| Preface |
| About the Editor |
| List of Contributors |
| Phthalocyanines: Synthesis, Supramolecular Organization, and Physical Properties / Gema de la Torre ; Monica Nicolau ; Tomas TorresChapter 1： |
| Introduction / 1.： |
| Synthesis of Phthalocyanines and Structurally Related Compounds / 2.： |
| Synthesis of Phthalocyanines / 2.1.： |
| Phthalocyanine-Related Compounds / 2.2.： |
| Organization of Phthalocyanines in Condensed Phases / 3.： |
| Liquid Crystals / 3.1.： |
| Thin Films Processing / 3.2.： |
| Conducting Properties of Metallophthalocyanines / 4.： |
| Intrinsic Molecular Semiconductors / 4.1.： |
| Organized Phthalocyanines / 4.2.： |
| Nonlinear Optical Properties of Phthalocyanines and Related Compounds / 5.： |
| Second-Order Nonlinear Optics of Phthalocyanines and Related Compounds / 5.1.： |
| Third-Order NLO Properties of Phthalocyanines and Related Compounds / 5.2.： |
| Acknowledgments |
| References |
| Sandwich-Type Phthalocyaninato and Porphyrinato Metal Complexes / Jianzhuang Jiang ; Kuninobu Kasuga ; Dennis P. ArnoldChapter 2： |
| Synthetic Methods |
| Homoleptic Sandwich-Type Phthalocyaninato Metal Complexes |
| Heteroleptic Sandwich-Type Phthalocyaninato Metal Complexes |
| Homoleptic Sandwich-Type Porphyrinato Metal Complexes / 2.3.： |
| Heteroleptic Sandwich-Type Porphyrinato Metal Complexes / 2.4.： |
| Mixed Sandwich-Type Porphyrinato and Phthalocyaninato Metal Complexes / 2.5.： |
| Structures |
| Homoleptic Phthalocyaninato Double-Deckers |
| Homoleptic Porphyrinato Double-Deckers |
| Heteroleptic Porphyrinato and/or Phthalocyaninato Double-Deckers / 3.3.： |
| Homoleptic Porphyrinato Metal Triple-Deckers, and Mixed Porphyrinato and Phthalocyaninato Metal Triple-Deckers / 3.4.： |
| Spectroscopic Characterization |
| [superscript 1]H NMR Spectra |
| Mass Spectra |
| Electronic Absorption (UV-vis and near IR) Spectra / 4.3.： |
| Infrared Spectra / 4.4.： |
| Resonance Raman Spectra / 4.5.： |
| Electron Spin Resonance Spectra / 4.6.： |
| Physical Properties |
| Electrochemical and Spectroelectrochemical Properties |
| Potential Applications / 6.： |
| Electrochromic Materials / 6.1.： |
| Molecular Semiconductors / 6.2.： |
| Liquid Crystal Molecular Semiconductors / 6.3.： |
| Molecular Electronics and Iono-electronics / 6.4.： |
| Gas-sensors / 6.5.： |
| Second and Third-order Nonlinear Optical Materials / 6.6.： |
| Molecular Magnetics / 6.7.： |
| Summary / 7.： |
| Electronic Properties of Molecular Organic Semiconductor Thin Films / Derck SchlettweinChapter 3： |
| Molecular Properties in View of Thin Film Devices |
| Groups of Materials / 1.1.： |
| Electrical Characteristics / 1.3.： |
| Linear Optical Characteristics / 1.4.： |
| Model Compounds / 1.5.： |
| Thin Film Preparation |
| Physical Vapor Deposition |
| From Solution |
| Thin Film Characterization |
| Transmission Electron Microscopy (TEM) |
| X-Ray Diffraction (XRD) |
| Low Energy Electron Diffraction (LEED) |
| Reflection High Energy Electron Diffraction (RHEED) |
| Scanning Tunneling Microscopy (STM) / 3.5.： |
| Atomic Force Microscopy (AFM) / 3.6.： |
| X-Ray Absorption Fine Structure (NEXAFS, XANES) / 3.7.： |
| Vibrational Spectroscopy (IR, Raman, HREELS) / 3.8.： |
| Frontier Energy Levels in Molecular Semiconductors |
| Electrochemical Experiments |
| Ultraviolet Photoelectron Spectroscopy (UPS) |
| Influence of Molecular Structure on Thin Film Growth |
| Electrical Conductivity Changes Related to Growth Modes |
| OMBE-Film Structure and Molecular Interaction Within Films |
| Intermolecular Coupling in Polycrystalline Films / 5.3.： |
| Photoelectrochemical Reactions |
| Origin of Photocurrents and Conduction Type of Materials |
| Reactant Adsorption and Surface States |
| Electrical Conductivity and Thermoelectric Power |
| Charge Carrier Generation / 7.1.： |
| Mechanism of Conduction / 7.2.： |
| Solid State Contact Behavior / 8.： |
| Organic Photovoltaic Cells and Organic Light-Emitting Diodes / 8.1.： |
| UPS Studies / 8.2.： |
| Redox Interactions of Thin Films with the Gas Phase / 9.： |
| Substituted Phthalocyanines / 9.1.： |
| Perylene Pigments / 9.2.： |
| Conclusions and Outlook / 10.： |
| Polydiacetylenes / Han Zuilhof ; Helma M. Barentsen ; Marinus van Dijk ; Ernst J. R. Sudholter ; Romano J. O. M. Hoofman ; Laurens D. A. Siebbeles ; Matthijs P. de Haas ; John M. WarmanChapter 4： |
| Formation of Polydiacetylenes |
| Crystals and Liquid Crystals |
| Gels |
| Films |
| Electronic Structure |
| Linear Optical Properties |
| Color of Polydiacetylenes |
| Electronically Excited States |
| Chromism in Polydiacetylenes |
| Applications of the Chromism in Polydiacetylenes |
| Nonlinear Optical Properties |
| Conductive Properties |
| Background |
| Chemical Doping |
| Charge Injection |
| Photoconductivity |
| Radiation-Induced Conductivity |
| Charge Carrier Mobility |
| Anisotropy |
| Structural and Optical Properties of Conjugated Molecules in Perhydrotriphenylene (PHTP) and in Other Channel-Forming Inclusion Compounds / Chiara Botta ; Dino R. Ferro ; Giuseppe Di Silvestro ; Riccardo TubinoChapter 5： |
| The Inclusion Process of Conjugated Molecules in PHTP Channels |
| Structure of PHTP Inclusion Compounds |
| Thermodynamical Behavior of Inclusion Compounds |
| Phase Diagrams of Selected Guests in PHTP |
| The Coinclusion Phenomenon in PHTP Inclusion Compounds |
| Molecular Modeling of Guest-Host Interactions in PHTP Inclusion Compounds |
| Methods of Molecular Mechanics for PHTP Inclusion Compounds |
| An Application: The Case of the T5-PHTP Complex |
| Design of Macroscopically Polarized NLO in PHTP Inclusion Compounds |
| Absorption and Emission of Conjugated Molecules Included in PHTP |
| Molecular Excitons |
| Weak Excited State Coupling: The Case of Anthracene and Terphenyl |
| Strong Excited State Coupling: The Case of Oligothiophenes |
| Photophysics of Oligothiophene Inclusion Compounds / 5.4.： |
| Other Channel Forming Inclusion Compounds |
| Urea and Thiourea Inclusion Complexes of Conjugated Molecules |
| Zeolites as Host Frameworks for Conjugated Molecules |
| Silica Nanopores |
| Charge Transfer Properties of Photosynthetic and Respiratory Proteins / G. Matthias UllmannChapter 6： |
| Biochemical Terminology |
| Protein-Mediated Charge Transfer |
| Protein-Mediated Electron Transfer |
| Marcus Theory |
| Pathways Model of Electron Transfer in Proteins |
| Protein-Mediated Proton Transfer |
| Protonation and Oxidation Probabilities in Proteins |
| Plastocyanin-Cytochrome c Complex |
| Photosynthesis |
| Chloroplast Structure |
| The Light Reactions |
| The Dark Reactions |
| The Reaction of Cytochrome f with Plastocyanin and Cytochrome c[subscript 6] |
| pH-Dependent Coordination of the Copper in Plastocyanin |
| Cellular Respiration |
| The Structure of Mitochondria |
| Reactions of the Respiration Chain |
| Cytochrome bc[subscript 1]-A Molecular Switch |
| ATP synthase-A Molecular Motor |
| Summary and Outlook / 11.： |
| Optical and Electronic Properties of Carbon Nitride / David CameronChapter 7： |
| Historical Development of Carbon Nitride |
| Production Methods for Carbon Nitride |
| Chemical Vapor Deposition Methods |
| Physical Vapor Deposition Methods |
| High Pressure Methods |
| Electrolytic Methods |
| Structural Properties of Carbon Nitride |
| Crystallography |
| Vibrational Spectroscopy |
| Electronic Spectroscopy |
| Observed Bonding Structures in Carbon Nitride |
| Electronic and Optical Properties |
| Internal Electronic and Optical Properties |
| "External" Electronic and Optical Properties |
| Conclusions |
| Polyimides for Microelectronics and Tribology Applications / M. Fahim ; J. Bijwe ; Hari Singh NalwaChapter 8： |
| Chemistry and Synthesis |
| General Properties |
| Applications |
| Polyimides for Microelectronics Packaging |
| Material Requirements |
| Earlier Developments |
| Recent Developments |
| Polyimides for Tribology |
| Developments in Polyimide Tribology |
| Developments in Polyetherimide Tribology |
| Anomalous Charge Transport and Polarization in Semiconductors Oxides and Porous Film Electrodes / G. Garcia-Belmonte ; J. BisquertChapter 9： |
| Relaxation Phenomena of Barriers and Trapping States in Semiconductor Contacts |
| Frequency Dependence of the Barrier Complex Capacitance |
| Relaxation Models |
| Electronic Ceramics |
| Anomalous Transport and Low-Frequency Dispersion Phenomenology |
| Low-Frequency Dispersion Phenomena |
| Anomalous Transport in Amorphous Semiconductors |
| TiO[subscript 2] Electrical Properties as a Function of Temperature |
| Electrical Characterization of Porous Film Electrodes |
| Impedance of Porous Film Electrodes |
| Anomalous Transport Effects on Film Electrodes |
| Conducting Polymer Electrodes |
| Electroactive and Photoactive Dendrimers / Chelladurai DevadossChapter 10： |
| Design of Dendrimers |
| Synthesis of Dendrimers |
| Divergent Growth Method |
| Convergent Growth Method |
| Characterization of Denrimers |
| Electroactive Dendrimers |
| Electrochemical Study |
| Fabrication of Organic Light Emitting Diodes |
| Conducting Dendrimers |
| Photoactive Dendrimers |
| Photoinduced Electron Transfer |
| Excitation Energy Transfer |
| Photoisomerization |
| Dendrimer as Photoresist |
| Summary and Future Outlook |
| Electrical Properties of Organic Monolayer Films / Mitsumasa IwamotoChapter 11： |
| Maxwell Displacement Current (MDC) and its Application |
| Monolayers as Dielectric Materials |
| MDC Measurement |
| Tunneling Current and Electronic Device Application |
| Nanometric Interfacial Electrostates Phenomena in Ultrathin Films |
| Electrically Insulating Ultrathin Films |
| Semiconductor Films |
| I-V Characteristic |
| Index |
図書
