The chemistry of nanomaterials : synthesis, properties and applications in 2 volumes

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The chemistry of nanomaterials : synthesis, properties and applications in 2 volumes / C. N. R. Rao, A. Müller, A. K. Cheetham (eds.)

資料種別:

図書

出版情報:

Weinheim : Wiley-VCH, c2004

形態:

2v. (xx, 741 p.) ; 25 cm

著者名:

ISBN:

9783527306862 [3527306862] (: set)

書誌ID:

BA66453611

子書誌情報

フルテキスト

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書誌詳細

注記:

Includes bibliographical references and index

主題:

Nanostructures; Solid state chemistry

言語:

英語

目次情報:

Preface

List of Contributors

Nanomaterials:

An Introduction. / Volume 1：

Strategies for the Scalable Synthesis of Quantum Dots and Related Nanodimensional Materials. / 1：

Moving Nanoparticles Around: Phase-Transfer Processes in Nanomaterials Synthesis. / C. N. R. Rao

Mesoscopic Assembly and Other Properties of Metal and Semiconductor Nanocrystals.

Oxide Nanoparticles.Sonochemistry and Other Novel Methods Developed for the Synthesis of Nanoparticles. / A. Muller

Solvothermal Synthesis of Non-Oxide Nanomaterials.

Nanotubes and Nanowires.Synthesis, Assembly and Reactivity of Metallic Nanorods. / A. K. Cheetham

Oxide-Assisted Growth of Silicon and Related Nanowires Growth Mechanism, Structure and Properties.

Electronic Structure and Spectroscopy of Semiconductor Nanocrystals.

Nanomaterials--An Introduction

Core-shell Semiconductor Nanocrystals for Biological Labeling.

Large Semiconductor Molecules. / 1.1：

Oxomolybdates:

Size Effects

From Structures to Functions in a New Era of Nanochemistry.

Nanostructural Polymers / 1.2：

Recent Developments in the Chemistry and Chemical Applications of Porous Silicon.

Synthesis and Assembly

Nanocatalysis.

Nanoporous Materials.Photochemistry and Electrochemistry of Nanoassemblies. / 1.3：

Electrochemistry with Nanoparticles

Techniques

Nanolithography and Nanomanipulation.

Applications and Technology Development / 1.4：

Nanoelectronics / 1.5：

Other Aspects / 1.6：

Concluding Remarks / 1.7：

Bibliography

Strategies for the Scalable Synthesis of Quantum Dots and Related Nanodimensional Materials / P. O'Brien ; N. Pickett2：

Introduction / 2.1：

Defining Nanodimensional Materials / 2.2：

Potential Uses for Nanodimensional Materials / 2.3：

The General Methods Available for the Synthesis of Nanodimensional Materials / 2.4：

Precipitative Methods / 2.4.1：

Reactive Methods in High Boiling Point Solvents / 2.4.2：

Hydrothermal and Solvothermal Methods / 2.4.3：

Gas-Phase Synthesis of Semiconductor Nanoparticles / 2.4.4：

Synthesis in a Structured Medium / 2.4.5：

The Suitability of Such Methods for Scaling / 2.5：

Conclusions and Perspectives on the Future / 2.6：

Acknowledgements

References

Moving Nanoparticles Around: Phase-Transfer Processes in Nanomaterials Synthesis / M. Sastry3：

Water-Based Gold Nanoparticle Synthesis / 3.1：

Advantages / 3.2.1：

Disadvantages / 3.2.2：

Organic Solution-Based Synthesis of Gold Nanoparticles / 3.3：

Moving Gold Nanoparticles Around / 3.3.1：

Phase Transfer of Aqueous Gold Nanoparticles to Non-Polar Organic Solvents / 3.4.1：

Transfer of Organically Soluble Gold Nanoparticles to Water / 3.4.2：

Acknowledgments

Mesoscopic Assembly and Other Properties of Metal and Semiconductor Nanocrystals / G. U. Kulkarni ; P. J. Thomas4：

Abstract

Synthetic Strategies / 4.1：

General Methods / 4.2.1：

Size Control / 4.2.2：

Shape Control / 4.2.3：

Tailoring the Ligand Shell / 4.2.4：

Programmed Assemblies / 4.3：

One-Dimensional Arrangements / 4.3.1：

Two-Dimensional Arrays / 4.3.2：

Three-Dimensional Superlattices / 4.3.3：

Superclusters / 4.3.4：

Colloidal Crystals / 4.3.5：

Nanocrystal Patterning / 4.3.6：

Emerging Applications / 4.4：

Isolated Nanocrystals / 4.4.1：

Collective Properties / 4.4.2：

Nanocomputing / 4.4.3：

Conclusions / 4.5：

Oxide Nanoparticles / R. Seshadri5：

Magnetite Particles in Nature / 5.1：

Routes for the Preparation of Isolated Oxide Nanoparticles / 5.3：

Hydrolysis / 5.3.1：

Oxidation / 5.3.2：

Thermolysis / 5.3.3：

Metathesis / 5.3.4：

Solvothermal Methods / 5.3.5：

Prospects / 5.4：

Sonochemistry and Other Novel Methods Developed for the Synthesis of Nanoparticles / Y. Mastai ; A. Gedanken6：

Sonochemistry / 6.1：

Sonochemical Fabrication of Nanometals / 6.1.1：

Sonochemical Fabrication of Nano-Metallic Oxides / 6.1.2：

Sonoelectrochemistry / 6.2：

Sonoelectrochemical Synthesis of Nanocrystalline Materials / 6.2.1：

Microwave Heating / 6.3：

Microwave Synthesis of Nanomaterials / 6.3.1：

Solvothermal Synthesis of Non-Oxide Nanomaterials / Y. T. Qian ; Y. L. Gu ; J. Lu7：

Solvothermal Synthesis of III-V Nanomaterials / 7.1：

Synthesis of Diamond, Carbon Nanotubes and Carbides / 7.3：

Synthesis of Si[subscript 3]N[subscript 4], P[subscript 3]N[subscript 5], Metal Nitrides and Phosphides / 7.4：

Synthesis of BN, B[subscript 4]C, BP and Borides / 7.5：

Synthesis of One-Dimensional Metal Chalcogenide Nanocrystallites / 7.6：

Room Temperature Synthesis of Nanomaterials / 7.7：

Nanotubes and Nanowires / A. Govindaraj8：

Carbon Nanotubes / 8.1：

Synthesis / 8.2.1：

Structure and Characterization / 8.2.2：

Mechanism of Formation / 8.2.3：

Chemically Modified Carbon Nanotubes / 8.2.4：

Electronic Structure, Properties and Devices / 8.2.5：

Inorganic Nanotubes / 8.3：

Preliminaries / 8.3.1：

General Synthetic Strategies / 8.3.2：

Structures / 8.3.3：

Useful Properties of Inorganic Nanotubes / 8.3.4：

Nanowires / 8.4：

Properties of Nanowires / 8.4.1：

Synthesis, Assembly and Reactivity of Metallic Nanorods / C. J. Murphy ; N. R. Jana ; L. A. Gearheart ; S. O. Obare ; K. K. Caswell ; S. Mann ; C. J. Johnson ; S. A. Davis ; E. Dujardin ; K. J. Edler9：

Seed-Mediated Growth Approach to the Synthesis of Inorganic Nanorods and Nanowires / 9.1：

Assembly of Metallic Nanorods: Self-Assembly vs. Designed Chemical Linkages / 9.3：

Reactivity of Metallic Nanoparticles Depends on Aspect Ratio / 9.4：

Conclusions and Future Prospects / 9.5：

Oxide-Assisted Growth of Silicon and Related Nanowires: Growth Mechanism, Structure and Properties / S. T. Lee ; R. Q. Zhang ; Y. Lifshitz10：

Oxide-Assisted Nanowire Growth / 10.1：

Discovery of Oxide-Assisted Growth / 10.2.1：

Oxide-Assisted Nucleation Mechanism / 10.2.2：

Oxide-Assisted Growth Mechanism / 10.2.3：

Comparison between Metal Catalyst VLS Growth and OAG / 10.2.4：

Control of SiNW Nanostructures in OAG / 10.3：

Morphology Control by Substrate Temperature / 10.3.1：

Diameter Control of Nanowires / 10.3.2：

Large-Area Aligned and Long SiNWs via Flow Control / 10.3.3：

Si Nanoribbons / 10.3.4：

Nanowires of Si Compounds by Multistep Oxide-Assisted Synthesis / 10.4：

Nanocables / 10.4.1：

Metal Silicide/SiNWs from Metal Vapor Vacuum Arc Implantation / 10.4.2：

Synthesis of Oriented SiC Nanowires / 10.4.3：

Implementation of OAG to Different Semiconducting Materials / 10.5：

Chemical Properties of SiNWs / 10.6：

Stability of H-Terminated SiNW Surfaces / 10.6.1：

Reduction of Metals in Liquid Solutions / 10.6.2：

Chemical Sensing of SiNWs / 10.6.3：

Use of SiNWs as Templates for Nanomaterial Growth / 10.6.4：

Optical and Electrical Properties of SiNWs / 10.7：

Raman and PL of SiNWs / 10.7.1：

Field Emission from Different Si-Based Nanostructures / 10.7.2：

STM and STS Measurements of SiNWs and B-Doped SiNWs / 10.7.3：

Periodic Array of SiNW Heterojunctions / 10.7.4：

Modeling / 10.8：

High Reactivity of Silicon Suboxide Vapor / 10.8.1：

Thermal and Chemical Stabilities of Pure Silicon Nanostructured Materials / 10.8.2：

Thermal and Chemical Stabilities of Hydrogenated Silicon Nanostructures / 10.8.3：

Summary / 10.9：

Acknowledgment

Electronic Structure and Spectroscopy of Semiconductor Nanocrystals / S. Sapra ; D. D. SarmaVolume 2：

Structural Transformations / 11.1：

Ultraviolet-Visible Absorption Spectroscopy / 11.3：

Fluorescence Spectroscopy / 11.4：

Electronic Structure Calculations / 11.5：

Effective Mass Approximation / 11.5.1：

Empirical Pseudopotential Method / 11.5.2：

Tight-Binding Method / 11.5.3：

Photoemission Studies / 11.6：

Core Level Photoemission / 11.6.1：

Valence Band Photoemission / 11.6.2：

Core-Shell Semiconductor Nanocrystals for Biological Labeling / R. E. Bailey ; S. Nie11.7：

Optical Properties / 12.1：

Surface Modification and Bioconjugation / 12.3：

Applications / 12.5：

Large Semiconductor Molecules / J. F. Corrigan ; M. W. DeGroot13：

Nickel Chalcogenides / 13.1：

Group XI Chalcogenides / 13.3：

Copper Sulfide and Copper Selenide Nanoclusters / 13.3.1：

Cu[subscript 2-x]Te and Ag[subscript 2]Te / 13.3.2：

Ag[subscript 2]S / 13.3.3：

Ag[subscript 2]Se / 13.3.4：

Group XII-chalogenides and the Quantum Confinement Effect / 13.4：

CdS / 13.4.1：

Ternary MM'E / 13.5：

Metal Pnictides from E(SiMe[subscript 3])[subscript 3] Reagents / 13.6：

Conclusions and Outlook / 13.7：

Oxomolybdates: From Structures to Functions in a New Era of Nanochemistry / S. Roy14：

Introduction: Similarities between Nanotechnology in Nature and Chemistry? / 14.1：

Sizes, Shapes, and Complexity of Nano-objects are Determined by the Nature and Variety of the Constituent Building Blocks / 14.2：

Nanoscaled Clusters with Unusual Form-Function Relationships / 14.3：

Perspectives for Materials Science and Nanotechnology: En Route to Spherical-Surface, Nanoporous-Cluster, and Super-Supramolecular Chemistry Including the Option of Modelling Cell Response / 14.4：

Nanostructured Polymers / S. Ramakrishnan15：

Macromolecular Structural Control / 15.1：

Living Polymerization / 15.2.1：

Polymer Conformational Control / 15.3：

Morphology of Block Copolymers / 15.4：

Nanostructures Based on Bulk Phase Separation / 15.5：

Nanostructures Based on Lyotropic Mesophases / 15.6：

Core-Crosslinked Systems / 15.6.1：

Shell-Crosslinked Systems / 15.6.2：

Nanocages / 15.6.3：

Rod-Coil Diblock Copolymers / 15.7：

Nanostructures from Polymerized Surfactant Assemblies / 15.8：

Summary and Outlook / 15.9：

Recent Developments in the Chemistry and Chemical Applications of Porous Silicon / J. M. Schmeltzer ; J. M. Buriak16：

Preparation and Characterization of Porous Silicon Substrates / 16.1：

Surface Chemistry of Porous Silicon Surfaces / 16.3：

Chemical Applications Based on Porous Silicon / 16.4：

Bioactive Porous Silicon / 16.4.1：

Micro Enzyme Reactors ([mu]IMERS) and Total Analysis Systems ([mu]TAS) / 16.4.2：

Porous Silicon Sensors / 16.4.3：

Explosive Porous Silicon / 16.4.4：

Desorption/Ionization on Silicon Mass Spectrometry (DIOS-MS) / 16.4.5：

Conclusion / 16.5：

Nanocatalysis / S. Abbet ; U. Heiz17：

Chemical Reactions on Point Defects of Oxide Surfaces / 17.1：

Chemical Reactions and Catalytic Processes on Free and Supported Clusters / 17.3：

Catalytic Processes on Free Metal Clusters / 17.3.1：

Chemical Reactions and Catalytic Cycles on Supported Clusters / 17.3.2：

Turn-Over Frequencies of Catalytic Reactions on Supported Clusters / 17.3.3：

Chemical Reactions Induced by Confined Electrons / 17.4：

Nanoporous Materials / P. M. Forster17.5：

Stability of Open-Framework Materials / 18.1：

Aluminosilicate Zeolites / 18.3：

Open-Framework Metal Phosphates / 18.4：

Aluminum Phosphates / 18.4.1：

Phosphates of Gallium and Indium / 18.4.2：

Tin(II) Phosphates and Antimony(III) Phosphates / 18.4.3：

Transition Metal Phosphates / 18.4.4：

Chalcogenides, Halides, Nitrides and Oxides / 18.5：

Sulfides and Selenides / 18.5.1：

Halides / 18.5.2：

Nitrides / 18.5.3：

Binary Metal Oxides / 18.5.4：

Sulfates / 18.5.5：

Hybrid Nanoporous Materials / 18.6：

Coordination Polymers / 18.6.1：

Hybrid Metal Oxides / 18.6.2：

Photochemistry and Electrochemistry of Nanoassemblies / P. V. Kamat18.7：

Metal and Semiconductor Nanostructures / 19.1：

Photoinduced Charge Transfer Processes in Semiconductor Nanoparticle Systems / 19.2：

Photoinduced Transformations of Metal Nanoparticles / 19.3：

Transient Bleaching of the Surface Plasmon Band / 19.3.1：

Laser Induced Fusion and Fragmentation of Metal Nanoclusters / 19.3.2：

Photoinduced Energy and Electron Transfer Process between Excited Sensitizer and Metal Nanocore / 19.3.3：

Electrochemistry of Semiconductor Nanostructures / 19.4：

Nanostructured Metal Oxide Films / 19.4.1：

Nanostructured Oxide Films Modified with Dyes and Redox Chromophores / 19.4.2：

Photocurrent Generation / 19.4.3：

Electrochemistry of Metal Nanostructures / 19.5：

Semiconductor-Metal Nanocomposites / 19.6：

Improving the Efficiency of Photocatalytic Transformations / 19.6.1：

Fermi Level Equilibration / 19.6.2：

Acknowledgement / 19.7：

Outline / S. Devarajan ; S. Sampath20：

Preparation of Nanostructures / 20.1：

Electrochemistry with Metallic Nanoparticles / 20.3：

Monolayer-Protected Nanoclusters / 20.3.1：

Nanoelectrode Ensembles / 20.3.2：

Single Electron Events / 20.4：

Probing Nanoparticles using Electrochemistry Coupled with Spectroscopy / 20.5：

Nanosensors / 20.6：

Biosensors / 20.6.1：

Chemical Sensors / 20.6.2：

Electrocatalysis / 20.7：

Summary and Perspectives / 20.8：

Nanolithography and Nanomanipulation / A. K. Raychaudhuri21：

Template Fabrication / 21.1：

Polycarbonate Etched Track Templates / 21.2.1：

Fabrication of Anodized Alumina Membrane / 21.2.2：

Anodized Alumina Membrane as a Mask for Physical Vapor Deposition / 21.2.3：

Templates Made in Block Copolymers / 21.2.4：

Fabrication of Nanostructures in the Templates / 21.3：

Electrodeposition / 21.3.1：

Sol-Gel Method / 21.3.2：

CVD Method / 21.3.3：

Scanning Probe Based Anodic Oxidation as a Tool for the Fabrication of Nanostructures / 21.4：

Oxidation of Metallic Substrates / 21.4.1：

Oxidation of Semiconducting Substrates / 21.4.2：

Use of Scanning Probe Microscopy in Dip Pen Nanolithography / 21.5：

Use of Scanning Probe Microscopy in Nanomanipulation / 21.6：

Nano-Electromechanical Systems / 21.7：

Index

Preface

List of Contributors

Nanomaterials:

An Introduction. / Volume 1：

Strategies for the Scalable Synthesis of Quantum Dots and Related Nanodimensional Materials. / 1：

Moving Nanoparticles Around: Phase-Transfer Processes in Nanomaterials Synthesis. / C. N. R. Rao

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