Introduction |
Energy level designations |
Effective Hamiltonians. |
Energy matrix. |
Diagonal elements. |
Off-diagonal elements. |
Energy expressions referred to the ground state. |
Vibrational states. |
Rotational states. |
Conversion table for energy-related units and selected fundamental constants. |
Formulas for determining rotational constants |
Effective parameters. |
Band center and band origin. |
Comments on BHO (HBO) (see Chap.6 of subvolume II/20B1). |
Diagonalizing the energy matrix. |
Effective molecular parameters. |
Unperturbed vibrational states. |
Effects of perturbations. |
Quadrupole coupling. |
Potential energy function (PEF) |
PEF expanded as a Taylor series. |
Curvilinear valence coordinates and Morse functions. |
Dimensionless normal coordinates. |
Specific forms of the PEF. Dipole moment |
General equations. |
Specifics related to COS (OCS) (see Chap.38 of subvolume II/20B1). |
Intensities |
Intensities of spectral lines. |
Integrated absorption intensities. |
Total internal partition sum. |
F-factors (Herman-Wallis factors). |
Intensity expressions. |
Intensity units and conversion table. |
Line profiles. |
Lorentz profile. |
Doppler profile. |
Voigt profile. |
Galatry profile. |
Miscellaneous topics. |
Some definitions related to collisions. |
Foreign gas broadening. |
Line coupling. |
Temperature dependence of broadening. |
Einstein coefficient of spontaneous emission. |
Rotational state transfer. |
Renner |
Teller effect (some aspects) |
Some functional relations specially applicable to the molecular constants of CO2 (see Chaps. 40.1 ... 40.14 of subvolumes II/20B2a and ") |
Designations of the energy levels of CO2. |
Resonances in CO2. |
Potential-energy function (PEF). |
Interaction potential. Dipole moment. |
Transition dipole moment. |
Hitelor (High Temperature Low Resolution data base). |
Line mixing. |
Several functional relations in which effects of collisions are included. |
Collisional broadening. |
Binary absorption coefficient. |
Normalized absorption coefficient. |
Collision induced contribution in the band intensity. |
Self broadening and its temperature dependence. |
Transmittance at the center of a spectral line. |
Line mixing (temperature and pressure dependence). |
Temperature dependence of line mixing. |
Pressure dependence of line mixing. |
Some formulas for the absorption coefficient k(n). |
Impact approximation. |
First order theory of Rosenkranz. |
CO2 laser wave guide amplification and power saturation. |
Some symbolism appearing in N2O data |
List of symbols |
References |
Introduction |
Energy level designations |
Effective Hamiltonians. |