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1.

図書

図書
edited by Ilan Marek
出版情報: Weinheim : Wiley-VCH, c2002  xxv, 512 p. ; 25 cm
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Foreword
Preface
List of Contributors
Synthesis and Reactivity of Zirconocene Derivatives / Ei-ichi Negishi ; Shouquan Huo1:
Introduction and Historical Background / 1.1:
Fundamental Patterns of Transformations of Zirconocene Derivatives / 1.2:
Synthesis of Organic Derivatives of ZrCp[subscript 2] / 1.3:
Reactivity of Organylzirconocene Compounds / 1.4:
References
Zirconacyclopentadienes in Organic Synthesis / Tamotsu Takahashi ; Yanzhong Li2:
Introduction / 2.1:
Preparation and Reaction of Zirconacyclopentadienes / 2.2:
Carbon--Carbon Bond Formation / 2.3:
Conclusion / 2.4:
Elaboration of Organozirconium Species by Insertion of Carbenoids / Sally Dixon ; Richard J. Whitby3:
Carbonylation and Isonitrile Insertion / 3.1:
Insertion of 1-Halo-1-lithio Species into Organozirconocenes / 3.3:
References and Notes / 3.4:
Hydrozirconation and Further Transmetalation Reactions / Bruce H. Lipshutz ; Steven S. Pfeiffer ; Kevin Noson ; Takashi Tomioka4:
Hydrozirconation/Quenching / 4.1:
Hydrozirconation: Ring-Forming and Ring-Opening Reactions / 4.3:
Acyl Zirconocenes / 4.4:
Allylic Zirconocenes / 4.5:
Cross-Coupling Reactions / 4.6:
Zirconium to Copper / 4.7:
Zirconium to Zinc / 4.8:
Zirconium to Boron / 4.9:
Zirconium to Nickel / 4.10:
Summary and Outlook / 4.11:
Acylzirconocenes in Organic Synthesis / Yuji Hanzawa5:
Synthesis and Stability of Acylzirconocene Complexes / 5.1:
Reactions of Acylzirconocene Complexes / 5.3:
Reactions of Acylzirconocene Chlorides as "Unmasked" Acyl Group Donors / 5.4:
Reactivity of [alpha],[beta]-Unsaturated Acylzirconocene Chlorides toward Nucleophiles / 5.5:
Chiral Zirconium Catalysts for Enantioselective Synthesis / Amir H. Hoveyda5.6:
Zr-Catalyzed Enantioselective C-C Bond-Forming Reactions / 6.1:
Zr-Catalyzed Enantioselective C-N Bond-Forming Reactions / 6.3:
Zr-Catalyzed Enantioselective C-H Bond-Forming Reactions / 6.4:
gem-Metallozirconocenes in Organic Synthesis / Valery M. Dembitsky ; Morris Srebnik6.5:
1,1-Aluminiozirconocene Complexes / 7.1:
1,1-Boriozirconocene Complexes / 7.3:
1,1-Lithiozirconocene Reagents / 7.4:
1,1-Stanniozirconocene Reagents / 7.5:
1,1-Galliozirconocene Complexes / 7.6:
1,1-Germaniozirconocene Complexes / 7.7:
1,1-Zinciozirconocene Reagents / 7.8:
1,1-Dizirconocene Complexes / 7.9:
Cationic Zirconocene Species in Organic Synthesis / Keisuke Suzuki ; Lukas Hintermann ; Shigeo Yamanoi7.10:
General Introduction / 8.1:
Glycosylations with Cp[subscript 2]ZrCl[subscript 2]/Silver Salt Activators / 8.2:
Nucleophilic Additions to Aldehydes and Epoxides / 8.3:
Carbometalation of Alkynes and Alkenes / 8.4:
Cationic Zirconocene Complexes as Lewis Acid Catalysts / 8.5:
Miscellaneous Reactions / 8.6:
Titanium(II) Alkoxides in Organic Synthesis / Fumie Sato ; Hirokazu Urabe8.7:
Generation of ([eta superscript 2]-alkyne)Ti(OiPr)[subscript 2] and its Utilization in Organic Synthesis / 9.1:
Preparation of Allyl- and Allenyltitanium Reagents and their Synthetic Utility / 9.3:
Intramolecular Nucleophilic Acyl Substitution (INAS) Mediated by 1 / 9.4:
Intramolecular Coupling of Alkenes and Acetylenes / 9.5:
Concluding Remarks / 9.6:
Organometallic Chemistry of Titanocene and Zirconocene Complexes with Bis(trimethylsilyl)acetylene as the Basis for Applications in Organic Synthesis / Uwe Rosenthal ; Vladimir V. Burlakov10:
Reactions of Titanocene and Zirconocene Sources / 10.1:
Alkenes >C=C< / 10.3:
Diacetylenes / 10.4:
Dialkenes / 10.5:
Double Bonds to Heteroatoms >C=X(-) / 10.6:
Selected Combinations of Functional Groups / 10.7:
Miscellaneous / 10.8:
Titanium-Mediated Syntheses of Cyclopropanols and Cyclopropylamines / Armin de Meijere ; Sergei I. Kozhushkov ; Andrei I. Savchenko10.9:
Reaction Modes of Titanium Alkyl Derivatives Possessing [beta]-Hydrogen Atoms / 11.1:
Preparation of Cyclopropanols / 11.3:
Preparation of Cyclopropylamines / 11.4:
Applications in Natural Product Syntheses and Syntheses of Compounds with Potentially Useful Properties / 11.5:
Titanocene-Catalyzed Epoxide Opening / Andreas Gansauer ; Bjorn Rinker11.6:
Stoichiometric Opening of Epoxides by Electron Transfer / 12.1:
Synthesis and Reactivity of Allyltitanium Derivatives / Jan Szymoniak ; Claude Moise12.3:
Allyl Bis(cyclopentadienyl)titanium Reagents / 13.1:
Allyl Mono(cyclopentadienyl)titanium Reagents / 13.3:
Allyltitanium Reagents without Cyclopentadienyl Groups / 13.4:
Titanium-Based Olefin Metathesis and Related Reactions / Takeshi Takeda13.5:
Reactions of Titanium Carbene Complexes with Carbon--Carbon Double Bonds / 14.1:
Reactions of Titanium Carbene Complexes with Carbon--Oxygen Double Bonds / 14.3:
Reactions of Titanium Carbene Complexes with Triple Bonds / 14.4:
Index / 14.5:
Foreword
Preface
List of Contributors
2.

図書

図書
edited by D.C. Sherrington, A.P. Kybett
出版情報: Cambridge, U.K. : Royal Society of Chemistry, c2001  ix, 270 p. ; 24cm
シリーズ名: Special publication / Royal Society of Chemistry ; no. 266
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Selectivity in Oxidation Catalysis / B. K. Hodnett
The Development and Application of Supported Reagents for Multi-step Organic Synthesis / Steven V. Ley ; Ian R. Baxendale
Mesoporous Molecular Sieve Catalysts: Relationships between Reactivity and Long Range Structural Order/Disorder / Thomas J. Pinnavaia ; Thomas R. Pauly ; Seong Su Kim
Zeolite Beta and Its Uses in Organic Reactions / J.C. van der Waal ; H. van Bekkum
Chiral Mesoporous Hybrid Organic-Inorganic Materials in Enantioselective Catalysis / Daniel Brunel
Immobilised Lewis Acids and Their Use in Organic Chemistry / James H. Clark ; Arnold Lambert ; Duncan J. Macquarrie ; David J. Nightingale ; Peter M. Price ; J. Katie Shorrock ; Karen Wilson
Influence of Zeolite Composition on Catalytic Activity / M. Guisnet
Synthesis of Soluble Libraries of Macrocycles from Polymers: Investigations of Some Possible Screening Methods Using Polymers / P. Hodge ; C.L. Ruddick ; A. Ben-Haida ; I. Goodbody ; R.T. Williams
Immobilised Catalysts and Their Use in the Synthesis of Fine and Intermediate Chemicals / Wolfgang F. Holderich ; Hans H. Wagner ; Michael H. Valkenberg
Catalytic Aziridination and Epoxidation of Alkenes Using Modified Microporous and Mesoporous Materials / Graham J. Hutchings ; Christopher Langham ; Paola Piaggio ; Sophia Taylor ; Paul McMorn ; David J. Willock ; Donald Bethell ; Philip C. Bulman Page ; Chris Sly ; Fred Hancock ; Frank King
Enantioselective Alkylation of Benzaldehyde by Diethylzinc with (-)-Ephedrine Supported on MTS. A New Class of More Efficient Catalysts / S. Abramson ; M. Lasperas ; D. Brunel
Supported Perfluoroalkanedisulphonic Acids as Catalysts in Isobutane Alkylation / A. de Angelis ; P. Ingallina ; W.O. Parker, Jr. ; M. G. Clerici ; C. Perego
Polymer Immobilised TEMPO (PIPO): An Efficient Catalytic System for Environmentally Benign Oxidation of Alcohols / A. Dijksman ; I.W.C.E. Arends ; R.A. Sheldon
The Preparation and Functionalisation of (Vinyl)Polystyrene PolyHIPE. Short Routes to Binding Functional Groups through a Dimethylene Spacer / A. Mercier ; H. Deleuze ; B. Maillard ; O. Mondain-Monval
Polynitrogen Strong Bases as Immobilized Catalysts / G. Gelbard ; F. Vielfaure-Joly
Selective Synthesis of 2-Acetyl-6-methoxynaphthalene over HBEA Zeolite / E. Fromentin ; J.-M. Coustard
The Influence of "Superacidic" Modification on ZrO[subscript 2] and Fe[subscript 2]O[subscript 3] Catalysts for Methane Combustion / A.S.C. Brown ; J.S.J. Hargreaves ; M.-L. Palacios ; S.H. Taylor
Structure and Reactivity of Polymer-supported Carbonylation Catalysts / Anthony Haynes ; Peter M. Maitlis ; Ruhksana Quyoum ; Harry Adams ; Richard W. Strange
An Original Behaviour of Copper(II)-exchanged Y Faujasite in the Ruff Oxidative Degradation of Calcium Gluconate / Gwenaelle Hourdin ; Alain Germain ; Claude Moreau ; Francois Fajula
Polymer-bound Organometallic Complexes as Catalysts for Use in Organic Synthesis / Nicholas E. Leadbeater
Dehydroisomerisation of n-Butane into Isobutene over Ga-Containing Zeolite Catalysts / D.B. Lukyanov ; T. Vazhnova
Guanidine Catalysts Supported on Silica and Micelle Templated Silicas. New Basic Catalysts for Organic Chemistry / James E.G. Mdoe ; Gilbert Renard ; Alexandre Blanc
Organic Modification of Hexagonal Mesoporous Silica / Dominic B. Jackson
Towards Phthalocyanine Network Polymers for Heterogeneous Catalysis / Neil B. McKeown ; Hong Li ; Saad Makhseed
Suzuki Coupling Using Pd(0) and KF/Al[subscript 2]O[subscript 3] / G.W. Kabalka ; R.M. Pagni ; C.M. Hair ; L. Wang ; V. Namboodiri
Unusual Regioselectivities Observed in the Oligomerization of Propene on Nickel(II) Ion-exchanged Silica-Alumina Catalysts / Christakis P. Nicolaides ; Michael S. Scurrell
Selectivity through the Use of Heterogeneous Catalysts / Keith Smith
Novel Lewis-acidic Catalysts by Immobilisation of Ionic Liquids / M.H. Valkenberg ; C. deCastro ; W.F. Holderich
Heterogeneous Enantioselective Hydrogenation of Trifluoromethyl Ketones / M. von Arx ; T. Mallat ; A. Baiker
Structural and Reactive Properties of Supported Transition Metal Triflates
Soluble Fluoropolymer Catalysts for Hydroformylation of Olefins in Fluorous Phases and Supercritical CO[subscript 2] / W. Chen ; A.M. Banet-Osuna ; A. Gourdier ; L. Xu ; J. Xiao
Subject Index
Selectivity in Oxidation Catalysis / B. K. Hodnett
The Development and Application of Supported Reagents for Multi-step Organic Synthesis / Steven V. Ley ; Ian R. Baxendale
Mesoporous Molecular Sieve Catalysts: Relationships between Reactivity and Long Range Structural Order/Disorder / Thomas J. Pinnavaia ; Thomas R. Pauly ; Seong Su Kim
3.

図書

図書
Noboru Ono
出版情報: New York : Wiley-VCH, c2001  xvi, 372 p. ; 25 cm
シリーズ名: Organic nitro chemistry series
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Series Foreword
Preface
Acknowledgments
Abbreviations
Introduction / 1.:
Preparation of Nitro Compounds / 2.:
Nitration of Hydrocarbons / 2.1:
Aromatic Compounds / 2.1.1:
Alkanes / 2.1.2:
Activated C-H Compounds / 2.1.3:
Alkenes / 2.1.4:
Synthesis of [alpha]-Nitro Ketones / 2.1.5:
Nitration of Alkyl Halides / 2.1.6:
Synthesis of Nitro Compounds by Oxidation / 2.2:
Oxidation of Amines / 2.2.1:
Oxidation of Oximes / 2.2.2:
The Nitro-Aldol (Henry) Reaction / 3.:
Preparation of [beta]-Nitro Alcohols / 3.1:
Derivatives from [beta]-Nitro Alcohols / 3.2:
Nitroalkenes / 3.2.1:
Nitroalkanes / 3.2.2:
[alpha]-Nitro Ketones / 3.2.3:
[beta]-Amino Alcohols / 3.2.4:
Nitro Sugars and Amino Sugars / 3.2.5:
Stereoselective Henry Reactions and Applications to Organic Synthesis / 3.3:
Michael Addition / 4.:
Addition to Nitroalkenes / 4.1:
Conjugate Addition of Heteroatom-Centered Nucleophiles / 4.1.1:
Conjugate Addition of Heteroatom Nucleophiles and Subsequent Nef Reaction / 4.1.2:
Conjugate Addition of Carbon-Centered Nucleophiles / 4.1.3:
Addition and Elimination Reaction of [beta]-Heterosubstituted Nitroalkenes / 4.2:
Michael Addition of Nitroalkanes / 4.3:
Intermolecular Addition / 4.3.1:
Intramolecular Addition / 4.3.2:
Asymmetric Michael Addition / 4.4:
Chiral Alkenes and Chiral Nitro Compounds / 4.4.1:
Chiral Catalysts / 4.4.2:
Alkylation, Acylation, and Halogenation of Nitro Compounds / 5.:
Alkylation of Nitro Compounds / 5.1:
Acylation of Nitroalkanes / 5.2:
Ring Cleavage of Cyclic [alpha]-Nitro Ketones (Retro-Acylation) / 5.3:
Alkylation of Nitro Compounds via Alkyl Radicals / 5.4:
Alkylation of Nitro Compounds Using Transition Metal Catalysis / 5.5:
Butadiene Telomerization / 5.5.1:
Pd-Catalyzed Allylic C-Alkylation of Nitro Compounds / 5.5.2:
Arylation of Nitro Compounds / 5.6:
Introduction of Heteroatoms to Nitroalkanes / 5.7:
Conversion of Nitro Compounds into Other Compounds / 6.:
Nef Reaction (Aldehydes, Ketones, and Carboxylic Acids) / 6.1:
Treatment With Acid (Classical Procedure) / 6.1.1:
Oxidative Method / 6.1.2:
Reductive Method / 6.1.3:
Direct Conversion of Nitroalkenes to Carbonyl Compounds / 6.1.4:
Nitrile Oxides and Nitriles / 6.2:
Reduction of Nitro Compounds into Amines / 6.3:
Ar-NH[subscript 2] From Ar-NO[subscript 2] / 6.3.1:
R-NH[subscript 2] From R-NO[subscript 2] / 6.3.2:
Oximes, Hydroxylamines, and Other Nitrogen Derivatives / 6.3.3:
Substitution and Elimination of NO[subscript 2] in R-NO[subscript 2] / 7.:
R-Nu from R-NO[subscript 2] / 7.1:
Radical Reactions (S[subscript RN]1) / 7.1.1:
Ionic Process / 7.1.2:
Intramolecular Nucleophilic Substitution Reaction / 7.1.3:
Allylic Rearrangement / 7.1.4:
R-H from R-NO[subscript 2] / 7.2:
Radical Denitration / 7.2.1:
Ionic Denitration / 7.2.2:
Alkenes from R-NO[subscript 2] / 7.3:
Radical Elimination / 7.3.1:
Ionic Elimination of Nitro Compounds / 7.3.2:
Cycloaddition Chemistry of Nitro Compounds / 8.:
Diels-Alder Reactions / 8.1:
Nitroalkenes Using Dienophiles / 8.1.1:
Asymmetric Diels-Alder Reaction / 8.1.2:
1,3-Dipolar Cycloaddition / 8.2:
Nitrones / 8.2.1:
Nitrile Oxides / 8.2.2:
Nitronates / 8.2.3:
Nitroalkenes as Heterodienes in Tandem [4+2]/[3+2] Cycloaddition / 8.3:
Nitroalkenes as Heterodienes / 8.3.1:
Tandem [4+2]/[3+2] Cycloaddition of Nitroalkenes / 8.3.2:
Nucleophilic Aromatic Displacement / 9.:
S[subscript N]Ar / 9.1:
Nucleophilic Aromatic Substitution of Hydrogen (NASH) / 9.2:
Carbon Nucleophiles / 9.2.1:
Nitrogen and Other Heteroatom Nucleophiles / 9.2.2:
Applications to Synthesis of Heterocyclic Compounds / 9.2.3:
Synthesis of Heterocyclic Compounds / 10.:
Pyrroles / 10.1:
Synthesis of Indoles / 10.2:
Synthesis of Other Nitrogen Heterocycles / 10.3:
Three-Membered Ring / 10.3.1:
Five- and Six-Membered Saturated Rings / 10.3.2:
Miscellaneous / 10.3.3:
Index
Series Foreword
Preface
Acknowledgments
4.

図書

図書
Roderick Bates
出版情報: Sheffield, [Eng.] : Sheffield Academic , Malden, Ma. : Blackwell Science, 2000  ix, 190 p. ; 24 cm
シリーズ名: Postgraduate chemistry series
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5.

図書

図書
edited by Manfred Schlosser
出版情報: Chichester : J. Wiley, 2004, c2002  x, 1243 p. ; 25 cm
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List of Contributors
Preface to the First Edition
Preface to the Second Edition
Organoalkali Chemistry / Manfred SchlosserI:
Organotin Chemistry / James A. MarshallII:
Organoboron Chemistry / Keith SmithIII:
Organoaluminum Chemistry / Hisashi YamamotoIV:
Organozinc Chemistry / Eiichi NakamuraV:
Organocopper Chemistry / Bruce H. LipshutzVI:
Organotitanium Chemistry / Manfred T. ReetzVII:
Organozirconium Chemistry / Ei-ichi NegishiVIII:
Organoiron and Organochromium Chemistry / Martin F. SemmelhackIX:
Organopalladium Chemistry / Louis S. HegedusX:
Index
List of Contributors
Preface to the First Edition
Preface to the Second Edition
6.

図書

図書
Kin-ya Akiba
出版情報: Hoboken, N.J. : Wiley, c2011  xi, 275 p. ; 24 cm
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7.

図書

図書
volume editor, W.-D. Fessner ; with contributions by A. Archelas ... [et al.]
出版情報: Berlin ; Tokyo : Springer-Verlag, c1999  viii, 266 p. ; 25 cm
シリーズ名: Topics in current chemistry = Fortschritte der chemischen Forschung ; 200
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Screening for Novel Enzymes / D.C. Demirjian ; P.C. Shah ; F. Moris-Varas
Superior Biocatalysts by Directed Evolution / K.-E. Jaeger ; M.T. Reetz
Catalytic Antibodies for Organic Synthesis / J.-L. Reymond
Immobilized Enzymes: Methods and Applications / W. Tischer ; F. Wedekind
Phospholiphases as Synthetic Catalysts / S. Servi
Biocatalytic Approaches for the Synthesis of Enantiopure Epoxides / A. Archelas ; R. Furstoss
Oxynitrilases: From Cyanogenesis to Asymmetric Synthesis / M. Schmidt ; H. Griengl
Glycolsytransferase-Catalyzed Synthesis of Non-Natural Oligosaccharides / R. Ohrlein
Screening for Novel Enzymes / D.C. Demirjian ; P.C. Shah ; F. Moris-Varas
Superior Biocatalysts by Directed Evolution / K.-E. Jaeger ; M.T. Reetz
Catalytic Antibodies for Organic Synthesis / J.-L. Reymond
8.

図書

図書
Michael P. Doyle, M. Anthony McKervey, Tao Ye
出版情報: New York : John Wiley & Sons, c1998  xvii, 652 p. ; 25 cm
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Preface
Acknowledgments
Synthesis of [alpha]-Diazocarbonyl Compounds / 1.:
Introduction / 1.1:
Acylation of Diazoalkanes / 1.2:
Preparation of Diazomethane from Diazald
Preparation of a Diazoketone from an Acid Chloride: Synthesis of 1-Diazo-4-phenyl-2-butanone
Preparation of a Diazoketone from Mixed Carbonic Anhydrides: Synthesis of N-tert-Butoxycarbonyl-L-Phenylalanyl Diazomethane
Diazo Transfer Reactions / 1.3:
Simple Diazo Transfer Reactions / 1.3.1:
Simple Diazo Transfer Reaction: Synthesis of tert-Butyl [alpha]-Diazoacetoacetate
Deformylating Diazo Transfer and Related Modifications / 1.3.2:
Deformylating Diazo Transfer Reaction: Synthesis of 2-Diazocyclohexanone
Detrifluoroacetylating Diazo Transfer: Synthesis of (E)-1-Diazo-4-Phenyl-3-Buten-2-one
Effects of Base and Solvent on Diazo Transfer / 1.3.3:
Direct Diazo Transfer Using 2,4,6-Triisopropyl-phenylsulfonyl Azide: Synthesis of 2-Diazo-5-methoxy-1-tetralone
Effects of Transfer Reagent on Diazo Transfer and Hazards Evaluation / 1.3.4:
Synthesis of 4-Dodecylbenzenesulfonyl Azide
Other Routes to Diazocarbonyl Compounds / 1.4:
Glyoxylic Acid Chloride p-Toluenesulfonyl-hydrazone: Preparation of Diazoester 158
Chemical Modification of Diazocarbonyl Compounds / 1.5:
Conclusion: Safety and Handling of Diazocarbonyl Compounds / 1.6:
References / 1.7:
Catalysts for Metal Carbene Transformations / 2.:
Electrophilic Addition to Diazo Compounds / 2.1:
Mechanism of Catalytic Diazo Decomposition. Metal Carbene Generation and Reactions / 2.2:
Mechanism of Catalytic Diazo Decomposition. Electrophilic Addition by Metal Olefin Complexes / 2.3:
Copper Catalysts for Diazo Decomposition / 2.4:
Oxidation States for Copper / 2.4.1:
Ligands for Copper / 2.4.2:
Ligand Preparation
Cobalt Catalysts for Diazo Decomposition / 2.5:
Palladium Catalysts for Diazo Decomposition / 2.6:
Rhodium Catalysts for Diazo Decomposition / 2.7:
Dirhodium (II) Carboxylates / 2.7.1:
Rhodium(II) Perfluorobutyrate
Dirhodium(II) Tetrakis[4-tert-butyl-N-benzenesulfonyl-L-prolinate]
Dirhodium(II) Carboxamidates / 2.7.2:
Dirhodium(II) Caprolactamate
Dirhodium(II) Tetrakis[methyl 2-oxooxazolidine-4(S)-carboxylate], Rh[subscript 2](4S-MEOX)[subscript 4]
Hexarhodium Hexadecacarbonyl / 2.7.3:
Dirhodium(II) Phosphates and Orthometallated Phosphines / 2.7.4:
Rhodium(III) Porphyrins / 2.7.5:
Ruthenium Catalysts for Diazo Decomposition / 2.8:
Other Transition Metals as Catalysts for Diazo Decomposition / 2.9:
Osmium / 2.9.1:
Iron / 2.9.2:
Platinum and Nickel / 2.9.3:
The Chromium Triad / 2.9.4:
Metal Carbenes as Stoichiometric Reagents / 2.10:
Insertion Reactions / 2.11:
Catalytic Intermolecular Carbon-Hydrogen Insertion Reactions / 3.1:
Catalytic Intramolecular Carbon-Hydrogen Insertion Reactions: General Considerations / 3.2:
Catalytic Intramolecular Carbon-Hydrogen Insertion Reactions of Diazoketones: Regioselectivity for Cyclopentanone Formation / 3.3:
Catalytic Intramolecular Carbon-Hydrogen Insertion Reactions of Diazoketones and Diazoesters: Diastereoselectivity and Synthetic Applications / 3.4:
Catalytic Intramolecular Carbon-Hydrogen Insertion Reactions of Diazoacetates: Lactone Formation / 3.5:
Catalytic Dinitrogen Extrusion from l-(--)-Menthyl Diazoacetoacetate
Catalytic Intramolecular Carbon-Hydrogen Insertion Reactions of Diazoacetamides: Lactam Formation / 3.6:
Catalyst-Dependent Chemoselectivity and Regioselectivity for Carbon-Hydrogen Insertion / 3.7:
Enantioselectivity in Intramolecular Carbon-Hydrogen Insertion Reactions / 3.8:
Synthesis of (+)-Arctigenin
Synthesis of (4R,5R)-(+)-2-Deoxyxylolactone
Diastereoselection and Regioselection in Carbon-Hydrogen Insertion Reactions Promoted by Chiral Catalysts / 3.9:
Diastereoselection in Carbon-Hydrogen Insertion Reactions Controlled with the Use of Chiral Auxiliaries / 3.10:
Silicon-Hydrogen and Related Insertion Reactions / 3.11:
Intermolecular Cyclopropanation and Related Addition Reactions / 3.12:
Cyclopropanation with Diazomethane / 4.1:
Cyclopropanation Reactions with Diazocarbonyl Compounds. General / 4.2:
Intermolecular Cyclopropanation Reactions of Diazocarbonyl Compounds. Diastereoselectivity / 4.3:
2,6-Di-tert-butyl-4-methylphenyl Diazoacetate (BDA)
Intermolecular Cyclopropanation Reactions of Diazocarbonyl Compounds. Regioselectivity and Relative Reactivities / 4.4:
Mechanism of Cyclopropanation. Stereochemistry of Cyclopropane Formation / 4.5:
Intermolecular Cyclopropanation Reactions of Diazocarbonyl Compounds. Enantioselectivity / 4.6:
Salicylaldimine-Copper Catalysts / 4.6.1:
Semicorrin-Copper Catalysts / 4.6.2:
bis(Oxazoline)-Copper Catalysts / 4.6.3:
Pyridine-Ligated Copper Catalysts / 4.6.4:
Other Chiral Copper Catalysts / 4.6.5:
Chiral Dirhodium(II) Carboxylates / 4.6.6:
Chiral Dirhodium(II) Carboxamidates / 4.6.7:
Other Chiral Rhodium Catalysts / 4.6.8:
Pybox-Ruthenium Catalysts / 4.6.9:
Cobalt Catalysts / 4.6.10:
Donor-Acceptor Cyclopropanes in Organic Synthesis / 4.7:
Vinyldiazoacetates--Intermolecular Annulation Reactions / 4.8:
Formal [3+4]-Cycloaddition / 4.8.1:
Formal [3+2]-Cycloaddition / 4.8.2:
1,3-Dipolar Ketocarbene Addition / 4.9:
Intermolecular Cyclopropanation and Subsequent Reactions in Synthesis / 4.10:
Cyclopropenation of Alkynes / 4.11:
Aziridination / 4.12:
Addition to Imines / 4.12.1:
Nitrene Addition to Alkenes / 4.12.2:
Intramolecular Cyclopropanation and Related Addition Reactions / 4.13:
Intramolecular Cyclopropanation of Diazoketones / 5.1:
Vinylcyclopropylcarbonyl Compounds in Organic Synthesis / 5.2:
Intramolecular Cyclopropanation of Diazoesters and Diazoamides / 5.3:
Regioselectivity and Chemoselectivity in Intramolecular Cyclopropanation Reactions / 5.4:
Enantioselective Intramolecular Cyclopropanation Reactions / 5.5:
Synthesis of (1R,5S)-(--)-6,6-Dimethyl-3-oxabicyclo-[3.1.0]hexan-2-one
Synthesis of (1S,5R)-(+)-3,6,6-Trimethyl-3-azabicyclo-[3.1.0]hexan-2-one
Diastereocontrol in Intramolecular Cyclopropanation Reactions / 5.6:
Macrocyclic Cyclopropanation / 5.7:
Intramolecular Cyclopropenation Reactions: Tandem/Cascade Processes / 5.8:
Cycloaddition and Substitution Reactions with Aromatic and Heteroaromatic Compounds / 5.9:
Intermolecular Reactions with Benzene and its Derivatives / 6.1:
Diazoesters / 6.1.1:
Diazoketones / 6.1.2:
Intramolecular Cycloaddition Reactions with Benzene Derivatives / 6.2:
Diazoketone Cyclization onto a Benzene Ring: 3,4-Dihydro-1(2H)-Azulenone [1(2H)-Azulenone, 3,4-dihydro-] / 6.2.1:
Diazoesters and Diazoamides / 6.2.2:
Chemoselectivity in Aromatic Cycloaddition / 6.2.3:
Asymmetric Synthesis in Aromatic Cycloaddition / 6.2.4:
Substitution Reactions with Aromatic Compounds / 6.3:
Rhodium(II) Acetate-Catalyzed Decomposition of 2-Diazo-3-oxobutanamides
Chemoselectivity in Aromatic Substitution / 6.3.1:
Asymmetric Synthesis in Aromatic Substitution / 6.3.2:
Cycloaddition and Substitution Reactions with Heterocyclic Aromatic Compounds / 6.4:
Furans / 6.4.1:
Reaction of EDA with Furan
Pyrroles / 6.4.2:
Thiophenes / 6.4.3:
Generation and Reactions of Ylides from Diazocarbonyl Compounds / 6.5:
Formation of Sulfur Ylides / 7.1:
Formation of Stable Sulfonium and Sulfoxonium Ylides from Diazocarbonyl Precursors / 7.2.1:
Intermolecular Formation of Sulfur Ylides and Subsequent Reactions / 7.2.2:
Reaction of 2-Phenyl-1,3-dithiane with EDA
Intramolecular Formation of Sulfur Ylides and Subsequent Reactions / 7.2.3:
[beta]-Elimination and Related [1,4] Rearrangement / 7.2.4:
Chemo- and Stereoselectivity in Sulfur Ylide Formation and Subsequent Rearrangement / 7.2.5:
Formation of Oxonium Ylides / 7.3:
Intermolecular Formation of Oxonium Ylides and Subsequent Reactions / 7.3.1:
Intramolecular Formation of Oxonium Ylides and Subsequent Reactions / 7.3.2:
[2,3]-Sigmatropic Rearrangement of Cyclic Oxonium Ylide: Synthesis of 8-Chloro-5,7-dimethoxy-2-carbomethoxy-2-[1-(S)- methyl-2-butenyl]benzofuran-3-one
Chemo-, Diastereo-, and Enantioselectivity in Oxonium Ylide Formation / 7.3.3:
Formation of Nitrogen Ylides from Diazocarbonyl Compounds / 7.4:
Intermolecular Formation of Nitrogen Ylides and Subsequent Reactions / 7.4.1:
Intramolecular Formation of Nitrogen Ylides and Subsequent Reactions / 7.4.2:
Formation of Carbonyl Ylides from Diazocarbonyl Compounds / 7.5:
Intermolecular Carbonyl Ylide Formation and Subsequent Reactions / 7.5.1:
Intramolecular Carbonyl Ylide Formation and Subsequent Reactions / 7.5.2:
Intramolecular Carbonyl Ylide Formation and Subsequent 1,3-Dipolar Cycloaddition Reaction: Synthesis of 6,8-Dioxabicyclo[3.2.1]octane Ring Systems
Chemoselectivity in Carbonyl Ylide Formation / 7.5.3:
Formation of Thiocarbonyl Ylides from Diazocarbonyl Compounds / 7.6:
X-H Insertion Reactions of Diazocarbonyl Compounds (X = N, O, S, Se, P, Halogen) / 7.7:
N-H Insertion / 8.1:
Intermolecular N-H Reactions / 8.2.1:
Intramolecular N-H Insertion / 8.2.2:
Asymmetric N-H Insertion / 8.2.3:
O-H Insertion with Water, Alcohols, and Phenols / 8.3:
Intermolecular O-H Insertion / 8.3.1:
2-Isopropoxycyclohexanone
Intramolecular O-H Insertion / 8.3.2:
Asymmetric O-H Insertion / 8.3.3:
O-H Insertion Reactions with Carboxylic Acids, Carboxylic Esters, and Sulfonic Acids / 8.4:
(S)-3-N-(Phthalimido)-4-phenyl-1-(methane-sulfonyloxy)butan-2-one
S-H Insertion / 8.5:
2-(Phenylthio)-6-phenyl-3-hexanone
Se-H Insertion / 8.6:
P-H Insertion / 8.7:
X-H Insertion (X = Halogen) / 8.8:
The Wolff Rearrangement and Related Reactions / 8.9:
The Arndt-Eistert Homologation / 9.1:
Ethyl 1-Naphthylacetate
3(S)-Methyl-3-(N-tert-butoxycarbonylamino)-6-(N-bis-benzyloxycarbonyl guanidyl)hexanoate
Protected Homopeptide
Ring Contraction via the Wolff Rearrangement / 9.2:
Formation and Photochemical Wolff Rearrangement of Cyclic [alpha]-Diazoketones: D-Norandrost-5-en-3[beta]-ol-16-carboxylic Acids
The Wolff Rearrangement with Cycloaddition Reactions / 9.3:
The Vinylogous Wolff Rearrangement / 9.4:
Miscellaneous Applications of the Wolff Rearrangement / 9.5:
Conclusions / 9.6:
Reactions of [alpha]-Diazocarbonyl Compounds with Aldehydes and Ketones / 9.7:
Base Promoted Reactions of [alpha]-Diazocarbonyl Compounds with Aldehydes and Ketones / 10.1:
Base-Promoted Reactions of [alpha]-Diazocarbonyl Compounds with Aldehydes: Synthesis of (N-Butoxy-carbonyl-L-Phenylalanyl)-Methyl Phenyl Ketone
Acid-Catalyzed Reactions of [alpha]-Diazocarbonyl Compounds with Aldehydes / 10.3:
Synthesis of [beta]-Dicarbonyl Compounds via Tin(II) Chloride-Catalyzed Reaction: Conversion of Hydrocinnamaldehyde into Ethyl 3-Oxo-5-phenylvalerate
Synthesis of Tetrahydrofurans / 10.4:
Tetrahydrofuran Annulation with [beta]-p-Methoxybenzyl Pivalaldehyde and Ethyl Diazoacetate: Synthesis of Substituted Tetrahydrofuran 14
Olefination of Aldehydes and Ketones with Diazocarbonyl Compounds / 10.5:
Acid-Catalyzed Reactions of [alpha]-Diazocarbonyl Compounds with Ketones / 10.6:
Homologation of Cyclobutanone Ring with Ethyl Diazoacetate: Synthesis of Methyl (2S,3aR,6aS)-1,2,3,3a,4,5,6,6a-Octahydro-2-methyl-4-oxopentalene-2-carboxylate
Acid-Promoted Cyclization of Unsaturated and Aromatic Diazo Ketones / 10.7:
Cyclization of [gamma, delta]-Unsaturated Diazoketones / 11.1:
Cyclization of [beta, gamma]-Unsaturated Diazoketones / 11.3:
Intramolecular Alkylation of Diazoketones through Aryl Participation / 11.4:
Ar[subscript 1]-5 Participation in the Cyclization of Aromatic Diazoketones / 11.4.1:
Ar[subscript 1]-6 Participation in the Cyclization of Aromatic Diazoketones / 11.4.2:
Ar[subscript 1]-4 Cyclization in the Cyclization of Aromatic Diazoketones / 11.4.3:
Synthesis of Heterocycles by Acid-Promoted Cyclization of [alpha]-Diazocarbonyl Compounds / 11.5:
Miscellaneous Diazocarbonyl Reactions / 11.6:
Oxidation of Diazocarbonyl Compounds / 12.1:
Oxidation of N-Benzyloxycarbonyl-L-phenylalanyl diazomethane with Dimethyldioxirane. Preparation of an N-Protected Amino Glyoxal Hydrate
[beta]-Hydride Elimination / 12.3:
Preparation of Methyl (Z)-2-Undecenoate from Methyl 2-Diazoundecanoate
X-Y Insertion Reactions / 12.4:
X-Y = The Halogens / 12.4.1:
X-Y = Arenesulfonyl Halides (ArS-X) / 12.4.2:
X-Y = Areneselenyl Halides and Diphenyl Diselenide (ArSe-X) / 12.4.3:
Preparation of 2-Phenylselenyl-2-cyclohexen-1-one from 2-Diazocyclohexanone
X-Y = Trialkylboranes (R-BR[subscript 2]) / 12.4.4:
Dimerization Reactions / 12.5:
Diazocarbonyl Compounds as 1,3-Dipoles in [3+2] Cycloaddition Reactions / 12.6:
Index / 12.7:
Preface
Acknowledgments
Synthesis of [alpha]-Diazocarbonyl Compounds / 1.:
9.

図書

図書
[The proceedings of The Royal Society of Chemistry Third International Symposium on Supported Reagents and Catalysts in Chemistry (3rd ISSRC) held at the University of Limerick on 8-11 July, 1997] ; edited by B.K. Hodnett ... [et al.]
出版情報: Cambridge : Royal Society of Chemistry, 1998  xxiv, 243 p. ; 24cm
シリーズ名: Special publication / Royal Society of Chemistry ; no.216
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10.

図書

図書
volume editor, Michael J. Krische ; with contributions by B. Breit... [et al.]
出版情報: Berlin : Springer, c2007  x, 264 p. ; 24 cm
シリーズ名: Topics in current chemistry = Fortschritte der chemischen Forschung ; 279
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目次情報: 続きを見る
Nickel-Catalyzed Reductive Couplings of Aldehydes and Alkynes / J. Montgomery ; G. J. Sormunen
Reductive C-C Bond Formation after Epoxide Opening via Electron Transfer / A. Gansauer ; J. Justicia ; C.-A. Fan ; D. Worgull ; F. Piestert
Catalytic Reductive Coupling of Carbonyl Compounds - The Pinacol Coupling Reaction and Beyond / T. Hirao
Catalytic Reductive Coupling of Alkenes and Alkynes to Carbonyl Compounds and Imines Mediated by Hydrogen / H. Iida ; M. J. Krische
Reductive Aldol, Michael, and Mannich Reactions / H. Nishiyama ; T. Shiomi
Recent Advances in Alkene Hydroformylation / B. Breit
Nickel-Catalyzed Reductive Coupling of Dienes and Carbonyl Compounds / M. Kimura ; Y. Tamaru
Reductive Coupling of Unactivated Alkenes and Alkynes / R. D. Broene
Author Index Volumes 251-279
Subject Index
Nickel-Catalyzed Reductive Couplings of Aldehydes and Alkynes / J. Montgomery ; G. J. Sormunen
Reductive C-C Bond Formation after Epoxide Opening via Electron Transfer / A. Gansauer ; J. Justicia ; C.-A. Fan ; D. Worgull ; F. Piestert
Catalytic Reductive Coupling of Carbonyl Compounds - The Pinacol Coupling Reaction and Beyond / T. Hirao
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