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1.

図書
図書
1. Solar hydrogen and nanotechnology : 14-17 August 2006, San Diego, California, USA
Lionel Vayssieres, chair/editor ; sponsored and published by SPIE--the International Society for Optical Engineering
出版情報: Bellingham, Wash. : SPIE, c2006  1 v. (various pagings) ; 28 cm
シリーズ名: Proceedings / SPIE -- the International Society for Optical Engineering ; v. 6340
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2.

図書
図書
2. Photocatalysis : fundamentals, materials and applications
Jinlong Zhang ... [et al.]
出版情報: Singapore : Springer, c2018  xii, 409 p. ; 25 cm
シリーズ名: Lecture notes in chemistry ; 100
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3.

図書
図書
3. Photosensitization and photocatalysis using inorganic and organometallic compounds
edited by K. Kalyanasundaram and M. Grätzel
出版情報: Dordrecht ; Boston : Kluwer Academic Publishers, c1993  xvi, 465 p. ; 24 cm
シリーズ名: Catalysis by metal complexes ; v. 14
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Preface
Evolution of Inorganic and Organometallic Photochemistry
Historical Perspectives and Commentary / A.W. Adamson
Intermolecular Energy and Electron Transfer Processes / V. Balzani ; M. Maestri
Photocatalysis: Definitions and Classifications / H. Hennig ; R. Billing ; H. Knoll
Charge Transfer Excitation of Coordination Compounds
Generation of Reactive Intermediates / A. Vogler ; H. Kunkely
Photoredox and Sensitization Processes involving Transition Metal Polypyridine Complexes / K. Kalyanasundaram
Intramolecular Energy and Electron Transfer in Polynuclear Complexes / F. Scandola ; C.A. Bignozzi ; M.T. Indelli
Photocatalysis: Reduction of CO2 and Water-Gas Shift Reaction catalysed by 2,2'-bipyridine or 1,10-phenanthroline Co(II), Ru(II), Re(I) and Ir(III) complexes / R. Ziessel
Metal Complexes as Photosensitizers in Photoelectrochemical Cells / M. Gratzel
Photosensitization by (Metallo)porphyrins: Formation and Photophysical Properties of Porphyrin Assemblies / A. Harriman
Photocatalytic and Photoredox Properties of Polyoxometalate Systems / C.L. Hill ; C.M. Prosser-McCartha
Photocatalytic Transformations of Organic Substrates using INorganic Salts and Complexes / U. Kolle
Photocatalytic Reactions involving Metal Carbonyls / P.C. Ford ; W. Boese ; B. Lee ; K.L. MacFarlane
Photocatalysis - C-H Activation / R.H. Crabtree
Electron Donor-Acceptor Interactions and Photoinduced Electron Transfer of Organometallic Compounds / T.M. Bockman ; J.K. Kochi
Index
Preface
Evolution of Inorganic and Organometallic Photochemistry
Historical Perspectives and Commentary / A.W. Adamson
4.

図書
図書
4. Solar hydrogen generation : transition metal oxides in water photoelectrolysis (: hbk.)
Jinghua Guo, Xiaobo Chen
出版情報: New York : McGraw-Hill, c2012  xvii, 185 p. ; 24 cm
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Preface
Hydrogen Generation: Electrochemistry and Photoelectrolysis / 1：
Electrochemistry / 1.1：
Photocatalysis / 1.2：
Photocatalytic Reactions, Oxidation, and Reduction / 2：
Basic Points in Photocatalytic Reactions / 2.1：
Semiconductor Catalysts / 2.2：
Biomimetic Catalysts / 2.3：
Nanostructured Catalysts / 2.4：
Transition Metal Oxides / 3：
Metal Oxide Semiconductors / 3.1：
Heterogeneous Photocatalyst Materials / 3.2：
d° Metal Oxide Photocatalyts / 3.3：
Ti-, Zr-Based Oxides / 3.3.1：
Nb-, Ta-Based Oxides / 3.3.2：
W-, Mo-Based Oxides / 3.3.3：
Other d° Metal Oxides / 3.3.4：
d10 Metal Oxide Photocatalysts / 3.4：
f° Metal Oxide Photocatalysts / 3.5：
Crystal Structure and Electronic Structure / 4：
Crystal Structure / 4.1：
TiO2 / 4.2：
Fe Oxides / 4.3：
Electronic Structure of 3d Transition Metal Oxides / 4.4：
Ti02 / 4.4.1：
ZnO / 4.4.2：
Optical Properties and Light Absorption / 5：
Impurity, Dopants, and Defects / 5.1：
Single-Element Doped TiO2 / 6.1：
Metal Doped Ti02 / 6.1.1：
Nonmetal Doped TiO2 / 6.1.2：
Metal/Nonmetal Ion Co-doping / 6.2：
Doped ZnO / 6.3：
Controlling Band Structure by Making Solid Solutions / 6.4：
Oxide Solid Solutions / 6.4.1：
Oxynitride Solid Solutions / 6.4.2：
Organic and Inorganic Systems / 6.5：
Surface and Morphology / 7：
Surface and Interface Chemistry / 7.1：
Nanostructure and Morphology / 7.2：
Quantum-Sized Transition Metal Oxides / 7.2.1：
TiO2 Quantum Dots / 7.2.2：
Bandgap Engineering for Visible Light Response / 7.2.3：
Bandgap at the Surface / 7.2.4：
Bandgap Change from Crystal Structure / 7.2.5：
Soft X-ray Spectroscopy and Electronic Structure / 8：
Soft X-ray Absorption and Emission Spectroscopy / 8.1：
Resonantly Excited Soft X-ray Emission Spectroscopy / 8.2：
Electronic Structure of Metal Oxide Catalysts / 8.3：
Fe2O3 Catalysts / 8.3.1：
Co Nanocrystals and Co3O4 Catalysts / 8.3.3：
In Situ Electronic Structure Characterization / 8.3.4：
NiCL, Water Solutions / 8.5：
In Situ Study of Electrochemical Reaction / 8.6：
References
Index
Preface
Hydrogen Generation: Electrochemistry and Photoelectrolysis / 1：
Electrochemistry / 1.1：
5.

図書
図書
5. Photocatalysis (:hbk)
volume editor Carlo Alberto Bignozzi ; with contributions by B.D. Alexander ... [et al.]
出版情報: Heidelberg ; London : Springer, c2011  xi, 220 p. ; 25 cm
シリーズ名: Topics in current chemistry = Fortschritte der chemischen Forschung ; 303
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6.

図書

東工大
目次DB
図書
東工大
目次DB
6. Photocatalysis : science and technology (: Springer ; : Kodansha)
Masao Kaneko, Ichiro Okura (eds.)
出版情報: Tokyo : Kodansha , Berlin ; London : Springer, c2002  xvi, 356 p. ; 25 cm
シリーズ名: Biological and medical physics series
Physics and astronomy online library
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List of Contributors
Preface
   1 Introduction 1
   1.1 Background 1
   1.2 Aim and Outline of This Volume 2
   1.3 Summary 4
   1.4 Future Perspectives 4
   References 5
Ⅰ Fundamental Aspects of Photocatalysts
   2 Photoelectrochemical Processes of Semiconductors 9
   2.1 Semiconductor Electrodes for Solar Energy Conversion 11
   2.2 Reduction of CO2 at Illuminated Semiconductor Electrodes 15
   2.3 Photocatalysis 18
   2.3.1 General Remarks 18
   2.3.2 Mechanistic Studies 19
   2.3.3 Low Intensity Illumination 22
   2.3.4 Applications 24
   References 26
   3 Design, Preparation and Characterization of Highly Active Metal Oxide Photocatalysts 29
   3.1 Introduction 29
   3.2 Photocatalytic Activity 29
   3.2.1 Effect of Surface Area on Photocatalytic Activity 30
   3.2.2 Effect of Electron-hole Recombination on Photocatalytic Activity 32
   3.2.3 Design of Photocatalysts of High Activity 33
   3.3 Preparation of Titanium (IV) Oxide Powders 33
   3.3.1 Sulfate Method 33
   3.3.2 Chloride Method (Vapor Method) 34
   3.3.3 Alkoxide Method 34
   3.3.4 Specific Methods 34
   3.3.5 Activation of TiO2 Photocatalysts 36
   3.4 Preparation of Other Photocatalysts 38
   3.5 Characterization of TiO2 Photocatalysts of Both High Crystallinity and Large Surface Area 38
   3.5.1 Photocatalytic Activity of HyCOM TiO2 in Aqueous Suspension Systems 38
   3.5.2 Correlation Between Physical Properties and Photocatalytic Activity of HyCOM TiO2 39
   3.5.3 Novel Hypothesis for Activity of Photocatalyst 43
   3.6 Preparation and Characterization of Photocatalytic Thin Films 44
   3.6.1 Preparation of Photocatalytic TiO2 Thin Films 44
   3.6.2 Characterization of Photocatalytic Thin Films Prepared from HyCOM TiO2 Powders 45
   3.7 Summary 47
   References 47
   4 Photoelectrochemistry at Semiconductor/Liquid Interfaces 51
   4.1 Introduction 51
   4.2 Basic Properties of Semiconductor/Liquid Interface 52
   4.2.1 Band Bending 52
   4.2.2 Barrier Height and Flat Band Potential 54
   4.2.3 Electron Transfer and Corrosion Reactions 57
   4.3 Photoelectrochemistry at Atomically Well-defined Surfaces 59
   4.3.1 Atomically Flat H-terminated Si Surfaces 59
   4.3.2 Selective Exposition of (100) Face on n-TiO2 (Rutile) by Photoetching 62
   4.4 Photoelectrochemistry at Metal Dot-coated Semiconductors 64
   4.4.1 Ideal Semiconductor Electrodes 64
   4.4.2 Metal-loaded TiO2 Electrodes 66
   References 67
   5 Photoelectrochemical Reactions at Semiconductor Microparticle 69
   5.1 Introduction 69
   5.2 Energy Structure of Semiconductor Microparticle 69
   5.2.1 Depletion Layer 69
   5.2.2 Electric Heterogeneity of Surface 71
   5.2.3 Size Quantization Effect 72
   5.3 Kinetics at Semiconductor Microparticle 72
   5.3.1 Recombination Model 73
   5.3.2 2D Ladder Model 74
   5.3.3 Effect of Size 76
   5.4 Observation of Primary Reaction Intermediates 77
   5.4.1 ESR Analysis for Irradiated TiO2 Particles 78
   5.4.2 Direct Observation of Intermediate Radicals 81
   5.4.3 Chemiluminescent Probe for Active Oxygens 83
   References 85
   6 New Approaches in Solution-phase Processing of Semiconductor Thin Films 87
   6.1 Introduction 87
   6.2 Previous Methods for Solution-phase Deposition of Semiconductor Thin Films 89
   6.2.1 Chemical Bath Deposition of Metal Sulfide Thin Films 89
   6.2.2 Electrodeposition of Metal Sulfide Thin Films 90
   6.2.3 Chemical and Electrochemical Deposition of Metal Oxide Thin Films 92
   6.3 Electrochemically Induced Chemical Deposition (EICD) of Cds Thin Films 93
   6.3.1 Idea 93
   6.3.2 Morphological and Structural Analysis 94
   6.3.3 Growth Kinetics and Mechanism of EICD Process 95
   6.3.4 Modification of EICD Process 97
   6.4 True Electrodeposition of Metal Sulfide Thin Films by Reduction of Thiocyanato Complexes 97
   6.4.1 Idea 97
   6.4.2 Thermodynamic Consideration 98
   6.4.3 Electrochemical Layer-by-layer Growth of CdS Thin Films 98
   6.4.4 Electrodeposition of Other Metal Sulfides 100
   6.5 Electrochemical Self-assembly of ZnO/Dye Hybrid Thin Films 100
   6.5.1 Idea 100
   6.5.2 Electrochemical Self-assembly of ZnO/Dye Hybrid Structure 102
   6.5.3 Mechanism of Electrochemical Self-assembly 104
   6.6 Summary 104
   References 105
Ⅱ Application to Environmental Cleaning
   7 Self-cleaning Properties of TiO2-coated Substrates 109
   7.1 Introduction 109
   7.2 Photocatalytic Decomposition 110
   7.2.1 Air Purifying Effect 110
   7.2.2 Sterilization Effect 111
   7.2.3 Anti-fouling Effect 113
   7.2.4 Photo-induced High Amphiphilicity 114
   7.3 Conclusions 120
   References 121
   8 Cleaning Atmospheric Environment 123
   8.1 Introduction 123
   8.2 Photocatalytic Activities of TiO2 124
   8.2.1 Oxidation of Air Pollutants by Photogenerated Active Oxygen Species 124
   8.2.2 Photocatalytic Reactions of Volatile Hydrocarbons 125
   8.2.3 Photocatalytic Reactions of Halogenated Hydrocarbons 136
   8.2.4 Nitrogen Oxides (Nox) 143
   8.3 Development of Air Purifying Materials Based on Photocatalyst 147
   8.3.1 Immobilization of Powder Photocatalysts 147
   8.3.2 Preparation of Air-purifying Materials 148
   8.3.3 Performance Characteristics of Air-purifying Materials 149
   8.4 Application of Photocatalysis to Cleaning of Atmospheric Environment 151
   8.4.1 Passive Purification of Polluted Air 151
   8.4.2 Active Air Purification of Closed Space 153
   8.5 Summary 154
   References 155
   9 Water Purification - Degradation of Aqueous Pollutant and Application to Water Treatment 157
   9.1 Introduction 157
   9.2 Photocatalytic Characteristics of Titanium Dioxide 157
   9.3 Photocatalytic Degradation of Pollutant 160
   9.3.1 Volatile Organohalide Compound 160
   9.3.2 Pesticides 162
   9.3.3 Other Organic Compounds 164
   9.3.4 Environmental Hormones (Endocrine Disruptors) 165
   9.4 Enhancement of Degradation Rate 166
   9.4.1 Pt-loading 166
   9.4.2 Addition of H2O2 167
   9.4.3 Ozone 169
   9.4.4 Increase in Adsorption 169
   9.5 Solar System for Water Treatment 171
   9.6 Immobilization of TiO2 and Instrumentation 171
   9.7 Conclusion and Outlook 172
   References 172
   10 Second-generation TiO2 Photocatalysts Able to Initiate Reactions Under Visible Light Irradiation 175
   10.1 Introduction 175
   10.2 Experimental Section 175
   10.3 Results and Discussion 176
   10.4 Conclusion 182
   References 182
Ⅲ Application to Photoenergy Conversion
   11 Photocatalytic Organic Syntheses Using Semiconductor Particles 185
   11.1 Introduction 185
   11.2 Principle of Photocatalysis by Semiconductor Particles 186
   11.3 Photocatalytic Reactions by Semiconductor Suspension 187
   11.4 Redox Combined Photocatalytic Processes for Nitrogen-containing Substrates 189
   11.5 Further Development to Stereoselective Organic Synthesis of Nitrogen-containing Compounds 191
   11.6 Introduction of Oxygen Atoms into Organic Compounds 194
   11.6.1 Stereospecific Epoxidation of 2-hexene on Photoirradiated TiO2 Powders Using Molecular Oxygen as Oxidant 195
   11.6.2 Selective Oxidation of Naphthalene by Molecular Oxygen and Water Using TiO2 Photocatalysts 196
   11.6.3 Photocatalytic Oxygenation: Summary 198
   11.7 Concluding Remarks 199
   References 199
   12 Sonophotocatalysis - Joint System of Sonochemical and Photocatalytic Reactions 203
   12.1 Introduction - What is Sonophotocatalysis? 203
   12.2 Utilization of Sonophotocatalytic Reaction 204
   12.2.1 Sonophotocatalysis of Water 204
   12.2.2 Sonophotocatalysis of Artificial Seawater 216
   12.2.3 Sonophotocatalyses of Organic Compounds 219
   12.3 Conclusion and Future Scopes 220
   References 221
   13 Gas-phase Water Photolysis by NaOH-coated Photocatalysts 223
   13.1 Introduction 223
   13.2 Water Photolysis by Pt/TiO2 224
   13.3 Water Photolysis by Metallized Semiconductor Powders 226
   13.3.1 Gas-phase Water Photolysis by NaOH-coating 226
   13.3.2 Factors Influencing Yield of Water Photolysis 229
   13.4 Concluding Remarks 233
   References 234
   14 Water Photolysis by TiO2 Particles - Significant Effect of Na2CO3 Addition on Water Splitting 235
   14.1 Introduction 235
   14.2 Significant Effect of Carbonate Salt Addition on Water Splitting from Pt/TiO2 Water Suspension 236
   14.3 Role of Carbonate Salts on Water Splitting and Reaction Mechanism 240
   14.4 Effective Screening of Active Photocatalysts for Water Splitting Using Na2CO3 Addition Method 242
   14.5 Solar Hydrogen Production Using Na2CO3 Addition Method 246
   14.6 Conclusion 248
   References 248
   15 Water Photolysis by Titanates with Tunnel Structures 249
   15.1 Water Photolysis by RuO2/BaTi4O9 with Pentagonal Prism Tunnel Structure 250
   15.2 Water Photolysis by RuO2/N2Ti6O13 with Rectangular Tunnel Structure 257
   References 260
   16 Water Photolysis by Layered Compounds 261
   16.1 Introduction 261
   16.2 Layered Oxides of Transition Metals 261
   16.3 K4Nb6O17 263
   16.3.1 Structure and Physico-chemical Properties 263
   16.3.2 Photocatalytic Overall Water Splitting 265
   16.3.3 Structure of Ni-loaded K4Nb6O17 and Reaction Mechanism 267
   16.4 Perovskite-related Layered Oxides 268
   16.5 Summary 276
   References 276
   17 Splitting of Water by Combining Two Photocatalytic Reactions via Quinone Redox Couple Dissolved in Oil Phase: Artificial Photosynthesis 279
   17.1 Introduction 279
   17.2 Strategy for Water Splitting by Mimicking Photosynthesis 280
   17.3 Photocatalytic Hydrogen and Oxygen Evolution in Separate Systems 281
   17.3.1 Photooxidation of Water Using TiO2 Particles 282
   17.3.2 Photoreduction of Water Using Pt-loaded TiO2 Particles 285
   17.4 Approaches to Electrochemical and Chemical Combinations of Two Photocatalytic Reactions 286
   17.5 Splitting of Water by a Combination of Two Photocatalytic Reactions via DDQ/DDHQ 289
   17.6 Conclusions 291
   References 291
   18 Sensitization by Metal Complexes Towards Future Artificial Photosynthesis 293
   18.1 Introduction 293
   18.2 Photoinduced Hydrogen Evolution in Homogeneous Four-component Systems 294
   18.2.1 Photoinduced Hydrogen Evolution with Porphyrin Metal Complexes and Hydrogenase 294
   18.2.2 Photoinduced Hydrogen Evolution Using Cytochrome c3 as Electron Carrier 296
   18.2.3 Photoinduced Hydrogen Evolution Using Chemically-modified Chlorophyll 298
   18.3 Photoinduced Hydrogen Evolution with Viologen-linked orphyrin Metal Complexes 299
   18.3.1 Photoinduced Hydrogen Evolution with Water-soluble Viologen-linked Cationic Porphyrin Metal Complexes and Hydrogenase 300
   18.3.2 Photoinduced Hydrogen Evolution with Water-soluble Viologen-linked Anionic Porphyrin and Hydrogenase 302
   18.4 Other Systems for Hydrogen Evolution Using Natural Photosensitizers 303
   18.5 Conclusion 306
   References 306
   19 Catalyses and Sensitization for Water Reaction Towards Future Artificial Photosynthesis 309
   19.1 Introduction 309
   19.2 Design of Artificial Photosynthesis 309
   19.2.1 Photosynthesis and Energy Cycle on Earth 309
   19.2.2 Artificial Photosynthesis 311
   19.3 Molecular Catalysts for Water Reactions and CO2 Reduction 312
   19.3.1 Catalysis in Water Oxidation 312
   19.3.2 Catalysis in Proton Reduction 316
   19.3.3 Catalysis in Carbon Dioxide Reduction 316
   19.4 Photoexcited State Electron Transfer in Heterogeneous Phases 317
   19.5 Sensitization of TiO2 Powders and Films in Water 320
   19.6 Conclusion and Future Prospects 322
   References 323
   20 Photoelectric TiO2 Solar Cells 325
   20.1 Introduction 325
   20.2 Dye-sensitization of Semiconductors 325
   20.2.1 History 325
   20.2.2 Innovative Dye-sensitized Solar Cells 327
   20.2.3 Fabrication of Dye-sensitized TiO2 Solar Cells 328
   20.2.4 Characterization of Innovative Dye-sensitized TiO2 Solar Cells 329
   20.3 Electron-transfer Sensitization on TiO2 330
   20.3.1 Bonding Structure of Dye on TiO2 Influencing ηei 331
   20.3.2 Dynamics in Electron Transfer from Photoexcited Dye 2 to TiO2 331
   20.3.3 Electron Transfer Between Oxidized Dye 2 and I-/I3- Electrolyte 332
   20.4 Electron Transport in Porous TiO2 Electrodes 333
   20.4.1 Electron Transport Models for High ηet 334
   20.4.2 Time-course Analysis 335
   20.4.3 Frequency Analysis 335
   20.4.4 Effect of TiO2 Films on Performance of Dye-sensitized Solar Cells 337
   20.5 Sensitization Dyes 337
   20.5.1 Ruthenium Polypyridine Complexes 337
   20.5.2 Other Metal Complexes 339
   20.5.3 Organic Dyes 340
   20.5.4 Natural Dyes 342
   20.6 Recent Research Progress in Dye-sensitized Solar Cells 343
   20.7 Future Work on Dye-sensitized Solar Cells 344
   20.8 Concluding Remarks 345
   References 346
Index 349
List of Contributors
Preface
   1 Introduction 1
7.

電子ブック
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7. Advances in CO[2] capture, sequestration, and conversion (: electronic bk)
Fangming Jin, editor, Liang-Nian He, editor, Yun Hang Hu, editor ; sponsored by the ACS Division of Energy and Fuels
出版情報: [Washington, DC] : American Chemical Society, c2022  1 online resource (381 p.)
シリーズ名: ACS symposium series ; 1194
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8.

電子ブック
ＥＢ
8. Nanostructured photocatalysts : from materials to applications in solar fuels and environmental remediation (: electronic bk)
edited by Rabah Boukherroub, Satishchandra B. Ogale, Neil Robertson
出版情報: [Amsterdam] : Elsevier ScienceDirect Books, [202-]  1 online resource (xv, 283 p.)
シリーズ名: Micro and nano technologies series
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9.

電子ブック
ＥＢ
9. Current developments in photocatalysis and photocatalytic materials : new horizons in photocatalysis (: electronic bk)
edited by Xinchen Wang, Masakazu Anpo, Xianzhi Fu
出版情報: [Amsterdam] : Elsevier ScienceDirect Books, [202-]  1 online resource (xxx, 536 p.)
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10.

図書
図書
10. Solar hydrogen and nanotechnology II : 27-30 August 2007, San Diego, California, USA (: pbk)
Jinghua Guo, editor ; sponsored and published by SPIE
出版情報: Bellingham, Wash. : SPIE, c2007  1 v. (various pagings) ; 28 cm
シリーズ名: Proceedings / SPIE -- the International Society for Optical Engineering ; v. 6650
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