Transition metal carbonyl cluster chemistry

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Transition metal carbonyl cluster chemistry / Paul J. Dyson and J. Scott Mclndoe

資料種別:

図書

出版情報:

Amsterdam : Gordon and Breach Science, c2000

形態:

xi, 166 p. ; 26 cm

シリーズ名:

Advanced chemistry texts ; v. 2 <BA53464502>

著者名:

ISBN:

9789056992897 [9056992899]

書誌ID:

BA53464648

子書誌情報

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書誌詳細

注記:

Includes bibliographical references (p. 157) and indexes

主題:

有機化学

言語:

英語

目次情報:

Foreword

Preface

Introduction / Chapter 1：

Definition and Scope / 1.1：

Transition Metal Carbonyl Clusters / 1.2：

When Does a Cluster Become Metal-like? / 1.2.1：

Growth in Transition Metal Carbonyl Cluster Chemistry / 1.2.2：

Electron Counting and Metal-Metal Bonding / Chapter 2：

The Ligands / 2.1：

The Eighteen-Electron Rule / 2.2：

The Effective Atomic Number (EAN) Rule / 2.3：

Wade's Rules / 2.4：

The Isolobal Principle / 2.5：

Polyhedral Skeletal Electron Pair Theory (PSEPT) / 2.6：

The Capping Principle / 2.7：

Condensed Polyhedra / 2.8：

Structure / Chapter 3：

Mononuclear and Dinuclear Complexes / 3.1：

Trinuclear and Tetranuclear Clusters / 3.2：

Pentanuclear and Hexanuclear Clusters / 3.3：

Capped Polyhedra / 3.4：

Coupled and Condensed Polyhedra / 3.5：

Open and Planar Clusters / 3.6：

Larger Clusters / 3.7：

Clusters with Metal-Metal Multiple Bonds / 3.8：

Ligands / Chapter 4：

Carbon Monoxide / 4.1：

Bonding Modes of CO / 4.1.1：

Other Effects / 4.1.2：

Ligands Related to CO / 4.2：

Phosphorus Ligands / 4.3：

Interstitial Main Group Atoms / 4.4：

Hydride Ligands / 4.5：

Unsaturated Organic Ligands / 4.6：

Alkene and Alkyne Ligands / 4.6.1：

Unsaturated Rings / 4.6.2：

Other Ligands / 4.7：

Characterisation Techniques / Chapter 5：

Infrared Spectroscopy / 5.1：

Mass Spectrometry / 5.2：

Nuclear Magnetic Resonance Spectroscopy / 5.3：

[superscript 1]H NMR Spectroscopy / 5.3.1：

Variable-temperature NMR Spectroscopy / 5.3.2：

[superscript 13]C NMR Spectroscopy / 5.3.3：

X-ray Crystallography / 5.4：

Representations of X-ray Structures / 5.4.1：

Disorder / 5.4.2：

Neutron Diffraction / 5.4.3：

Miscellaneous Characterisation Techniques / 5.5：

Electron Paramagnetic Resonance Spectroscopy / 5.5.1：

UV-visible Spectroscopy / 5.5.2：

Mossbauer Spectroscopy / 5.5.3：

Cluster-surface Analogy / 5.6：

Synthesis / Chapter 6：

Simple Homoleptic Carbonyls / 6.1：

High Nuclearity Carbonyl Clusters / 6.2：

Preparation from Salts / 6.2.1：

Thermolysis and Pyrolysis / 6.2.2：

Reduction and Oxidation / 6.2.3：

Redox Condensation Reactions / 6.2.4：

Cluster Build-up Reactions from Preformed High Nuclearity Clusters / 6.2.5：

Reactivity / Chapter 7：

Reduction / 7.1：

Protonation / 7.2：

Substitution / 7.3：

Association and Dissociation / 7.4：

Oxidative Addition and Reductive Elimination / 7.5：

Carbide Formation / 7.6：

Cluster Decomposition Reactions / 7.7：

Reactions with Organic Ligands / Chapter 8：

Alkyl and Alkylidyne Clusters / 8.1：

Alkenes, Alkynes and Allyls / 8.2：

C[subscript 5]-Rings / 8.3：

C[subscript 6]-Rings / 8.4：

C[subscript 7] and C[subscript 8]-Rings / 8.5：

Heterocycles / 8.6：

Heteronuclear Carbonyl Clusters / Chapter 9：

Condensation Reactions / 9.1：

Ligand Displacement / 9.1.2：

Addition Reactions / 9.1.3：

Redox Condensation / 9.1.4：

Bridging Ligands / 9.1.5：

Condensation with Electrophilic Capping Groups / 9.1.6：

Serendipitous Syntheses / 9.1.7：

Heterosite Reactivity / 9.2：

Organic Transformations Using Stoichiometric and Catalytic Quantities of Clusters / Chapter 10：

Establishing Catalysis by Clusters / 10.1：

Hydrogenation Reactions / 10.2：

Hydroformylation / 10.3：

The Water-Gas Shift Reaction / 10.4：

C-H Bond Activation and C-C Bond Formation / 10.5：

Mixed-metal Clusters in Catalysis / 10.6：

Supported Cluster Catalysis and Use of Non-organic Solvents / 10.7：

Solid Supported Clusters / 10.7.1：

Biphasic 'Liquid-liquid' Supports / 10.7.2：

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