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図書

図書
出版情報: 東京 : 日本産業廃棄物処理振興センター, 1998.4
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図書

図書
高杉良[著]
出版情報: 東京 : 講談社, 1998.2  333p ; 15cm
シリーズ名: 講談社文庫
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図書

東工大
目次DB

図書
東工大
目次DB
Tomoya Kitazume and Takashi Yamazaki
出版情報: Tokyo : Kodansha , Amsterdam : Gordon and Breach Science Publishers, 1998  vii, 260p. ; 24 cm
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Preface
General Remarks
Abbreviations
Chapter 1 Introduction 1
   1.1 Effect of Fluorine on Physical Properties 1
   1.1.1 Mimic and Block Effects 1
   1.1.2 Effect of the Electron-withdrawing Nature of Fluorine 3
   1.1.2.1 Deactivation Effect 3
   1.1.2.2 Activation Effect 5
   1.1.3 Conformational Preference Including Hydrogen Bonding Ability 7
   1.1.4 Steric Size of Fluorine-containing Groups 9
   1.2 Effect of Fluorine on Chemical Reactivity 10
   1.2.1 Stability of Cationic or Anionic Species Next to Fluorine or Fluoroalkyl Groups 10
   1.2.2 SN1 and SN2 Reactivity of Fluorinated Materials 14
   1.3 Preparation of Fluorine-containing Materials 16
   1.4 Handling Fluorinated Materials 20
   1.5 References and Notes 21
Chapter 2 Preparation of Monofluorinated Materials 31
   2.1 Fluorination 31
   2.1.1 Nucleophilic Fluorination (Substitution) 31
   2.1.2 Nucleophilic Fluorination (Addition) 42
   2.1.3 Nucleophilic Fluorination (Miscellaneous) 44
   2.1.4 Electrophilic Fluorination 45
   2.2 Carbon-Carbon Bond-forming Reactions 49
   2.2.1 Aldol Type Reactions 49
   2.2.2 Wittig Type Reactions 53
   2.2.3 Rearrangement and Cycloaddition 57
   2.2.4 Alkylations 59
   2.2.5 Miscellaneous 62
   2.3 Removal of Fluorine from Difluorinated Materials 68
   2.4 Optically Active Materials by Bioorganic Methods 70
   2.5 Substitution Reactions 72
   2.6 Miscellaneous Reactions 74
Chapter 3 Preparation of Difluorinated Materials 79
   3.1 Fluorination 79
   3.1.1 Nucleophilic Fluorination 79
   3.1.2 Electrophilic Fluorination 81
   3.1.3 Miscellaneous 82
   3.2 Difluoromethylenation 83
   3.3 Introduction of Difluoromethyl and Related Groups 85
   3.4 Carbon-Carbon Bond-forming Reactions 91
   3.4.1 Reformatsky Type Reactions 91
   3.4.2 Aldol Reactions and Claisen Condensation 95
   3.4.3 Diels-Alder Reactions 98
   3.4.4 Claisen Rearrangement 100
   3.4.5 Alkylations and Acylations 102
   3.5 Removal of Fluorine from Trifluorinated Materials 106
   3.6 Reactions of Hemiacetals 111
   3.7 Oxidations and Reductions 115
   3.8 Miscellaneous Reactions 118
Chapter 4 Preparation of Trifluorinated Materials 121
   4.1 Introduction of a Trifluoromethyl Group 121
   4.1.1 Introduction of a Trifluoromethyl Group (Nucleophilic) 121
   4.1.2 Introduction of a Trifluoromethyl Group (Electrophilic, Radical) 127
   4.1.3 Introduction of a Trifluoromethyl Group (Miscellaneous) 131
   4.2 Conversion to a Trifluoromethyl Group 132
   4.3 Carbon-Carbon Bond-forming Reactions 135
   4.3.1 Aldol Type Reactions 135
   4.3.2 Michael Reactions 140
   4.3.3 Ene Reactions 146
   4.3.4 Diels-Alder Reactions and 1,3-Dipolar Cycloadditions 148
   4.3.5 Wittig Type Reactions 152
   4.3.6 Rearrangements 154
   4.3.7 Nucleophilic Additions 158
   4.3.8 Electrophilic Additions 166
   4.3.9 Miscellaneous 172
   4.4 Reactions with Hetero Nucleophiles 175
   4.4.1 Reactions with Nitrogen Nucleophiles 175
   4.4.2 Reactions with Oxygen Nucleophiles 177
   4.4.3 Reaction with a Sulfur Nucleophile 181
   4.5 Dehydrations 183
   4.6 Oxidations and Reductions 184
   4.6.1 Oxidations 184
   4.6.2 Reductions 189
   4.7 Optical Resolutions 194
   4.7.1 Bioorganic Methods 194
   4.7.2 Chemical Method 198
   4.8 Miscellaneous Reactions 199
Chapter 5 Preparation of Poly- or Perfluorinated Materials 209
   5.1 Introduction of Poly- or Perfluorinated Groups 209
   5.1.1 Introduction of Poly- or Perfluorinated Groups (Nucleophilic) 209
   5.1.2 Introduction of Poly- or Perfluorinated Groups (Electrophilic, Radical) 212
   5.2 Carbon-Carbon Bond-forming Reactions 216
   5.2.1 Aldol Type Reactions 216
   5.2.2 Wittig Reactions 221
   5.2.3 Alkylations 223
   5.2.4 Anti-Michael Reactions 225
   5.2.5 Miscellaneous 228
   5.3 Miscellaneous Reactions 230
Appendix Representative Distributors of Fluorochemicals 233
Appendix Availability of Fluorinated Reagents 235
Compound Index 239
Reagent Index 243
Product Index 247
Author Index 256
Preface
General Remarks
Abbreviations
4.

図書

図書
Louis Sachar
出版情報: New York : Farrar, Straus and Giroux, 1998  233 p. ; 22 cm
シリーズ名: Frances Foster books
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NHK「オトナの試験」制作班編
出版情報: 名古屋 : KTC中央出版, 1998.12-  冊 ; 21cm
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text by Teiji Itoh
出版情報: Tokyo ; New York : Kodansha International, 1998, c1984  244 p. ; 31 cm
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図書
赤木望著
出版情報: 東京 : たま出版, 1998.11  194p ; 20cm
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小川喜道著
出版情報: 東京 : 文芸社, 1998.12  184p ; 20cm
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アンドリュー・デュアー編
出版情報: 東京 : 二見書房, 1998.12  71p ; 30cm
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藤家洋一著
出版情報: 東京 : ERC出版, 1998.12  220p ; 21cm
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