| Preface |
| Recent Developments of Precision Polymers and Nano-organized Systems in Japan: An Overview 1 |
| I. Sequentially Controlled Polymers |
| I-1. Control of Molecular Weight, Its Distribution and Stereoregularity |
| Development of a Synthetic Method of Ordered Polymers with A-C-B Sequency by Alternating Copolymerization and Transformation of Polymer Backbones A. Kameyama 11 |
| Controlled Polymerization Using Mesopores T. Aida 15 |
| Ni-catalyzed Living Polymerization of Allenes M. Suzuki, I. Tomita and T. Endo 19 |
| Synthesis of Stereoregular End-functional Polymers and Construction of Uniform Polymer Architecture T. Kitayama 23 |
| Novel Silicon-containing Amphiphilic Polymers: Synthesis and Creation of Polymeric Nanostructures H. Yamaoka and K. Matsumoto 27 |
| Silole and Germole Incorporated Polysilanes H. Sakurai 31 |
| Iー2. ABC Triblock Copolymers and Sequential Polymers |
| Precise Synthesis of Multiblock Copolymers and Telechelics and Their Surface Nanostructure T. Ishizone and S. Nakahama 35 |
| Synthesis of Sequential Polymers by Living Cationic Polymerization for Nano-organized Polymer Architectures M. Sawamoto 39 |
| Novel Nanopattern Formation in ABC Triblock Copolymers H. Hasegawa, Y. Tanaka, T. Hashimoto, K. Sugiyama, A. Hirao and S. Nakahama 43 |
| Synthesis of Sequential Star-shaped Polymers with Well-defined Structures by Living Cationic Polymerization S. Kanaoka 47 |
| Effect of End Group Chemistry on Surface Aggregation Structure of Diblock Copolymer and Polymer Blend Thin Films A. Takahara, S. Nakahama and T. Kajiyama 51 |
| Syntheses of Bioactive Polysaccharides with Contolled Sequences K. Hatanaka 55 |
| I-3 Organized Structure of a Single Macromolecule |
| Unimolecular Micelles of Amphiphilic Polyelectrolytes Y. Morishima 59 |
| II. Chiral Polymers |
| II-1. Catalysts for Asymmetric Polymerization |
| Synthesis of Chiral Organotransition Metal Complexes and Their Catalysis in Screw-Sense-Selective Polymerization of Isocyanides S. Takahashi, K. Onitsuka and F. Takei 65 |
| Asymmetric Alternating Copolymerization of Olefins with Carbon Monoxide K. Nozaki 69 |
| II-2. Synthesis of Chiral Polymers |
| Efficient Methods for Asymmetric Synthesis of Functional Organic Compounds T. Nakai 73 |
| Synthesis of Optically Active Polyolefins Having a Helical Structure K. Soga, H. Oonishi and T. Uozumi 77 |
| Synthesis of Optically Active Polymers Using Novel Asymmetric Polyaddition Reactions S. Itsuno 81 |
| Synthesis and Structure of Optically Active Helical Polymers Having Axially Chiral Units in the Main Chain T. Takata 85 |
| Polymerization of Chiral Cyclic Carbonates Catalyzed by Rare Earth Metal Complexes E. Ihara, N. Kitamura and H. Yasuda 89 |
| Chirality Induction Arising from Chiral Twist of Templates in Cyclocopolymerization K. Yokota 93 |
| Synthesis of Novel Liquid Crystalline Polymers with Helical or Molecular Asymmetric Structure Y. Kawakami 97 |
| Synthesis and Characterization of Stereoregular and Chiral Substituted Polyacetylenes T. Masuda and R. Nomura 101 |
| Optically Active Nano-molecules Consisting of Chiral Helicenedicarboxylic Acid M. Yamaguchi 105 |
| Asymmetric Anionic Polymerization of N-Substituted Maleimide with Organometal-Chiral Ligand Complex T. Oishi 109 |
| II-3. Properties of Chiral Polymers |
| Helicity Induction and Chirality Recognition on Stereoregular Polyphenylacetylenes and Polythiophene Derivatives E. Yashima and Y. Okamoto 113 |
| New Isocyanurate-Polypeptide Organized Systems: Design and Ability of Chiral Recognition H. Sugimoto 117 |
| Chiral Molecular Square and 41 Helical Chain Containing Optically Active Spirosilanes as Key Building Units S. Yamaguchi and K. Tamao 121 |
| III. Building Blocks of Nano-organized Systems - Synthesis and Structure |
| III-1. Metallic and Inorganic Nano-particles |
| Synthesis, Structure and Catalysis of Metallic Nanoclusters N. Toshima and Y. Shiraishi 127 |
| Templating Fabrication of Platinum Nanoparticles and Wires in Mesoporous Channels of FSM-16 - Structural Characterization and Catalytic Behaviors A. Fukuoka and M. Ichikawa 131 |
| Size Control of Ultrafine Metal Particles by Hybridization with Polymer and Their Two-dimensional Arrangement M. Miyake 135 |
| III-2. Spherical Organic Molecules - Fullerenes, Dendrimers and Microspheres |
| Regioselective Synthesis of [60] Fullerene Bisadducts and Their Properties J. Nishimura 139 |
| Block Dendrimers as Spherical Elemental Units for Nano-Organized Systems M. Okada and K. Aoi 143 |
| Synthesis of Hyperbranched Aromatic Polymers from Self-polycondensation of AB n Type Monomers M. Kakimoto and M. Jikei 147 |
| III-3. Cyclodextrin and Polyrotaxane |
| Construction of αーCyclodextrin-based Pseudo-rotaxanes and Rotaxanes with 2-D or 3-D Structure N. Nakashima 151 |
| Solution Property of a Polyrotaxane in Relation to Stimuli-responsive Movement of β-Cyclodextrins H. Fujita, T. Ooya and N. Yui 155 |
| IV. Organization of Macromolecules in Nano-Scale |
| IV-1. Supramolecular Assemblies |
| Design and Construction of Supramolecular Nanotubules A. Harada 161 |
| Supramolecular Liquid Crystals and Liquid-crystalline Gels: Self-organization of Dynamically Functional Materials T. Kato 165 |
| Membrane Morphology Controlled by Chirality K. Kano and S. Negi 169 |
| Supramolecular Assemblies of Steroids: Nano-Organized Hybrid Systems Based on Chiral and Sequential Carbon Chains M. Miyata and K. Sada 173 |
| Construction of Two-dimensional Nano-organized Systems Functionalized as Artificial Cell-surface Receptors J. Kikuchi 177 |
| Synthesis of Hybrid Polymers Which Bind Guests in Water by Hydrogen Bond Formation H. Asanuma and M. Komiyama 181 |
| Functional 2D Organized Supramolecules by Coordinate Bonds Y. Kobuke 185 |
| IV-2. Layer-by-Layer Assemblies |
| Recent Developments in Preparation of Cross-linked Ultrathin Polymer Films T. Kunitake 189 |
| Alternating Layer-by-Layer Vapor Deposition Polymerization in a Nylon System N. Okui 193 |
| Application of Self-assembled Clay as an Electrode Modifier Y. Hotta, A. Yamagishi, M. Takahashi and M. Taniguchi 197 |
| IV-3. Organized Systems with Biomacromolecules |
| Toward the Creation of an Artificial Cellular System K. Yoshikawa and S. Nomura 201 |
| Hierarchical Structuring of DNA and DNA-Mimetics Template Polymerization of Nucleobase Monolayers Based on Molecular Recognition and Mesoscopic Patterning of DNA M. Shimomura, J. Matsumoto, T. Sawadaishi and K. Ijiro 205 |
| Assembly of Metal Complexes by DNA S. Takenaka 209 |
| Molecular Design of Polypeptides and Proteins with Artificial Electron Transporting Functions M. Sisido 213 |
| Electron Transfer Reaction of Glucose Oxidase Conjugated with Redox Active Polymers M. Watanabe, K. Ban, Y. Tamada and T. Saito 217 |
| Synthesis and Accelerated Electron Transfer Reaction of Protein Hybrids H. Ohno 221 |
| V. Hybrid Nano-organized Systems |
| V-1. Metal-organic Hybrid Systems |
| Preparation and Characterization of Micelles, Vesicles and Metal Nanoparticles Protected by Organic Molecules T. Tominaga 227 |
| Catalyc Functions of Hybrid Vesicles Composed of Artificial Lipids and Metal Complexes Y. Hisaeda 231 |
| V-2. Inorganic-organic Hybrid Systems |
| Crystalline Calcium Carbonate Containing Copoly(carboxylate-amide) with Sterically Disposed NH...O Hydrogen Bond N. Ueyama, H. Kozuki, T. Okamura and A. Nakamura 235 |
| Unique Inorganic-organic Hybrid Systems Self-organized by Triple Hydrogen-bonding Interaction and Their Functions H. Masuda, H. Kitamura, K. Jitsukawa and H. Einaga 239 |
| Preparation and Characterization of CdS Nanocluster/Polymer Hybrid Systems N. Kitamura and H. Yao 243 |
| V-3. Macromolecules on the Surface |
| Stepwise Fabrication of Ultrathin Polymer Films by a Repetitive Adsorption/Drying Process T. Serizawa and M. Akashi 247 |
| Accumulation of Polymer Chains on Various Polymer Colloids H. Kitano 251 |
| Construction, Characterization and Application of Nano-Organized Electrode Systems T. Ohsaka 255 |
| VI. New Functions and Properties of Nano-organized Systems |
| VI-1. Electronic and Magnetic Functions and Properties |
| Development of an Organosulfur-conducting Polymer Composite for Lithium Batteries with High Energy Density N. Oyama, F. Matsumoto, Y. Inatomi and O. Hatozaki 261 |
| Gelators and Nano-organized Systems: Preparation and Characterization of Organogel Electrolytes Using Gelators K. Hanabusa and H. Shirai 265 |
| Creation of Novel Families of Low Molecular Weight Organic Gels and Their Properties and Functions Y. Shirota 269 |
| Mechanistic Analysis of Charge Transport in Nano-structured Polymers M. Kaneko 273 |
| Mono- and Multilayer Film Formation with Organosulfur Compounds on Metal Surface and Protection Ability of the Film against Corrosion of Copper H. Tsutsumi 277 |
| Synthesis and Properties of Multinuclear Polymeric Complexes through Isonitrile Bridges T. Iyoda 281 |
| Nano-size Extension of High-spin Polymers and Their Magnetic Property H. Nishide 285 |
| VI-2. Photonic Functions and Properties |
| Photoresponsive Two-dimensional Polymer Assemblies T. Seki 289 |
| Nano-organized Polymer Assemblies with Molecular Photofunctionality T. Miyashita 293 |
| Structure and Photoreaction of Molecular Monolayers and Template Surfaces Using Particle Array Films T. Miwa and A. Fujishima 297 |
| Hole Burning Spectroscopy of Dye/Polymer Hybrid Nano-organized Systems K. Horie 301 |
| Preparation of Hybrid Nano Composites of Liquid Crystalline Polymer/Chromophore Systems and Their Application to Active Optical Devices T. Watanabe, Y. Hirose, M. Tokita, S. Miyata and J. Watanabe 305 |
| A Study of Photoconversion Processes in Hybrid Nano-organized Films Composed of Polymers and Photofunctional Dyes S. Yamada 309 |
| Construction of Nanosize Heterojunction Using Inorganic/Organic Ordered Materials for Efficient Photoenergy Conversion S. Yanagida, K. Murakoshi, Y. Wada and T. Kitamura 313 |
| VI-3. Biomedical Functions and Properties |
| Design of Two-Dimensional Glycolipid Membranes and Their Functions Y. Okahata, S. Fukusho, T. Mori and T. Sato 317 |
| A Core-Shell Type Polymeric Micelle with Pilot Molecules on the Surface for Use as a High-performance Drug Vehicle Y. Nagasaki and K. Kataoka 321 |
| Preparation of Microspheres Having Functional Hairy Layers and Their Properties H. Kawaguchi 325 |
| Nano-organized Hybrid Systems Comprising DNA M. Maeda 329 |
| Biologically Active Compound-induced Structural Changes of Analogous Macromolecules to Biopolymers and Their Molecular Recognition T. Aoki and K. Sanui 333 |
| Development of Bioactive Sugar Complexes and Sugar-linked Polyamines S. Yano and T. Kakuchi 337 |
| Subject Index 341 |
| Authors' Index 349 |
| Preface |
| Recent Developments of Precision Polymers and Nano-organized Systems in Japan: An Overview 1 |
| I. Sequentially Controlled Polymers |
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