Preface |
List of Contributors |
Catalysis Involving the H* Transfer Reactions of First-Row Transition Metals / John Hartung ; Jack R. Norton1: |
H* Transfer Between M-H Bonds and Organic Radicals / 1.1: |
H* Transfer Between Ligands and Organic Radicals / 1.2: |
H* Transfer Between M-H and C-C Bonds / 1.3: |
Chain Transfer Catalysis / 1.4: |
Catalysis of Radical Cydizations / 1.5: |
Competing Methods for the Cyclization of Dienes / 1.6: |
Summary and Conclusions / 1.7: |
References |
Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum / Richard R. Schrock2: |
Some Characteristics of Triamidoamine Complexes / 2.1Introduction: |
Possible [HIPTN3N]Mo Intermediates in a Catalytic Reduction of Molecular Nitrogen / 2.3: |
MoN2 and MoN2- / 2.3.1: |
Mo-N=NH / 2.3.2: |
Conversion of Mo(N2) into Mo-N=NH / 2.3.3: |
[Mo=N-NH2]+ / 2.3.4: |
Mo=N and [Mo=NH]+ / 2.3.5: |
Mo(NH3) and [Mo(NH3)+ / 2.3.6: |
Interconversion of Mo(NH3) and Mo(N2) / 2.4: |
Catalytic Reduction of Dinitrogen / 2.5: |
MoH and Mo(H2) / 2.6: |
Ligand and Metal Variations / 2.7: |
Comments / 2.8: |
Acknowledgements |
Molybdenum and Tungsten Catalysts for Hydrogenation, Hydrosilylation and Hydrolysis / R. Morris Bullock3: |
Introduction / 3.1: |
Proton Transfer Reactions of Metal Hydrides / 3.2: |
Hydride Transfer Reactions of Metal Hydrides / 3.3: |
Stoichiometric Hydride Transfer Reactivity of Anionic Metal Hydride Complexes / 3.4: |
Catalytic Hydrogenation of Ketones with Anionic Metal Hydrides / 3.5: |
Ionic Hydrogenation of Ketones Using Metal Hydrides and Added Acid / 3.6: |
Ionic Hydrogenations from Dihydrides: Delivery of the Proton and Hydride from One Metal / 3.7: |
Catalytic Ionic Hydrogenations With Mo and W Catalysts / 3.8: |
Mo Phosphine Catalysts With Improved lifetimes / 3.9: |
Tungsten Hydrogenation Catalysts with N-Heterocyclic Carbene Ligands / 3.10: |
Catalysts for Hydrosilylation of Ketones / 3.11: |
Cp2Mo Catalysts for Hydrolysis, Hydrogenations and Hydrations / 3.12: |
Conclusion / 3.13: |
Modern Alchemy: Replacing Precious Metals with Iron in Catalytic Alkene and Carbonyl Hydrogenation Reactions / Paul J. Chink4: |
Alkene Hydrogenation / 4.1: |
Iron Carbonyl Complexes / 4.2.1: |
Iron Phosphine Compounds / 4.2.2: |
Bis(imino)pyridine Iron Complexes / 4.2.3: |
α-Diimine Iron Complexes / 4.2.4: |
Carbonyl Hydrogenation / 4.3: |
Hydrosilylation / 4.3.1: |
Bifunctional Complexes / 4.3.2: |
Outlook / 4.4: |
Olefin Oligomerizations and Polymerizations Catalyzed by Iron and Cobalt Complexes Bearing Bis(imino)pyridine Ligands / Vernon C. Gibson ; Gregory A. Solan5: |
Precatalyst Synthesis / 5.1: |
Ligand Preparation / 5.2.1: |
Complexation with MX2 (M = Fe, Co) / 5.2.2: |
Precatalyst Activation and Catalysis / 5.3: |
Olefin Polymerization / 5.3.1: |
Catalytic Evaluation / 5.3.1.1: |
Steric Versus Electronic Effects / 5.3.1.2: |
Effect of MAO Concentration / 5.3.1.3: |
Effects of Pressure and Temperature / 5.3.1.4: |
α-Olefin Monomers / 5.3.1.5: |
Olefin Oligomerization / 5.3.2: |
Substituent Effects / 5.3.2.1: |
Schulz-Flory Distributions / 5.3.2.3: |
Poisson Distributions / 5.3.2.4: |
The Active Catalyst and Mechanism / 5.3.2.5: |
Active Species / 5.4.: |
Iron Catalyst / 5.4.1.1: |
Cobalt Catalyst / 5.4.1.2: |
Propagation and Chain Transfer Pathways/Theoretical Studies / 5.4.2: |
Well-Defined Iron and Cobalt Alkyls / 5.4.3: |
Other Applications / 5.5: |
Immobilization / 5.5.1: |
Reactor Blending and Tandem Catalysis / 5.5.2: |
Conclusions and Outlook / 5.6: |
Cobalt and Nickel Catalyzed Reactions Involving C-H and C-N Activation Reactions / Renee Becker ; William D. Jones6: |
Catalysis with Cobal / 6.1: |
Catalysis with Nickel / 6.3: |
A Modular Approach to the Development of Molecular Electrocatalysts for H2 Oxidation and Production Based on Inexpensive Metals / M. Rakowski DuBois ; Daniel L. DuBois7: |
Concepts in Catalyst Design Based on Structural Studies of Hydrogenase Enzymes / 7.1: |
A Layered or Modular Approach to Catalyst Design / 7.3: |
Using the First Coordination Sphere to Control the Energies of Catalytic Intermediates / 7.4: |
Using the Second Coordination Sphere to Control the Movement of Protons between the Metal and the Exterior of the Molecular Catalyst / 7.5: |
Integration of the First and Second Coordination Spheres / 7.6: |
Summary / 7.7: |
Nickel-Catalyzed Reductive Couplings and Cyclizations / Hasnain A. Malik ; Ryan D. Baxter ; John Montgomery8: |
Couplings of Alkynes with α,β-Unsaturated Carbonyls / 8.1: |
Three-Component Couplings via Alkyl Group Transfer-Methods Development / 8.2.1: |
Reductive Couplings via Hydrogen Atom Transfer-Methods Development / 8.2.2: |
Mechanistic Insights / 8.2.3: |
Metallacycle-Based Mechanistic Pathway / 8.2.3.1: |
Use in Natural Product Synthesis / 8.2.4: |
Couplings of Alkynes with Aldehydes / 8.3: |
Three-Component Couplings via Alkyl Group Transfer-Method Development / 8.3.1: |
Reductive Couplings via Hydrogen Atom Transfer-Method Development / 8.3.2: |
Simple Aldehyde and Alkyne Reductive Couplings / 8.3.2.1: |
Directed Processes / 8.3.2.2: |
Diastereoselective Variants: Transfer of Chirality / 8.3.2.3: |
Asymmetric Variants / 8.3.2.4: |
Cydocondensations via Hydrogen Gas Extrusion / 8.3.3: |
Copper-Catalyzed Ligand Promoted Ullmann-type Coupling Reactions / Yongwen Jiang ; Dawei Ma8.3.5: |
C-N Bond Formation / 9.1: |
Arylation of Amines / 9.2.1: |
Arylation of Aliphatic Primary and Secondary Amines / 9.2.1.1: |
Arylation of Aryl Amines / 9.2.1.2: |
Arylation of Ammonia / 9.2.1.3: |
Arylation and Vinylation of N-Heterocycles / 9.2.2: |
Coupling of Aryl Halides and N-Heterocycles / 9.2.2.1: |
Coupling of Vinyl Bromides and N-Heterocycles / 9.2.2.2: |
Aromatic Amidation / 9.2.3: |
Cross-Coupling of aryl Halides with Amides and Carbamates / 9.2.3.1: |
Cross-Coupling of Vinyl Halides with Amides or Carbamates / 9.2.3.2: |
Cross-Coupling of Alkynl Halides with Amides or Carbamates / 9.2.3.3: |
Azidation / 9.2.4: |
C-0 Bond Formation / 19.3: |
Synthesis of Diaryl Ethers / 9.3.1: |
Aryloxylation of Vinyl Halides / 9.3.2: |
Cross-Coupling of Aryl Halides with Aliphatic Alcohols / 9.3.3: |
C-C Bond Formation / 9.4: |
Cross-Coupling with Terminal Acetylene / 9.4.1: |
The Arylation of Activated Methylene Compounds / 9.4.2: |
Cyanation / 9.4.3: |
C-S Bond Formation / 9.5: |
The Formation of Bisaryl- and Arylalkyl-Thioethers / 9.5.1: |
The Synthesis of Alkenylsulfides / 9.5.2: |
Assembly of aryl Sulfones / 9.5.3: |
C-P Bond Formation / 9.6: |
Copper-Catalyzed Azide-Alkyne Cycloaddition (CuAAC) / M.G. Finn ; Valery V. Fokin9.7: |
Azide-Alkyne Cycloaddition: Basics / 10.1: |
Copper-Catalyzed Cycloadditions / 10.3: |
Catalysts and Ligands / 10.3.1: |
CuAAC with In Situ Generated Azides / 10.3.2: |
Mechanistic Aspects of the CuAAC / 10.3.3: |
Reactions of Sulfonyl Azides / 10.3.4: |
Copper-Catalyzed Reactions with Other Dipolar Species / 10.3.5: |
Examples of Application of the CuAAC Reaction / 10.3.6: |
Synthesis of Compound libraries for Biological Screening / 10.3.6.1: |
Copper-Binding Adhesives / 10.3.6.2: |
Representative Experimental Procedures / 10.3.7: |
"Frustrated Lewis Pairs": A Metal-Free Strategy for Hydrogenation Catalysis / Douglas W. Stephan11: |
Phosphine-Borane Activation of H2 / 11.1: |
"Frustrated Lewis Pairs" / 11.2: |
Metal-Free Catalytic Hydxogenation / 11.3: |
Future Considerations / 11.4: |
Index |
Preface |
List of Contributors |
Catalysis Involving the H* Transfer Reactions of First-Row Transition Metals / John Hartung ; Jack R. Norton1: |