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1.

図書

図書
Alexander McKillop
出版情報: New York : Pergamon, 1997  xix, 153 p. ; 25 cm
シリーズ名: Tetrahedron organic chemistry series ; v. 16
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Selected Problems: A tandem route to 1,2,3,4-tetrasubstituted naphthalenes
The Hooker oxidation
Benzopyrene synthesis - by accident
Lactone ammonolysis
Acid-catalysed condensation of indole with acetone
Flash vacuum pyrolysis of o-xylylene dimers
A ""stable enol"" that doesn't exist
Reaction of benzothiazole with DMAD
Ring contractions of a dibenzothiepinone
Rearrangement of 6-hydroxyprotopine to dihydrosanguinarine
An intramolecular Wittig reaction
Easy contruction of a tricyclic indole related to
Selected Problems: A tandem route to 1,2,3,4-tetrasubstituted naphthalenes
The Hooker oxidation
Benzopyrene synthesis - by accident
2.

図書

図書
J. L. Malleron, J. C. Fiaud and J. Y. Legros
出版情報: London : Academic, c1997  304 p. ; 30 cm
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Abbreviations
Introduction
Graphical Abstracts of Reaction Numbers (RXN)
Reactions Catalyzed by Palladium Complexes: Cross-Coupling of Organometallics with RX Derivatives
Cross-Coupling of Organometallicswith RCOX Derivatives
Cross-Coupling of Siloxycyclopropanes with RX and RCOX Derivatives
Cross-Coupling of Terminal Alkynes with RX Derivatives
Intermolecular HECK Reaction
Intramolecular HECK Reaction
Intramolecular Coupling of Di(Vinyl Halides)
Tandem HECK-Anion Capture Process of Alkenes, Alkyenes, Alkynes, Allenes and Dienes
Tandem HECK-Anion Capture Process of Norbonene and Related Compounds
Tandem Arylsulfonation-Cyclization Process
Tandem Cyclization-Anion Capture (-Carbonylation) Processof Alkenes and Alkynes
Tandem Cyclization-Anion Capture (-Carbonylation) Process of Ene-Vinyl, Ene-Aryl, and Ene-Alkyl Halides
Tandem Cyclization-Anion Capture Process of Yne-Vinyl and Yne-Aryl Halides
Hydroarylation and Hydrovinylation of Alkenes andAlkynes
Reduction of Alkenes
Semihydrogenation of Alkynes and 1,3-Dienes
Hydroboration, Hydrogennyladon, Hydrosilylation and Hydrostannation of Alkynes, Allenes, Dienes, and Enynes
Hydroselenation of Alkynes
1,4-Disilyation of Conjugated Enones
Hydrocarboxylation, Hydrocarboalkoxylation and Hydrocarboamination of Alkenes and Alkynes
Tandem Carbonylation-Arylation with Alkynes
1,2-Dimetallation of Alkynes and Alkenes and Related Reactions
1,2-Dimetallation of Isonitriles
1,2-Dimetallation of Allenes
Coupling of Aryl Derivatives with Alkenes Involving a Pd(II) Catalyst
Homocoupling of Aryl and Vinyl Derivatives
Codimerization of Alkynes
Codimerization of Terminal Alkynes with Allenes
Codimerization of Alkynes and Allyl Halides
Cyclopropanation of Alkenes and 1,3-Dienes by Diazomethane
Rearrangement of (-Hydroxy Diazo Compounds
Substitution, Addition, and Elimination on Pro-(-Allyl Substrates
[3,3]-Sigmatropic Rearrangement and [1,3]-Shift on Allylic Derivatives
1,3-Diene Monoepoxide Rearrangement
Ring Extension of Cyclobutane Derivatives
[3+2], [3+4], [3+6], [1+2] Cycloadditions
Intramolecular Ene-Like Reactions
Cyclization of Hexatrienolate Derivatives
Amination or Amidation of Alkenes
Alkoxylation of Alkenes and Alkynes
Acetalization of Alkenes
Allylic Acyloxylation of Cycloalkenes
Tandem Acyloxylation-Cyclization of 1,5-Dienes
Tandem Acycloxychlorination-Cyclization of 1,6-Dienes
1,4-Acycloxychlorination of 1,3-Dienes
1,4-Diacyloxylation of 1,3-Dienes and Related Reactions
Intramolecular Amination, Alkoxylation of Acyloxylation of Alkynes
Tandem Intramolecular Amination, Alkoxylation, or Acyloxylation-Allylation of Alkynes and Allenes
Tandem Intramolecular Amination, Alkoxylation, or Acyloxylation-Carbonylation of Alkynes
Intramolecular Amination or Alkoxylation of Alkenes
Tandem Intramolecular Amination or Alkoxylation-Carbonylation of Alkenes and Allenes
Reductive Cyclization with Diynes and Enynes
Cycloisomerization of Diynes and Enynes
Cycloaddition of Aziridines with Carbodiimides
Telomerization of 1,3-Dienes with Nucleophiles
WACKER Process
Preparation of Ketones from Alcohols or Derivatives via a (-Hydride Elimination
Preparation of ((-Unsaturated Carbonyl Derivatives via a (-Hydride Elimination
Preparation of (-Diketones Derivatives via an Oxidative Rearrangement of a Propargyl Acetate
Carbonylation
Isomerization of Alkynes
Addition of Thiols to Alkynes
Preparation of Allylic Acetates from Alkynes by Tandem Redox-Addition
Tandem Cyclization-Capture Process of Enynes
Aldol-Like Condensation of Enol Esters with Aldehydes
Addition of Fluoroalkyl Iodides to Alkenes or Alkynes via a Pd(I) Species
Intermolecular Tandem Carbonylation-Coupling-Cyclization Process of Aryl Halides with Terminal Alkynes.Intramolecular Coupling of Aryl Halides with Arenes
Tandem Intramolecular Alkoxylation-Vinylation of Alkenes
Carbonylative [2+2] Cycloaddition
Dicarboalkoxylation of Alkenes
Addition of Pronucleophile
Abbreviations
Introduction
Graphical Abstracts of Reaction Numbers (RXN)
3.

図書

図書
Miloš Hudlický
出版情報: Washington, DC : American Chemical Society, 1990  xx, 433 p. ; 24 cm
シリーズ名: ACS monograph ; no. 186
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Oxidation Agents
Dehydrogenations
Oxidations
Preparative Procedures
Oxidation Agents
Dehydrogenations
Oxidations
4.

図書

図書
Marye Anne Fox, James K. Whitesell
出版情報: Boston : Jones and Bartlett, c1994  xxvi, 870 p. ; 29 cm
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Structure and Bonding in Alkanes / 1:
Alkenes, Aromatic Hydrocarbons, and Alkynes / 2:
Functional Groups Containing Heteroatoms / 3:
Chromatography and Spectroscopy / 4:
Stereochemistry / 5:
Understanding Organic Reactions / 6:
Mechanisms of Organic Reactions / 7:
Substitution by Nucleophiles at sp3-Hybridized Carbon / 8:
Elimination Reactions / 9:
Addition to Carbon-Carbon Multiple Bonds / 10:
Electrophilic Aromatic Substitution / 11:
Nucleophilic Addition and Substitution at Carbonyl Groups / 12:
Substitution Alpha to Carbonyl Groups / 13:
Skeletal-Rearrangement Reactions / 14:
Multistep Syntheses / 15:
Polymeric Materials / 16:
Naturally Occurring Oxygen-Containing Compounds / 17:
Naturally Occurring Nitrogen-Containing Compounds / 18:
Noncovalent Reactions and Molecular Recognition / 19:
Catalyzed Reactions / 20:
Cofactors for Biological Redox Reactions / 21:
Energy Storage in Organic Molecules / 22:
Molecular Basis for Drug Action / 23:
Structure and Bonding in Alkanes / 1:
Alkenes, Aromatic Hydrocarbons, and Alkynes / 2:
Functional Groups Containing Heteroatoms / 3:
5.

図書

図書
John McMurry
出版情報: Pacific Grove, Calif. : Brooks/Cole Pub. Co., c1994  xx, 536, 16 p. ; 25 cm
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Preface
A Note for Students
Structure and Bonding; Acids and Bases / 1:
Atomic Structure / 1.1:
Electron Configuration of Atoms / 1.2:
Development of Chemical Bonding Theory / 1.3:
The Nature of Chemical Bonds / 1.4:
Forming Covalent Bonds: Valence Bond Theory / 1.5:
Hybridization: sp[superscript 3] Orbitals and the Structure of Methane / 1.6:
Hybridization: sp[superscript 3] Orbitals and the Structure of Ethane / 1.7:
Hybridization: sp[subscript 2] Orbitals and the Structure of Ethylene / 1.8:
Hybridization: sp Orbitals and the Structure of Acetylene / 1.9:
Polar Covalent Bonds: Electronegativity / 1.10:
Acids and Bases: The Bronsted--Lowry Definition / 1.11:
Acids and Bases: The Lewis Definition / 1.12:
The Nature of Organic Compounds: Alkanes / 2:
Functional Groups / 2.1:
Alkanes and Alkyl Groups: Isomers / 2.2:
Naming Branched-Chain Alkanes / 2.3:
Properties of Alkanes / 2.4:
Conformations of Ethane / 2.5:
Drawing Chemical Structures / 2.6:
Cycloalkanes / 2.7:
Cis--Trans Isomerism in Cycloalkanes / 2.8:
Conformations of Some Cycloalkanes / 2.9:
Axial and Equatorial Bonds in Cyclohexane / 2.10:
Conformational Mobility of Cyclohexane / 2.11:
The Nature of Organic Reactions: Alkenes / 3:
Naming Alkenes / 3.1:
Electronic Structure of Alkenes / 3.2:
Cis--Trans Isomers of Alkenes / 3.3:
Sequence Rules: The E,Z Designation / 3.4:
Kinds of Organic Reactions / 3.5:
How Reactions Occur: Mechanisms / 3.6:
The Mechanism of an Organic Reaction: Addition of HCl to Ethylene / 3.7:
Describing a Reaction: Reaction Energy Diagrams and Transition States / 3.8:
Describing a Reaction: Intermediates / 3.9:
Reactions of Alkenes and Alkynes / 4:
Addition of HX to Alkenes: Hydrohalogenation / 4.1:
Orientation of Alkene Addition Reactions: Markovnikov's Rule / 4.2:
Carbocation Structure and Stability / 4.3:
Addition of H[subscript 2]O to Alkenes: Hydration / 4.4:
Addition of X[subscript 2] to Alkenes: Halogenation / 4.5:
Addition of H[subscript 2] to Alkenes: Hydrogenation / 4.6:
Oxidation of Alkenes: Hydroxylation and Cleavage / 4.7:
Biological Addition Reactions of Alkenes / 4.8:
Addition of Radicals to Alkenes: Polymers / 4.9:
Conjugated Dienes / 4.10:
Stability of Allylic Carbocations: Resonance / 4.11:
Drawing and Interpreting Resonance Forms / 4.12:
Alkynes and Their Reactions / 4.13:
Aromatic Compounds / 5:
Structure of Benzene: The Kekule Proposal / 5.1:
Structure of Benzene: The Resonance Proposal / 5.2:
Naming Aromatic Compounds / 5.3:
Electrophilic Aromatic Substitution Reactions: Bromination / 5.4:
Other Electrophilic Aromatic Substitution Reactions / 5.5:
The Friedel--Crafts Alkylation and Acylation Reactions / 5.6:
Substituent Effects in Electrophilic Aromatic Substitution / 5.7:
An Explanation of Substituent Effects / 5.8:
Oxidation and Reduction of Aromatic Compounds / 5.9:
Polycyclic Aromatic Hydrocarbons / 5.10:
Organic Synthesis / 5.11:
Stereochemistry / 6:
Stereochemistry and the Tetrahedral Carbon / 6.1:
The Reason for Handedness in Molecules: Chirality / 6.2:
Optical Activity / 6.3:
Specific Rotation / 6.4:
Pasteur's Discovery of Enantiomers / 6.5:
Sequence Rules for Specifying Configuration / 6.6:
Diastereomers / 6.7:
Meso Compounds / 6.8:
Molecules with More Than Two Stereocenters / 6.9:
Racemic Mixtures and the Resolution of Enantiomers / 6.10:
Physical Properties of Stereoisomers / 6.11:
A Brief Review of Isomerism / 6.12:
Chirality in Nature / 6.13:
Alkyl Halides / 7:
Naming Alkyl Halides / 7.1:
Preparing Alkyl Halides / 7.2:
Reactions of Alkyl Halides: Grignard Reagents / 7.3:
Nucleophilic Substitution Reactions / 7.4:
The S[subscript N]2 Reaction / 7.5:
The S[subscript N]1 Reaction / 7.6:
Eliminations: The E2 Reaction / 7.7:
Eliminations: The E1 Reaction / 7.8:
A Summary of Reactivity: S[subscript N]1, S[subscript N]2, E1, E2 / 7.9:
Substitution Reactions in Living Organisms / 7.10:
Alcohols, Phenols, and Ethers / 8:
Naming Alcohols, Phenols, and Ethers / 8.1:
Properties of Alcohols, Phenols, and Ethers: Hydrogen Bonding / 8.2:
Properties of Alcohols and Phenols: Acidity / 8.3:
Synthesis of Alcohols / 8.4:
Reactions of Alcohols / 8.5:
Synthesis and Reactions of Phenols / 8.6:
Synthesis and Reactions of Ethers / 8.7:
Cyclic Ethers: Epoxides / 8.8:
Thiols and Sulfides / 8.9:
Aldehydes and Ketones: Nucleophilic Addition Reactions / 9:
The Nature of Carbonyl Compounds / 9.1:
Naming Aldehydes and Ketones / 9.2:
Synthesis of Aldehydes and Ketones / 9.3:
Oxidation of Aldehydes / 9.4:
Nucleophilic Addition Reactions of Aldehydes and Ketones: Reduction / 9.5:
Nucleophilic Addition of Water: Hydration / 9.6:
Nucleophilic Addition of Alcohols: Acetal Formation / 9.7:
Nucleophilic Addition of Amines: Imine Formation / 9.8:
Nucleophilic Addition of Grignard Reagents: Alcohol Formation / 9.9:
Conjugate Nucleophilic Addition Reactions / 9.10:
Some Biological Nucleophilic Addition Reactions / 9.11:
Carboxylic Acids and Derivatives / 10:
Naming Carboxylic Acids and Derivatives / 10.1:
Occurrence and Properties of Carboxylic Acids / 10.2:
Synthesis of Carboxylic Acids / 10.3:
Nucleophilic Acyl Substitution Reactions / 10.4:
Reactions of Carboxylic Acids / 10.5:
Chemistry of Acid Halides / 10.6:
Chemistry of Acid Anhydrides / 10.7:
Chemistry of Esters / 10.8:
Chemistry of Amides / 10.9:
Chemistry of Nitriles / 10.10:
Polymers from Carbonyl Compounds: Nylons and Polyesters / 10.11:
Carbonyl Alpha-Substitution Reactions and Condensation Reactions / 11:
Keto--Enol Tautomerism / 11.1:
Reactivity of Enols: The Mechanism of Alpha-Substitution Reactions / 11.2:
Alpha Halogenation of Aldehydes and Ketones / 11.3:
Acidity of Alpha Hydrogen Atoms: Enolate Ion Formation / 11.4:
Reactivity of Enolate Ions / 11.5:
Alkylation of Enolate Ions / 11.6:
Carbonyl Condensation Reactions / 11.7:
Condensations of Aldehydes and Ketones: The Aldol Reaction / 11.8:
Dehydration of Aldol Products: Synthesis of Enones / 11.9:
Condensations of Esters: The Claisen Condensation Reaction / 11.10:
Biological Carbonyl Reactions / 11.11:
Amines / 12:
Naming Amines / 12.1:
Structure and Properties of Amines / 12.2:
Basicity of Amines / 12.3:
Synthesis of Amines / 12.4:
Reactions of Amines / 12.5:
Heterocyclic Amines / 12.6:
Alkaloids: Naturally Occurring Amines / 12.7:
Structure Determination / 13:
Infrared Spectroscopy and the Electromagnetic Spectrum / 13.1:
Infrared Spectroscopy of Organic Molecules / 13.2:
Ultraviolet Spectroscopy / 13.3:
Interpreting Ultraviolet Spectra: The Effect of Conjugation / 13.4:
Nuclear Magnetic Resonance Spectroscopy / 13.5:
The Nature of NMR Absorptions / 13.6:
Chemical Shifts / 13.7:
Chemical Shifts in [superscript 1]H NMR Spectra / 13.8:
Integration of [superscript 1]H NMR Spectra: Proton Counting / 13.9:
Spin--Spin Splitting in [superscript 1]H NMR Spectra / 13.10:
Uses of [superscript 1]H NMR Spectra / 13.11:
[superscript 13]C NMR Spectroscopy / 13.12:
Biomolecules: Carbohydrates / 14:
Classification of Carbohydrates / 14.1:
Configurations of Monosaccharides: Fischer Projections / 14.2:
D,L Sugars / 14.3:
Configurations of Aldoses / 14.4:
Cyclic Structures of Monosaccharides: Hemiacetal Formation / 14.5:
Monosaccharide Anomers: Mutarotation / 14.6:
Reactions of Monosaccharides / 14.7:
Polysaccharides / 14.9:
Other Important Carbohydrates / 14.10:
Cell-Surface Carbohydrates and Carbohydrate Vaccines / 14.11:
Biomolecules: Amino Acids, Peptides, and Proteins / 15:
Structures of Amino Acids / 15.1:
Isoelectric Points / 15.2:
Peptides and Proteins / 15.3:
Covalent Bonding in Peptides / 15.4:
Peptide Structure Determination: Amino Acid Analysis / 15.5:
Peptide Sequencing: The Edman Degradation / 15.6:
Peptide Synthesis / 15.7:
Classification of Proteins / 15.8:
Protein Structure / 15.9:
Enzymes / 15.10:
How Do Enzymes Work? Citrate Synthase / 15.11:
Biomolecules: Lipids and Nucleic Acids / 16:
Lipids / 16.1:
Fats and Oils / 16.2:
Soaps / 16.3:
Phospholipids / 16.4:
Steroids / 16.5:
Nucleic Acids and Nucleotides / 16.6:
Structure of DNA / 16.7:
Base Pairing in DNA: The Watson--Crick Model / 16.8:
Nucleic Acids and Heredity / 16.9:
Replication of DNA / 16.10:
Structure and Synthesis of RNA: Transcription / 16.11:
RNA and Protein Biosynthesis: Translation / 16.12:
Sequencing DNA / 16.13:
The Polymerase Chain Reaction / 16.14:
The Organic Chemistry of Metabolic Pathways / 17:
An Overview of Metabolism and Biochemical Energy / 17.1:
Catabolism of Fats: [beta]-Oxidation Pathway / 17.2:
Catabolism of Carbohydrates: Glycolysis / 17.3:
The Citric Acid Cycle / 17.4:
Catabolism of Proteins: Transamination / 17.5:
The Organic Chemistry of Metabolic Pathways: A Summary / 17.6:
Appendixes
Nomenclature of Polyfunctional Organic Compounds / A:
Glossary / B:
Answers to Selected In-Chapter Problems / C:
Index
Preface
A Note for Students
Structure and Bonding; Acids and Bases / 1:
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