Regio- and stereo-controlled oxidations and reductions

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Regio- and stereo-controlled oxidations and reductions / edited by Stanley M. Roberts, John Whittall

資料種別:

図書

出版情報:

Chichester : J. Wiley & Sons, c2007

形態:

xxii, 312 p. ; 24 cm

シリーズ名:

Catalysts for fine chemical synthesis ; v. 5 <BA5862286X>

著者名:

ISBN:

9780470090220 [0470090227]

書誌ID:

BA83557726

子書誌情報

フルテキスト

所蔵情報

他の版・巻

書誌詳細

注記:

Includes bibliographical references and index

主題:

Catalysts; Organic compounds--Synthesis; Oxidation; Reduction (Chemistry)

言語:

英語

目次情報:

Series Preface

Preface to Volume 5

Abbreviations

Industrial Catalysts for Regio- or Stereo-Selective Oxidations and Reductions A Review of Key Technologies and Targets / John Whittall1：

Introduction / 1.1：

Reduction of Carbon-Carbon Double Bonds / 1.2：

Privileged structures: [alpha]-amino acids and itaconic acids / 1.2.1：

[beta]-Amino acids / 1.2.2：

[alpha]-Alkyl substituted acids / 1.2.3：

[alpha]-Alkoxy substituted acids / 1.2.4：

Unsaturated nitriles / 1.2.5：

Alkenes and allyl alcohols / 1.2.6：

[alpha],[beta]-Unsaturated aldehyde reduction / 1.2.7：

Ketone and Imine Reduction / 1.3：

Catalytic hydrogenation of ketones and imines / 1.3.1：

Asymmetric transfer hydrogenation (ATH) catalysts / 1.3.2：

Modified borane reagents / 1.3.3：

Biocatalysts (alcohol dehydrogenases and ketoreductases) / 1.3.4：

Oxidation / 1.4：

Sharpless chiral epoxidation of allyl alcohols / 1.4.1：

Dioxirane catalyzed epoxidation / 1.4.2：

Amines and iminium salts / 1.4.3：

Phase transfer catalysts / 1.4.4：

The Julia-Colonna method (polyleucine oxidation) / 1.4.5：

Organocatalytic [alpha]-hydroxylation of ketones / 1.4.6：

Baeyer-Villiger oxidation / 1.4.7：

Chiral sulfoxides / 1.4.8：

References

Asymmetric Hydrogenation of Alkenes, Enones, Ene-Esters and Ene-Acids / 2：

(S)-2,2[prime]-Bis{[di(4-methoxyphenyl)phosphinyl]oxy}-5,5[prime],6,6[prime],7,7[prime],8,8[prime]-octahydro-1,1[prime]-binaphthyl as a ligand for rhodium-catalyzed asymmetric hydrogenation / Ildiko Gergely ; Csaba Hegedus ; Jozsef Bakos2.1：

Synthesis of (S)-5,5[prime],6,6[prime],7,7[prime],8,8[prime]-Octahydro-1,1[prime]-bi-2-naphthol / 2.1.1：

Synthesis of (S)-2,2[prime]-Bis{[di(4-methoxyphenyl)phosphinyl]oxy}-5,5[prime],6,6[prime],7,7[prime],8,8[prime]-octahydro-1,1[prime]-binaphthyl / 2.1.2：

Asymmetric hydrogenation of Dimethyl itaconate / 2.1.3：

Conclusion

Synthesis and application of phosphinite oxazoline iridium complexes for the asymmetric hydrogenation of alkenes / Frederik Menges ; Andreas Pfaltz2.2：

Synthesis of (4S,5S)-2-(5-Methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-1,3-diphenyl-propan-2-ol / 2.2.1：

Synthesis of (4S,5S)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenyl-ethyl]-diphenylphosphinite / 2.2.2：

Synthesis of (4S,5S)-[([eta superscript 4]-1,5-Cyclooctadiene)-{2-(2-phenyl-5-methyl-4,5-dihydro-oxazol-4-yl)-1,3-diphenyl-2-diphenylphosphinite-propane}iridium(I)]-tetrakis[3,5-bis(trifluoromethyl)phenyl]borate / 2.2.3：

Asymmetric hydrogenation of trans-[alpha]-Methylstilbene / 2.2.4：

Synthesis and application of heterocyclic phosphine oxazoline (HetPHOX) iridium complexes for the asymmetric hydrogenation of alkenes / Pier Giorgio Cozzi2.3：

Synthesis of (4S)-tert-Butyl-2-(thiophene-2-yl)-4,5-dihydrooxazole / 2.3.1：

Synthesis of (4S)-tert-Butyl-2-(3-diphenylphosphino-thiophene-2-yl)-4,5-dihydrooxazole / 2.3.2：

Synthesis of (4S)-[([eta superscript 4]-1,5-Cyclooctadiene)-{4-tert-butyl-2-(3-diphenylphosphino-thiophene-2-yl)-4,5-dihydrooxazole}iridium(I)]-tetrakis [3,5-bis(trifluoromethyl)phenyl]borate / 2.3.3：

(R)-2,2[prime],6,6[prime]-Tetramethoxy-bis[di(3,5-dimethylphenyl)phosphino]-3,3[prime]-bipyridine [(R)-Xyl-P-Phos] as a ligand for rhodium-catalyzed asymmetric hydrogenation of [alpha]-dehydroamino acids / Jing Wu ; Albert S.C. Chan2.3.4：

Synthesis of 3-Bromo-2,6-dimethoxypyridine / 2.4.1：

Synthesis of Bis(3,5-dimethylphenyl)phosphine chloride / 2.4.2：

Synthesis of 3-Bromo-2,6-dimethoxy-4-di(3,5-dimethylphenyl)phosphinopyridine / 2.4.3：

2,2[prime],6,6[prime]-Tetramethoxy-bis[di(3,5-dimethylphenyl)phosphinoyl]-3,3[prime]-bipyridine / 2.4.4：

Optical resolution of ([plus or minus])-6 with (-) or (+)-2,3-0,0[prime]-Dibenzoyltartaric acid monohydrate [(R)-6 or (S)-6)] / 2.4.6：

(R)-2,2[prime],6,6[prime]-Tetramethoxy-bis[di(3,5-dimethylphenyl)phosphino]-3,3[prime]-bipyridine [(R)-Xyl-P-Phos, (R)-1] / 2.4.7：

Preparation of the stock solution of [Rh(R-Xyl-P-Phos)(COD)]BF[subscript 4] / 2.4.8：

A typical procedure for the asymmetric hydrogenation of methyl (Z)-2-Acetamidocinnamate / 2.4.9：

(R,R)-2,3-Bis(tert-butylmethylphosphino)quinoxaline (QuinoXP) as a ligand for rhodium-catalyzed asymmetric hydrogenation of prochiral amino acid and amine derivatives / Tsuneo Imamoto ; Aya Koide2.5：

Synthesis of (R)-tert-Butyl(hydroxymethyl)methylphosphine-borane / 2.5.1：

Synthesis of (R)-Benzoyloxy(tert-butyl)methylphosphine-borane / 2.5.2：

Synthesis of (S)-tert-Butylmethylphosphine-borane / 2.5.3：

(R,R)-2,3-Bis(tert-butylmethylphosphino)quinoxaline (QuinoxP) / 2.5.4：

Asymmetric hydrogenation of Methyl (E)-3-acetylamino-2-butenoate catalyzed by Rh(I)-(R,R)-2,3-Bis(tert-butylmethylphosphino)quinoxaline / 2.5.5：

Rhodium-catalyzed asymmetric hydrogenation of indoles / Ryoichi Kuwano ; Masaya Sawamura2.6：

Synthesis of (R)-2-[(S)-1-(Dimethylamino)ethyl]-1-iodoferrocene / 2.6.1：

Synthesis of (R)-2-[(S)-1-(Diphenylphosphinyl)ethyl]-1-iodoferrocene / 2.6.2：

Synthesis of (R,R)-2,2[prime]-Bis[(S)-1-(diphenylphosphinyl)ethyl]-1,1[Prime]-biferrocene / 2.6.3：

Synthesis of (R,R)-2,2[Prime]-Bis[(S)-1-(diphenylphosphino)ethyl]-1,1[Prime]-biferrocene [abbreviated to (S,S)-(R,R)-PhTRAP] / 2.6.4：

Catalytic asymmetric hydrogenation of N-Acetyl-2-butylindole / 2.6.5：

Catalytic asymmetric hydrogenation of 3-Methyl-N-(p-toluenesulfonyl)indole / 2.6.6：

Asymmetric Reduction of Ketones / 3：

(R,R)-Bis(diphenylphosphino)-1,3-diphenylpropane as a versatile ligand for enantioselective hydrogenations / Natalia Dubrovina ; Armin Borner3.1：

Synthesis of (S,S)-1,3-Diphenylpropane-1,3-diol / 3.1.1：

Synthesis of (S,S)-Methanesulfonyloxy-1,3-diphenylpropane-1,3-diol / 3.1.2：

Synthesis of (R,R)-Bis(diphenylphosphino)-1,3-diphenylpropane / 3.1.3：

Synthesis of both enantiomers of 1-Phenylethanol by reduction of acetophenone with Geotrichum candidum IFO 5767 / Kaoru Nakamura ; Mikio Fujii ; Yoshiteru Ida3.2：

Cultivation of G. candidum IFO 5767 / 3.2.1：

Synthesis of (S)-1-Phenylethanol / 3.2.2：

Synthesis of (R)-1-Phenylethanol / 3.2.3：

Titanocene-catalyzed reduction of ketones in the presence of water. A convenient procedure for the synthesis of alcohols via free-radical chemistry / Antonio Rosales ; Juan M. Cuerva ; J. Enrique Oltra3.3：

Titanocene-catalyzed reduction of Acetophenone in the presence of water / 3.3.1：

Titanocene-catalyzed synthesis of Methyl 4-deuterio-4-phenyl-4-hydroxybutanoate / 3.3.2：

Xyl-tetraPHEMP: a highly efficient biaryl ligand in the [diphosphine RuCl[subscript 2] diamine]-catalyzed hydrogenation of simple aromatic ketones / Paul H. Moran ; Julian P. Henschke ; Antonio Zanotti-Gerosa ; Ian C. Lennon3.4：

Synthesis of Tri(3,5-dimethylphenyl)phosphine oxide / 3.4.1：

Synthesis of Bis(3,5-dimethylphenyl)-(2-iodo-3,5-dimethylphenyl)phosphine oxide / 3.4.2：

Synthesis of rac-4,4[prime],6,6[prime]-Tetramethyl-2,2[prime]-bis[bis(3,5-dimethylphenyl)phosphinoyl]-biphenyl / 3.4.3：

Synthesis of rac-4,4[prime],6,6[prime]-Tetramethyl-2,2[prime]-bis[bis(3,5-dimethylphenyl)phosphino]-biphenyl [abbreviated to (rac)-Xyl-tetraPHEMP] / 3.4.4：

Synthesis of [(R)-N,N-Dimethyl(1-methyl)benzylaminato-C[superscript 2],N]-{rac-4,4[prime],6,6[prime]-tetramethyl-2,2[prime]-bis[bis(3,5-dimethylphenyl)phosphino]-biphenyl}-palladium(II) tetrafluoroborate and separation of the diastereomers / 3.4.5：

Synthesis of (S)-4,4[prime],6,6[prime]-Tetramethyl-2,2[prime]-bis[bis(3,5-dimethylphenyl)phosphino]-biphenyl: [abbreviated to (S)-Xyl-tetraPHEMP) and (R)-4,4[prime],6,6[prime]-Tetramethyl-2,2[prime]-bis[bis(3,5-dimethylphenyl)phosphino]-biphenyl [abbreviated to (R)-Xyl-tetraPHEMP] / 3.4.6：

Synthesis of [(R)-Xyl-tetraPHEMP RuCl[subscript 2] (R,R)-DPEN] and [(S)-Xyl-tetraPHEMP RuCl[subscript 2] (S,S)-DPEN] / 3.4.7：

Reduction of Acetophenone using [(S)-Xyl-tetraPHEMP RuCl[subscript 2] (S,S)-DPEN] as a precatalyst / 3.4.8：

N-Arenesulfonyl- and N-Alkylsulfamoyl-1,2-diphenylethylenediamine ligands for ruthenium-catalyzed asymmetric transfer hydrogenation of activated ketones / Michel (Massoud S.) Stephan ; Barbara Mohar3.5：

Synthesis of N-Arenesulfonyl-1,2-diphenylethylenediamines / 3.5.1：

Preparation of Ru(II)-N-arenesulfonyl-1,2-diphenylethylenediamine complexes / 3.5.2：

Asymmetric transfer hydrogenation of Ethyl benzoylacetate / 3.5.3：

The synthesis and application of BrXuPHOS: a novel monodentate phosphorus ligand for the asymmetric hydrogenation of ketones / Martin Wills ; Yingjian Xu ; Garden Docherty ; Gary Woodward3.6：

Synthesis of (S)-BrXuPHOS / 3.6.1：

Synthesis of (S,S,SS)-BrXuPHOS-Ru-DPEN / 3.6.2：

General procedure of asymmetric hydrogenation of acetophenone / 3.6.3：

Acknowledgement

In Situ formation of ligand and catalyst: application in ruthenium-catalyzed enantioselective reduction of ketones / Jenny Wettergren ; Hans Adolfsson3.7：

Synthesis of (S)-3-Fluoro-1-phenylethanol / 3.7.1：

Synphos and Difluorphos as ligands for ruthenium-catalyzed hydrogenation of alkenes and ketones / Severine Jeulin ; Virginie Ratovelomanana-Vidal ; Jean-Pierre Genet3.8：

Synthesis of [RuCl((S)-SYNPHOS)(p-cymene)]Cl / 3.8.1：

Synthesis of [RuCl((S)-DIFLUORPHOS)(p-cymene)]Cl / 3.8.2：

Synthesis of [RuI((S)-DIFLUORPHOS)(p-cymene)]I / 3.8.3：

Synthesis of [NH[subscript 2]R[subscript 2]] [(RuCl(PP))[subscript 2]([Mu]-Cl)[subscript 3]] PP = SYNPHOS or DIFLUORPHOS and R = Me or Et / 3.8.4：

Synthesis of [NH[subscript 2]Me[subscript 2]][RuCl-(S)-DIFLUORPHOS][subscript 2][[Mu]-Cl][subscript 3] / 3.8.5：

Synthesis of in situ generated [RuBr[subscript 2]((S)-SYNPHOS)] and [RuBr[subscript 2]((S)-DIFLUORPHOS)] / 3.8.6：

An arene ruthenium complex with polymerizable side chains for the synthesis of immobilized catalysts / Estelle Burri ; Silke B. Wendicke ; Kay Severin3.9：

Synthesis of 2-Methyl-cyclohexa-2,5-dienecarboxylic acid 2-(2-methyl-acryloyloxy)-ethyl ester / 3.9.1：

Synthesis of [[eta superscript 6]-(2-Methyl-benzoic acid 2-(2-methyl-acryloyloxy)-ethyl ester)RuCl[subscript 2]][subscript 2] / 3.9.2：

Selective reduction of carbonyl group in [beta], [gamma]-unsaturated [alpha]-alpha-ketoesters by transfer hydrogenation with Ru-(p-cymene) (TsDPEN) / Minjie Guo ; Dao Li ; Yanhui Sun ; Zhaoguo Zhang3.10：

Synthesis of Di-[Mu]-chloro-bis[chloro([eta superscript 6]-1-isopropyl-4-methyl-benzene)ruthenium(II) / 3.10.1：

Synthesis of ([plus or minus])-Monotosylate-1,2-diphenyl-1,2-ethylenediamine / 3.10.2：

Synthesis of Ru complex Ru(p-cymene)(TsDPEN) / 3.10.3：

Ru-TsDPEN catalyzed transfer hydrogenation reaction of [beta],[gamma]-unsaturated-[alpha]-ketoesters / 3.10.4：

Preparation of polymer-supported Ru-TsDPEN catalysts and their use for the enantioselective synthesis of (S)-fluoxetine / Liting Chai ; Yangzhou Li ; Quanrui Wang3.11：

Synthesis of the supported ligand 9 / 3.11.1：

Synthesis of ligand 17 / 3.11.2：

General procedure for asymmetric transfer hydrogenation / 3.11.3：

Preparation of (S)-Fluoxetine hydrochloride / 3.11.4：

Polymer-supported chiral sulfonamide-catalyzed reduction of [beta]-keto nitriles: a practical synthesis of (R)-Fluoxetine / Guang-yin Wang ; Gang Zhao3.12：

Synthesis of (R)-3-Amino-1-phenyl-propan-1-ol / 3.12.1：

Synthesis of (R)-ethyl 3-hydroxy-3-phenylpropylcarbamate / 3.12.2：

Synthesis of (R)-3-(Methylamino)-1-phenylpropan-1-ol / 3.12.3：

Synthesis of (R)-Fluoxetine / 3.12.4：

Imine Reduction and Reductive Amination / 4：

Metal-free reduction of imines: enantioselective Bronsted acid-catalyzed transfer hydrogenation using chiral BINOL-phosphates as catalysts / Magnus Rueping ; Erli Sugiono ; Cengiz Azap ; Thomas Theissmann4.1：

Synthesis of (R)-2,2[prime]-Bis-methoxymethoxy-[1,1[prime]] binaphthalene (MOM-BINOL) / 4.1.1：

Synthesis of (R)-3,3[prime]-Diiodo-2,2[prime]-bis(methoxymethoxy)-1,1[prime]-binaphthalene / 4.1.2：

Synthesis of 3,3[prime]-Bis-(3,5[prime]-bis-trifluoromethyl-phenyl)-2,2[prime]-bismethoxymethoxy [1,1[prime]-binaphthalene] / 4.1.3：

Synthesis of (R)-3,3[prime]-[3,5-Bis(trifluoromethyl)phenyl]-1,1[prime]-binaphthylphosphate / 4.1.4：

General procedure for the transfer hydrogenation of ketimines / 4.1.5：

Synthesis of [1-(2,4-Dimethyl-phenyl)-ethyl]-(4-methoxy-phenyl)-amine / 4.1.6：

Metal-free Bronsted acid-catalyzed transfer hydrogenation: enantioselective synthesis of tetrahydroquinolines / Andrey P. Antonchick4.2：

General procedure for the transfer hydrogenation of quinolines / 4.2.1：

Synthesis of 7-Chloro-4-phenyl-1,2,3,4-tetrahydroquinoline / 4.2.2：

Synthesis of (S)-2-Phenyl-1,2,3,4-tetrahydroquinoline / 4.2.3：

Synthesis of (R)-2-(2-(Benzo[1,3]dioxol-5-yl)ethyl)-1,2.3,4-tetrahydro-quinoline / 4.2.4：

A highly stereoselective synthesis of 3[alpha]-Amino-23,24-bisnor-5[alpha]-cholane via reductive amination / Sharaf Nawaz Khan ; Nam Ju Cho ; Hong-Seok Kim4.3：

Synthesis of Tris[(2-ethylhexanoyl)oxy]borohydride / 4.3.1：

Synthesis of 3[alpha]-Acetamino-23,24-bisnor-5[alpha]-cholane / 4.3.2：

Synthesis of 3[alpha]-N-1-[N(3-[4-Aminobutyl])-1,3-diaminopropane]-23,24-bisnor-5[alpha]-cholane / 4.3.3：

Acknowledgements

Oxidation of Primary and Secondary Alcohols / 5：

Copper(Il) catalyzed oxidation of primary alcohols to aldehydes with atmospheric oxygen / Suribabu Jammi ; Tharmalingan Punniyamurthy5.1：

Synthesis of copper(II) complex 1 / 5.1.1：

Typical procedure for the oxidation of primary alcohols to aldehydes / 5.1.2：

Solvent-free dehydrogenation of secondary alcohols in the absence of hydrogen abstractors using Robinson's catalyst / G.B.W.L Ligthart ; R.H. Meijer ; J. v. Buijtenen ; J. Meuldijk ; J.A.J.M. Vekemans ; L.A. Hulshof5.2：

Dehydrogenation of 2-Octanol using Ru(OCOCF[subscript 3])[subscript 2](CO)(PPh[subscript 3])[subscript 2] as a catalyst / 5.2.1：

2-Iodoxybenzoic acid (IBX)/n-Bu[subscript 4]NBr/CH[subscript 2]Cl[subscript 2]-H[subscript 2]O: a mild system for the selective oxidation of secondary alcohols / Krisada Kittigowittana ; Manat Pohmakotr ; Vichai Reutrakul ; Chutima Kuhakarn5.3：

Synthesis of 1-Hydroxy-5-decanone / 5.3.1：

Hydroxylation, Epoxidation and Related Reactions / 6：

Proline-catalyzed [alpha]-aminoxylation of aldehydes and ketones / Yujiro Hayashi ; Mitsuru Shoji6.1：

Synthesis of (R)-2-Anilinoxypropanol / 6.1.1：

Synthesis of (R)-7-Anilinoxy-1,4-dioxaspiro[4.5]decan-8-one / 6.1.2：

Ru/Silia Cat TEMPO-mediated oxidation of alkenes to [alpha]-hydroxyacids / Rosaria Ciriminna ; Mario Pagliaro6.2：

Synthesis of Silia Cat TEMPO / 6.2.1：

Synthesis of 2-(4-Chlorophenyl)-1,2-propanediol / 6.2.2：

Synthesis of 2-(4-Chlorophenyl)-1,2-hydroxypropanoic acid / 6.2.3：

Catalytic enantioselective epoxidation of trans-disubstituted and trisubstituted alkenes with arabinose-derived ulose / Tony K. M. Shing ; Gulice Y.C. Leung ; To Luk6.3：

Synthesis of 2[prime],3[prime]-Diisobutyl acetal / 6.3.1：

Synthesis of ulose / 6.3.2：

Asymmetric epoxidation of trans-[alpha]-Methylstilbene using ulose as catalyst at 0 [degree]C / 6.3.3：

VO(acac)[subscript 2]/TBHP catalyzed epoxidation of 2-(2-Alkenyl)phenols. highly regio- and diastereoselective oxidative cyclisation to 2,3-Dihydrobenzofuranols and 3-Chromanols / Alessandra Lattanzi ; Arrigo Scettri6.4：

VO(acac)[subscript 2]/TBHP catalyzed epoxidation of 2-(3,7-Dimethyl-octa-2,6-dienyl)-phenol / 6.4.1：

VO(acac)[subscript 2]/TBHP/TFA catalyzed oxidative cyclization of 2-(3,7-Dimethyl-octa-2,6-dienyl)-phenol / 6.4.2：

An Oxalolidinone ketone catalyst for the asymmetric epoxidation of cis-olefins / David Goeddel ; Yian Shi6.5：

Amadori rearrangement to give 1-Dibenzylamino-1-deoxy-D-fructose / 6.5.1：

Acetal protection of 1-Dibenzylamino-1-deoxy-D-fructose / 6.5.2：

Hydrogenation of the Dibenzylamine / 6.5.3：

Phosgene cyclization of aminoalcohol / 6.5.4：

Alcohol oxidation / 6.5.5：

Synthesis of ketone 2 / 6.5.6：

Asymmetric epoxidation of cis-[beta]-Methylstyrene / 6.5.7：

[alpha]-Fluorotropinone immobilised on silica: a new stereoselective heterogeneous catalyst for epoxidation of alkenes with oxone / Giovanni Sartori ; Alan Armstrong ; Raimondo Maggi ; Alessandro Mazzacani ; Raffaella Sartorio ; France Bigi ; Belen Dominguez-Fernandez6.6：

Synthesis of silica KG-60-supported enantiomerically enriched [alpha]-Fluorotropinone / 6.6.1：

Synthesis of enantiomerically enriched epoxides / 6.6.2：

Asymmetric epoxidation catalyzed by novel azacrown ether-type chiral quaternary ammonium salts under phase-transfer catalytic conditions / Kazushige Hori ; Keita Tani ; Yasuo Tohda6.7：

Synthesis of precursor of the azacrown ether / 6.7.1：

Synthesis of the azacrown ether / 6.7.2：

Synthesis of the azacrown ether-type quaternary ammonium salt / 6.7.3：

Asymmetric epoxidation of (E)-Chalcone catalyzed by the azacrown ether-type quaternary ammonium salt as chiral PTC / 6.7.4：

Enantioselective epoxidation of olefins using phase transfer conditions and a chiral [azepinium][TRISPHAT] salt as catalyst / Jerome Vachon ; Celine Perollier ; Alexandre Martinez ; Jerome Lacour6.8：

Enantioselective epoxidation of 1-Phenyl-3,4-dihydronaphthalene / 6.8.1：

Catalytic asymmetric epoxidation of [alpha],[beta]-unsaturated esters promoted by a Yttrium-biphenyldiol complex / Masakatsu Shibasaki ; Hiroyuki Kakei ; Shigeki Matsunaga6.9：

Synthesis of (aS,R)-6,6[prime]-[(Propylene)dioxy]biphenyl-2,2[prime]-diol / 6.9.1：

Synthesis of (aS,R)-2,2-[Oxybis(ethylene)dioxy]-6,6[prime]-[(propylene)dioxy]biphenyl / 6.9.2：

Synthesis of (S)-6,6[prime]-[Oxybis(ethylene)dioxy]biphenyl-2,2[prime]-diol / 6.9.3：

Enantiomeric enrichment of (S)-6,6[prime]-[Oxybis(ethylene)dioxy]biphenyl-2,2[prime]-diol / 6.9.4：

Catalytic asymmetric epoxidation of [alpha],[beta]-unsaturated esters / 6.9.5：

Catalytic enantioselective epoxidation of [alpha],[beta]-enones with a binol-zinc-complex / Ana Minatti ; Karl Heinz Dotz6.10：

Synthesis of (E)-(2S,3R)-Phenyl-(3-phenyloxiran-2-yl)methanone / 6.10.1：

Asymmetric epoxidation of Phenyl-2-(3[prime]-pyridylvinyl)sulfone using polyleucine hydrogen peroxide gel / Mike R. Pitts6.11：

Preparation of polyleucine-hydrogen peroxide gel / 6.11.1：

Synthesis of Phenyl-2-(3[prime]-pyridylvinyl) sulfone (2) / 6.11.2：

Oxidation of Ketones to Lactones or Enones / 7：

Synthesis of 2-(Phosphinophenyl)pyrindine ligand and its application to palladium-catalyzed asymmetric Baeyer-Villiger oxidation of prochiral cyclobutanones / Katsuji Ito ; Tsutomu Katsuki7.1：

Synthesis of (7R)-2-(2-Hydroxyphenyl)-7-isopropyl-6,7-dihydro-5H-1-pyrindine / 7.1.1：

2-[2-(Diphenylphosphinoyl)phenyl]-7-isopropyl-6,7-dihydro-5H-1-pyrindine / 7.1.2：

2-[2-(Diphenylphosphanyl)phenyl]-7-isopropyl-6,7-dihydro-5H-1-pyrindine / 7.1.3：

Asymmetric Baeyer-Villiger oxidation of 3-Phenylcyclobutanone / 7.1.4：

(D)-Codeinone from (D)-Dihydrocodeinone via the use of modified o-iodoxybenzoic acid (IBX). A convenient oxidation of ketones to enones / Paul Mather7.2：

Synthesis of IBX / 7.2.1：

Synthesis of codeinone / 7.2.2：

Oxidative C-C Coupling / 8：

Enantioselective oxidative coupling of 2-Naphthols catalyzed by a novel chiral vanadium complex / Nan-Sheng Xie ; Quan-Zhong Liu ; Zhi-Bin Luo ; Liu-Zhu Gong ; Ai-Qiao Mi ; Yao-Zhong Jiang8.1：

Synthesis of 3,3-Diformyl-2,2[prime]-biphenol / 8.1.1：

Synthesis of chiral vanadium complexes / 8.1.2：

Catalytic oxidative coupling of 7-Alkoxy-1-naphthols by chiral vanadium complexes / 8.1.3：

Reference

Catalytic oxidative cross-coupling reaction of 2-Naphthol derivatives / Shigeki Habaue ; Tomohisa Temma8.2：

Synthesis of Methyl 2,2[prime]-dihydroxy-1,1[prime]-binaphthalene-3-carboxylate / 8.2.1：

Oxidative coupling of benzenes with [alpha],[beta]-unsaturated aldehydes by Pd(OAc)[subscript 2]/ HPMoV/ O[subscript 2] system / Tomoyuki Yamada ; Satoshi Sakaguchi ; Yasutaka Ishii8.3：

Synthesis of Cinnamaldehyde / 8.3.1：

Oxidation of Sulfides and Sulfoxides / 9：

The first example of direct oxidation of sulfides to sulfones by an osmate-molecular oxygen system / Boyapati M. Choudary ; Chinta Reddy ; V. Reddy ; Billakanti V. Prakash ; Mannepalli L. Kantam ; B. Sreedhar9.1：

Synthesis of osmate exchanged Mg-Al layered double hydroxides (LDH-OsO[subscript 4]) / 9.1.1：

Synthesis of Methyl phenyl sulfone or Methylsulfonylbenzene / 9.1.2：

Selective oxidation of sulfides to sulfoxides and sulfones using hydrogen peroxide in the presence of zirconium tetrachloride / Kiumar Bahrami9.2：

Oxidation of Benzyl 4-bromobenzyl sulfide to Benzyl 4-bromobenzyl sulfoxide using H[subscript 2]O[subscript 2] in the presence of zirconium tetrachloride / 9.2.1：

Oxidation of Benzyl 4-bromobenzyl sulfide to Benzyl 4-bromobenzyl sulfone using H[subscript 2]O[subscript 2] in the presence of zirconium tetrachloride / 9.2.2：

WO[subscript 3]-30 % H[subscript 2]O[subscript 2]-cinchona alkaloids: a new heterogeneous catalytic system for asymmetric oxidation and kinetic resolution of racemic sulfoxides / Vinay V. Thakur ; A. Sudalai9.3：

Synthesis of (R)-2-[[[3-Methyl-4-(2,2,2-trifluoroethoxy)-2-pyridyl]methyl]sulfinyl]-1H-benzimadazole {(R)-(+)-Lansoprazole} / 9.3.1：

Synthesis of (R)-(+)-Phenyl benzyl sulfoxide / 9.3.2：

Benzyl-4,6-O-isopropylidene-[alpha]-(D)-glucopyranoside, 2-deoxy-2-[[(2-hydroxy-3,5-di-tert-butylphenyl)methylene]amino] as a ligand for vanadium-catalyzed asymmetric oxidation of sulfides / Raffaella Del Litto ; Guiseppina Roviello ; Francesco Ruffo9.4：

Synthesis of Benzyl-4,6-O-isopropylidene-[alpha]-D-glucopyranoside, 2-deoxy-2-[[(2-hydroxy-3,5-di-tert-butylphenyl)methylene]imine] / 9.4.1：

Oxidation of Thioanisole / 9.4.2：

Asymmetric sulfoxidation of aryl methyl sulfides with hydrogen peroxide in water / Alessando Scarso ; Giorgio Strukul9.5：

Synthesis of complex (R)-BINAP)PtCl[subscript 2] / 9.5.1：

Synthesis of complex [((R)-BINAP)Pt((OH)][subscript 2](BF[subscript 4])[subscript 2] / 9.5.2：

Stereoselective catalytic oxidation of aryl methyl sulfides / 9.5.3：

Index

Series Preface

Preface to Volume 5

Abbreviations

Industrial Catalysts for Regio- or Stereo-Selective Oxidations and Reductions A Review of Key Technologies and Targets / John Whittall1：

Introduction / 1.1：

Reduction of Carbon-Carbon Double Bonds / 1.2：

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