Foreword |
Preface |
Contributors |
Preparation of Elemental Fluorine / Karl O. Christe1: |
Preparation of Highly Active Caesium Fluoride / Konrad Seppelt2: |
Preparation of Highly Active Silver Fluoride / 3: |
A Room Temperature, Non-Irradiative Synthesis of Xenon Difluoride (XeF2) / Ulf Breddemann ; John R. DeBackere ; Gary J. Schrobilgen4: |
Efficient Perfluorination of K2B12H12 in Neutralizing Acetonitrile / Dmitry V. Peryshkov ; Steven H. Strauss5: |
Efficient Preparation of the Highly Soluble ortho- and para-C60(CF2C6F5)2 Derivatives / Igor V. Kuvychko ; Bryon W. Larson ; Olga V. Boltalina6: |
Synthesis of Cs[1-H-CB11F11] / Josef Michl7: |
Synthesis of Zero-Valent Trifluoromethyl Chalcogenato Derivatives, [NMe4]ECF3 (E = S, Se, Te) and Related Compounds / Wieland Tyrra ; Silke Kremer8: |
Synthesis Methods for Exotic Inorganic Fluorides with Varied Applications / Dayal T. Meshri ; N. C. Mathur ; Ritesh R. Jain9: |
Tris(pentafluorophenyl)boran, B(C6F5)3, a Powerful, Well-soluble, and Non-oxidizing Lewis Acid and the Weakly Coordinating Tetrakis(pentafluorophenyl)borate Anion, [B(C6F5)4]? / Hermann-Josef Frohn10: |
Pentafluorophenyldifluoroboran, C6F5BF2, and Pentafluorophenyltrifluorosilane, C6F5SiF3, Versatile Reagents for Fluorine/Pentafluorophenyl Substitution Reactions in Strongly Oxidizing Hypervalent Non-metal Fluorides / 11: |
Iodine(III and V) Fluorides: Interesting Fluorinating Agents / 12: |
Tetramethylammonium Fluoride, [N(CH3)4]F, a Widely Applicable Reagent to Introduce Fluoride Ions and a Suitable Nucleophile to Initiate the Transfer of Perfluoroorganyl Groups to Electrophiles Hermann-Josef Frohn / 13: |
Preparation of Transition Metal Sulfide Fluorides / Michael Gerken14: |
Transition Metal Carbonyl Sulfur Dioxide and Thiazylfluoride Complexes: Reactions at the Metal Center and at the Ligand / Rüdiger Mews15: |
Cesium-, Mercury- and Silver-Salts with Sulfur-Nitrogen-Fluorine Anions: Useful Transfer-Reagents for NSF-Building Blocks / 16: |
Laboratory-Scale Synthesis of Gold Trifluoride and Uranium Hexafluoride / Thomas M. Klapötke17: |
Preparation of Fluorine Containing Molecular Halides and Hetero polar Salts with Elements of Group 15 and Niobium and Tantalum Halides / Ralf Haiges ; Lothar Kolditz18 Preparation of Transition Metal Fluorides using ClF3: |
Fluoro- and Fluorohydroxy Complexes of As, Sb, and Sn / 20: |
Trifluoromethyl Compounds via Electrophilic and Nucleophilic Reactions / Jeanne M. Shreeve21: |
Introduction of Fluorine into Compounds via Electrophilic and Nucleophilic Reactions / 22: |
The ?Real? Iodine and Bromine Mono-Fluorides / Shlomo Rozen23: |
The Versatile Chemistry of Acetyl Hypofluorite ? Hypofluorite not Bonded to Polyhaloalkyl group Shlomo Rozen / 24: |
The Surprising Chemistry of Bromine Trifluoride / 25 Direct Fluorination of Organic Compounds with Elemental Fluorine: |
Preparation of Silicon- and Sulfur-Based Fluorinated Methane Derivatives as Versatile Fluoromethylation Reagents / G. K. Surya Prakash ; Fang Wang27: |
Pentafluoroethyl Lithium: Reactions with Carbonyl Compounds and Epoxides / Gerd-Volker Röschenthaler28: |
Synthesis of ?-hydroxy-α,α-difluoromethylenephosphonates / 29: |
Synthesis of Pentafluoro-?6-sulfanyl Substituted Acetylenes for Liquid Crystals / 30: |
Delocalized Lipophilic Cations as a Source of Naked Fluoride and Phase-transfer Catalysts / 31: |
Methyltrifluoropyruvate Imines Possessing N-oxalyl and N-phosphonoformyl Groups ? Precursors to a Variety of α-CF3-α-amino Acid Derivatives / 32: |
Rhodium-mediated Synthesis of (3,3,3-Trifluoropropyl)trimethoxysilane and (3,3,3 trifluoropropyl)triphenylsilane / Falk Wehmeier ; Thomas Braun33: |
Rhodium-mediated Synthesis of a Tetrafluoropyridyl-2-boronate Ester / Michael Teltewskoi34: |
Palladium-mediated Synthesis of 4-Vinyltetrafluoropyridine and 2,3,5,6-Tetrafluoropyridine / David Breyer35: |
Preparation of Polyfluoroaryl-1,2-difluorovinylsilanes / Donald J. Burton ; Ba V. Nguyen36: |
Preparation of (Z)-2-iodo-1,2-difluorostyrenes / Ling Xue37: |
Preparation of 1,4-Bis(Z-2-iodo-1,2-difluoroethenyl)benzene / Craig A. Wesolowski38: |
Stereospecific Carboamidation Route to (Z)-N-Phenyl-2,3-difluoro-3-(triethylsilyl) acrylamide / 39: |
Preparation of 2-Trifluoromethyl-3,3,3-trifluoropropanal / Donald A. Wiebe40: |
Synthesis of Tetrafluorocatechol / Sudharsanam Ramanathan ; Dayong Sang ; Vivek Kumar ; David M. Lemal41: |
Preparation of an Unsymmetrial Bis((perfluoroalkyl)sulfonyl)imide / Darryl D. DesMarteau ; Thomas D. Hickman42: |
Preparation of Perfluoroalkyl Sulfilimines and Sulfoximines / Emmanuel Magnier43: |
Preparation of Trifluoromethylsulfonium Salts / 44: |
Preparation of Organometallic Fluorides of Main Group and Transition Elements / Herbert W. Roesky45: |
Preparation of Pentafluorosulfanyl Carbonyl Compounds / John T. Welch46: |
Synthesis of Fluorine Containing Heterocycles from α,α-Dihydropolyfluoroalkylsulfides and Fluorinated Thiocarboxylic Acids / Teruo Umemoto ; Vadim M. Timoshemko ; Yuriy G.Shermolovich47 Preparation of Power-variable Electrophilic Trifluoromethylating Agents, S-(Trifluoromethyl)dibenzothiophenium Salts Series: |
Synthesis of Octafluorocyclooctatetraene / John M. Buzby ; Aldos C. Barefoot ; III ; Michael W. Grayston ; Evan D. Laganis ; Roy F. Waldron49: |
Preparation of Fluoroolefins / Moritz F. Kühnel ; Dieter Lentz50: |
Preparation of Ionic Liquids of Fluorocomplex and Oxofluorocomplex Anions by Fluoroacid-base Reactions / Kazuhiko Matsumoto ; Rika Hagiwara51: |
Synthesis of Difluorocyclopropyl Building Blocks: 2,2-Difluorocyclopropylmethanol and 2-(Bromomethyl)-1,1-Difluorocyclopropane / Wei Xu ; William R. Dolbier, Jr52: |
Preparation of 1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane and Perfluoro[2.2]paracyclophane / William R. Dolbier ; Jr., Jian-Xi Duan ; Alex J. Roche ; Lianhao Zhang53: |
Efficient Preparation of Bioorganic Fluorine Compounds / Xiao-Long Qiu54: |
1,3-Dipolar Cycloaddition Reactions to Fluoroalkenes / Hanna Wójtowicz-Rajchel, Henryk Koroniak55: |
Synthesis of Fluorinated Vinyl Derivatives of Nucleic Acid Bases / Hanna Wójtowicz-Rajchel ; Donata Pluskota-Karwatka ; Henryk Koroniak56: |
Synthesis of CF3-substituted Aziridine Ring by the Gabriel Reaction / Tomasz Cytlak ; Bartosz Marciniak57: |
Preparation of α-Fluoro Amino and α-Fluoro Enamino Reagents / Justyna Walkowiak58: |
Synthesis of Original Fluoromonomers and Their Radical copolymerization with Vinylidene fluoride / Bruno Ameduri59: |
Convergent 18F Radiosynthesis / V. Gouverneur, O. Lozano60: |
Asymmetric Fluorocyclization Reactions / V. Gouverneur ; O. Lozano61: |
Preparation of Allylic Fluorides / 62: |
Dehydroxyfluorinations of Primary or Secondary Alcohols Using Perfluoro n-butylsulfonyl Fluoride (nonaflyl Fluoride, NfF) in Combination with 1,8-Diaza-bicyclo[5.4.0]undec-7-ene (DBU) / Orlin Petrov ; Matthias Schneider ; Rolf Bohlmann ; Stephan Vettel ; Helmut Vorbrüggen63: |
Preparation of Rare Earth Fluorosulfides and Oxyfluorosulfides / A. Demourgues ; A.Tressaud64: |
Preparation of Carbon-Fluorine Compounds and Fluoride or Oxide Fluoride-Intercalated Graphites / Tsuyoshi Nakajima65: |
Safe Synthesis of Superstoichiometric Mesoporous Fluorocarbons / Valentin N. Mitkin66: |
Preparation of Fluorinated ?-Alumina / Erhard Kemnitz ; Toma? Skapin ; John M. Winfield67: |
Index |