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1.

図書
図書
1. Spectroscopic methods in organic chemistry. 7th ed (: pbk)
Ian Fleming, Dudley Williams
出版情報: Cham : Springer, c2019  xi, 432 p. ; 24 cm
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2.

図書
図書
2. Selected organic syntheses : a guidebook for organic chemists (pbk.)
Ian Fleming
出版情報: London ; New York : Wiley, c1973  viii, 227 p ; 24 cm
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3.

図書
図書
3. Pericyclic reactions. 2nd ed (: pbk)
Ian Fleming
出版情報: Oxford : Oxford University Press, c2015  viii, 118 p. ; 25 cm
シリーズ名: Oxford chemistry primers
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4.

図書
図書
4. Frontier orbitals and organic chemical reactions (: cloth ; : pbk)
Ian Fleming
出版情報: London ; New York : Wiley, c1976  249 p. ; 24 cm
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Molecular Orbitals and Frontier Orbitals
Ionic Reactions
Thermal Pericyclic Reactions
Radical Reactions
Photochemical Reactions
Exceptions
Molecular Orbitals and Frontier Orbitals
Ionic Reactions
Thermal Pericyclic Reactions
5.

図書
図書
5. 有機機器分析 : IR・UV・NMR・MS. 第4版
Dudley H. Williams, Ian Fleming [著] ; 高橋武美, 露木孝彦, 廣田洋共訳
出版情報: 東京 : 廣川書店, 1990.11  xiv,302p ; 22cm
シリーズ名: 廣川化学シリーズ ; 22
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6.

図書
図書
6. フロンティア軌道法入門 : 有機化学への応用
I. フレミング著 ; 竹内敬人, 友田修司訳
出版情報: 東京 : 講談社, 1978.9  xi, 288p ; 22cm
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7.

図書
図書
7. Molecular orbitals and organic chemical reactions. Student ed. (: hbk. ; : pbk.)
Ian Fleming
出版情報: Chichester : John Wiley & Sons, 2009  xv, 360 p. ; 24 cm
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Preface
Molecular Orbital Theory / 1：
The Atomic Orbitals of a Hydrogen Atom / 1.1：
Molecules made from Hydrogen Atoms / 1.2：
C-H and C-C Bonds / 1.2.1：
The Atomic Orbitals of a Carbon Atom / 1.3.1：
Methane / 1.3.2：
Methylene / 1.3.3：
Hybridisation / 1.3.4：
C-C ? Bonds and ? Bonds: Ethane / 1.3.5：
C=C ? Bonds: Ethylene / 1.3.6：
Conjugation-Hückel Theory / 1.4：
The Allyl System / 1.4.1：
Butadiene / 1.4.2：
Longer Conjugated Systems / 1.4.3：
Aromaticity / 1.5：
Aromatic Systems / 1.5.1：
Antiaromatic Systems / 1.5.2：
The Cyclopentadienyl Anion and Cation / 1.5.3：
Homoaromaticity / 1.5.4：
Spiro Conjugation / 1.5.5：
Strained ? Bonds-Cyclopropanes and Cyclobutanes / 1.6：
Cyclopropanes / 1.6.1：
Cyclobutanes / 1.6.2：
Heteronuclear Bonds, C-M, C-X and C=O / 1.7：
Atomic orbital energies and electronegativity / 1.7.1：
C-X ? Bonds / 1.7.2：
C-M ? Bonds / 1.7.3：
C=O ? Bonds / 1.7.4：
Heterocyclic Aromatic Systems / 1.7.5：
The Tau Bond Model / 1.8：
Spectroscopic Methods / 1.9：
Ultraviolet Spectroscopy / 1.9.1：
Photoelectron Spectroscopy / 1.9.2：
Nuclear Magnetic Resonance Spectroscopy / 1.9.3：
Electron Spin Resonance Spectroscopy / 1.9.4：
Exercises / 1.10：
The Structures of Organic Molecules / 2：
The Effects of ? Conjugation / 2.1：
A Notation for Substituents / 2.1.1：
The Effect of Substituents on the Stability of Alkenes / 2.1.2：
The Effect of Substituents on the Stability of Carbocations / 2.1.3：
The Effect of Substituents on the Stability of Carbanions / 2.1.4：
The Effect of Substituents on the Stability of Radicals / 2.1.5：
Energy-Raising Conjugation / 2.1.6：
? Conjugation-Hyperconjugation / 2.2：
C-H and C-C Hyperconjugation / 2.2.1：
C-M Hyperconjugation / 2.2.2：
Negative Hyperconjugation / 2.2.3：
The Configurations and Conformations of Molecules / 2.3：
Restricted Rotation in ?-Conjugated Systems / 2.3.1：
Preferred Conformations from Conjugation in the ? Framework / 2.3.2：
Other Noncovalent Interactions / 2.4：
The Hydrogen Bond / 2.4.1：
Hypervalency / 2.4.2：
Polar Interactions, and van der Waals and other Weak Interactions / 2.4.3：
Chemical Reactions-How Far and How Fast / 2.5：
Factors Affecting the Position of an Equilibrium / 3.1：
The Principle of Hard and Soft Acids and Bases (HSAB) / 3.2：
Transition Structures / 3.3：
The Perturbation Theory of Reactivity / 3.4：
The Salem-Klopman Equation / 3.5：
Hard and Soft Nucleophiles and Electrophiles / 3.6：
Other Factors Affecting Chemical Reactivity / 3.7：
Ionic Reactions-Reactivity / 4：
Single Electron Transfer (SET) in Ionic Reactions / 4.1：
Nucleophilicity / 4.2：
Heteroatom Nucleophiles / 4.2.1：
Solvent Effects / 4.2.2：
Alkene Nucleophiles / 4.2.3：
The ?-Effect / 4.2.4：
Ambident Nucleophiles / 4.3：
Thiocyanate Ion, Cyanide Ion and Nitrite Ion (and the Nitronium Cation) / 4.3.1：
Enolate Ions / 4.3.2：
Allyl Anions / 4.3.3：
Aromatic Electrophilic Substitution / 4.3.4：
Electrophilicity / 4.4：
Trigonal Electrophiles / 4.4.1：
Tetrahedral Electrophiles / 4.4.2：
Hard and Soft Electrophiles / 4.4.3：
Ambident Electrophiles / 4.5：
Aromatic Electrophiles / 4.5.1：
Aliphatic Electrophiles / 4.5.2：
Carbenes / 4.6：
Nucleophilic Carbenes / 4.6.1：
Electrophilic Carbenes / 4.6.2：
Aromatic Carbenes / 4.6.3：
Ionic Reactions-Stereochemistry / 4.7：
The Stereochemistry of the Fundamental Organic Reactions / 5.1：
Substitution at a Saturated Carbon / 5.1.1：
Elimination Reactions / 5.1.2：
Nucleophilic and Electrophilic Attack on a ? Bond / 5.1.3：
The Stereochemistry of Substitution at Trigonal Carbon / 5.1.4：
Diastereoselectivity / 5.2：
Nucleophilic Attack on a Double Bond with Diastereotopic Faces / 5.2.1：
Nucleophilic and Electrophilic Attack on Cycloalkenes / 5.2.2：
Electrophilic Attack on Open-Chain Double Bonds with Diastereotopic Faces / 5.2.3：
Diastereoselective Nucleophilic and Electrophilic Attack on Double Bonds Free of Steric Effects / 5.2.4：
Thermal Pericyclic Reactions / 5.3：
The Four Classes of Pericyclic Reactions / 6.1：
Evidence for the Concertedness of Bond Making and Breaking / 6.2：
Symmetry-Allowed and Symmetry-Forbidden Reactions / 6.3：
The Woodward-Hoffmann Rules-Class by Class / 6.3.1：
The Generalised Woodward-Hoffmann Rule / 6.3.2：
Explanations for the Woodward-Hoffmann Rules / 6.4：
The Aromatic Transition Structure / 6.4.1：
Frontier Orbitals / 6.4.2：
Correlation Diagrams / 6.4.3：
Secondary Effects / 6.5：
The Energies and Coefficients of the Frontier Orbitals of Alkenes and Dienes / 6.5.1：
Diels-Alder Reactions / 6.5.2：
1,3-Dipolar Cycloadditions / 6.5.3：
Other Cycloadditions / 6.5.4：
Other Pericyclic Reactions / 6.5.5：
Periselectivity / 6.5.6：
Torquoselectivity / 6.5.7：
Radical Reactions / 6.6：
Nucleophilic and Electrophilic Radicals / 7.1：
The Abstraction of Hydrogen and Halogen Atoms / 7.2：
The Effect of the Structure of the Radical / 7.2.1：
The Effect of the Structure of the Hydrogen or Halogen Source / 7.2.2：
The Addition of Radicals to ? Bonds / 7.3：
Attack on Substituted Alkenes / 7.3.1：
Attack on Substituted Aromatic Rings / 7.3.2：
Synthetic Applications of the Chemoselectivity of Radicals / 7.4：
Stereochemistry in some Radical Reactions / 7.5：
Ambident Radicals / 7.6：
Neutral Ambident Radicals / 7.6.1：
Charged Ambident Radicals / 7.6.2：
Radical Coupling / 7.7：
Photochemical Reactions / 7.8：
Photochemical Reactions in General / 8.1：
Photochemical Ionic Reactions / 8.2：
Aromatic Nucleophilic Substitution / 8.2.1：
Aromatic Side-Chain Reactivity / 8.2.2：
Photochemical Pericyclic Reactions and Related Stepwise Reactions / 8.3：
The Photochemical Woodward-Hoffmann Rule / 8.3.1：
Regioselectivity of Photocycloadditions / 8.3.2：
Other Kinds of Selectivity in Pericyclic and Related Photochemical Reactions / 8.3.3：
Photochemically Induced Radical Reactions / 8.4：
Chemiluminescence / 8.5：
References / 8.6：
Index
C--H and C--C Bonds
C--C ? Bonds and ? Bonds: Ethane
Conjugation--Hückel Theory
Strained ? Bonds--Cyclopropanes and Cyclobutanes
Heteronueclear Bonds, C--M, C--X and C=O
C--X ? Bonds
C--M ? Bonds
? Conjugation--Hyperconjugation
C--H and C--C Hyperconjugation
C--M Hyperconjugation
Chemical Reactions--How Far and How Fast / 2 5：
Ionic Reactions--Reactivity
Ionic Reactions--Stereochemistry
The Stereochemistry of Subsitution at Trigonal Carbon
The Woodward-Hoffmann Rules--Class by Class
Preface
Molecular Orbital Theory / 1：
The Atomic Orbitals of a Hydrogen Atom / 1.1：
8.

図書
図書
8. Comprehensive organic synthesis : selectivity, strategy & efficiency in modern organic chemistry (: set - v. 9)
editor-in-chief, Barry M. Trost ; deputy editor-in-chief, Ian Fleming
出版情報: Oxford : Pergamon Press, 1991  9 v. ; 28 cm
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Selected chapters: Uncatalyzed Additions of Nucleophilic Alkenes to C=X
Allyl organometallics
Heteroatom-stabilized allylic anions
Propargyl and allenyl organometallics
The Aldol reaction: general acid and base catalysis
The Aldol reaction: group I and group II enolates
The Aldol reaction: group III enolates
Zinc enolates: the Reformatsky and Blaise Reactions
The Aldol reaction: transition metal enolates
The Knoevenagel reaction
The Perkin reaction
Darzens' glycidic ester condensation
Use of enzymatic Aldol reactions in synthesis
Metalloenamines
Hydrazone anions
Catalyzed Additions of Nucleophilic Alkenes to C=X
The Prins and related reactions
Allylsilanes, allylstannanes and related systems
Asymmetric synthesis with enol ethers
Reactions of activated dienes with aldehydes
Addition-Elimination Reactions (Acylations)
The aliphatic Friedel-Crafts reaction
The biomolecular aromatic Friedel-Crafts reaction
The Reimer-Tiemann reaction
The Vilsmeier-Haack reaction
Acylation of esters, ketones and nitriles
The Eschenmoser coupling reaction
Additions of Nucleophilic Alkenes to C=NR and C=NR 2 +
The bimolecular aliphatic Mannich and related reactions
The bimolecular aromatic Mannich reaction
The intramolecular Mannich and related reactions
Additions to Nlt;/i>-acyliminium ions
The Passerini and Ugi reactions
Author index
Subject index
Polar Additions to Activated Alkenes and Alkynes
Stabilized nucleophiles with electron deficient alkenes and alkynes
Conjugate additions of reactive carbanions to activated alkenes and alkynes
Conjugate additions of carbon ligands to activated alkenes and alkynes mediated by Lewis acids
Organocuprates in the conjugate addition reaction
Asymmetric nucleophilic addition to electron deficient alkenes
Nucleophilic addition-electrophilic coupling with a carbanion intermediate
Addition of H-X reagents to alkenes and alkynes
Electrophilic addition of X-Y reagents to alkenes and alkynes
Electrophilic heteroatom cyclizations
Nucleophilic Aromatic Substitutions
Arene substitution via nucleophilic addition to electron deficient arenes
Nucleophilic coupling with aryl radicals
Nucleophilic coupling with arynes
Nucleophilic addition to arene-metal complexes
Polar Additions to Alkenes and Alkynes
Heteroatom nucleophiles with metal-activated alkenes and alkynes
Carbon nucleophiles with alkenes and alkynes
Nucleophiles with allyl-metal complexes
Nucleophiles with cationic pentadienyl-metal complexes
Carbon electrophiles with dienes and polyenes promoted by transition metals
Nonpolar Additions to Alkenes and Alkynes
Radical addition reactions
Radical cyclizations and sequential radical reactions
Vinyl substitutions with organopalladium intermediates
Carbometallation of alkenes and alkynes
Hydroformylation and related additions of carbon monoxide to alkenes and alkynes
Methylene and nonfunctionalized alkylidene transfer to form cyclopropanes
Formation and further transformations of 1,1-dihalocyclopropanes
Addition of ketocarbenes to alkenes, alkynes and aromatic systems
Intermolecular 1,3-dipolar cycloadditions
Intramolecular 1,3-dipolar cycloadditions
Selected contents: Ene Reactions
Ene reactions with alkenes as enophiles
Metallo-ene reactions
[2 + 2] Cycloadditions
Thermal cyclobutane ring formation
Formation of four-membered heterocycles
Di-pgr;-methane photoisomerizations
Oxa-di-pgr;-methane photoisomerizations
[3 + 2] Cycloadditions
Thermal cycloadditions
Transition metal mediated cycloadditions
[4 + 2] Cycloadditions
Intermolecular Diels-Alder reactions
Retrograde Diels-Alder reactions
Higher-Order Cycloadditions
[4 + 3] cycloadditions
[4 + 4] and [6 + 4] cycloadditions
[3 + 2] and [5 + 2] arene-alkene photocyloadditions
Electrocyclic Processes
Cyclobutene ring opening reactions
1,3-cyclohexadiene formation reactions
Nazarov and related cationic cyclizations
Sigmatropic Processes
Cope, oxy-cope and anionic oxy-cope rearrangements
Claisen rearrangements
Consecutive rearrangements
Small-Ring Rearrangements
Rearrangements of vinylcyclopropanes and related systems
Charge-accelerated rearrangements
Other Transition Metal Associated Reactions
The Pauson-Khand reaction
Metal-carbene cycloadditions
Metal-catalyzed cycloaddition of small ring compounds
Selected contents1
Additions to C-X pgr;-Bonds,
Nonstabilized carbanion equivalents / Part 1：
Heteroatom-stabilized carbanion equivalents
Transformation of the carbonyl group into nonhydroxylic groups
Uncatalyzed additions of nucleophilic alkenes to C=X / 2：
Catalyzed additions of nulceophilic alkenes to C=X
Addition-elimination reactions (acylations)
Additions of nucleophilic alkenes to C=NR and C=NR 2 +
Carbon-Carbon sgr;-Bond Formation / 3：
Alkylation of carbon
Coupling reactions
Rearrangement reactions
Other carbon-carbon bond forming reactions
Additions to and Substitutions at C-C pgr;-Bonds / 4：
Polar additions to activated alkenes and alkynes
Nucleophilic aromatic substitutions
Polar additions to alkenes and alkynes
Nonpolar additions to alkenes and alkynes
Combining C-C pgr;-Bonds / 5：
Ene reactions
[2+2] cycloadditions
[3+2] cycloadditions
[4+2] cycloadditions
Higher-order cycloadditions
Electrocyclic processes
Sigmatropic processes
Small-ring rearrangements
Other transition metal associated reactions
Heteroatom Manipulation / 6：
Displacement by substitution processes
Acylation-type reactions
Protecting groups
Functional group interconversion
Elimination reactions
Oxidation / 7：
Oxidation of unactivated C-H bonds
Oxidation of activated C-H bonds
Oxidation of C=C bonds
Oxidation of C-X bonds
Oxidation of C-C bonds
Oxidation of heteroatoms
Special topics
Reduction / 8：
Reduction of C=X bonds
Reduction of X=Y bonds
Reduction of C=C and Cequiv;C bonds
Reduction of C-X to C-H
Indexes / 9：
Cumulative author index
Cumulative subject index
Displacement by Substitution Processes
Synthesis of alcohols and ethers
Synthesis of glycosides
Synthesis of amines and ammonium salts
Synthesis of nitroso, nitro and related compounds
Synthesis of sulfides, sulfoxides and sulfones
Synthesis of phosphonium ylides
Synthesis of halides
Formation of pseudohalides, nitriles and related compounds
Ritter-type reactions
Acylation-Type Reactions
Synthesis of acid halides, anhydrides and related compounds
Synthesis of activated esters and related compounds
Synthesis of amides and related compounds
Synthesis of thioamides and thiolactams
Synthesis of thioesters and thiolactones
Selenoesters of all oxidation states
Synthesis of iminium salts, orthoesters and related compounds
Inorganic acid derivatives
Protecting Groups
Alcohols, amines and thiols, including multiple protecting groups
Functional Group Interconversion
Carbonyl group derivatization
Use of carbonyl derivatives for heterocyclic synthesis
Functional group transformations via carbonyl derivatives
Degradation reactions
Functional group transformation via allyl rearrangement
2,3-sigmatropic rearrangements
Polonovski- and Pummerer-type reactions and the Nef reaction
Elimination Reactions
Eliminations to form alkenes, allenes and alkynes and related reactions
Reductive elimination, vicinal deoxygenation and vicinal desilylation
The Cope elimination, sulfoxide elimination and related thermal reactions
Fragmentation reactions
Selected contents: Oxidation of Unactivated C-H Bonds
Oxidation by chemical methods
Oxidation by nitrene insertion
Oxidation by microbial methods
Oxidation of Activated C-H Bonds
Oxidation adjacent to C=C bonds
Oxidation adjacent to sulfur
Oxidation adjacent to nitrogen
Oxidation adjacent to oxygen of ethers
Oxidation adjacent to oxygen of alcohols by other methods
Synthesis of quinones
Oxidation of C=C Bonds
Addition reactions with formation of carbon-oxygen bonds: (i) General methods of epoxidation
Addition reactions with formation of carbon-oxygen bonds: (iv) The Wacker oxidation and related reactions
Addition reactions with formation of carbon-nitrogen bonds
Cleavage reactions
Oxidation of C-X Bonds
Oxidation of carbon-boron bonds
Oxidation of carbon-metal bonds
Oxidation of carbon-halogen bonds
Oxidation of C-C Bonds
The Baeyer-Villiger reaction
The Beckmann and related reactions
Glycol cleavage reactions
Oxidation of Heteroatoms
Oxidation of nitrogen and phosphorus
Oxidation of sulfur, selenium and tellurium
Special Topics
Oxidation by electrochemical methods
Oxidative rearrangement reactions
Electron transfer oxidation
Selected contents: Reduction of C=X Bonds
Reduction of C=O to CHOH by metal hydrides
Reduction of C=N to CHNH by metal hydrides
Reduction of C=X to CHXH by hydride delivery from carbon
Reduction of C=X to CHXH by dissolving metals and related methods
Reduction of C=X to CHXH by catalytic hydrogenation
Reduction of carboxylic acids to alcohols, ethers and amines
Reduction of carboxylic acids to aldehydes by metal hydrides
Reduction of carboxylic acids to aldehydes by other methods
Reduction of C=X to CH 2 by dissolving metals and related methods
Reduction of X=Y Bonds
Reduction of nitro and nitroso compounds
Reduction of N=N, N-N, N-O and O-O bonds
Reduction of S=O and SO 2 to S, of P=O to P, and of S-X to SH
Reduction of C=C and Cequiv;C Bonds
Heterogeneous catalytic hydrogenation of C=C and Cequiv;C
Homogeneous catalytic hydrogenation of C=C and Cequiv;C
Reduction of C=C and Cequiv;C by noncatalytic chemical methods
Partial and complete reduction of pyridines and their benzo analogs
Hydrozirconation of C=C and Cequiv;C, and hydrometallation by other metals
Hydroboration of C=C and Cequiv;C
Hydroalumination of C=C and Cequiv;C
Hydrosilylation of C=C and Cequiv;C
Reductions of C-X to C-H
Reduction of saturated alkyl halides to alkanes
Reduction of saturated alcohols and amines to alkenes
Reduction of epoxides
Reduction of ketones to alkenes
Hydrogenolysis of allyl and benzyl halides and related compounds
Reduction of agr;-substituted carbonyl compounds-CX-CO- to carbonyl compounds -CH-CO-
Nonstabilized Carbanion Equivalents.
Carbanions of alkali and alkaline earth cations
synthesis and structural characterization / (i)：
selectivity of carbonyl addition reactions / (ii)：
Organoaluminum reagents
Organocopper reagents
Organo-titanium and organo-zirconium reagents
Organochromium reagents
Organo-zinc, -cadmium and -mercury reagents
Organocerium reagents
Samarium and ytterbium reagents
Lewis acid carbonyl complexation
Lewis acid promoted addition reactions of organometallic compounds
Nucleophilic addition to imines and imine derivatives
Nucleophilic addition to carboxylic acid derivatives
Heteroatom-Stabilized Carbanion Equivalents
Nitrogen stabilization
Boron stabilization
Sulfur stabilization
The Benzoin and related reactions
Silicon stabilization
Selenium stabilization
Transformation of the Carbonyl Group into Nonhydroxylic Groups
Alkene synthesis
Epoxidation and related processes
Skeletal reorganizations: chain extension and ring expansion
Alkylation of Carbon
Alkylations of enols and enolates
Alkylations of nitrogen-stabilized carbanions
Alkylations of sulphur-and selenium-stabilized carbanions
Alkylations of other heteroatom-stabilized carbanions
Alkylations of nonstabilized carbanions
Alkylations of vinyl carbanions
Alkylations of alkynyl carbanions
Friedel-Crafts alkylations
Polyene cyclizations
Transannular electrophilic cyclizations
Coupling Reactions
Coupling reactions between sp 3 carbon centers
Coupling reactions between sp 3 and sp 2 carbon centers
Coupling reactions between sp 2 carbon centers
Coupling reactions between sp 2 and sp carbon centers
Coupling reactions between sp carbon centers
Pinacol coupling reactions
Acyloin coupling reactions
Kolbe reactions
Oxidative coupling of phenols and phenol ethers
Rearrangement Reactions
Wagner-Meerwein rearrangements
The Pinacol rearrangement
Acid-catalyzed rearrangements of epoxides
The semipinacol and other rearrangements
Dienone-phenol rearrangements and related reactions
Benzil-benzilic acid rearrangements
The Favorskii rearrangement
The Ramberg-Bauml;cklund rearrangement
The Wolff rearrangement
The Stevens and related rearrangements
The Wittig rearrangement
Other Carbon-Carbon Bond Forming Reactions
Carbonylation and decarbonylation reactions
Carbon-carbon bond formation by C-H insertion
Selected chapters: Uncatalyzed Additions of Nucleophilic Alkenes to C=X
Allyl organometallics
Heteroatom-stabilized allylic anions
9.

図書

東工大
目次DB
図書
東工大
目次DB
9. ペリ環状反応 : 第三の有機反応機構
I.フレミング著 ; 鈴木啓介, 千田憲孝訳
出版情報: 京都 : 化学同人, 2002.6  xi, 143p ; 24cm
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1章 ペリ環状反応とは 1
   1.1 イオン反応,ラジカル反応,そしてペリ環状反応 1
   1.2 4種類のペリ環状反応 3
   1.3 環化付加反応 4
   1.4 電子環状反応 6
   1.5 シグマトロピー転位 6
   1.6 グループ移動反応 8
   【より深く学ぶための参考書】 9
   【問題】 9
2章 環化付加反応 11
   2.1 Diels-Alder反応 11
   2.2 1,3-双極環化付加反応 15
   2.3 カチオンやアニオンの[4+2]環化付加反応 19
   2.4 6個以上の電子が関与する環化付加反応 22
   2.5 許容反応と禁制反応 24
   2.6 光化学的環化付加反応 25
   2.7 環化付加反応の立体化学 26
   2.8 環化付加反応の位置選択性 33
   2.9 分子内環化付加反応 36
   2.10 環化付加反応がすべてペリ環状型というわけではない 37
   2.11 キレトロピー反応 41
   【より深く学ぶための参考書】 42
   【問題】 43
3章 Woodward-Hoffmann則と分子軌道 47
   3.1 結合の形成と解裂の協奏性に関する証拠 47
   3.2 芳香族型の遷移状態 49
   3.3 フロンティア軌道 50
   3.4 相関図 52
   3.5 Woodward-Hoffmann則の環化付加反応への適用 60
   3.6 いくつかの例外的な[2+2]環化付加反応 68
   3.7 二次的効果 73
   【より深く学ぶための参考書】 83
   【問題】 84
4章 電子環状反応 87
   4.1 中性のポリエン 87
   4.2 共役系イオン 88
   4.3 立体化学 91
   4.4 Woodward-Hoffmann則の熱的な電子環状反応への適用 93
   4.5 光化学的電子環状反応 103
   【より深く学ぶための参考書】 105
   【問題】 105
5章 シグマトロピー転位 109
   5.1 [1,n]転位:スプラ面型とアンタラ面型 109
   5.2 [m,n]転位 119
   【より深く学ぶための参考書】 126
   【問題】 126
6章 グループ移動反応 129
   6.1 ジイミド還元およびその関連反応 129
   6.2 エン反応 130
   6.3 逆エン反応と他の熱的な脱離反応 133
   【より深く学ぶための参考書】 134
   【問題】 135
   【総合問題】 135
問題の解答 137
索引 141
1章 ペリ環状反応とは 1
   1.1 イオン反応,ラジカル反応,そしてペリ環状反応 1
   1.2 4種類のペリ環状反応 3
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