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1.

図書
図書
1. Principles of polymer chemistry. 2nd ed
A. Ravve
出版情報: New York : Kluwer Academic/Plenum Publishers, c2000  xv, 626 p. ; 26 cm.
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Preface
Introduction and Physical Properties of Polymers / 1：
Free-Radical Chain-Growth Polymerization / 2：
Ionic Chain-Growth Polymerization / 3：
Ring-Opening Polymerizations / 4：
Common Chain-Growth Polymers / 5：
Step-Growth Polymerization and Step-Growth Polymers / 6：
Naturally Occurring Polymers / 7：
Reactions of Polymers / 8：
Degradation of Polymers / 9：
Appendix
Index
Preface
Introduction and Physical Properties of Polymers / 1：
Free-Radical Chain-Growth Polymerization / 2：
2.

図書
図書
2. Polymers for Africa : selected contributions from the conference in Réduit (Mauritius), June 4-9, 2005
symposium editor: D. Jhurry
出版情報: Weinheim, Germany : WILEY-VCH, c2006  ix, 192 p. ; 24 cm
シリーズ名: Macromolecular symposia ; 231
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3.

図書
図書
3. Polymer reaction engineering VI : selected contributions from the conference in Halifax, Canada, May 21-26, 2006
symposium editor: R.A. Hutchinson
出版情報: Weinheim, Germany : WILEY-VCH, c2006  x, 308 p. ; 24 cm
シリーズ名: Macromolecular symposia ; 243
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4.

図書
図書
4. Statistical mechanics of polymers : new developments : selected contributions from the conference in Moscow (Russia), June 6-11, 2006
symposium editors: K. Binder, A.R. Khokhlov, S.L. Kuchanov
出版情報: Weinheim, Germany : WILEY-VCH, c2007  x, 154 p. ; 24cm
シリーズ名: Macromolecular symposia ; 252
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5.

図書
図書
5. Heterogeneous Ziegler-Natta catalysts : selected contributions from the conference in JAIST, Ishikawa (Japan), March 18-21, 2007
symposium editors: Boping Liu, Minoru Terano, Vincenzo Busico
出版情報: Weinheim, Germany : WILEY-VCH, c2007  xii, 196 p. ; 24cm
シリーズ名: Macromolecular symposia ; 260
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6.

図書
図書
6. Polymers from the inside out : an introduction to macromolecules
Alan E. Tonelli with Mohan Srinivasarao
出版情報: New York : John Wiley, 2001  xxv, 249 p. ; 25 cm
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Preface
Acknowledgments
Chapter Summary
Introduction / 1：
Long-Chain Molecules
Conformations, Sizes, and Shapes
Polymers and Time
Polymer Physics and Chemistry
Discussion Questions
References
Step-Growth Polymerization / 2：
General Characteristics
Molecular Weights of Step-Grown Polymers
Step-Growth Monomers
Step-Growth Polymers
Polyesters
Polyamides
Polyurethanes and Polyureas
Formaldehyde Thermosets
Step-Growth Polymerization in an Open System
Stoichiometric Control of Step-Growth Polymerization
Molecular Weights and Their Distribution
Kinetics of Step-Growth Polymerization
Chain-Growth Polymerization / 3：
Contrast Between Chain- and Step-Growth Polymerizations
Details of Chain-Growth Polymerization
Chain-Grown Polymer Sizes
Transfer of Chain Growth
Chain-Grown Polymers
Kinetics of Chain-Growth Polymerization
Chain-Grown Copolymers and the Copolymer Equation
Emulsion Polymerization
Living Chain-Growth Polymerization
The Microstructures of Polymers / 4：
Elements of Polymer Microstructure
Copolymer Sequences
Organization of Polymer Chains
Polymer Microstructures and Properties
Determination of Polymer Microstructure-NMR Spectroscopy
Connecting Polymer Microstructures with Their NMR Spectra
The Conformational Characteristics of Polymers / 5：
Rotational Isomeric State Model
Polymer Microstructures and Conformations
Polymer Conformations and Sizes
RIS Model and Polymer Dimensions
Environmental Effects on Polymer Conformations
Solution Properties of Polymers / 6：
Polymer Excluded Volume
Volume Influenced by a Randomly Coiling Polymer
Intrinsic Viscosity of a Polymer Solution
Turbulent Flow of Polymer Solutions
Polymer Solubility
Anisotropic, Liquid Crystalline Polymer Solutions
Polymer Molecular Weights Measured in Solution
Osmotic Pressure of Polymer Solutions
Light Scattering from Polymer Solutions
Estimation of Polymer Dimensions in Solution
Size-Exclusion Chromatography
Time-Dependence of Flowing Polymer Solutions
Bulk Properties of Polymers / 7：
Polymer Liquids
Polymer Glasses
Polymer Elastomers
Crystalline Polymers
Melting of Polymer Crystals
Polymer Fibers
Melt Viscosity
Polymer Glass-Transition Temperatures
Impact Strength of Polymers
Modulus of an Elastomeric Polymer Network
Polymer Melting
Naturally Occurring Biopolymers / 8：
Polysaccharides
Polypeptides and Proteins
Poly (Nucleic Acids)
DNA-Directed Protein Synthesis
Protein Folding
DNA Replication and Transcription
The Genetic Code
Index
Preface
Acknowledgments
Chapter Summary
7.

図書
図書
7. Electrochemical aspects of ionic liquids (: cloth)
edited by Hiroyuki Ohno
出版情報: Hoboken, N.J. : Wiley Interscience, c2005  xiii, 392 p. ; 25 cm
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Contributors
Preface
Acknowledgments
Importance and Possibility of Ionic Liquids / Hiroyuki OhnoChapter 1：
Physical Chemistry of Ionic Liquids, Inorganic and Organic, Protic and Aprotic / C. A. Angell ; W. Xu ; M. Yoshizawa ; A. Hayashi ; J.-P. Belieres ; P. Lucas ; M. VideaChapter 2：
Basic Electrochemistry / Part I：
General Techniques / Yasushi KatayamaChapter 3：
Electrochemical Windows of Room-Temperature Ionic Liquids / Hajime MatsumotoChapter 4：
Diffusion in Ionic Liquids and Correlation with Ionic Transport Behavior / Md. Abu Bin Hasan Susan ; Akihiro Noda ; Masayoshi WatanabeChapter 5：
Ionic Conductivity / Masahiro Yoshizawa ; Tomonobu MizumoChapter 6：
Optical Waveguide Spectroscopy / Kyoko FujitaChapter 7：
Electrolytic Reactions / Toshio FuchigamiChapter 8：
Electrodeposition of Metals in Ionic Liquids / Chapter 9：
Bioelectrochemistry / Part II：
Enzymatic Reactions / Tomoya KifazumeChapter 10：
Molecular Self-assembly in Ionic Liquids / Nobuo Kimizuka ; Takuya NakashimaChapter 11：
Solubilization of Biomaterials into Ionic Liquids / Yukinobu Fukaya ; Naomi NishimuraChapter 12：
Redox Reaction of Proteins / Chapter 13：
Ionic Devices / Part III：
Application of Ionic Liquids to Li Batteries / Hikari SakaebeChapter 14：
Application of Ionic Liquids to Photoelectrochemical Cells / Chapter 15：
Fuel Cell / Chapter 16：
Application of Ionic Liquids to Double-Layer Capacitors / Makoto UeChapter 17：
Functional Design / Part IV：
Novel Fluoroanion Salts / Rika Hagiwara ; Kazuhiko MatsumotoChapter 18：
Neutralized Amines / Chapter 19：
Zwitterionic Liquids / Asako NaritaChapter 20：
Alkali Metal Ionic Liquid / Wataru OgiharaChapter 21：
Polyether/Salt Hybrids / Chapter 22：
Electric Conductivity and Magnetic Ionic Liquids / Gunji SaitoChapter 23：
Ionic Liquids in Ordered Structures / Part V：
Ion Conduction in Plastic Crystals / Maria Forsyth ; Jennifer M. Pringle ; Douglas R. MacFarlaneChapter 24：
Liquid Crystalline Ionic Liquids / Takashi Kato ; Masafumi YoshioChapter 25：
Gel-Type Polymer Electrolytes / Part VI：
Ionic Liquid Gels / Kenji HanabusaChapter 26：
Zwitterionic Liquid/Polymer Gels / Chapter 27：
Ionic Liquidized DNA / Chapter 28：
Polymerized Ionic Liquids / Part VII：
Ion Conductive Polymers / Chapter 29：
Amphoteric Polymers / Chapter 30：
Polymer Brushes / Chapter 31：
Future Prospects / Hroyuki OhnoChapter 32：
Index
Contributors
Preface
Acknowledgments
8.

図書
図書
8. Three-dimensional free-radical polymerization : cross-linked and hyper-branched polymers
Gennady V. Korolyov, Michael M. Mogilevich
出版情報: Berlin : Springer, c2009  xv, 270 p. ; 24cm
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Three-Dimensional Free-Radical Polymerization. Cross-Linked Polymers / Part I：
Microheterogeneous Mechanism of Three-Dimensional Free-Radical Polymerization / 1：
Microheterogeneous Model of Polymerization Process / 1.1：
Polymerization Process: Stages of Formation of the Microheterogeneous Structure for Cross-Linked Polymers / 1.2：
Formation of Polymer Grains at the Initial Stage of Polymerization / 1.2.1：
Growth of Polymer Grains During Polymerization / 1.2.2：
Accretion of Polymer Grains at the Final Stages of Polymerization / 1.2.3：
Structural and Physical Processes Taking Place During Three-Dimensional Free-Radical Polymerization / 1.3：
Microsyneresis of Liquid Components in Reaction Medium / 1.3.1：
Microredistribution of Substances Dissolved in Liquid Components / 1.3.2：
Local Glass Transition of Highly Cross-Linked Micro-Volumes of Polymer / 1.3.3：
Microheterogeneous Structure of Cross-Linked Polymers / 1.4：
Interlayers Between Polymer Grains / 1.4.1：
Polymer Grains / 1.4.2：
References
Kinetic Features of Three-Dimensional Free-Radical Polymerization / 2：
Kinetic Features of Individual Stages of Polymerization / 2.1：
Initial Stage of Polymerization / 2.1.1：
Stages of Auto-Acceleration and Auto-Deceleration / 2.1.2：
Inhibited Polymerization / 2.2：
Polymerization in Solutions / 2.3：
Polymerization in Films Under the Conditions of Oxygen Diffusion / 2.4：
Vinyl Compounds / 2.4.1：
Allyl Compounds / 2.4.2：
Three-Dimensional Free-Radical Polymerization as a Tool for Macromolecular Design of Cross-Linked Polymers / 2.5：
Living Chain Three-Dimensional Radical Polymerization / 3：
Living Chains in Free-Radical Polymerization / 3.1：
Implementation of Living Chains Conditions in Three-Dimensional Free-Radical Polymerization / 3.2：
Copolymerization of Styrene with Dimethacrylates in the Presence of Alkoxyamines / 3.2.1：
Polymerization of Dimethacrylates of Poly(Ethylene Glycol)s in the Presence of Complex CuBr with Organic Ligands / 3.2.2：
Living Chain Three-Dimensional Free-Radical Polymerization as a Tool for Macromolecular Design of Cross-Linked Polymers / 3.3：
Kinetic Features of Three-Dimensional Free-Radical Copolymerization / 4：
Kinetic Features of Three-Dimensional Copolymerization of Oligomer and Vinyl Monomers / 4.1：
Variation of Copolymer Composition During Three-Dimensional Free-Radical Copolymerization of Oligomers and Vinyl Monomer / 4.2：
Critical Conversion (Gel Point) in Three-Dimensional Free-Radical Polymerization / 5：
Inapplicability of Known Critical Conversion Calculation Methods to Three-Dimensional Free-Radical Polymerization / 5.1：
Novel Approach to Calculating Critical Conversion in Three-Dimensional Free-Radical Polymerization / 5.2：
Results of Critical Conversion Calculation for Different Cases of Three-Dimensional Free-Radical Polymerization / 5.3：
Living Chains Three-Dimensional Polymerization and Copolymerization (Without Chain Termination) / 5.3.1：
Three-Dimensional Polymerization and Copolymerization with Quadratic or Linear Chain Termination / 5.3.2：
Three-Dimensional Polymerization with "Pendent" Double Bonds Taken into Account (Chain Termination by Disproportionation) / 5.3.3：
Summary of Results of Theoretical Calculations for Critical Conversion / 5.3.4：
Comparison of Results of Theoretical Calculations for Critical Conversion with Experimental Data / 5.4：
Inhibited Polymerization of Dimethacrylates / 5.4.1：
Copolymerization of Divinyl Benzene (m-DVB) with Styrene / 5.4.2：
Properties of Cross-Linked Polymers and Copolymers / 6：
Cross-Linked Poly(acrylates). Physical and Mechanical Properties / 6.1：
Influence of Chemical Structure of Oligomers upon Physical and Mechanical Properties of Cross-Linked Poly(acrylates) / 6.1.1：
Influence of Physical Network Density upon Physical and Mechanical Properties of Cross-Linked Poly(acrylates) / 6.1.2：
Cross-Linked Copolymers. Physical and Mechanical Properties / 6.2：
Mechanism of Copolymers Transition into Forced-Elastic State / 6.2.1：
Influence of Cyclization on Physical and Mechanical Properties of Copolymers / 6.2.2：
Cross-Linked Copolymers. Thermo-Mechanical Properties / 6.3：
Mechanism of Copolymers Transition into High-Elastic State / 6.3.1：
Comparison of Transitions into High-Elastic State with those into Forced-Elastic State / 6.3.2：
Diffusion-Sorption Properties of Copolymers / 6.4：
Three-Dimensional Free-Radical Polymerization. Hyper-Branched Polymers / Part II：
Synthesis of Hyper-Branched Polymers / 7：
Classification of Reactions for Hyper-Branched Polymer Synthesis / 7.1：
Synthesis of Hyper-Branched Polymers Via Three-Dimensional Free-Radical (Co)polymerization with Regulation of Polymer Chain Length / 7.2：
Regulation of Chain Length Through Initiation Rate Variation / 7.2.1：
Regulation of Chain Length by Chain Transfer Agents and Chain Transfer Catalysts / 7.2.2：
Regulation of Chain Length Through the Use of Intrachain Reactions of Chain Carrier Radicals / 7.2.3：
Regulation of Chain Length Through the Use of Molecular Oxygen as an Inhibitor / 7.2.4：
Synthesis of Hyper-Branched Polymers Via Living Chains Free-Radical Three-Dimensional Polymerization / 7.3：
Living Chains Free-Radical Three-Dimensional Polymerization as Reaction for Hyper-Branched Polymers Synthesis / 7.3.1：
Living Chains Polymerization of Vinyl Monomers with Diethyldithiocarbamate Groups / 7.3.2：
Properties and Application of Hyper-Branched Polymers / 8：
"Structure-Property" Relationship and Purposeful Generation of Hyper-Branched Polymer Properties That Are in Demand in Practice / 8.1：
Hyper-Branched Polymers as Modifiers of Polymeric Materials / 8.2：
Major Fields for Hyper-Branched Polymers Application / 8.3：
HBP: Main Achievements and Problems to Be Solved Without Delay / 8.4：
Methods for Studying Three-Dimensional Free-Radical Polymerization and Cross-Linked Polymers / 9：
Calorimetry / 9.1：
IR Spectroscopy / 9.2：
Other Methods of Kinetic Measurements / 9.3：
Light Scattering / 9.4：
EPR / 9.5：
Studying the Kinetics of Free-Radical Accumulation in Nonstationary Mode / 9.5.1：
Studying the Kinetics of Decay of Accumulated Free Radicals / 9.5.2：
Structural and Physical Studies Using EPR / 9.5.3：
NMR / 9.6：
Physicomechanical and Thermo-Mechanical Methods / 9.7：
Volumetric Method / 9.8：
Complex Methods / 9.9：
Index
Three-Dimensional Free-Radical Polymerization. Cross-Linked Polymers / Part I：
Microheterogeneous Mechanism of Three-Dimensional Free-Radical Polymerization / 1：
Microheterogeneous Model of Polymerization Process / 1.1：
9.

図書

東工大
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図書
東工大
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9. Heterogeneous kinetics : theory of Ziegler-Natta-Kaminsky polymerization (Kodansha ; Springer)
Tominaga Keii
出版情報: Tokyo : Kodansha , Berlin : Springer, c2004  xiii, 249 p. ; 25 cm
シリーズ名: Springer series in chemical physics ; 77
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Preface vii
Part I General Theory
   1 The Nature of Chemical Kinetics 3
   1.1 What Is Chemical Kinetics? 3
   1.2 How to Describe Chemical Reaction Rates? 4
   1.3 Can the Rate Equation Be Predicted from the Chemical Equation? 5
   1.4 Rate Equation of Reverse Reaction 7
   References 9
   2 Thermodynamics of Chemical Reactions 11
   2.1 The Chemical Equation of Reaction Is the Law of Conservation of Mass 11
   2.2 Thermodynamic Definition of Reactions 11
   2.3 Chemical Affinity: Thermodynamic Force of Reaction 12
   2.4 Gibbs Energy of Chemical Reaction 15
   2.5 Chemical Affinity in 1806 16
   2.6 Applications of Chemical Affinity: Direction of Chemical Changes 18
   References 19
   3 Experimental Methods and Treatment of Data 21
   3.1 Principle of Rate Measurements 21
   3.2 Treatment of Rate Data 22
   3.3 A Kinetic Measurement of Ethene Hydrogenation with H4Ru4(CO)12 24
   3.3.1 Apparatus and Procedure 25
   3.3.2 Reaction between H4Ru4(CO)12 and Ethene 26
   3.3.3 Catalytic Hydrogenation 27
   References 33
   4 Theory of Complex Reactions: Reaction Path 35
   4.1 Complex Reactions and Elementary Reactions 35
   4.2 Theory of Reaction Path 36
   4.3 Quasi-stationary State Approximation 38
   References 39
   5 Theory of Elementary Reactions 41
   5.1 Starting Point of the Theory of Elementary Reactions: The Arrhenius Equation Is an Approximation of the van't Hoff Equation 41
   5.2 Kinetic Data 46
   5.3 McC. Lewis' Collision Theory of Active Molecules 48
   5.4 Active Molecule and Critical Colliding State 49
   5.5 Potential Energy Surfaces 52
   5.6 Eyring's Theory of Activated Complex 56
   5.7 Activation Free Energy and Entropy 59
   References 62
   6 Coordination Equilibrium and Kinetics 63
   6.1 Horiuti's Theory 63
   6.1.1 Definition and Theorems 63
   6.1.2 Rates of Elementary Reactions 64
   6.2 Coordination Equilibrium 68
   6.2.1 Ideal Coordination 68
   6.2.2 Induced Coordination 70
   6.2.3 Coordination on Cluster of Sites 71
   6.2.4 Coordination on Nonuniform Surface Sites 75
   6.2.5 Relation between Two Models of Coordination on Uniform and Nonuniform Sites 76
   6.2.6 Theory of Coordination on Nonuniform Sites 78
   6.3 Coordination Reactions 81
   6.3.1 Turnover Frequency 81
   6.3.2 Michaelis-Menten Equatlon 83
   6.3.3 Relation between Energies of Coordination and Activation 85
   References 85
Part II Kinetics of Ziegler-Natta-Kaminsky Polymerization
   7 Traditional Kinetics of Ziegler-Natta-Kaminsky Polymerization 89
   7.1 Historical Introduction 89
   7.2 Kinetic Observables and Variables 91
   7.2.1 Rate of Polymerization 91
   7.2.2 Molecular Weight Distribution 92
   7.2.3 Polymerization Time 94
   7.3 Traditional Kinetics 97
   7.3.1 Ideal Kinetic Model: Stationary Rate and MWD 97
   7.3.2 Extension of the Ideal Model 102
   7.3.3 Plausibility and Uncertainty of Traditional Kinetics 108
   References 111
   8 Coordination Kinetics of Ziegler-Natta-Kaminsky Polymerization 113
   8.1 Critical State and Its Initial States 113
   8.2 Monomer Concentration in Solution or Partial Pressure in Gas Phase: Which Is Better as a Kinetic Variable? 116
   8.3 Coordination Kinetics of Elementary Reactions of Growing Polymers: Which Is the Rate-determining Step, Coordination or Insertion? 118
   8.4 Transfer Reaction by Monomer and the First Monomer Insertion 121
   8.5 Solvent Effect 124
   8.6 Coordination Kinetics of Copolymerization 127
   References 129
   9 Homogeneous Polymerization 131
   9.1 Living Polymerization of Propene with V(acac)3/AIR2X Catalysts 131
   9.1.1 Principal Kinetics of Living Polymerization with V(acac)3/Al(C2H5)2Cl 133
   9.1.2 Further Analysis in Accordance with Coordination Kinetics 136
   9.1.3 Reactions of Living Polypropylene with Additive 140
   9.2 Pseudo-living Polymerization of Propene with Soluble Catalysts 145
   9.2.1 Ethene Polymerization with Cp2Ti(C2H5)Cl/Al(C2H5)Cl2 145
   9.2.2 MMA Polymerization with Me2C(Cp)(Ind)Zr(Me)(thf)+BPh4- 146
   9.3 Stationary Propene Polymerization with Vanadium-based Catalysts 151
   9.3.1 Molecular Weight Distribution at Elevated Temperatures 155
   9.4 Kinetics of Polymerization with Metallocene/MAO Catalysts－Trigger, Single-site Two-state or Slow-initiation Model 156
   9.4.1 Kinetic Features and Topics of Kaminsky Polymerization 157
   9.4,2 Trigger Model and Slow-initiation Model 159
   9.4.3 Single-site Two-state Model 160
   References 161
   10 Propene Polymerization with Heterogeneous Ziegler-Natta Catalysts: TiCl3-and MgCl2-supported TiCl4 Catalysts 163
   10.1 Transitional Analysis of Mass Transfer 163
   10.1.1 Pure Polymerization Rate Free from Mass Transfer Effect 167
   10.2 Kinetic Behavior of TiCl3/Al(C2H5)2Y(Y=C2H5, H, Cl, Br, I) 168
   10.2.1 Polymerization Rate during Polymerization 169
   10.2.2 Temperature Dependence of the Stationary Rate 178
   10.2,3 Effect of Hydrogen Addition 179
   10.3 Elimination and Substitution of Cocatalyst during Polymerization: Kinetic Relaxation Method 179
   10.3.1 Rate of Polymerization after Elimination of Cocatalyst 180
   10.3.2 Reversible Changes in the Kinetic Curve with Cocatalyst Substitutions 183
   10.3.3 Pretreatment of TiC13 with Various Halide Compounds 187
   10.3.4 MWDs during Polymerization 188
   10.3.5 Effects of Temperature, Hydrogen Pressure, Monomer Pressure and Cocatalyst Concentration 190
   10.4 MgCl2-supported TiCl4/Al(C2H5)3 Catalyst 192
   10.4.1 Dependence of Polymerization Rate on Time 193
   10.4.2 Kinetic Behavior during Polymerization 195
   10.4.3 Effect of External Electron Donor 202
   10.4,4 Elimination of Cocatalyst during Polymerization 203
   10.4.5 Quasi-living Stages 203
   10.5 Radio-CO Tagging Method and CO Quenching Method 205
   References 213
   11 Kinetic Mechanism of Molecular Weight Distribution and Isotacticity 215
   11.1 Kinetic Features of Molecular Weight Distribution and Isotacticity 215
   11.2 Rival Theories of Broad MWDS 216
   11.2.1 Broad MWDS in the Stationary State 216
   11.2.2 Experimental Test of Rival Theories for Stationary Broad MWDs 223
   11.2.3 MWDs during Quasi-living Polymerization 226
   11.2.4 Possible Kinetic Models of Broadening MWDs 230
   11.3 Kinetic Model of Isotacticity 233
   11.3.1 Characterization of Stereoregularity 233
   11.3.2 Kinetic Models of Stereospecificity 240
   References 243
   Index 245
Preface vii
Part I General Theory
   1 The Nature of Chemical Kinetics 3
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