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図書

図書
Gennady V. Korolyov, Michael M. Mogilevich
出版情報: Berlin : Springer, c2009  xv, 270 p. ; 24cm
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Three-Dimensional Free-Radical Polymerization. Cross-Linked Polymers / Part I:
Microheterogeneous Mechanism of Three-Dimensional Free-Radical Polymerization / 1:
Microheterogeneous Model of Polymerization Process / 1.1:
Polymerization Process: Stages of Formation of the Microheterogeneous Structure for Cross-Linked Polymers / 1.2:
Formation of Polymer Grains at the Initial Stage of Polymerization / 1.2.1:
Growth of Polymer Grains During Polymerization / 1.2.2:
Accretion of Polymer Grains at the Final Stages of Polymerization / 1.2.3:
Structural and Physical Processes Taking Place During Three-Dimensional Free-Radical Polymerization / 1.3:
Microsyneresis of Liquid Components in Reaction Medium / 1.3.1:
Microredistribution of Substances Dissolved in Liquid Components / 1.3.2:
Local Glass Transition of Highly Cross-Linked Micro-Volumes of Polymer / 1.3.3:
Microheterogeneous Structure of Cross-Linked Polymers / 1.4:
Interlayers Between Polymer Grains / 1.4.1:
Polymer Grains / 1.4.2:
References
Kinetic Features of Three-Dimensional Free-Radical Polymerization / 2:
Kinetic Features of Individual Stages of Polymerization / 2.1:
Initial Stage of Polymerization / 2.1.1:
Stages of Auto-Acceleration and Auto-Deceleration / 2.1.2:
Inhibited Polymerization / 2.2:
Polymerization in Solutions / 2.3:
Polymerization in Films Under the Conditions of Oxygen Diffusion / 2.4:
Vinyl Compounds / 2.4.1:
Allyl Compounds / 2.4.2:
Three-Dimensional Free-Radical Polymerization as a Tool for Macromolecular Design of Cross-Linked Polymers / 2.5:
Living Chain Three-Dimensional Radical Polymerization / 3:
Living Chains in Free-Radical Polymerization / 3.1:
Implementation of Living Chains Conditions in Three-Dimensional Free-Radical Polymerization / 3.2:
Copolymerization of Styrene with Dimethacrylates in the Presence of Alkoxyamines / 3.2.1:
Polymerization of Dimethacrylates of Poly(Ethylene Glycol)s in the Presence of Complex CuBr with Organic Ligands / 3.2.2:
Living Chain Three-Dimensional Free-Radical Polymerization as a Tool for Macromolecular Design of Cross-Linked Polymers / 3.3:
Kinetic Features of Three-Dimensional Free-Radical Copolymerization / 4:
Kinetic Features of Three-Dimensional Copolymerization of Oligomer and Vinyl Monomers / 4.1:
Variation of Copolymer Composition During Three-Dimensional Free-Radical Copolymerization of Oligomers and Vinyl Monomer / 4.2:
Critical Conversion (Gel Point) in Three-Dimensional Free-Radical Polymerization / 5:
Inapplicability of Known Critical Conversion Calculation Methods to Three-Dimensional Free-Radical Polymerization / 5.1:
Novel Approach to Calculating Critical Conversion in Three-Dimensional Free-Radical Polymerization / 5.2:
Results of Critical Conversion Calculation for Different Cases of Three-Dimensional Free-Radical Polymerization / 5.3:
Living Chains Three-Dimensional Polymerization and Copolymerization (Without Chain Termination) / 5.3.1:
Three-Dimensional Polymerization and Copolymerization with Quadratic or Linear Chain Termination / 5.3.2:
Three-Dimensional Polymerization with "Pendent" Double Bonds Taken into Account (Chain Termination by Disproportionation) / 5.3.3:
Summary of Results of Theoretical Calculations for Critical Conversion / 5.3.4:
Comparison of Results of Theoretical Calculations for Critical Conversion with Experimental Data / 5.4:
Inhibited Polymerization of Dimethacrylates / 5.4.1:
Copolymerization of Divinyl Benzene (m-DVB) with Styrene / 5.4.2:
Properties of Cross-Linked Polymers and Copolymers / 6:
Cross-Linked Poly(acrylates). Physical and Mechanical Properties / 6.1:
Influence of Chemical Structure of Oligomers upon Physical and Mechanical Properties of Cross-Linked Poly(acrylates) / 6.1.1:
Influence of Physical Network Density upon Physical and Mechanical Properties of Cross-Linked Poly(acrylates) / 6.1.2:
Cross-Linked Copolymers. Physical and Mechanical Properties / 6.2:
Mechanism of Copolymers Transition into Forced-Elastic State / 6.2.1:
Influence of Cyclization on Physical and Mechanical Properties of Copolymers / 6.2.2:
Cross-Linked Copolymers. Thermo-Mechanical Properties / 6.3:
Mechanism of Copolymers Transition into High-Elastic State / 6.3.1:
Comparison of Transitions into High-Elastic State with those into Forced-Elastic State / 6.3.2:
Diffusion-Sorption Properties of Copolymers / 6.4:
Three-Dimensional Free-Radical Polymerization. Hyper-Branched Polymers / Part II:
Synthesis of Hyper-Branched Polymers / 7:
Classification of Reactions for Hyper-Branched Polymer Synthesis / 7.1:
Synthesis of Hyper-Branched Polymers Via Three-Dimensional Free-Radical (Co)polymerization with Regulation of Polymer Chain Length / 7.2:
Regulation of Chain Length Through Initiation Rate Variation / 7.2.1:
Regulation of Chain Length by Chain Transfer Agents and Chain Transfer Catalysts / 7.2.2:
Regulation of Chain Length Through the Use of Intrachain Reactions of Chain Carrier Radicals / 7.2.3:
Regulation of Chain Length Through the Use of Molecular Oxygen as an Inhibitor / 7.2.4:
Synthesis of Hyper-Branched Polymers Via Living Chains Free-Radical Three-Dimensional Polymerization / 7.3:
Living Chains Free-Radical Three-Dimensional Polymerization as Reaction for Hyper-Branched Polymers Synthesis / 7.3.1:
Living Chains Polymerization of Vinyl Monomers with Diethyldithiocarbamate Groups / 7.3.2:
Properties and Application of Hyper-Branched Polymers / 8:
"Structure-Property" Relationship and Purposeful Generation of Hyper-Branched Polymer Properties That Are in Demand in Practice / 8.1:
Hyper-Branched Polymers as Modifiers of Polymeric Materials / 8.2:
Major Fields for Hyper-Branched Polymers Application / 8.3:
HBP: Main Achievements and Problems to Be Solved Without Delay / 8.4:
Methods for Studying Three-Dimensional Free-Radical Polymerization and Cross-Linked Polymers / 9:
Calorimetry / 9.1:
IR Spectroscopy / 9.2:
Other Methods of Kinetic Measurements / 9.3:
Light Scattering / 9.4:
EPR / 9.5:
Studying the Kinetics of Free-Radical Accumulation in Nonstationary Mode / 9.5.1:
Studying the Kinetics of Decay of Accumulated Free Radicals / 9.5.2:
Structural and Physical Studies Using EPR / 9.5.3:
NMR / 9.6:
Physicomechanical and Thermo-Mechanical Methods / 9.7:
Volumetric Method / 9.8:
Complex Methods / 9.9:
Index
Three-Dimensional Free-Radical Polymerization. Cross-Linked Polymers / Part I:
Microheterogeneous Mechanism of Three-Dimensional Free-Radical Polymerization / 1:
Microheterogeneous Model of Polymerization Process / 1.1:
2.

電子ブック

EB
Krzysztof Matyjaszewski, Thomas P. Davis
出版情報: [S.l.] : Wiley Online Library, [20--]  1 online resource (xii, 920 p.)
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目次情報: 続きを見る
Introduction / Krzysztof Matyjaszewski ; Thomas P. Davis
Contributors
Theory of Radical Reactions / Johan P. A. Heuts1:
Small Radical Chemistry / Martin Newcomb2:
General Chemistry of Radical Polymerization / Bunichiro Yamada ; Per B. Zetterlund3:
The Kinetics of Free Radical Polymerization / Christopher Barner-Kowollik ; Philipp Vana4:
Copolymerization Kinetics / Michelle L. Coote5:
Heterogeneous Systems / Alex M. van Herk ; Michael Monteiro6:
Industrial Applications and Processes / Michael Cunningham ; Robin Hutchinson7:
General Concepts and History of Living Radical Polymerization / 8:
Kinetics of Living Radical Polymerization / Takeshi Fukuda ; Atsushi Goto ; Yoshinobu Tsujii9:
Nitroxide Mediated Living Radical Polymerization / Craig J. Hawker10:
Fundamentals of Atom Transfer Radical Polymerization / Jianhui Xia11:
Control of Free Radical Polymerization by Chain Transfer Methods / John Chiefari ; Ezio Rizzardo12:
Control of Stereochemistry of Polymers in Radical Polymerization / Akikazu Matsumoto13:
Macromolecular Engineering by Controlled Radical Polymerization / Yves Gnanou ; Daniel Taton14:
Experimental Procedures and Techniques for Radical Polymerization / Stefan A. F. Bon ; David M. Haddleton15:
Future Outlook and Perspectives / 16:
Index
Introduction / Krzysztof Matyjaszewski ; Thomas P. Davis
Contributors
Theory of Radical Reactions / Johan P. A. Heuts1:
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