferrocene [abbreviated to (S,S)-(R,R)-PhTRAP] / 2.6.4:
Catalytic asymmetric hydrogenation of N-Acetyl-2-butylindole / 2.6.5:
Catalytic asymmetric hydrogenation of 3-Methyl-N-(p-toluenesulfonyl)indole / 2.6.6:
Asymmetric Reduction of Ketones / 3:
(R,R)-Bis(diphenylphosphino)-1,3-diphenylpropane as a versatile ligand for enantioselective hydrogenations / Natalia Dubrovina ; Armin Borner3.1:
Synthesis of (S,S)-1,3-Diphenylpropane-1,3-diol / 3.1.1:
Synthesis of (S,S)-Methanesulfonyloxy-1,3-diphenylpropane-1,3-diol / 3.1.2:
Synthesis of (R,R)-Bis(diphenylphosphino)-1,3-diphenylpropane / 3.1.3:
Synthesis of both enantiomers of 1-Phenylethanol by reduction of acetophenone with Geotrichum candidum IFO 5767 / Kaoru Nakamura ; Mikio Fujii ; Yoshiteru Ida3.2:
Cultivation of G. candidum IFO 5767 / 3.2.1:
Synthesis of (S)-1-Phenylethanol / 3.2.2:
Synthesis of (R)-1-Phenylethanol / 3.2.3:
Titanocene-catalyzed reduction of ketones in the presence of water. A convenient procedure for the synthesis of alcohols via free-radical chemistry / Antonio Rosales ; Juan M. Cuerva ; J. Enrique Oltra3.3:
Titanocene-catalyzed reduction of Acetophenone in the presence of water / 3.3.1:
Titanocene-catalyzed synthesis of Methyl 4-deuterio-4-phenyl-4-hydroxybutanoate / 3.3.2:
Xyl-tetraPHEMP: a highly efficient biaryl ligand in the [diphosphine RuCl[subscript 2] diamine]-catalyzed hydrogenation of simple aromatic ketones / Paul H. Moran ; Julian P. Henschke ; Antonio Zanotti-Gerosa ; Ian C. Lennon3.4:
Synthesis of Tri(3,5-dimethylphenyl)phosphine oxide / 3.4.1:
Synthesis of Bis(3,5-dimethylphenyl)-(2-iodo-3,5-dimethylphenyl)phosphine oxide / 3.4.2:
Synthesis of rac-4,4[prime],6,6[prime]-Tetramethyl-2,2[prime]-bis[bis(3,5-dimethylphenyl)phosphinoyl]-biphenyl / 3.4.3:
Synthesis of rac-4,4[prime],6,6[prime]-Tetramethyl-2,2[prime]-bis[bis(3,5-dimethylphenyl)phosphino]-biphenyl [abbreviated to (rac)-Xyl-tetraPHEMP] / 3.4.4:
Synthesis of [(R)-N,N-Dimethyl(1-methyl)benzylaminato-C[superscript 2],N]-{rac-4,4[prime],6,6[prime]-tetramethyl-2,2[prime]-bis[bis(3,5-dimethylphenyl)phosphino]-biphenyl}-palladium(II) tetrafluoroborate and separation of the diastereomers / 3.4.5:
Synthesis of (S)-4,4[prime],6,6[prime]-Tetramethyl-2,2[prime]-bis[bis(3,5-dimethylphenyl)phosphino]-biphenyl: [abbreviated to (S)-Xyl-tetraPHEMP) and (R)-4,4[prime],6,6[prime]-Tetramethyl-2,2[prime]-bis[bis(3,5-dimethylphenyl)phosphino]-biphenyl [abbreviated to (R)-Xyl-tetraPHEMP] / 3.4.6:
Synthesis of [(R)-Xyl-tetraPHEMP RuCl[subscript 2] (R,R)-DPEN] and [(S)-Xyl-tetraPHEMP RuCl[subscript 2] (S,S)-DPEN] / 3.4.7:
Reduction of Acetophenone using [(S)-Xyl-tetraPHEMP RuCl[subscript 2] (S,S)-DPEN] as a precatalyst / 3.4.8:
N-Arenesulfonyl- and N-Alkylsulfamoyl-1,2-diphenylethylenediamine ligands for ruthenium-catalyzed asymmetric transfer hydrogenation of activated ketones / Michel (Massoud S.) Stephan ; Barbara Mohar3.5:
Synthesis of N-Arenesulfonyl-1,2-diphenylethylenediamines / 3.5.1:
Preparation of Ru(II)-N-arenesulfonyl-1,2-diphenylethylenediamine complexes / 3.5.2:
Asymmetric transfer hydrogenation of Ethyl benzoylacetate / 3.5.3:
The synthesis and application of BrXuPHOS: a novel monodentate phosphorus ligand for the asymmetric hydrogenation of ketones / Martin Wills ; Yingjian Xu ; Garden Docherty ; Gary Woodward3.6:
Synthesis of (S)-BrXuPHOS / 3.6.1:
Synthesis of (S,S,SS)-BrXuPHOS-Ru-DPEN / 3.6.2:
General procedure of asymmetric hydrogenation of acetophenone / 3.6.3:
Acknowledgement
In Situ formation of ligand and catalyst: application in ruthenium-catalyzed enantioselective reduction of ketones / Jenny Wettergren ; Hans Adolfsson3.7:
Synthesis of (S)-3-Fluoro-1-phenylethanol / 3.7.1:
Synphos and Difluorphos as ligands for ruthenium-catalyzed hydrogenation of alkenes and ketones / Severine Jeulin ; Virginie Ratovelomanana-Vidal ; Jean-Pierre Genet3.8:
Synthesis of [RuCl((S)-SYNPHOS)(p-cymene)]Cl / 3.8.1:
Synthesis of [RuCl((S)-DIFLUORPHOS)(p-cymene)]Cl / 3.8.2:
Synthesis of [RuI((S)-DIFLUORPHOS)(p-cymene)]I / 3.8.3:
Synthesis of [NH[subscript 2]R[subscript 2]] [(RuCl(PP))[subscript 2]([Mu]-Cl)[subscript 3]] PP = SYNPHOS or DIFLUORPHOS and R = Me or Et / 3.8.4:
Synthesis of [NH[subscript 2]Me[subscript 2]][RuCl-(S)-DIFLUORPHOS][subscript 2][[Mu]-Cl][subscript 3] / 3.8.5:
Synthesis of in situ generated [RuBr[subscript 2]((S)-SYNPHOS)] and [RuBr[subscript 2]((S)-DIFLUORPHOS)] / 3.8.6:
An arene ruthenium complex with polymerizable side chains for the synthesis of immobilized catalysts / Estelle Burri ; Silke B. Wendicke ; Kay Severin3.9:
Synthesis of 2-Methyl-cyclohexa-2,5-dienecarboxylic acid 2-(2-methyl-acryloyloxy)-ethyl ester / 3.9.1:
Synthesis of [[eta superscript 6]-(2-Methyl-benzoic acid 2-(2-methyl-acryloyloxy)-ethyl ester)RuCl[subscript 2]][subscript 2] / 3.9.2:
Selective reduction of carbonyl group in [beta], [gamma]-unsaturated [alpha]-alpha-ketoesters by transfer hydrogenation with Ru-(p-cymene) (TsDPEN) / Minjie Guo ; Dao Li ; Yanhui Sun ; Zhaoguo Zhang3.10:
Synthesis of Di-[Mu]-chloro-bis[chloro([eta superscript 6]-1-isopropyl-4-methyl-benzene)ruthenium(II) / 3.10.1:
Synthesis of ([plus or minus])-Monotosylate-1,2-diphenyl-1,2-ethylenediamine / 3.10.2:
Synthesis of Ru complex Ru(p-cymene)(TsDPEN) / 3.10.3:
Ru-TsDPEN catalyzed transfer hydrogenation reaction of [beta],[gamma]-unsaturated-[alpha]-ketoesters / 3.10.4:
Preparation of polymer-supported Ru-TsDPEN catalysts and their use for the enantioselective synthesis of (S)-fluoxetine / Liting Chai ; Yangzhou Li ; Quanrui Wang3.11:
Synthesis of the supported ligand 9 / 3.11.1:
Synthesis of ligand 17 / 3.11.2:
General procedure for asymmetric transfer hydrogenation / 3.11.3:
Preparation of (S)-Fluoxetine hydrochloride / 3.11.4:
Polymer-supported chiral sulfonamide-catalyzed reduction of [beta]-keto nitriles: a practical synthesis of (R)-Fluoxetine / Guang-yin Wang ; Gang Zhao3.12:
Synthesis of (R)-3-Amino-1-phenyl-propan-1-ol / 3.12.1:
Synthesis of (R)-ethyl 3-hydroxy-3-phenylpropylcarbamate / 3.12.2:
Synthesis of (R)-3-(Methylamino)-1-phenylpropan-1-ol / 3.12.3:
Synthesis of (R)-Fluoxetine / 3.12.4:
Imine Reduction and Reductive Amination / 4:
Metal-free reduction of imines: enantioselective Bronsted acid-catalyzed transfer hydrogenation using chiral BINOL-phosphates as catalysts / Magnus Rueping ; Erli Sugiono ; Cengiz Azap ; Thomas Theissmann4.1:
Synthesis of (R)-2,2[prime]-Bis-methoxymethoxy-[1,1[prime]] binaphthalene (MOM-BINOL) / 4.1.1:
Synthesis of (R)-3,3[prime]-Diiodo-2,2[prime]-bis(methoxymethoxy)-1,1[prime]-binaphthalene / 4.1.2:
Synthesis of 3,3[prime]-Bis-(3,5[prime]-bis-trifluoromethyl-phenyl)-2,2[prime]-bismethoxymethoxy [1,1[prime]-binaphthalene] / 4.1.3:
Synthesis of (R)-3,3[prime]-[3,5-Bis(trifluoromethyl)phenyl]-1,1[prime]-binaphthylphosphate / 4.1.4:
General procedure for the transfer hydrogenation of ketimines / 4.1.5:
Synthesis of [1-(2,4-Dimethyl-phenyl)-ethyl]-(4-methoxy-phenyl)-amine / 4.1.6:
Metal-free Bronsted acid-catalyzed transfer hydrogenation: enantioselective synthesis of tetrahydroquinolines / Andrey P. Antonchick4.2:
General procedure for the transfer hydrogenation of quinolines / 4.2.1:
Synthesis of 7-Chloro-4-phenyl-1,2,3,4-tetrahydroquinoline / 4.2.2:
Synthesis of (S)-2-Phenyl-1,2,3,4-tetrahydroquinoline / 4.2.3:
Synthesis of (R)-2-(2-(Benzo[1,3]dioxol-5-yl)ethyl)-1,2.3,4-tetrahydro-quinoline / 4.2.4:
A highly stereoselective synthesis of 3[alpha]-Amino-23,24-bisnor-5[alpha]-cholane via reductive amination / Sharaf Nawaz Khan ; Nam Ju Cho ; Hong-Seok Kim4.3:
Synthesis of Tris[(2-ethylhexanoyl)oxy]borohydride / 4.3.1:
Synthesis of 3[alpha]-Acetamino-23,24-bisnor-5[alpha]-cholane / 4.3.2:
Synthesis of 3[alpha]-N-1-[N(3-[4-Aminobutyl])-1,3-diaminopropane]-23,24-bisnor-5[alpha]-cholane / 4.3.3:
Acknowledgements
Oxidation of Primary and Secondary Alcohols / 5:
Copper(Il) catalyzed oxidation of primary alcohols to aldehydes with atmospheric oxygen / Suribabu Jammi ; Tharmalingan Punniyamurthy5.1:
Synthesis of copper(II) complex 1 / 5.1.1:
Typical procedure for the oxidation of primary alcohols to aldehydes / 5.1.2:
Solvent-free dehydrogenation of secondary alcohols in the absence of hydrogen abstractors using Robinson's catalyst / G.B.W.L Ligthart ; R.H. Meijer ; J. v. Buijtenen ; J. Meuldijk ; J.A.J.M. Vekemans ; L.A. Hulshof5.2:
Dehydrogenation of 2-Octanol using Ru(OCOCF[subscript 3])[subscript 2](CO)(PPh[subscript 3])[subscript 2] as a catalyst / 5.2.1:
2-Iodoxybenzoic acid (IBX)/n-Bu[subscript 4]NBr/CH[subscript 2]Cl[subscript 2]-H[subscript 2]O: a mild system for the selective oxidation of secondary alcohols / Krisada Kittigowittana ; Manat Pohmakotr ; Vichai Reutrakul ; Chutima Kuhakarn5.3:
Synthesis of 1-Hydroxy-5-decanone / 5.3.1:
Hydroxylation, Epoxidation and Related Reactions / 6:
Proline-catalyzed [alpha]-aminoxylation of aldehydes and ketones / Yujiro Hayashi ; Mitsuru Shoji6.1:
Synthesis of (R)-2-Anilinoxypropanol / 6.1.1:
Synthesis of (R)-7-Anilinoxy-1,4-dioxaspiro[4.5]decan-8-one / 6.1.2:
Ru/Silia Cat TEMPO-mediated oxidation of alkenes to [alpha]-hydroxyacids / Rosaria Ciriminna ; Mario Pagliaro6.2:
Synthesis of Silia Cat TEMPO / 6.2.1:
Synthesis of 2-(4-Chlorophenyl)-1,2-propanediol / 6.2.2:
Synthesis of 2-(4-Chlorophenyl)-1,2-hydroxypropanoic acid / 6.2.3:
Catalytic enantioselective epoxidation of trans-disubstituted and trisubstituted alkenes with arabinose-derived ulose / Tony K. M. Shing ; Gulice Y.C. Leung ; To Luk6.3:
Synthesis of 2[prime],3[prime]-Diisobutyl acetal / 6.3.1:
Synthesis of ulose / 6.3.2:
Asymmetric epoxidation of trans-[alpha]-Methylstilbene using ulose as catalyst at 0 [degree]C / 6.3.3:
VO(acac)[subscript 2]/TBHP catalyzed epoxidation of 2-(2-Alkenyl)phenols. highly regio- and diastereoselective oxidative cyclisation to 2,3-Dihydrobenzofuranols and 3-Chromanols / Alessandra Lattanzi ; Arrigo Scettri6.4:
VO(acac)[subscript 2]/TBHP catalyzed epoxidation of 2-(3,7-Dimethyl-octa-2,6-dienyl)-phenol / 6.4.1:
VO(acac)[subscript 2]/TBHP/TFA catalyzed oxidative cyclization of 2-(3,7-Dimethyl-octa-2,6-dienyl)-phenol / 6.4.2:
An Oxalolidinone ketone catalyst for the asymmetric epoxidation of cis-olefins / David Goeddel ; Yian Shi6.5:
Amadori rearrangement to give 1-Dibenzylamino-1-deoxy-D-fructose / 6.5.1:
Acetal protection of 1-Dibenzylamino-1-deoxy-D-fructose / 6.5.2:
Hydrogenation of the Dibenzylamine / 6.5.3:
Phosgene cyclization of aminoalcohol / 6.5.4:
Alcohol oxidation / 6.5.5:
Synthesis of ketone 2 / 6.5.6:
Asymmetric epoxidation of cis-[beta]-Methylstyrene / 6.5.7:
[alpha]-Fluorotropinone immobilised on silica: a new stereoselective heterogeneous catalyst for epoxidation of alkenes with oxone / Giovanni Sartori ; Alan Armstrong ; Raimondo Maggi ; Alessandro Mazzacani ; Raffaella Sartorio ; France Bigi ; Belen Dominguez-Fernandez6.6:
Synthesis of silica KG-60-supported enantiomerically enriched [alpha]-Fluorotropinone / 6.6.1:
Synthesis of enantiomerically enriched epoxides / 6.6.2:
Asymmetric epoxidation catalyzed by novel azacrown ether-type chiral quaternary ammonium salts under phase-transfer catalytic conditions / Kazushige Hori ; Keita Tani ; Yasuo Tohda6.7:
Synthesis of precursor of the azacrown ether / 6.7.1:
Synthesis of the azacrown ether / 6.7.2:
Synthesis of the azacrown ether-type quaternary ammonium salt / 6.7.3:
Asymmetric epoxidation of (E)-Chalcone catalyzed by the azacrown ether-type quaternary ammonium salt as chiral PTC / 6.7.4:
Enantioselective epoxidation of olefins using phase transfer conditions and a chiral [azepinium][TRISPHAT] salt as catalyst / Jerome Vachon ; Celine Perollier ; Alexandre Martinez ; Jerome Lacour6.8:
Enantioselective epoxidation of 1-Phenyl-3,4-dihydronaphthalene / 6.8.1:
Catalytic asymmetric epoxidation of [alpha],[beta]-unsaturated esters promoted by a Yttrium-biphenyldiol complex / Masakatsu Shibasaki ; Hiroyuki Kakei ; Shigeki Matsunaga6.9:
Synthesis of (aS,R)-6,6[prime]-[(Propylene)dioxy]biphenyl-2,2[prime]-diol / 6.9.1:
Synthesis of (aS,R)-2,2-[Oxybis(ethylene)dioxy]-6,6[prime]-[(propylene)dioxy]biphenyl / 6.9.2:
Synthesis of (S)-6,6[prime]-[Oxybis(ethylene)dioxy]biphenyl-2,2[prime]-diol / 6.9.3:
Enantiomeric enrichment of (S)-6,6[prime]-[Oxybis(ethylene)dioxy]biphenyl-2,2[prime]-diol / 6.9.4:
Catalytic asymmetric epoxidation of [alpha],[beta]-unsaturated esters / 6.9.5:
Catalytic enantioselective epoxidation of [alpha],[beta]-enones with a binol-zinc-complex / Ana Minatti ; Karl Heinz Dotz6.10:
Synthesis of (E)-(2S,3R)-Phenyl-(3-phenyloxiran-2-yl)methanone / 6.10.1:
Asymmetric epoxidation of Phenyl-2-(3[prime]-pyridylvinyl)sulfone using polyleucine hydrogen peroxide gel / Mike R. Pitts6.11:
Preparation of polyleucine-hydrogen peroxide gel / 6.11.1:
Synthesis of Phenyl-2-(3[prime]-pyridylvinyl) sulfone (2) / 6.11.2:
Oxidation of Ketones to Lactones or Enones / 7:
Synthesis of 2-(Phosphinophenyl)pyrindine ligand and its application to palladium-catalyzed asymmetric Baeyer-Villiger oxidation of prochiral cyclobutanones / Katsuji Ito ; Tsutomu Katsuki7.1:
Synthesis of (7R)-2-(2-Hydroxyphenyl)-7-isopropyl-6,7-dihydro-5H-1-pyrindine / 7.1.1:
2-[2-(Diphenylphosphinoyl)phenyl]-7-isopropyl-6,7-dihydro-5H-1-pyrindine / 7.1.2:
2-[2-(Diphenylphosphanyl)phenyl]-7-isopropyl-6,7-dihydro-5H-1-pyrindine / 7.1.3:
Asymmetric Baeyer-Villiger oxidation of 3-Phenylcyclobutanone / 7.1.4:
(D)-Codeinone from (D)-Dihydrocodeinone via the use of modified o-iodoxybenzoic acid (IBX). A convenient oxidation of ketones to enones / Paul Mather7.2:
Synthesis of IBX / 7.2.1:
Synthesis of codeinone / 7.2.2:
Oxidative C-C Coupling / 8:
Enantioselective oxidative coupling of 2-Naphthols catalyzed by a novel chiral vanadium complex / Nan-Sheng Xie ; Quan-Zhong Liu ; Zhi-Bin Luo ; Liu-Zhu Gong ; Ai-Qiao Mi ; Yao-Zhong Jiang8.1:
Synthesis of 3,3-Diformyl-2,2[prime]-biphenol / 8.1.1:
Synthesis of chiral vanadium complexes / 8.1.2:
Catalytic oxidative coupling of 7-Alkoxy-1-naphthols by chiral vanadium complexes / 8.1.3:
Reference
Catalytic oxidative cross-coupling reaction of 2-Naphthol derivatives / Shigeki Habaue ; Tomohisa Temma8.2:
Synthesis of Methyl 2,2[prime]-dihydroxy-1,1[prime]-binaphthalene-3-carboxylate / 8.2.1:
Oxidative coupling of benzenes with [alpha],[beta]-unsaturated aldehydes by Pd(OAc)[subscript 2]/ HPMoV/ O[subscript 2] system / Tomoyuki Yamada ; Satoshi Sakaguchi ; Yasutaka Ishii8.3:
Synthesis of Cinnamaldehyde / 8.3.1:
Oxidation of Sulfides and Sulfoxides / 9:
The first example of direct oxidation of sulfides to sulfones by an osmate-molecular oxygen system / Boyapati M. Choudary ; Chinta Reddy ; V. Reddy ; Billakanti V. Prakash ; Mannepalli L. Kantam ; B. Sreedhar9.1:
Synthesis of osmate exchanged Mg-Al layered double hydroxides (LDH-OsO[subscript 4]) / 9.1.1:
Synthesis of Methyl phenyl sulfone or Methylsulfonylbenzene / 9.1.2:
Selective oxidation of sulfides to sulfoxides and sulfones using hydrogen peroxide in the presence of zirconium tetrachloride / Kiumar Bahrami9.2:
Oxidation of Benzyl 4-bromobenzyl sulfide to Benzyl 4-bromobenzyl sulfoxide using H[subscript 2]O[subscript 2] in the presence of zirconium tetrachloride / 9.2.1:
Oxidation of Benzyl 4-bromobenzyl sulfide to Benzyl 4-bromobenzyl sulfone using H[subscript 2]O[subscript 2] in the presence of zirconium tetrachloride / 9.2.2:
WO[subscript 3]-30 % H[subscript 2]O[subscript 2]-cinchona alkaloids: a new heterogeneous catalytic system for asymmetric oxidation and kinetic resolution of racemic sulfoxides / Vinay V. Thakur ; A. Sudalai9.3:
Synthesis of (R)-2-[[[3-Methyl-4-(2,2,2-trifluoroethoxy)-2-pyridyl]methyl]sulfinyl]-1H-benzimadazole {(R)-(+)-Lansoprazole} / 9.3.1:
Synthesis of (R)-(+)-Phenyl benzyl sulfoxide / 9.3.2:
Benzyl-4,6-O-isopropylidene-[alpha]-(D)-glucopyranoside, 2-deoxy-2-[[(2-hydroxy-3,5-di-tert-butylphenyl)methylene]amino] as a ligand for vanadium-catalyzed asymmetric oxidation of sulfides / Raffaella Del Litto ; Guiseppina Roviello ; Francesco Ruffo9.4:
Synthesis of Benzyl-4,6-O-isopropylidene-[alpha]-D-glucopyranoside, 2-deoxy-2-[[(2-hydroxy-3,5-di-tert-butylphenyl)methylene]imine] / 9.4.1:
Oxidation of Thioanisole / 9.4.2:
Asymmetric sulfoxidation of aryl methyl sulfides with hydrogen peroxide in water / Alessando Scarso ; Giorgio Strukul9.5:
Synthesis of complex (R)-BINAP)PtCl[subscript 2] / 9.5.1:
Synthesis of complex [((R)-BINAP)Pt((OH)][subscript 2](BF[subscript 4])[subscript 2] / 9.5.2:
Stereoselective catalytic oxidation of aryl methyl sulfides / 9.5.3:
Index
Series Preface
Preface to Volume 5
Abbreviations
4.

図書

図書
edited by Kevin Burgess
出版情報: New York : Wiley-Interscience, c2000  xiv, 277 p. ; 24 cm
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Preface
Contributors
Solid-Phase Syntheses of Guanidines / Kevin Burgess ; Jiong Chen1:
Introduction / 1.1.:
Outline of Some Solution-Phase Approaches to Guanidines / 1.2.:
Solid-Phase Syntheses Involving Resin-Bound Electrophiles / 1.3.:
Solid-Phase Syntheses Involving Electrophiles in Solution / 1.4.:
Other Supported Guanidines / 1.5.:
Conclusion / 1.6.:
References
Palladium-Catalyzed Carbon-Carbon Bond Formation on Solid Support / Matthew H. Todd ; Chris Abell2:
Heck Reaction / 2.1.:
Stille Reaction / 2.3.:
Suzuki Reaction / 2.4.:
Miscellaneous Reactions / 2.5.:
Concluding Remarks / 2.6.:
Benzofused Heterocycles Via Solid-Phase S[subscript N]AR Reactions / Matthias K. Schwarz ; Mark A. Gallop3:
Formation of [6,7]- and [6,8]-Fused Systems / 3.1.:
Formation of [6,6]-Fused Systems / 3.3.:
Formation of [6,5]-Fused Systems / 3.4.:
Conclusions and Outlook / 3.5.:
Solid-Phase Synthesis of Sequence-Specific Phenylacetylene Oligomers / Jeffrey S. Moore ; David J. Hill ; Matthew J. Mio4:
Strategies / 4.1.:
Synthetic Tactics / 4.3.:
Illustrative Applications / 4.4.:
Scope and Limitations / 4.5.:
Representative Procedures / 4.6.:
Polymer-Assisted Solution-Phase Methods for Chemical Library Synthesis / Daniel L. Flynn ; Rajesh V. Devraj ; John J. Parlow5:
Reactant Sequestration / 5.1.:
Byproduct Sequestration / 5.3.:
Solution-Phase Derivatization to Facilitate Polymer-Assisted Sequestration / 5.4.:
Soluble Bifunctional Reagents / 5.5.:
Polymer-Supported Substrates / 5.6.:
Polymer-Supported Reagents / 5.7.:
Polymer-Supported Catalysts / 5.8.:
Polymers for Reaction Quenching/Workup / 5.9.:
Combinations of Solid- and Solution-Phase Techniques in Organic Synthesis / 5.10.:
Multistep/One-Chamber Solution-Phase Synthesis / 5.11.:
Polymer-Assisted Technologies in Multistep Solution-Phase Syntheses / 5.12.:
Solid-Phase Organic Synthesis on Radiation-Grafted Polymer Surfaces: Application of Synphase Crowns to Multiple Parallel Syntheses / Ian W. James ; Geoffrey Wickham ; Nicholas J. Ede ; Andrew M. Bray5.13.:
Multiple Parallel Syntheses of Individual Compounds / 6.1.:
Synthetic Applications of Synphase Crowns / 6.2.:
Linker Development Using Synphase Crowns / 6.3.:
Tagging Methods for Identifying Individual Crowns / 6.4.:
Future Developments / 6.5.:
Vibrational Spectroscopy for Optimization of Solid-Phase Organic Syntheses / Bing Yan7:
Spectroscopic Methods Applicable to Different Sample Sizes / 7.1.:
Optimization in Solid-Phase Organic Syntheses / 7.3.:
Recent Advances in Solid-Phase Synthesis of Natural Products / Lawrence J. Wilson7.4.:
Prostaglandins / 8.1.:
Epothilone a / 8.3.:
(S)-Zearalenone / 8.4.:
DL-Muscone / 8.5.:
Taxoid Libraries from Baccatin III / 8.6.:
Sarcodictyin Libraries / 8.7.:
Lavendustin A / 8.8.:
Indolyl Diketopiperazines / 8.9.:
Balanol Analogs / 8.10.:
Pseudoalkaloids from Shikimic Acid / 8.11.:
Conclusions / 8.12.:
Index
Preface
Contributors
Solid-Phase Syntheses of Guanidines / Kevin Burgess ; Jiong Chen1:
5.

図書

図書
edited by Robert M. Coates and Scott E. Denmark
出版情報: Chichester : John Wiley & Sons, c1999  xvi, 746 p. ; 29 cm
シリーズ名: Handbook of reagents for organic synthesis ; [1]
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Partial table of contents
Classes
Acetylenes and Allenes
Aluminum and Boron Reagents
Reagents
Enolates, Homoenolates, and Dicarbonyl Compounds
Epoxides
Halo Compounds
Transition Metal and Lanthanide Reagents
Zinc Reagents
Acetyl Chloride
Acetylene
Acrylonitrile
Allenylboronic Acid
Benzenediazonium Tetrafluoroborate
1,4-Benzoquinone
9-Borabicyclo[3.3.1]nonane Dimer
2-(2-Bromoethyl)-1,3-dioxane
Bromoform
Chlorosulfonyl Isocyanate
Chlorotrimethylsilane
Diethyl Malonate
Diethylzinc
Dimethylformamide Diethyl Acetal
Dimethyl(methylene)ammonium Iodide
Epichlorohydrin
Ethoxyacetylene
3-Hydroxyisoborneol
Iodoform
Iodomethane
Mandelic Acid
Manganese(III) Acetate
Methylcopper-Boron Trifluoride Etherate
Methyl Cyanoformate
Potassium Cyanide
Propargyl Chloride
Triethylaluminum
Triethylborane
Vinyltributylstannane
Zinc-Copper Couple
List of Contributors
Indexes
Partial table of contents
Classes
Acetylenes and Allenes
6.

図書

図書
U.T. Bornscheuer, R.J. Kazlauskas
出版情報: Weinheim : Wiley-VCH, c1999  xiii, 336 p. ; 25 cm
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Introduction / 1:
Designing Enantioselective Reactions / 2:
Kinetic Resolutions / 2.1:
Asymmetric Syntheses / 2.2:
Choosing Reaction Media: Water and Organic Solvents / 3:
Hydrolysis in Water / 3.1:
Transesterifications and Condensations in Organic Solvents / 3.2:
Other Reaction Media / 3.3:
Immobilization / 3.4:
Protein Sources and Optimization of Biocatalyst Performance / 4:
Accessing Biodiversity / 4.1:
Creating Improved Biocatalysts / 4.2:
Catalytic Promiscuity in Hydrolases / 4.3:
Lipases and Esterases / 5:
Availability, Structures and Properties / 5.1:
Survey of Enantioselective Lipase-Catalyzed Reactions / 5.2:
Chemo-and Regioselective Lipase-Catalyzed Reactions / 5.3:
Reactions Catalyzed by Esterases / 5.4:
Proteases and Amidases / 6:
Occurrence and Availability of Proteases and Amidases / 6.1:
General Features of Subtilisin, Chymotrypsin, and Other Proteases and Amidases / 6.2:
Structures of Proteases and Amidases / 6.3:
Survey of Enantioselective Protease-and Amidase-Catalyzed Reactions / 6.4:
Phospholipases / 7:
Phospholipase A 1 / 7.1:
Phospholipase A 2 / 7.2:
Phospholipase C / 7.3:
Phospholipase D / 7.4:
Epoxide Hydrolases / 8:
Mammalian Epoxide Hydrolases / 8.1:
Microbial Epoxide Hydrolases / 8.3:
Hydrolysis of Nitriles / 9:
Mild Conditions / 9.1:
Regioselective Reactions of Dinitriles / 9.3:
Enantioselective Reactions / 9.4:
Other Hydrolases / 10:
Glycosidases / 10.1:
Haloalcohol Dehalogenases / 10.2:
Phosphotriesterases / 10.3:
Abbreviations
References
Index
Introduction / 1:
Designing Enantioselective Reactions / 2:
Kinetic Resolutions / 2.1:
7.

図書

図書
edited by Steven D. Burke and Rick L. Danheiser
出版情報: Chichester : John Wiley & Sons, c1999  viii, 550 p. ; 29 cm
シリーズ名: Handbook of reagents for organic synthesis ; [2]
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Partial table of contents
Aluminum Amalgam
Aluminum Hydride
Borane-Tetrahydrofuran
Bromine
Chromium(II) Chloride
Chromium(VI) Oxide
Hydrogen Sulfide
Iodosylbenzene
Lithium-Ethylamine
Lithium Naphthalenide
Manganese Dioxide
Mercury(II) Oxide
Palladium on Carbon
Palladium(II) Hydroxide on Carbon
Peracetic Acid
Rhodium on Alumina
Ruthenium Catalysts
Ruthenium(VIII) Oxide
Sodium-Alcohol
Sodium Amalgam
Sodium-Ammonia
Sulfur
Thallium(III) Nitrate Trihydrate
Thallium(III) Trifluoroacetate
Thexylborane
Zinc
Zinc Borohydride
Zinc/Copper Couple
List of Contributors
Indexes
Partial table of contents
Aluminum Amalgam
Aluminum Hydride
8.

図書

図書
edited by Hans J. Reich and James H. Rigby
出版情報: Chichester : John Wiley & Sons, c1999  xii, 494 p. ; 29 cm
シリーズ名: Handbook of reagents for organic synthesis ; [3]
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Preface
Introduction
Organic Synthesis Examples
Recent Review Articles and Monographs
A-Z list of Reagents
List of Contributors
Reagent Formula Index
Subject Index
Preface
Introduction
Organic Synthesis Examples
9.

図書

図書
edited by Anthony J. Pearson and William R. Roush
出版情報: Chichester : John Wiley & Sons, c1999  xii, 513 p. ; 29 cm
シリーズ名: Handbook of reagents for organic synthesis ; [4]
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Partial table of contents
Acetic Anhydride
Acetyl Chloride (+ co-reactants)
Aluminum Chloride
Boron Trifluorideetherate
Bromodimethylborane
2,2-Dimethyl-1,3-propanediol
Dimethyl Sulfate
Diphenylbis(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propoxy)-sulfirane
Ethylaluminum Dichloride
N-Ethylbenzisoxazolium Tetrafluoroborate
Hydrazine
1-Hydroxybenzotriazole
Lithium Bromide
Lithium Chloride
Lithium Iodide
Montmorillonite K-10
2-Morpholinoethyl Isocyanide
Phenyl Phosphorodi(1-imidazolate)
Phosgene
1,3-Propanediol
1,3-Propanedithiol
Silver(I) Tetrafluoroborate
Triethylaluminum
Triethyl Orthoformate
Trifluoroacetic Anhydride
Zinc Bromide
Zinc Chloride
Zinc Iodide
Zinc Bis(p-toluenesulfonate)
List of Contributors
Indexes
Partial table of contents
Acetic Anhydride
Acetyl Chloride (+ co-reactants)
10.

図書

図書
by Richard C. Larock
出版情報: New York : Wiley-VCH, c1999  xliii, 2583 p. ; 26 cm
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Quick-Start Instructions
Personalizing the COT Infobase
Searching the COT Infobase
Quick-Start Instructions
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Searching the COT Infobase
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