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図書

図書
John McMurry
出版情報: Pacific Grove, CA : Brooks/Cole Pub. Co., c2000  xliii, 1284, 56, 28 p. ; 26 cm.
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2.

図書

図書
Susan McMurry
出版情報: Pacific Grove, Calif. : Brooks/Cole, c2000 , Tokyo : 東京化学同人 (発売), 2001.4  845 p. ; 28 cm
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3.

図書

図書
Klaus Weissermel, Hans-Jürgen Arpe
出版情報: Weinheim : Wiley-VCH, 2003  xix, 491 p. ; 25 cm
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Various Aspects of Energy and Raw Material Supply / 1:
Basic Products of Industrial Syntheses / 2:
Olefins / 3:
Acetylene / 4:
1,3-Diolefins / 5:
Syntheses Involving Carbon Monoxide / 6:
Oxidation Products of Ethylene / 7:
Alcohols / 8:
Vinyl-Halogen and Vinyl-Oxygen Compounds / 9:
Components for Polyamides / 10:
Propene Conversion Products / 11:
Aromatics - Production and Conversion / 12:
Benzene Derivatives / 13:
Oxidation Products of Xylene and Naphthalene / 14:
Appendix / 15:
Index
Various Aspects of Energy and Raw Material Supply / 1:
Basic Products of Industrial Syntheses / 2:
Olefins / 3:
4.

図書

図書
Jie Jack Li
出版情報: Berlin ; Tokyo : Springer, c2003  xviii, 465 p. ; 25 cm
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Abbreviations
Abnormal Claisen rearrangement / 1:
Alder ene reaction / 2:
Aldol condensation / 3:
Allan-Robinson reaction / 4:
Alper carbonylation / 5:
Amadori rearrangement / 6:
Angeli-Rimini hydroxamic acid synthesis / 7:
ANRORC mechanism / 8:
Arndt-Eistert homologation / 9:
Auwers reaction / 10:
Baeyer-Drewson indigo synthesis / 11:
Baeyer-Villiger oxidation / 12:
Baker-Venkataraman rearrangement / 13:
Bamberger rearrangement / 14:
Bamford-Stevens reaction / 15:
Bargellini reaction / 16:
Bartoli indole synthesis / 17:
Barton decarboxylation / 18:
Barton-McCombie deoxygenation / 19:
Barton nitrite photolysis / 20:
Baylis-Hillman reaction / 21:
Beckmann rearrangement / 22:
Beirut reaction / 23:
Benzilic acid rearrangement / 24:
Benzoin condensation / 25:
Bergman cyclization / 26:
Biginelli pyrimidone synthesis / 27:
Birch reduction / 28:
Bischler-Möhlau indole synthesis / 29:
Bischler-Napieralski reaction / 30:
Blaise reaction / 31:
Blanc chloromethylation reaction / 32:
Boekelheide reaction / 33:
Boger pyridine synthesis / 34:
Boord reaction / 35:
Borsche-Drechsel cyclization / 36:
Boulton-Katritzky rearrangement / 37:
Bouveault aldehyde synthesis / 38:
Bouveault-Blanc reduction / 39:
Boyland-Sims oxidation / 40:
Bradsher reaction / 41:
Brook rearrangement / 42:
Brown hydroboration reaction / 43:
Bucherer carbazole synthesis / 44:
Bucherer reaction / 45:
Bucherer-Bergs reaction / 46:
Buchner-Curtius-Schlotterbeck reaction / 47:
Buchner method of ring expansion / 48:
Buchwald-Hartwig C-N bond and C-O bond formation reactions / 49:
Burgess dehydrating reagent / 50:
Cadiot-Chodkiewicz coupling / 51:
Cannizzaro dispropotionation reaction / 52:
Carroll rearrangement / 53:
Castro-Stephens coupling / 54:
Chapman rearrangement / 55:
Chichibabin amination reaction / 56:
Chichibabin pyridine synthesis / 57:
Chugaev reaction / 58:
Ciamician-Dennsted rearrangement / 59:
Claisen condensation / 60:
Claisen rearrangement / 61:
Clarke-Eschweiler reductive alkylation of amines / 62:
Clemmensen reduction / 63:
Combes quinoline synthesis / 64:
Conrad-Limpach reaction / 65:
Cook-Heilbron thiazole synthesis / 66:
Cope elimination reaction / 67:
Cope, oxy-Cope, and anionic oxy-Cope rearrangements / 68:
Corey-Bakshi-Shibata (CBS) reduction / 69:
Corey-Chaykovsky reaction / 70:
Corey-Fuchs reaction / 71:
Corey-Kim oxidation / 72:
Corey-Winter olefin synthesis / 73:
Cornforth rearrangement / 74:
Criegee glycol cleavage / 75:
Criegee mechanism of ozonolysis / 76:
Curtius rearrangement / 77:
Dakin oxidation / 78:
Dakin-West reaction / 79:
Danheiser annulation / 80:
Darzens glycidic ester condensation / 81:
Davis chiral oxaziridine reagent / 82:
de Mayo reaction / 83:
Demjanov rearrangement / 84:
Dess-Martin periodinane oxidation / 85:
Dieckmann condensation / 86:
Diels-Alder reaction / 87:
Dienone-phenol rearrangement / 88:
Di-?-methane rearrangement / 89:
Doebner reaction / 90:
Doebner-von Miller reaction / 91:
Doering-LaFlamme allene synthesis / 92:
Dornow-Wiehler isoxazole synthesis / 93:
Dötz reaction / 94:
Dowd ring expansion / 95:
Dutt-Wormall reaction / 96:
Eglinton reaction / 97:
Eschenmoser coupling reaction / 98:
Eschenmoser-Tanabe fragmentation / 99:
Étard reaction / 100:
Evans aldol reaction / 101:
Favorskii rearrangement and Quasi-Favorskii rearrangement / 102:
Feist-Bénary furan synthesis / 103:
Ferrier rearrangement / 104:
Finkelstein reaction / 105:
Fischer-Hepp rearrangement / 106:
Fischer indole synthesis / 107:
Fischer-Speier esterification / 108:
Fleming oxidation / 109:
Forster reaction / 110:
Frater-Seebach alkylation / 111:
Friedel-Crafts reaction / 112:
Friedländer synthesis / 113:
Fries rearrangement / 114:
Fritsch-Buttenberg-Wiechell rearrangement / 115:
Fujimoto-Belleau reaction / 116:
Fukuyama amine synthesis / 117:
Gabriel synthesis / 118:
Gassman indole synthesis / 119:
Gattermann-Koch reaction / 120:
Gewald aminothiophene synthesis / 121:
Glaser coupling / 122:
Gomberg-Bachmann reaction / 123:
Gribble indole reduction / 124:
Gribble reduction of diaryl ketones / 125:
Grignard reaction / 126:
Grob fragmentation / 127:
Guareschi-Thorpe condensation / 128:
Hajos-Wiechert reaction / 129:
Haller-Bauer reaction / 130:
Hantzsch pyridine synthesis / 131:
Hantzsch pyrrole synthesis / 132:
Haworth reaction / 133:
Hayashi rearrangement / 134:
Heck reaction / 135:
Hegedus indole synthesis / 136:
Hell-Volhardt-Zelinsky reaction / 137:
Henry reaction (nitroaldol reaction) / 138:
Herz reaction / 139:
Heteroaryl Heck reaction / 140:
Hiyama cross-coupling reaction / 141:
Hoch-Campbell aziridine synthesis / 142:
Hodges-Vedejs metallation of oxazoles / 143:
Hofmann rearrangement (Hofmann degradation reaction) / 144:
Hofmann-Löffler-Freytag reaction / 145:
Hofmann-Martius reaction (Reilly-Hickinbottom rearrangement) / 146:
Hooker oxidation / 147:
Horner-Wadsworth-Emmons reaction / 148:
Houben-Hoesch synthesis / 149:
Hunsdiecker reaction / 150:
Ing-Manske procedure / 151:
Jacobsen-Katsuki epoxidation / 152:
Jacobsen rearrangement / 153:
Japp-Klingemann hydrazone synthesis / 154:
Julia-Lythgoe olefination / 155:
Kahne glycosidation / 156:
Keck stereoselective allylation / 157:
Keck macrolactonization / 158:
Kemp elimination / 159:
Kennedy oxidative cyclization / 160:
Kharasch addition reaction / 161:
Knoevenagel condensation / 162:
Knorr pyrrole synthesis / 163:
Koch carbonylation reaction (Koch-Haaf carbonylation reaction) / 164:
Koenig-Knorr glycosidation / 165:
Kolbe electrolytic coupling / 166:
Kolbe-Schmitt reaction / 167:
Kostanecki reaction / 168:
Krapcho decarboxylation / 169:
Kröhnke reaction (pyridine synthesis) / 170:
Kumada cross-coupling reaction / 171:
Larock indole synthesis / 172:
Lawesson's reagent / 173:
Leuckart-Wallach reaction / 174:
Lieben haloform reaction / 175:
Liebeskind-Srogl coupling / 176:
Lossen rearrangement / 177:
Luche reduction / 178:
McFadyen-Stevens reduction / 179:
McLafferty rearrangement / 180:
McMurry coupling / 181:
Madelung indole synthesis / 182:
Mannich reaction / 183:
Marshall boronate fragmentation / 184:
Martin's sulfurane dehydrating reagent / 185:
Masamune-Roush conditions / 186:
Meerwein arylation / 187:
Meerwein-Ponndorf-Verley reduction / 188:
Meinwald rearrangement / 189:
Meisenheimer complex / 190:
Meisenheimer rearrangement / 191:
Meyer-Schuster rearrangement / 192:
Michael addition / 193:
Michaelis-Arbuzov phosphonate synthesis / 194:
Midland reduction / 195:
Miller-Loudon-Snyder nitrile synthesis / 196:
Mislow-Evans rearrangement / 197:
Mitsunobu reaction / 198:
Miyaura boration reaction / 199:
Moffatt oxidation / 200:
Morgan-Walls reaction (Pictet-Hubert reaction) / 201:
Mori-Ban indole synthesis / 202:
Morin rearrangement / 203:
Mukaiyama aldol reaction / 204:
Mukaiyama esterification / 205:
Myers-Saito cyclization / 206:
Nametkin rearrangement (retropinacol rearrangement) / 207:
Nazarov cyclization / 208:
Neber rearrangement / 209:
Nef reaction / 210:
Negishi cross-coupling reaction / 211:
Nenitzescu indole synthesis / 212:
Nicholas reaction / 213:
Noyori asymmetric hydrogenation / 214:
Nozaki-Hiyama-Kishi reaction / 215:
Oppenauer oxidation / 216:
Orton rearrangement / 217:
Overman rearrangement / 218:
Paal-Knorr furan synthesis / 219:
Paal-Knorr pyrrole synthesis / 220:
Parham cyclization / 221:
Passerini reaction / 222:
Paterno-Büchi reaction / 223:
Pauson-Khand cyclopentenone synthesis / 224:
Payne rearrangement / 225:
Pechmann condensation (coumarin synthesis) / 226:
Pechmann pyrazole synthesis / 227:
Perkin reaction (cinnamic acid synthesis) / 228:
Perkow vinyl phosphate synthesis / 229:
Peterson olefination / 230:
Pfau-Plattner azulene synthesis / 231:
Pfitzinger quinoline synthesis / 232:
Pictet-Gams isoquinoline synthesis / 233:
Pictet-Spengler tetrahydroisoquinoline synthesis / 234:
Pinacol rearrangement / 235:
Pinner synthesis / 236:
Polonovski reaction / 237:
Polonovski-Potier rearrangement / 238:
Pomeranz-Fritsch reaction / 239:
Prévost trans-dihydroxylation / 240:
Prilezhaev reaction / 241:
Prins reaction / 242:
Pschorr ring closure / 243:
Pummerer rearrangement / 244:
Ramberg-Bäcklund olefin synthesis / 245:
Reformatsky reaction / 246:
Regitz diazo synthesis / 247:
Reimer-Tiemann reaction / 248:
Reissert reaction (aldehyde synthesis) / 249:
Riley oxidation (selenium dioxide oxidation) / 250:
Ring-closing metathesis (RCM) using Grubbs and Schrock catalysts / 251:
Ritter reaction / 252:
Robinson annulation / 253:
Robinson-Schöpf reaction / 254:
Rosenmund reduction / 255:
Roush allylboronate reagent / 256:
Rubottom oxidation / 257:
Rupe rearrangement / 258:
Rychnovsky polyol synthesis / 259:
Sakurai allylation reaction (Hosomi-Sakurai reaction) / 260:
Sandmeyer reaction / 261:
Sarett oxidation / 262:
Schiemann reaction (Balz-Schiemann reaction) / 263:
Schlosser modification of the Wittig reaction / 264:
Schmidt reaction / 265:
Schmidt's trichloroacetimidate glycosidation reaction / 266:
Scholl reaction / 267:
Schöpf reaction / 268:
Schotten-Baumann reaction / 269:
Shapiro reaction / 270:
Sharpless asymmetric amino hydroxylation / 271:
Sharpless asymmetric epoxidation / 272:
Sharpless dihydroxylation / 273:
Shi asymmetric epoxidation / 274:
Simmons-Smith reaction / 275:
Simonini reaction / 276:
Simonis chromone cyclization / 277:
Skraup quinoline synthesis / 278:
Smiles rearrangement / 279:
Sommelet reaction / 280:
Sommelet-Hauser (ammonium ylide) rearrangement / 281:
Sonogashira reaction / 282:
Staudinger reaction / 283:
Stetter reaction (Michael-Stetter reaction) / 284:
Stevens rearrangement / 285:
Stieglitz rearrangement / 286:
Still-Gennari phosphonate reaction / 287:
Stille coupling / 288:
Stille-Kelly reaction / 289:
Stobbe condensation / 290:
Stollé synthesis / 291:
Stork enamine reaction / 292:
Strecker amino acid synthesis / 293:
Suzuki coupling / 294:
Swern oxidation / 295:
Tamao-Kumada oxidation / 296:
Tebbe olefination (Petasis alkenylation) / 297:
Thorpe-Ziegler reaction / 298:
Tiemann rearrangement / 299:
Tiffeneau-Demjanov rearrangement / 300:
Tishchenko reaction / 301:
Tollens reaction / 302:
Tsuji-Trost allylation / 303:
Ueno-Stork cyclization / 304:
Ugi reaction / 305:
Ullmann reaction / 306:
Vilsmeier-Haack reaction / 307:
von Braun reaction / 308:
von Richter reaction / 309:
Wacker oxidation / 310:
Wagner-Meerwein rearrangement / 311:
Wallach rearrangement / 312:
Weinreb amide / 313:
Weiss reaction / 314:
Wenker aziridine synthesis / 315:
Wharton oxygen transposition reaction / 316:
Willgerodt-Kindler reaction / 317:
Williamson ether synthesis / 318:
Wittig reaction / 319:
[1,2]-Wittig rearrangement / 320:
[2,3]-Wittig rearrangement / 321:
Wohl-Ziegler reaction / 322:
Wolff rearrangement / 323:
Wolff-Kishner reduction / 324:
Woodward cis-dihydroxylation / 325:
Wurtz reaction / 326:
Yamada coupling reagent / 327:
Yamaguchi esterification / 328:
Zaitsev elimination / 329:
Zincke reaction / 330:
Zinin benzidine rearrangement (semidine rearrangement) / 331:
Subject Index
Abbreviations
Abnormal Claisen rearrangement / 1:
Alder ene reaction / 2:
5.

図書

図書
Bernard Miller
出版情報: Upper Saddle River, N.J. : Prentice Hall, 2004  xvi, 411 p. ; 25 cm
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Introduction / 1:
Mechanisms of Reactions. Electron Delocalization and Resonance
Electrocyclic Reactions / 2:
Conrotatory and Disrotatory Processes
Explanations for the Woodward-Hoffman Rules
Electrocyclic Reactions with Odd Numbers of Atoms
Photochemical Cyclizations
Cycloaddiction and Cycloreversion Reactions / 3:
Suprafacial and Antarafacial Addition
Selection Rules for Cycloaddition and Cycloreversion Reactions
Examples of Thermal Cycloaddition Reactions
Photochemical Cycloadditions
Sigmatropic Reactions / 4:
Theory of Sigmatropic Shifts
Experimental Observations
Sigmatropic Rearrangements of Charged Systems
Linear Free-Energy Relationships / 5:
The Hammett Equation
Separation of Polar, Resonance, and Steric Effects
Migrations to Electron-Deficient Centers / 6:
Migrations to Electron-Deficient Carbons
The Nature of the Migrating Groups
Rearrangements of Carbocations. Long-Distance Migrations
Migrations to Nitrogen and Oxygen
Neighboring-Group Effects and Nonclassical Cations / 7:
Substitution with Retention of Configuration
Cyclic Halonium Ions
Sulfur and Nitrogen Mustards
Trans/Cis Rate Ratios. Neighboring Acetoxy Groups
Cyclic Phenonium Ions. Double Bonds as Neighboring Groups
Cyclopropane Rings as Neighboring Groups
Neighboring Alkyl Groups: 2-Norbornyl Cations
Rearrangements of Carbanions and Free Radicals / 8:
Carbanion Rearrangements
Rearrangements of Free Radicals
Carbenes, Carbenoids, and Nitrenes / 9:
Formation of Carbenes and Nitrenes
Singlet and Triplet Carbenes. Additions to Double Bonds
Insertion Reactions. Rearrangements
Six-Membered Heterocyclic Rings / 10:
Aromatic Heterocyclic Molecules
Reactions of Pyridine and Its Analogs
Synthesis of Six-Membered Heterocyclic Rings
Five-Membered Heterocyclic Rings / 11:
Electron Delocalization and Aromaticity
Reactions of Five-Membered Heterocyclic Rings
Synthesis of Five-Membered Heteroaromatic Rings
Index
Introduction / 1:
Mechanisms of Reactions. Electron Delocalization and Resonance
Electrocyclic Reactions / 2:
6.

図書

図書
T.W. Graham Solomons, Craig B. Fryhle
出版情報: Hoboken, N.J. : Wiley, c2004  xxxii, 1255, 8, 14, 4, 27 p. ; 26 cm.
シリーズ名: Wiley international editions
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Carbon Compounds and Chemical Bonds / Chapter 1:
Representative Carbon Compounds: Functional Groups, Intermolecular Forces, and Infrared (IR) Spectroscopy / Chapter 2:
An Introduction to Organic Reactions: Acids and Bases / Chapter 3:
Alkanes: Nomenclature, Conformational Analysis, and an Introduction to Synthesis / Chapter 4:
Stereochemistry: Chiral Molecules / Chapter 5:
Ionic Reactions-Nucleophilic Substitution and Elimination Reactions of Alkyl Halides / Chapter 6:
Alkenes and Alkynes I: Properties and Synthesis, Elimination Reactions of Alkyl Halides / Chapter 7:
Alkenes and Alkynes II: Addition Reactions / Chapter 8:
Nuclear Magnetic Resonance and Mass Spectrometry: Tools for Structure Determination / Chapter 9:
Radical Reactions / Chapter 10:
Alcohols and Ethers / Chapter 11:
Alcohols from Carbonyl Compounds / Chapter 12:
Oxidation-Reduction and Organometallic Compounds
Conjugated Unsaturated Systems / Chapter 13:
Aromatic Compounds / Chapter 14:
Reactions of Aromatic Compounds / Chapter 15:
Aldehydes and Ketones I: Nucleoph ilic Addition to the Carbonyl Group / Chapter 16:
Aldehydes and Ketones II: Aldol Reactions / Chapter 17:
Carboxylic Acids and Their Derivatives / Chapter 18:
Nucleophilic Addition-Elimination at the Acyl Carbon
Synthesis and Reactions of ?-Dicarbonyl Compounds: More Chemistry of Enolate Ions / Chapter 19:
Amines / Chapter 20:
Phenols and Aryl Halides: Nucleophilic Aromatic Substitution / Chapter 21:
Carbohydrates / Chapter 22:
Lipids / Chapter 23:
Amino Acids and Proteins / Chapter 24:
Nucleic Acids and Protein Synthesis / Chapter 25:
Answers to Selected Problems
Glossary
Photo and Illustration Credits
Index
Carbon Compounds and Chemical Bonds / Chapter 1:
Representative Carbon Compounds: Functional Groups, Intermolecular Forces, and Infrared (IR) Spectroscopy / Chapter 2:
An Introduction to Organic Reactions: Acids and Bases / Chapter 3:
7.

図書

図書
Gokel, George W., 1946- ; Dean, John Aurie, 1921-
出版情報: New York : McGraw-Hill Education , London : McGraw-Hill[m], 2003  800 p ; 23cm
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8.

図書

図書
Francis A. Carey and Richard J. Sundberg
出版情報: New York : Kluwer Academic/Plenum Publishers, c2000  xii, 823 p. ; 26 cm
シリーズ名: Advanced organic chemistry / Francis A. Carey and Richard J. Sundberg ; pt. A
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Chemical Bonding and Structure / Chapter 1.:
Valence Bond Description of Chemical Bonding / 1.1.:
Orbital Hybridization / 1.1.1.:
Resonance / 1.1.2.:
Bond Energy, Polarity, and Polarizability / 1.2.:
Bond Energies / 1.2.1.:
Electronegativity and Polarity / 1.2.2.:
Polarizability--Hardness and Softness / 1.2.3.:
Molecular Orbital Theory and Methods / 1.3.:
Huckel Molecular Orbital Theory / 1.4.:
Qualitative Application of Molecular Orbital Theory / 1.5.:
Application of Molecular Orbital Theory to Reactivity / 1.6.:
Interactions between [sigma] and [pi] Systems--Hyperconjugation / 1.7.:
Other Quantitative Descriptions of Molecular Structure / 1.8.:
Atoms in Molecules / 1.8.1.:
Electron Density Functionals / 1.8.2.:
Modern Valence Bond Approaches / 1.8.3.:
General References
Problems
Principles of Stereochemistry / Chapter 2.:
Enantiomeric Relationships / 2.1.:
Diastereomeric Relationships / 2.2.:
Stereochemistry of Reactions / 2.3.:
Prochiral Relationships / 2.4.:
Conformational, Steric, and Stereoelectronic Effects / Chapter 3.:
Strain and Molecular Mechanics / 3.1.:
Conformations of Acyclic Molecules / 3.2.:
Conformations of Cyclohexane Derivatives / 3.3.:
Carbocyclic Rings Other Than Six-Membered / 3.4.:
The Effect of Heteroatoms on Conformational Equilibria / 3.5.:
The Anomeric Effect / 3.6.:
Conformational Effects on Reactivity / 3.7.:
Angle Strain and Its Effect on Reactivity / 3.8.:
Relationships between Ring Size and Rate of Cyclization / 3.9.:
Torsional and Stereoelectronic Effects on Reactivity / 3.10.:
Study and Description of Organic Reaction Mechanismns / Chapter 4.:
Thermodynamic Data / 4.1.:
Kinetic Data / 4.2.:
Substituent Effects and Linear Free-Energy Relationships / 4.3.:
Basic Mechanistic Concepts: Kinetic versus Thermodynamic Control, Hammond's Postulate, the Curtin-Hammett Principle / 4.4.:
Kinetic versus Thermodynamic Control / 4.4.1.:
Hammond's Postulate / 4.4.2.:
The Curtin-Hammett Principle / 4.4.3.:
Isotope Effects / 4.5.:
Isotopes in Labeling Experiments / 4.6.:
Characterization of Reaction Intermediates / 4.7.:
Catalysis by Bronsted Acids and Bases / 4.8.:
Lewis Acid Catalysis / 4.9.:
Solvent Effects / 4.10.:
Substituent Effects in the Gas Phase / 4.11.:
Stereochemistry / 4.12.:
Conclusion / 4.13.:
Nucleophilic Substitution / Chapter 5.:
The Limiting Cases--Substitution by the Ionization (S[subscript N]1) Mechanism / 5.1.:
The Limiting Cases--Substitution by the Direct Displacement (S[subscript N]2) Mechanism / 5.2.:
Detailed Mechanistic Description and Borderline Mechanisms / 5.3.:
Carbocations / 5.4.:
Nucleophilicity and Solvent Effects / 5.5.:
Leaving-Group Effects / 5.6.:
Steric and Strain Effects on Substitution and Ionization Rates / 5.7.:
Effects of Conjugation on Reactivity / 5.8.:
Stereochemistry of Nucleophilic Substitution / 5.9.:
Neighboring-Group Participation / 5.10.:
Mechanism of Rearrangements of Carbocations / 5.11.:
The Norbornyl Cation and Other Nonclassical Carbocations / 5.12.:
Polar Addition and Elimination Reactions / Chapter 6.:
Addition of Hydrogen Halides to Alkenes / 6.1.:
Acid-Catalyzed Hydration and Related Addition Reactions / 6.2.:
Addition of Halogens / 6.3.:
Electrophilic Additions Involving Metal Ions / 6.4.:
Additions to Alkynes and Allenes / 6.5.:
The E2, E1, and E1cb Mechanisms / 6.6.:
Regiochemistry of Elimination Reactions / 6.7.:
Stereochemistry of E2 Elimination Reactions / 6.8.:
Dehydration of Alcohols / 6.9.:
Eliminations Not Involving C--H Bonds / 6.10.:
Carbanions and Other Nucleophilic Carbon Species / Chapter 7.:
Acidity of Hydrocarbons / 7.1.:
Carbanions Stabilized by Functional Groups / 7.2.:
Enols and Enamines / 7.3.:
Carbanions as Nucleophiles in S[subscript N]2 Reactions / 7.4.:
Reactions of Carbonyl Compounds / Chapter 8.:
Hydration and Addition of Alcohols to Aldehydes and Ketones / 8.1.:
Addition-Elimination Reactions of Ketones and Aldehydes / 8.2.:
Addition of Carbon Nucleophiles to Carbonyl Groups / 8.3.:
Reactivity of Carbonyl Compounds toward Addition / 8.4.:
Ester Hydrolysis / 8.5.:
Aminolysis of Esters / 8.6.:
Amide Hydrolysis / 8.7.:
Acylation of Nucleophilic Oxygen and nitrogen Groups / 8.8.:
Intramolecular Catalysis / 8.9.:
Aromaticity / Chapter 9.:
The Concept of Aromaticity / 9.1.:
The Annulenes / 9.2.:
Aromaticity in Charged Rings / 9.3.:
Homoaromaticity / 9.4.:
Fused-Ring Systems / 9.5.:
Heterocyclic Rings / 9.6.:
Aromatic Substitution / Chapter 10.:
Electrophilic Aromatic Substitution Reactions / 10.1.:
Structure-Reactivity Relationships / 10.2.:
Reactivity of Polycyclic and Heteroaromatic Compounds / 10.3.:
Specific Substitution Mechanisms / 10.4.:
Nitration / 10.4.1.:
Halogenation / 10.4.2.:
Protonation and Hydrogen Exchange / 10.4.3.:
Friedel-Crafts Alkylation and Related Reactions / 10.4.4.:
Friedel-Crafts Acylation and Related Reactions / 10.4.5.:
Coupling with Diazonium Compounds / 10.4.6.:
Substitution of Groups Other Than Hydrogen / 10.4.7.:
Nucleophilic Aromatic Substitution by the Addition-Elimination Mechanism / 10.5.:
Nucleophilic Aromatic Substitution by the Elimination-Addition Mechanism / 10.6.:
Concerted Pericyclic Reactions / Chapter 11.:
Electrocyclic Reactions / 11.1.:
Sigmatropic Rearrangements / 11.2.:
Cycloaddition Reactions / 11.3.:
Free-Radical Reactions / Chapter 12.:
Generation and Characterization of Free Radicals / 12.1.:
Background / 12.1.1.:
Stable and Persistent Free Radicals / 12.1.2.:
Direct Detection of Radical Intermediates / 12.1.3.:
Sources of Free Radicals / 12.1.4.:
Structural and Stereochemical Properties of Radical Intermediates / 12.1.5.:
Charged Radical Species / 12.1.6.:
Characteristics of Reaction Mechanisms Involving Radical Intermediates / 12.2.:
Kinetic Characteristics of Chain Reactions / 12.2.1.:
Free-Radical Substitution Reactions / 12.2.2.:
Oxidation / 12.3.1.:
Free-Radical Addition Reactions / 12.4.:
Addition of Hydrogen Halides / 12.4.1.:
Addition of Halomethanes / 12.4.2.:
Addition of Other Carbon Radicals / 12.4.3.:
Addition of Thiols and Thiocarboxylic Acids / 12.4.4.:
Halogen, Sulfur, and Selenium Group Transfer Reactions / 12.5.:
Intramolecular Free-Radical Reactions / 12.6.:
Rearrangement and Fragmentation Reactions of Free Radicals / 12.7.:
Rearrangement Reactions / 12.7.1.:
Fragmentation / 12.7.2.:
Electron-Transfer Reactions Involving Transition-Metal Ions / 12.8.:
S[subscript RN]1 Substitution Processes / 12.9.:
Photochemistry / Chapter 13.:
General Principles / 13.1.:
Orbital Symmetry Considerations Related to Photochemical Reactions / 13.2.:
Photochemistry of Carbonyl Compounds / 13.3.:
Photochemistry of Alkenes and Dienes / 13.4.:
Photochemistry of Aromatic Compounds / 13.5.:
References to Problems
Index
Chemical Bonding and Structure / Chapter 1.:
Valence Bond Description of Chemical Bonding / 1.1.:
Orbital Hybridization / 1.1.1.:
9.

図書

図書
Jag Mohan
出版情報: New Delhi : Narosa, 2001, c2000  viii, 512 p. ; 23 cm
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10.

図書

図書
Francis A. Carey and Richard J. Sundberg
出版情報: New York : Kluwer Academic/Plenum Publishers, c2001  xii, 965 p. ; 26 cm
シリーズ名: Advanced organic chemistry / Francis A. Carey and Richard J. Sundberg ; pt. B
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目次情報: 続きを見る
Alkylation of Nucleophilic Carbon Intermediates / Chapter 1.:
Generation of Carbanions by Deprotonation / 1.1.:
Regioselectivity and Stereoselectivity in Enolate Formation / 1.2.:
Other Means of Generating Enolates / 1.3.:
Alkylation of Enolates / 1.4.:
Generation and Alkylation of Dianions / 1.5.:
Medium Effects in the Alkylation of Enolates / 1.6.:
Oxygen versus Carbon as the Site of Alkylation / 1.7.:
Alkylation of Aldehydes, Esters, Amides, and Nitriles / 1.8.:
The Nitrogen Analogs of Enols and Enolates--Enamines and Imine Anions / 1.9.:
Alkylation of Carbon Nucleophiles by Conjugate Addition / 1.10.:
General References
Problems
Reaction of Carbon Nucleophiles with Carbonyl Groups / Chapter 2.:
Aldol Addition and Condensation Reactions / 2.1.:
The General Mechanism / 2.1.1.:
Mixed Aldol Condensations with Aromatic Aldehydes / 2.1.2.:
Control of Regiochemistry and Stereochemistry of Mixed Aldol Reactions of Aliphatic Aldehydes and Ketones / 2.1.3.:
Intramolecular Aldol Reactions and the Robinson Annulation / 2.1.4.:
Addition Reactions of Imines and Iminium Ions / 2.2.:
The Mannich Reaction / 2.2.1.:
Amine-Catalyzed Condensation Reactions / 2.2.2.:
Acylation of Carbanions / 2.3.:
The Wittig and Related Reactions of Phosphorus-Stabilized Carbon Nucleophiles / 2.4.:
Reactions of Carbonyl Compounds with [alpha]-Trimethylsilylcarbanions / 2.5.:
Sulfur Ylides and Related Nucleophiles / 2.6.:
Nucleophilic Addition--Cyclization / 2.7.:
Functional Group Interconversion by Nucleophilic Substitution / Chapter 3.:
Conversion of Alcohols to Alkylating Agents / 3.1.:
Sulfonate Esters / 3.1.1.:
Halides / 3.1.2.:
Introduction of Functional Groups by Nucleophilic Substitution at Saturated Carbon / 3.2.:
General Solvent Effects / 3.2.1.:
Nitriles / 3.2.2.:
Azides / 3.2.3.:
Oxygen Nucleophiles / 3.2.4.:
Nitrogen Nucleophiles / 3.2.5.:
Sulfur Nucleophiles / 3.2.6.:
Phosphorus Nucleophiles / 3.2.7.:
Summary of Nucleophilic Substitution at Saturated Carbon / 3.2.8.:
Nucleophilic Cleavage of Carbon-Oxygen Bonds in Ethers and Esters / 3.3.:
Interconversion of Carboxylic Acid Derivatives / 3.4.:
Preparation of Reactive Reagents for Acylation / 3.4.1.:
Preparation of Esters / 3.4.2.:
Preparation of Amides / 3.4.3.:
Electrophilic Additions to Carbon--Carbon Multiple Bonds / Chapter 4.:
Addition of Hydrogen Halides / 4.1.:
Hydration and Other Acid-Catalyzed Additions of Oxygen Nucleophiles / 4.2.:
Oxymercuration / 4.3.:
Addition of Halogens to Alkenes / 4.4.:
Electrophilic Sulfur and Selenium Reagents / 4.5.:
Addition of Other Electrophilic Reagents / 4.6.:
Electrophilic Substitution Alpha to Carbonyl Groups / 4.7.:
Additions to Allenes and Alkynes / 4.8.:
Addition at Double Bonds via Organoborane Intermediates / 4.9.:
Hydroboration / 4.9.1.:
Reactions of Organoboranes / 4.9.2.:
Enantioselective Hydroboration / 4.9.3.:
Hydroboration of Alkynes / 4.9.4.:
Reduction of Carbonyl and Other Functional Groups / Chapter 5.:
Addition of Hydrogen / 5.1.:
Catalytic Hydrogenation / 5.1.1.:
Other Hydrogen-Transfer Reagents / 5.1.2.:
Group III Hydride-Donor Reagents / 5.2.:
Reduction of Carbonyl Compounds / 5.2.1.:
Stereoselectivity of Hydride Reduction / 5.2.2.:
Reduction of Other Functional Groups by Hydride Donors / 5.2.3.:
Group IV Hydride Donors / 5.3.:
Hydrogen-Atom Donors / 5.4.:
Dissolving-Metal Reductions / 5.5.:
Reductive Removal of Functional Groups / 5.5.1.:
Reductive Carbon--Carbon Bond Formation / 5.5.3.:
Reductive Deoxygenation of Carbonyl Groups / 5.6.:
Reductive Elimination and Fragmentation / 5.7.:
Cycloadditions, Unimolecular Rearrangements, and Thermal Eliminations / Chapter 6.:
Cycloaddition Reactions / 6.1.:
The Diels--Alder Reaction: General Features / 6.1.1.:
The Diels--Alder Reaction: Dienophiles / 6.1.2.:
The Diels--Alder Reaction: Dienes / 6.1.3.:
Asymmetric Diels--Alder Reactions / 6.1.4.:
Intramolecular Diels--Alder Reactions / 6.1.5.:
Dipolar Cycloaddition Reactions / 6.2.:
[2 + 2] Cycloadditions and Other Reactions Leading to Cyclobutanes / 6.3.:
Photochemical Cycloaddition Reactions / 6.4.:
[3,3] Sigmatropic Rearrangements / 6.5.:
Cope Rearrangements / 6.5.1.:
Claisen Rearrangements / 6.5.2.:
[2,3] Sigmatropic Rearrangements / 6.6.:
Ene Reactions / 6.7.:
Unimolecular Thermal Elimination Reactions / 6.8.:
Cheletropic Elimination / 6.8.1.:
Decomposition of Cyclic Azo Compounds / 6.8.2.:
[beta] Eliminations Involving Cyclic Transition States / 6.8.3.:
Organometallic Compounds of the Group I, II, and III Metals / Chapter 7.:
Preparation and Properties / 7.1.:
Reactions of Organomagnesium and Organolithium Compounds / 7.2.:
Reactions with Alkylating Agents / 7.2.1.:
Reactions with Carbonyl Compounds / 7.2.2.:
Organic Derivatives of Group IIB and Group IIIB Metals / 7.3.:
Organozinc Compounds / 7.3.1.:
Organocadmium Compounds / 7.3.2.:
Organomercury Compounds / 7.3.3.:
Organoindium Reagents / 7.3.4.:
Organolanthanide Reagents / 7.4.:
Reactions Involving the Transition Metals / Chapter 8.:
Organocopper Intermediates / 8.1.:
Preparation and Structure of Organocopper Reagents / 8.1.1.:
Reactions Involving Organocopper Reagents and Intermediates / 8.1.2.:
Reactions Involving Organopalladium Intermediates / 8.2.:
Palladium-Catalyzed Nucleophilic Substitution and Alkylation / 8.2.1.:
The Heck Reaction / 8.2.2.:
Palladium-Catalyzed Cross Coupling / 8.2.3.:
Carbonylation Reactions / 8.2.4.:
Reactions Involving Organonickel Compounds / 8.3.:
Reactions Involving Rhodium and Cobalt / 8.4.:
Organometallic Compounds with [pi] Bonding / 8.5.:
Carbon--Carbon Bond-Forming Reactions of Compounds of Boron, Silicon, and Tin / Chapter 9.:
Organoboron Compounds / 9.1.:
Synthesis of Organoboranes / 9.1.1.:
Carbon--Carbon Bond-Forming Reactions of Organoboranes / 9.1.2.:
Organosilicon Compounds / 9.2.:
Synthesis of Organosilanes / 9.2.1.:
Carbon--Carbon Bond-Forming Reactions / 9.2.2.:
Organotin Compounds / 9.3.:
Synthesis of Organostannanes / 9.3.1.:
Reactions Involving Carbocations, Carbenes, and Radicals as Reactive Intermediates / 9.3.2.:
Reactions Involving Carbocation Intermediates / 10.1.:
Carbon-Carbon Bond Formation Involving Carbocations / 10.1.1.:
Rearrangement of Carbocations / 10.1.2.:
Related Rearrangements / 10.1.3.:
Fragmentation Reactions / 10.1.4.:
Reactions Involving Carbenes and Nitrenes / 10.2.:
Structure and Reactivity of Carbenes / 10.2.1.:
Generation of Carbenes / 10.2.2.:
Addition Reactions / 10.2.3.:
Insertion Reactions / 10.2.4.:
Generation and Reactions of Ylides by Carbenoid Decomposition / 10.2.5.:
Rearrangement Reactions / 10.2.6.:
Related Reactions / 10.2.7.:
Nitrenes and Related Intermediates / 10.2.8.:
Rearrangements to Electron-Deficient Nitrogen / 10.2.9.:
Reactions Involving Free-Radical Intermediates / 10.3.:
Sources of Radical Intermediates / 10.3.1.:
Introduction of Functionality by Radical Reactions / 10.3.2.:
Addition Reactions of Radicals to Substituted Alkenes / 10.3.3.:
Cyclization of Free-Radical Intermediates / 10.3.4.:
Fragmentation and Rearrangement Reactions / 10.3.5.:
Aromatic Substitution Reactions / Chapter 11.:
Electrophilic Aromatic Substitution / 11.1.:
Nitration / 11.1.1.:
Halogenation / 11.1.2.:
Friedel-Crafts Alkylations and Acylations / 11.1.3.:
Electrophilic Metalation / 11.1.4.:
Nucleophilic Aromatic Substitution / 11.2.:
Aryl Diazonium Ions as Synthetic Intermediates / 11.2.1.:
Substitution by the Addition-Elimination Mechanism / 11.2.2.:
Substitution by the Elimination-Addition Mechanism / 11.2.3.:
Transition-Metal-Catalyzed Substitution Reactions / 11.2.4.:
Aromatic Radical Substitution Reactions / 11.3.:
Substitution by the S[subscript RN]1 Mechanism / 11.4.:
Oxidations / Chapter 12.:
Oxidation of Alcohols to Aldehydes, Ketones, or Carboxylic Acids / 12.1.:
Transition-Metal Oxidants / 12.1.1.:
Other Oxidants / 12.1.2.:
Addition of Oxygen at Carbon-Carbon Double Bonds / 12.2.:
Epoxides from Alkenes and Peroxidic Reagents / 12.2.1.:
Transformations of Epoxides / 12.2.3.:
Reaction of Alkenes with Singlet Oxygen / 12.2.4.:
Cleavage of Carbon-Carbon Double Bonds / 12.3.:
Oxonolysis / 12.3.1.:
Selective Oxidative Cleavages at Other Functional Groups / 12.4.:
Cleavage of Glycols / 12.4.1.:
Oxidative Decarboxylation / 12.4.2.:
Oxidation of Ketones and Aldehydes / 12.5.:
Oxidation of Ketones and Aldehydes by Oxygen and Peroxidic Compounds / 12.5.1.:
Oxidation with Other Reagents / 12.5.3.:
Allylic Oxidation / 12.6.:
Oxidations at Unfunctionalized Carbon / 12.6.1.:
Planning and Execution of Multistep Syntheses / Chapter 13.:
Protective Groups / 13.1.:
Hydroxyl-Protecting Groups / 13.1.1.:
Amino-Protecting Groups / 13.1.2.:
Carbonyl-Protecting Groups / 13.1.3.:
Carboxylic Acid-Protecting Groups / 13.1.4.:
Synthetic Equivalent Groups / 13.2.:
Synthetic Analysis and Planning / 13.3.:
Control of Stereochemistry / 13.4.:
Illustrative Syntheses / 13.5.:
Juvabione / 13.5.1.:
Longifolene / 13.5.2.:
Prelog-Djerassi Lactone / 13.5.3.:
Taxol / 13.5.4.:
Epothilone A / 13.5.5.:
Solid-Phase Synthesis / 13.6.:
Solid-Phase Synthesis of Polypeptides / 13.6.1.:
Solid-Phase Synthesis of Oligonucleotides / 13.6.2.:
Combinatorial Synthesis / 13.7.:
References for Problems
Index
Alkylation of Nucleophilic Carbon Intermediates / Chapter 1.:
Generation of Carbanions by Deprotonation / 1.1.:
Regioselectivity and Stereoselectivity in Enolate Formation / 1.2.:
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