| Preface |
| Preface to the Second Edition |
| Preface to the First Edition |
| Fundamentals / 1： |
| Introductory Remarks / 1.0： |
| Introductory Definitions / 1.1： |
| The Zeroth Law of Thermodynamics / 1.2： |
| Mathematical Apparatus / 1.3： |
| Thermodynamic Forces / 1.4： |
| Elements of Work / 1.5： |
| The Element of Work for a System Subjected to Electromagnetic Fields / 1.6： |
| The First Law of Thermodynamics / 1.7： |
| The First Law of Thermodynamics as a Parable / 1.8： |
| The Second Law of Thermodynamics / 1.9： |
| Cyclic Processes in Relation to Reversibility and Irreversibility. Carnot Efficiency / 1.10： |
| An Entropy Analogy / 1.11： |
| Constraints, Equilibrium, Functions of State / 1.12： |
| Systematics of Thermodynamic Functions of State / 1.13： |
| Interrelations Involving Heat Capacities / 1.14： |
| The Joule-Thomson Experiment / 1.15： |
| Heat Measurements and Calorimetry / 1.16： |
| Determination of Enthalpies and Entropies of Materials / 1.17： |
| The Third Law of Thermodynamics / 1.18： |
| The Gibbs-Duhem Relation and Its Analogs / 1.19： |
| Thermodynamics of Open Systems / 1.20： |
| Effect of Chemical Changes on Composition / 1.21： |
| Legendre Transforms and Stability of a System / 1.22： |
| Equilibrium in Ideal Systems / 2： |
| Thermodynamics of Ideal Systems with Several Components and Phases / 2.0： |
| Coexistence of Phases: The Gibbs Phase Rule / 2.1： |
| Achievement of Equilibrium / 2.2： |
| System of One Component and Several Phases; The Clausius-Clapeyron Equation / 2.3： |
| Properties of Ideal Gases / 2.4： |
| Properties of Ideal Solutions in Condensed Phases / 2.5： |
| The Duhem-Margules Equation and its Consequences / 2.6： |
| Temperature Dependence of Composition of Solutions / 2.7： |
| Lowering of the Freezing Point and Elevation of the Boiling Point of a Solution / 2.8： |
| Chemical Equilibrium: General Principles and Application to Ideal Gases / 2.9： |
| Chemical Equilibrium in Homogeneous Condensed Ideal Solutions / 2.10： |
| Chemical Equilibrium in Ideal Heterogeneous Systems / 2.11： |
| Equilibrium Between Two Ideal Phases / 2.12： |
| Chemical Irreversibility in Chemical Reactions; The Affinity / 2.13： |
| Characterization of Nonideal Solutions / 3： |
| Thermodynamic Treatment of Nonideal Gas Mixtures / 3.0： |
| Temperature and Pressure Dependence of the Fugacity of a Gas / 3.2： |
| Thermodynamic Description of Real Solutions in the Condensed State / 3.3： |
| Characterization of Nonideal Solutions; Preliminaries / 3.4： |
| Standardization of Thermodynamic Analysis for Nonideal Solutions / 3.5： |
| Reformulation of the Thermodynamic Description of Nonideal Solutions / 3.6： |
| Characterization of Equilibrium in Nonideal Solutions / 3.7： |
| Variation of Activity, Activity Coefficients with Temperature and Presssure / 3.8： |
| Calorimetric Functions of State in Chemical Processes / 3.9： |
| Equilibrium Calculations / 3.10： |
| Determination of Activity Coefficients by Vapor Pressure Measurements / 3.11： |
| Oxidation Boundary for Magnetite-Zinc Ferrite Solid Solutions / 3.12： |
| Activity of Solvent and Solute from Lowering of the Freezing Point of the Solution / 3.13： |
| Mixing in Nonideal Solutions / 3.14： |
| Phase Stability: General Consequences of Deviations from Ideality / 3.15： |
| Discussion of Several Types of Phase Diagrams / 3.16： |
| Variation of Mutual Solubility with Temperature; Second Order Transitions / 3.17： |
| Thermodynamic Properties of Electrolytes / 4： |
| Introductory Comments / 4.0： |
| Activities of Strong Electrolytes / 4.1： |
| Theoretical Determination of Activities in Electrolyte Solutions; The Debye-Huckel Equation / 4.2： |
| Experimental Determination of Activities and Activity Coefficients of Strong Electrolytes / 4.3： |
| Equilibrium Properties of Weak Electrolytes / 4.4： |
| Galvanic Cells / 4.5： |
| Operation of Galvanic Cells / 4.6： |
| Galvanic Cells; Operational Analysis / 4.7： |
| Liquid Junction Potentials / 4.8： |
| EMF Dependence on Activities / 4.9： |
| Types of Operating Cells / 4.10： |
| Thermodynamic Information from Galvanic Cell Measurements / 4.11： |
| Thermodynamic Properties of Materials in Externally Applied Fields / 5： |
| Thermodynamics of Gravitational Fields / 5.0： |
| Thermodynamics of Adsorption Processes / 5.2： |
| Heats of Adsorption / 5.3： |
| Surface vs. Bulk Effects; Thermodynamics of Self-Assembly / 5.4： |
| Pressure of Electromagnetic Radiation / 5.5： |
| Thermodynamic Characterization of Electromagnetic Radiation / 5.6： |
| Effects of Electric Fields on Thermodynamic Properties of Matter / 5.7： |
| Systematization of Electromagnetic Field Effects in Thermodynamics / 5.8： |
| Adiabatic Demagnetization and Transitions to Superconductivity / 5.9： |
| Irreversible Thermodynamics / 6： |
| Generalities / 6.0： |
| Shock Phenomena / 6.2： |
| Linear Phenomenological Equations / 6.3： |
| Steady State Conditions and Prigogine's Theorem / 6.4： |
| Onsager Reciprocity Conditions / 6.5： |
| Thermomolecular Mechanical Effects / 6.6： |
| Electrokinetic Phenomena / 6.7： |
| The Soret Effect / 6.8： |
| Thermoelectric Effects / 6.9： |
| Irreversible Thermomagnetic Phenomena in Two Dimensions / 6.10： |
| Chemical Processes / 6.11： |
| Coupled Reactions: Special Example / 6.12： |
| Coupled Reactions, General Case / 6.13： |
| Critical Phenomena / 7： |
| Properties of Materials Near Their Critical Point / 7.0： |
| Homogeneity Requirements, Correlation Lengths, and Scaling Properties / 7.2： |
| Derivation of Griffith's and Rushbrooke's Inequality / 7.3： |
| Scaled Equation of State / 7.4： |
| Landau Theory of Critical Phenomena and Phase Transitions / 7.5： |
| A Final Speculation About Ultimate Temperatures-A Fourth Law of Thermodynamics? / 8： |
| Mathematical Proof of the Caratheodory Theorem and Resulting Interpretations; Derivation of the Debye-Huckel Equation / 9： |
| Proof of Holonomicity / 9.1： |
| Necessary Condition for Establishing the Caratheodory Theorem / 9.3： |
| Relevance to Thermodynamics / 9.4： |
| Derivation of the Limiting Form for the Debye-Huckel Equation / 9.5： |
| Index |
| Preface |
| Preface to the Second Edition |
| Preface to the First Edition |
図書
