Note: Each chaper concludes with Key Equations, Problems, and Suggested Reading |
The Nature of Physical Chemistry and the Kinetic Theory of Gases / 1: |
The Nature of Physical Chemistry / 1.1: |
Some Concepts from Classical Mechanics / 1.2: |
Systems, States, and Equilibrium / 1.3: |
Thermal Equilibrium / 1.4: |
Pressure and Boyle's Law Biography: Robert Boyle / 1.5: |
Gay-Lussac's (Charles's) Law / 1.6: |
The Ideal Gas Thermometer / 1.7: |
The Equation of State for an Ideal Gas / 1.8: |
The Kinetic-Molecular Theory of Ideal Gases / 1.9: |
The Barometric Distribution Law / 1.10: |
The Maxwell Distribution of Molecular Speeds and Translational Energies / 1.11: |
Real Gases / 1.12: |
Equations of State / 1.13: |
The Virial Equation Appendix: Some Definite and Indefinite Integrals Often Used in Physical Chemistry / 1.14: |
The First Law of Thermodynamics / 2: |
Origins of the First Law / 2.1: |
States and State Functions / 2.2: |
Equilibrium States and Reversibility / 2.3: |
Energy, Heat, and Work / 2.4: |
Thermochemistry / 2.5: |
Ideal Gas Relationships / 2.6: |
The Second and Third Laws of Thermodynamics Biography: Rudolph Julius Emmanuel Clausius / 2.7: |
The Carnot Cycle / 3.1: |
Irreversible Processes / 3.2: |
Molecular Interpretation of Entropy / 3.3: |
The Calculation of Entropy Changes / 3.4: |
The Third Law of Thermodynamics / 3.5: |
Conditions for Equilibrium / 3.6: |
The Gibbs Energy / 3.7: |
Some Thermodynamic Relationships / 3.8: |
The Gibbs-Helmholtz Equation / 3.9: |
Thermodynamic Limitations to Energy Conversion / 3.10: |
Chemical Equilibrium Biography: Jacobus Henricus van't Hoff / 4: |
Chemical Equilibrium Involving Ideal Gases / 4.1: |
Equilibrium in Nonideal Gaseous Systems / 4.2: |
Chemical Equilibrium in Solution / 4.3: |
Heterogeneous Equilibrium / 4.4: |
Tests for Chemical Equilibrium / 4.5: |
Shifts of Equilibrium at Constant Temperature / 4.6: |
Coupling of Reactions / 4.7: |
Temperature Dependence of Equilibrium Constants / 4.8: |
Pressure Dependence of Equilibrium Constants / 4.9: |
Phases and Solutions / 5: |
Phase Recognition / 5.1: |
Vaporization and Vapor Pressure / 5.2: |
Classification of Transitions in Single-Component Systems / 5.3: |
Ideal Solutions: Raoult's and Henry's Laws / 5.4: |
Partial Molar Quantities / 5.5: |
The Chemical Potential / 5.6: |
Thermodynamics of Solutions / 5.7: |
The Colligative Properties / 5.8: |
Phase Equilibria / 6: |
Equilibrium Between Phases / 6.1: |
One-Component Systems / 6.2: |
Binary Systems Involving Vapor / 6.3: |
Condensed Binary Systems / 6.4: |
Thermal Analysis / 6.5: |
More Complicated Binary Systems / 6.6: |
Crystal Solubility: The Krafft Boundary and Krafft Eutectic / 6.7: |
Ternary Systems / 6.8: |
Solutions of Electrolytes / 7: |
Faraday's Laws of Electrolysis Biography: Michael Faraday / 7.1: |
Molar Conductivity / 7.2: |
Weak Electrolytes: The Arrhenius Theory Biography: Svante August Arrhenius / 7.3: |
Strong Electrolytes / 7.4: |
Independent Migration of Ions / 7.5: |
Transport Numbers / 7.6: |
Ion Conductivities / 7.7: |
Thermodynamics of Ions / 7.8: |
Theories of Ions in Solution / 7.9: |
Activity Coefficients / 7.10: |
Ionic Equilibria / 7.11: |
Ionization of Water / 7.12: |
The Donnan Equilibrium / 7.13: |
Electrochemical Cells / 8: |
The Daniell Cell / 8.1: |
Standard Electrode Potentials / 8.2: |
Thermodynamics of Electrochemical Cells / 8.3: |
Types of Electrochemical Cells / 8.4: |
Applications of emf Measurements / 8.5: |
Fuel Cells / 8.6: |
Photogalvanic Cells / 8.7: |
Batteries, Old and New / 8.8: |
Chemical Kinetics I. The Basic Ideas / 9: |
Rates of Consumption and Formation / 9.1: |
Rate of Reaction / 9.2: |
Empirical Rate Equations / 9.3: |
Analysis of Kinetic Results / 9.4: |
Techniques for Very Fast Reactions / 9.5: |
Molecular Kinetics / 9.6: |
The Arrhenius Equation / 9.7: |
Potential-Energy Surfaces / 9.8: |
The Preexponential Factor Biography: Henry Eyring / 9.9: |
Reactions in Solution / 9.10: |
Reaction Dynamics / 9.11: |
Chemical Kinetics II. Composite Mechanisms / 10: |
Evidence for a Composite Mechanism / 10.1: |
Types of Composite Reactions / 10.2: |
Rate Equations for Composite Mechanisms / 10.3: |
Rate Constants, Rate Coefficients, and Equilibrium Constants / 10.4: |
Free-Radical Reactions / 10.5: |
Photochemical Reactions / 10.6: |
Radiation-Chemical Reactions / 10.7: |
Explosions / 10.8: |
Catalysis / 10.9: |
Reactions in Solution: Some Special Features / 10.10: |
Mechanisms of Polymerization in Macromolecules / 10.11: |
Kinetics of Polymerization / 10.12: |
Induction Periods, Oscillations, and Chaos / 10.13: |
Electrochemical Dynamics / 10.14: |
Quantum Mechanics and Atomic Structure / 11: |
Electromagnetic Radiation and the Old Quantum Theory / 11.1: |
Bohr's Atomic Theory / 11.2: |
The Foundations of Quantum Mechanics / 11.3: |
Schr?dinger's Wave Mechanics / 11.4: |
Quantum-Mechanical Postulates / 11.5: |
Quantum Mechanics of Some Simple Systems / 11.6: |
Quantum Mechanics of Hydrogenlike Atoms / 11.7: |
Physical Significance of the Orbital Quantum Numbers / 11.8: |
Angular Momentum and Magnetic Moment / 11.9: |
The Rigid Linear Rotor / 11.10: |
Spin Quantum Numbers / 11.11: |
Many-Electron Atoms / 11.12: |
Approximate Methods in Quantum Mechanics / 11.13: |
The Chemical Bond Biography: Gilbert Newton Lewis / 12: |
The Hydrogen Molecular-Ion, H2+ / 12.1: |
The Hydrogen Molecule / 12.2: |
H?ckel Theory for More Complex Molecules / 12.3: |
Valence-Bond Theory for More Complex Molecules / 12.4: |
Symmetry in Chemistry / 12.5: |
Symmetry of Molecular Orbitals Appendix: Character Tables / 12.6: |
Foundations of Chemical Spectroscopy / 13: |
Emission and Absorption Spectra / 13.1: |
Atomic Spectra Biography: Gerhard Herzberg / 13.2: |
Pure Rotational Spectra of Molecules / 13.3: |
Vibrational-Rotational Spectra of Molecules / 13.4: |
Raman Spectra / 13.5: |
Electronic Spectra of Molecules Appendix: Symmetry Species Corresponding to Infrared and Raman Spectra / 13.6: |
Some Modern Applications of Spectroscopy / 14: |
Laser Spectroscopy / 14.1: |
Spectral Line Widths / 14.2: |
Types of Lasers / 14.3: |
Laser Techniques for Chemistry / 14.4: |
Magnetic Spectroscopy / 14.5: |
Nuclear Magnetic Spectroscopy / 14.6: |
Electron Magnetic Resonance (EMR) / 14.7: |
M?ssbauer Spectroscopy / 14.8: |
Photoelectron Spectroscopy / 14.9: |
Photoacoustic Spectroscopy / 14.10: |
Chiroptical Methods / 14.11: |
Mass Spectrometry / 14.12: |
Statistical Mechanics / 15: |
Forms of Molecular Energy Biography: Ludwig Boltzmann / 15.1: |
Principles of Statistical Mechanics / 15.2: |
The Partition Function / 15.3: |
Thermodynamic Quantities from Partition Functions / 15.4: |
The Partition Function for Some Special Cases / 15.5: |
The Internal Energy, Enthalpy, and Gibbs Energy Functions / 15.6: |
The Calculation of Equilibrium Constants / 15.7: |
Transition-State Theory / 15.8: |
The Approach to Equilibrium / 15.9: |
The Canonical Ensemble / 15.10: |
The Solid State / 16: |
Crystal Forms and Crystal Lattices / 16.1: |
X-Ray Crystallography / 16.2: |
Experimental Methods Biography: Dorothy Crowfoot Hodgkin / 16.3: |
Theories of Solids / 16.4: |
Statistical Thermodynamics of Crystals: Theories of Heat Capacities / 16.5: |
Electrical Conductivity in Solids / 16.6: |
Optical Properties of Solids / 16.7: |
The Liquid State / 17: |
Liquids Compared with Dense Gases / 17.1: |
Liquids Compared with Solids / 17.2: |
Intermolecular Forces / 17.3: |
Theories and Models of Liquids / 17.4: |
Water, the Incomparable Liquid / 17.5: |
The Hydrophobic Effect / 17.6: |
Surface Chemistry and Colloids / 18: |
Adsorption / 18.1: |
Adsorption Isotherms / 18.2: |
Thermodynamics and Statistical Mechanics of Adsorption / 18.3: |
Chemical Reactions on Surfaces / 18.4: |
Surface Heterogeneity / 18.5: |
The Structure of Solid Surfaces and of Adsorbed Layers / 18.6: |
Surface Tension and Capillarity / 18.7: |
Liquid Films on Surfaces Biography: Agnes Pockels / 18.8: |
Colloidal Systems / 18.9: |
Transport Properties / 19: |
Viscosity / 19.1: |
Diffusion / 19.2: |
Sedimentation / 19.3: |
Units, Quantities, and Symbols: The SI/IUPAC Recommendations / Appendix A: |
Physical Constants / Appendix B: |
Some Mathematical Relationships / Appendix C: |
Standard Enthalpies, Entropies, and Gibbs Energies of Formation / Appendix D: |
Character Tables for Some Important Symmetry Groups in Chemistry Answers to Problems / Appendix E: |
Index |
Note: Each chaper concludes with Key Equations, Problems, and Suggested Reading |
The Nature of Physical Chemistry and the Kinetic Theory of Gases / 1: |
The Nature of Physical Chemistry / 1.1: |
Some Concepts from Classical Mechanics / 1.2: |
Systems, States, and Equilibrium / 1.3: |
Thermal Equilibrium / 1.4: |