| Introduction / 1： |
| Nonkinetic Method for the Elucidation of Reaction Mechanisms / 2： |
| Stoichiometry and reaction mechanisms |
| Structure of products |
| Structure of intermediates |
| Stereochemical experiments |
| Isotopic labeling experiments |
| Crossover experiments |
| Energetics of Chemical Reactions / 3： |
| Nomenclature of thermodynamic potential functions |
| Thermodynamic requirements for chemical reactions |
| Kinetic requirements for chemical reactions |
| The principle of microscopic reversibility |
| Kinetic and thermodynamic control |
| Kinetics of Elementary Reactions / 4： |
| Basic principles of reaction kinetics |
| The integrated rate equation |
| Pseudo-orders of simplified rate equations |
| Numerical determination of reaction order and rate constants from experimental data |
| Kinetics of Complex Reactions / 5： |
| Reversible reactions |
| Parallel reactions |
| Consecutive reactions |
| Approximate methods for analyzing complex reactions |
| Conclusions |
| Examples |
| Theories of Chemical Reactions / 6： |
| Temperature dependence of chemical equilibria |
| Temperature dependence of reaction rates |
| Collision theory |
| Transition-state theory |
| Structure of activated complexes |
| Entropy of activation |
| Enthalpy of activation |
| The isokinetic relationship |
| Volume of activation |
| Structure and Reactivity Relationships / 7： |
| The Hammett equation |
| The linear free-enthalpy relationship |
| The application of Hammett equation to multistep reactions |
| The sgr; +, sgr; -, and sgr; 0 substituent constants; the Yukawa-Tsuno equation |
| Separation of inductive and resonance effects |
| Separation of electronic and steric effects |
| Isotope Effects / 8： |
| Isotope effects on equilibria |
| Theory of kinetic isotope effect |
| Primary kinetic isotope effect |
| Secondary kinetic isotope effects |
| Solvent isotope effect |
| Environmental Effects / 9： |
| The structure of liquids |
| Solvation |
| Solvent effects in chemical equilibria |
| Solvent effect in chemical kinetics |
| Solvent effect on reaction rates |
| Specific solvation effects on reaction rates |
| Empirical solvent-polarity parameters |
| Salt effects |
| Acids, Bases, Electrophiles and Nucleophiles / 10： |
| Strengths of Broslash;nsted acids and bases |
| Structural effects on Broslash;nsted acidity and basicity |
| Solvent effect on acidity and basicity |
| Acidity of solvents and acidity functions |
| Very weak acids |
| Superacids |
| Lewis acids and Lewis bases |
| Nucleophiles and electrophiles |
| Homogeneous Catalysis / 11： |
| Acid-base catalysis |
| Rates of proton-transfer reactions |
| Broslash;nsted's law of catalysis |
| Reactions in strongly acidic media |
| Nucleophilic catalysis |
| Electrophilic catalysis |
| Neighboring group participation and intramolecular catalysis |
| Micellar catalysis |
| Enzymic catalysis |
| Introduction / 1： |
| Nonkinetic Method for the Elucidation of Reaction Mechanisms / 2： |
| Stoichiometry and reaction mechanisms |
図書
