Preface |
Acknowledgments |
Fundamentalsof NMR Spectroscopy in Liquids / 1: |
Introduction to NMR Spectroscopy / 1.1: |
Examples: NMR Spectroscopy of Oligosaccharides and Terpenoids / 1.2: |
Typical Values of Chemical Shifts and Coupling Constants / 1.3: |
Fundamental Concepts of NMR Spectroscopy / 1.4: |
Interpretation of Proton (1H) NMR Spectra / 2: |
Assignment / 2.1: |
Effect of Bo Field Strength on the Spectrum / 2.2: |
First-Order Splitting Patterns / 2.3: |
The Use of 1H-1H Coupling Constants to Determine Stereochemistry and Conformation / 2.4: |
Symmetry and Chirality in NMR / 2.5: |
The Origin of the Chemical Shift / 2.6: |
J Coupling to Other NMR-Active Nuclei / 2.7: |
Non-First-Order Splitting Patterns: Strong Coupling / 2.8: |
Magnetic Equivalence / 2.9: |
NMR Hardware and Software / 3: |
Sample Preparation / 3.1: |
Sample Insertion / 3.2: |
The Deuterium Lock Feedback Loop / 3.3: |
The Shim System / 3.4: |
Tuning and Matching the Probe / 3.5: |
NMR Data Acquisition and Acquisition Parameters / 3.6: |
Noise and Dynamic Range / 3.7: |
Special Topic: Oversampling and Digital Filtering / 3.8: |
NMR Data Processing-Overview / 3.9: |
The Fourier Transform / 3.10: |
Data Manipulation Before the Fourier Transform / 3.11: |
Data Manipulation After the Fourier Transform / 3.12: |
Carbon-13 ( 13 C) NMR Spectroscopy / 4: |
Sensitivity of 13 C / 4.1: |
Splitting of 13 C Signals / 4.2: |
Decoupling / 4.3: |
Heteronuclear Decoupling / 4.4: |
H Decoupled 13C Spectra |
Decoupling Hardware / 4.5: |
Decoupling Software: Parameters / 4.6: |
The Nuclear Overhauser Effect (NOE) / 4.7: |
Heteronuclear Decoupler Modes / 4.8: |
NMR Relaxation-Inversion-Recovery and the Nuclear Overhauser Effect (NOE) / 5: |
The Vector Model / 5.1: |
One Spin in a Magnetic Field / 5.2: |
A Large Population of Identical Spins: Net Magnetization / 5.3: |
Coherence: Net Magnetization in the x-y Plane / 5.4: |
Relaxation / 5.5: |
Summary of the Vector Model / 5.6: |
Molecular Tumbling and NMR Relaxation / 5.7: |
Inversion-Recovery: Measurement of T 1 Values / 5.8: |
Continuous-Wave Low-Power Irradiation of One Resonance / 5.9: |
Homonuclear Decoupling / 5.10: |
Presaturation of Solvent Resonance / 5.11: |
The Homonuclear Nuclear Overhauser Effect (NOE) / 5.12: |
Summary of the Nuclear Overhauser Effect / 5.13: |
The Spin Echo and the Attached Proton Test (APT) / 6: |
The Rotating Frame of Reference / 6.1: |
The Radio Frequency (RF) Pulse / 6.2: |
The Effect of RF Pulses / 6.3: |
Quadrature Detection, Phase Cycling, and the Receiver Phase / 6.4: |
Chemical Shift Evolution / 6.5: |
Scalar (J) Coupling Evolution / 6.6: |
Examples of J-coupling and Chemical Shift Evolution / 6.7: |
The Attached Proton Test (APT) / 6.8: |
The Spin Echo / 6.9: |
The Heteronuclear Spin Echo: Controlling J-Coupling Evolution and Chemical Shift Evolution / 6.10: |
Coherence Transfer: INEPT and DEPT / 7: |
Net Magnetization / 7.1: |
Magnetization Transfer / 7.2: |
The Product Operator Formalism: Introduction / 7.3: |
Single Spin Product Operators: Chemical Shift Evolution / 7.4: |
Two-Spin Operators: J-coupling Evolution and Antiphase Coherence / 7.5: |
The Effect of RF Pulses on Product Operators / 7.6: |
INEPT and the Transfer of Magnetization from 1 H to 13 C / 7.7: |
Selective Population Transfer (SPT) as a Way of Understanding INEPT Coherence Transfer / 7.8: |
Phase Cycling in INEPT / 7.9: |
Intermediate States in Coherence Transfer / 7.10: |
Zero- and Double-Quantum Operators / 7.11: |
Summary of Two-Spin Operators / 7.12: |
Refocused INEPT: Adding Spectral Editing / 7.13: |
DEPT: Distortionles / 7.14: |
Preface |
Acknowledgments |
Fundamentalsof NMR Spectroscopy in Liquids / 1: |