Preface |
Elementary Steps / 1: |
Introduction / 1.1: |
Metal Deposition / 1.2: |
Ligand Loss / 1.2.1: |
Reductive Elimination of C-, N-, O-Donor Fragments / 1.2.2: |
Metallic Nanoparticles / 1.2.4: |
Ligand Decomposition by Oxidation / 1.3: |
General / 1.3.1: |
Oxidation / 1.3.2: |
Catalysis Using Hydroperoxides / 1.3.2.1: |
Phosphines / 1.4: |
Oxidation of Phosphines / 1.4.1: |
Oxidative Addition of a P-C Bond to a Low-Valent Metal / 1.4.3: |
Nucleophilic Attack at Phosphorus / 1.4.4: |
Aryl Exchange Via Phosphonium Intermediates / 1.4.5: |
Aryl Exchange Via Metallophosphoranes / 1.4.6: |
Phosphites / 1.5: |
Imines and Pyridines / 1.6: |
Carbenes / 1.7: |
Introduction to NHCs as Ligands / 1.7.1: |
Reductive Elimination of NHCs / 1.7.2: |
Carbene Decomposition in Metathesis Catalysts / 1.7.3: |
Reactions of Metal-Carbon and Metal-Hydride Bonds / 1.8: |
Reactions with Protic Reagents / 1.8.1: |
Reactions of Zirconium and Titanium Alkyl Catalysts / 1.8.2: |
Reactions Blocking the Active Sites / 1.9: |
Polar Impurities / 1.9.1: |
Dimer Formation / 1.9.2: |
Ligand Metallation / 1.9.3: |
References |
Early Transition Metal Catalysts for Olefin Polymerization / 2: |
Ziegler-Natta Catalysts / 2.1: |
Effect of Catalyst Poisons / 2.1.1: |
Ethene Polymerization / 2.1.3: |
Metallocenes / 2.2: |
Metallocene/MAO Systems / 2.2.1: |
Metallocene/Borate Systems / 2.2.3: |
Other Single-Center Catalysts / 2.3: |
Constrained Geometry and Half-Sandwich Complexes / 2.3.1: |
Octahedral Complexes / 2.3.2: |
Diamide and Other Complexes / 2.3.3: |
Vanadium-Based Catalysts / 2.4: |
Chromium-Based Catalysis / 2.5: |
Conclusions / 2.6: |
Late Transition Metal Catalysts for Olefin Polymerization / 3: |
Nickel- and Palladium-based Catalysts / 3.1: |
Diimine Complexes / 3.1.1: |
Neutral Nickel(II) Complexes / 3.1.2: |
Other Nickel(II) and Palladium(II) Complexes / 3.1.3: |
Iron- and Cobalt-based Catalysts / 3.2: |
Bis(imino)Pyridyl Complexes / 3.2.1: |
Effects of Immobilization of Catalysts for Olefin Polymerization / 3.3: |
Metallocenes and Related Complexes / 4.1: |
Immobilized MAO/Metallocene Systems / 4.2.1: |
Immobilized Borane and Borate Activators / 4.2.2: |
Superacidic Supports / 4.2.3: |
Other Titanium and Zirconium Complexes / 4.2.4: |
Constrained Geometry Complexes / 4.3.1: |
Vanadium Complexes / 4.3.2: |
Chromium Complexes / 4.5: |
Nickel Complexes / 4.6: |
Iron Complexes / 4.7: |
Dormant Species in Transition Metal-Catalyzed Olefin Polymerization / 4.8: |
Propene Polymerization / 5.1: |
Metallocenes and Related Early Transition Metal Catalysts / 5.3: |
Cation-Anion Interactions / 5.3.1: |
Effects of 2,1-insertion in Propene Polymerization / 5.3.2: |
Chain Epimerization in Propene Polymerization / 5.3.4: |
Effects of Dormant Site Formation on Polymerization Kinetics / 5.3.6: |
Late Transition Metal Catalysts / 5.4: |
Resting States in Nickel Diimine-Catalyzed Polymerization / 5.4.1: |
Effects of Hydrogen in Bis(iminopyridyl) Iron-Catalyzed Polymerization / 5.4.2: |
Reversible Chain Transfer in Olefin Polymerization / 5.5: |
Transition Metal Catalyzed Olefin Oligomerization / 5.6: |
Zirconium Catalysts / 6.1: |
Titanium Catalysts / 6.3: |
Tantalum Catalysts / 6.4: |
Chromium Catalysts / 6.5: |
Chromium-catalyzed Trimerization / 6.5.1: |
Chromium-catalyzed Tetramerization of Ethene / 6.5.2: |
Chromium-Catalyzed Oligomerization / 6.5.3: |
Single-component Chromium Catalysts / 6.5.4: |
Nickel Catalysts / 6.6: |
Iron Catalysts / 6.7: |
Tandem Catalysis involving Oligomerization and Polymerization / 6.8: |
Asymmetric Hydrogenation / 6.9: |
Incubation by Dienes in Rhodium Diene Precursors / 7.1: |
Inhibition by Substrates, Solvents, Polar Additives, and Impurities / 7.3: |
Inhibition by Substrates: Iridium / 7.3.1: |
Inhibition by Substrates, Additives: Rhodium / 7.3.2: |
Inhibition by Substrates: Ruthenium / 7.3.3: |
Inhibition by Formation of Bridged Species / 7.4: |
Inhibition by Formation of Bridged Species: Iridium / 7.4.1: |
Inhibition by Formation of Bridged Species: Rhodium / 7.4.2: |
Inhibition by Ligand Decomposition / 7.5: |
Inhibition by the Product / 7.6: |
Inhibition by the Product: Rhodium / 7.6.1: |
Ruthenium / 7.6.2: |
Inhibition by Metal Formation; Heterogeneous Catalysis by Metals / 7.7: |
Selective Activation and Deactivation of Enantiomeric Catalysts / 7.8: |
Carbonylation Reactions / 7.9: |
Cobalt-Catalyzed Hydroformylation / 8.1: |
Rhodium-Catalyzed Hydroformylation / 8.3: |
Introduction of Rhodium-Catalyzed Hydroformylation / 8.3.1: |
Catalyst Formation / 8.3.2: |
Incubation by Impurities: Dormant Sites / 8.3.3: |
Decomposition of Phosphines / 8.3.4: |
Decomposition of Phosphites / 8.3.5: |
Decomposition of NHCs / 8.3.6: |
Two-Phase Hydroformylation / 8.3.7: |
Hydroformylation by Nanoparticle Precursors / 8.3.8: |
Palladium-Catalyzed Alkene-CO Reactions / 8.4: |
Brief Mechanistic Overview / 8.4.1: |
Early Reports on Decomposition and Reactivation / 8.4.3: |
Copolymerization / 8.4.4: |
Methoxy- and Hydroxy-carbonylation / 8.4.5: |
Methanol Carbonylation / 8.5: |
Mechanism and Side Reactions of the Monsanto Rhodium-Based Process / 8.5.1: |
The Mechanism of the Acetic Anhydride Process Using Rhodium as a Catalyst / 8.5.3: |
Phosphine-Modified Rhodium Catalysts / 8.5.4: |
Iridium Catalysts / 8.5.5: |
Metal-Catalyzed Cross-Coupling Reactions / 8.6: |
Introduction; A Few Historic Notes / 9.1: |
On the Mechanism of Initiation and Precursors / 9.2: |
Initiation via Oxidative Addition to Pd(0) / 9.2.1: |
Hydrocarbyl Pd Halide Initiators / 9.2.2: |
Metallated Hydrocarbyl Pd Halide Initiators / 9.2.3: |
Transmetallation / 9.3: |
Reductive Elimination / 9.4: |
Monodentate vs Bidentate Phosphines and Reductive Elimination / 9.4.1: |
Reductive Elimination of C-F Bonds / 9.4.2: |
Phosphine Decomposition / 9.5: |
Phosphine Oxidation / 9.5.1: |
P-C Cleavage of Ligands / 9.5.2: |
Metal Impurities / 9.6: |
Metal Nanoparticles and Supported Metal Catalysts / 9.7: |
Supported Metal Catalysts / 9.7.1: |
Metal Nanoparticles as Catalysts / 9.7.2: |
Metal Precipitation / 9.7.3: |
Alkene Metathesis / 9.8: |
Molybdenum and Tungsten Catalysts / 10.1: |
Decomposition Routes of Alkene Metathesis Catalysts / 10.2.1: |
Regeneration of Active Alkylidenes Species / 10.2.2: |
Decomposition Routes of Alkyne Metathesis Catalysts / 10.2.3: |
Rhenium Catalysts / 10.3: |
Catalyst Initiation and Decomposition / 10.3.1: |
Ruthenium Catalysts / 10.4: |
Initiation and Incubation Phenomena / 10.4.1: |
Decomposition of the Alkylidene Fragment / 10.4.3: |
Reactions Involving the NHC Ligand / 10.4.4: |
Reactions Involving Oxygenates / 10.4.5: |
Tandem Metathesis/Hydrogenation Reactions / 10.4.6: |
Index / 10.5: |