| Selected chapters: Uncatalyzed Additions of Nucleophilic Alkenes to C=X |
| Allyl organometallics |
| Heteroatom-stabilized allylic anions |
| Propargyl and allenyl organometallics |
| The Aldol reaction: general acid and base catalysis |
| The Aldol reaction: group I and group II enolates |
| The Aldol reaction: group III enolates |
| Zinc enolates: the Reformatsky and Blaise Reactions |
| The Aldol reaction: transition metal enolates |
| The Knoevenagel reaction |
| The Perkin reaction |
| Darzens' glycidic ester condensation |
| Use of enzymatic Aldol reactions in synthesis |
| Metalloenamines |
| Hydrazone anions |
| Catalyzed Additions of Nucleophilic Alkenes to C=X |
| The Prins and related reactions |
| Allylsilanes, allylstannanes and related systems |
| Asymmetric synthesis with enol ethers |
| Reactions of activated dienes with aldehydes |
| Addition-Elimination Reactions (Acylations) |
| The aliphatic Friedel-Crafts reaction |
| The biomolecular aromatic Friedel-Crafts reaction |
| The Reimer-Tiemann reaction |
| The Vilsmeier-Haack reaction |
| Acylation of esters, ketones and nitriles |
| The Eschenmoser coupling reaction |
| Additions of Nucleophilic Alkenes to C=NR and C=NR 2 + |
| The bimolecular aliphatic Mannich and related reactions |
| The bimolecular aromatic Mannich reaction |
| The intramolecular Mannich and related reactions |
| Additions to Nlt;/i>-acyliminium ions |
| The Passerini and Ugi reactions |
| Author index |
| Subject index |
| Polar Additions to Activated Alkenes and Alkynes |
| Stabilized nucleophiles with electron deficient alkenes and alkynes |
| Conjugate additions of reactive carbanions to activated alkenes and alkynes |
| Conjugate additions of carbon ligands to activated alkenes and alkynes mediated by Lewis acids |
| Organocuprates in the conjugate addition reaction |
| Asymmetric nucleophilic addition to electron deficient alkenes |
| Nucleophilic addition-electrophilic coupling with a carbanion intermediate |
| Addition of H-X reagents to alkenes and alkynes |
| Electrophilic addition of X-Y reagents to alkenes and alkynes |
| Electrophilic heteroatom cyclizations |
| Nucleophilic Aromatic Substitutions |
| Arene substitution via nucleophilic addition to electron deficient arenes |
| Nucleophilic coupling with aryl radicals |
| Nucleophilic coupling with arynes |
| Nucleophilic addition to arene-metal complexes |
| Polar Additions to Alkenes and Alkynes |
| Heteroatom nucleophiles with metal-activated alkenes and alkynes |
| Carbon nucleophiles with alkenes and alkynes |
| Nucleophiles with allyl-metal complexes |
| Nucleophiles with cationic pentadienyl-metal complexes |
| Carbon electrophiles with dienes and polyenes promoted by transition metals |
| Nonpolar Additions to Alkenes and Alkynes |
| Radical addition reactions |
| Radical cyclizations and sequential radical reactions |
| Vinyl substitutions with organopalladium intermediates |
| Carbometallation of alkenes and alkynes |
| Hydroformylation and related additions of carbon monoxide to alkenes and alkynes |
| Methylene and nonfunctionalized alkylidene transfer to form cyclopropanes |
| Formation and further transformations of 1,1-dihalocyclopropanes |
| Addition of ketocarbenes to alkenes, alkynes and aromatic systems |
| Intermolecular 1,3-dipolar cycloadditions |
| Intramolecular 1,3-dipolar cycloadditions |
| Selected contents: Ene Reactions |
| Ene reactions with alkenes as enophiles |
| Metallo-ene reactions |
| [2 + 2] Cycloadditions |
| Thermal cyclobutane ring formation |
| Formation of four-membered heterocycles |
| Di-pgr;-methane photoisomerizations |
| Oxa-di-pgr;-methane photoisomerizations |
| [3 + 2] Cycloadditions |
| Thermal cycloadditions |
| Transition metal mediated cycloadditions |
| [4 + 2] Cycloadditions |
| Intermolecular Diels-Alder reactions |
| Retrograde Diels-Alder reactions |
| Higher-Order Cycloadditions |
| [4 + 3] cycloadditions |
| [4 + 4] and [6 + 4] cycloadditions |
| [3 + 2] and [5 + 2] arene-alkene photocyloadditions |
| Electrocyclic Processes |
| Cyclobutene ring opening reactions |
| 1,3-cyclohexadiene formation reactions |
| Nazarov and related cationic cyclizations |
| Sigmatropic Processes |
| Cope, oxy-cope and anionic oxy-cope rearrangements |
| Claisen rearrangements |
| Consecutive rearrangements |
| Small-Ring Rearrangements |
| Rearrangements of vinylcyclopropanes and related systems |
| Charge-accelerated rearrangements |
| Other Transition Metal Associated Reactions |
| The Pauson-Khand reaction |
| Metal-carbene cycloadditions |
| Metal-catalyzed cycloaddition of small ring compounds |
| Selected contents1 |
| Additions to C-X pgr;-Bonds, |
| Nonstabilized carbanion equivalents / Part 1： |
| Heteroatom-stabilized carbanion equivalents |
| Transformation of the carbonyl group into nonhydroxylic groups |
| Uncatalyzed additions of nucleophilic alkenes to C=X / 2： |
| Catalyzed additions of nulceophilic alkenes to C=X |
| Addition-elimination reactions (acylations) |
| Additions of nucleophilic alkenes to C=NR and C=NR 2 + |
| Carbon-Carbon sgr;-Bond Formation / 3： |
| Alkylation of carbon |
| Coupling reactions |
| Rearrangement reactions |
| Other carbon-carbon bond forming reactions |
| Additions to and Substitutions at C-C pgr;-Bonds / 4： |
| Polar additions to activated alkenes and alkynes |
| Nucleophilic aromatic substitutions |
| Polar additions to alkenes and alkynes |
| Nonpolar additions to alkenes and alkynes |
| Combining C-C pgr;-Bonds / 5： |
| Ene reactions |
| [2+2] cycloadditions |
| [3+2] cycloadditions |
| [4+2] cycloadditions |
| Higher-order cycloadditions |
| Electrocyclic processes |
| Sigmatropic processes |
| Small-ring rearrangements |
| Other transition metal associated reactions |
| Heteroatom Manipulation / 6： |
| Displacement by substitution processes |
| Acylation-type reactions |
| Protecting groups |
| Functional group interconversion |
| Elimination reactions |
| Oxidation / 7： |
| Oxidation of unactivated C-H bonds |
| Oxidation of activated C-H bonds |
| Oxidation of C=C bonds |
| Oxidation of C-X bonds |
| Oxidation of C-C bonds |
| Oxidation of heteroatoms |
| Special topics |
| Reduction / 8： |
| Reduction of C=X bonds |
| Reduction of X=Y bonds |
| Reduction of C=C and Cequiv;C bonds |
| Reduction of C-X to C-H |
| Indexes / 9： |
| Cumulative author index |
| Cumulative subject index |
| Displacement by Substitution Processes |
| Synthesis of alcohols and ethers |
| Synthesis of glycosides |
| Synthesis of amines and ammonium salts |
| Synthesis of nitroso, nitro and related compounds |
| Synthesis of sulfides, sulfoxides and sulfones |
| Synthesis of phosphonium ylides |
| Synthesis of halides |
| Formation of pseudohalides, nitriles and related compounds |
| Ritter-type reactions |
| Acylation-Type Reactions |
| Synthesis of acid halides, anhydrides and related compounds |
| Synthesis of activated esters and related compounds |
| Synthesis of amides and related compounds |
| Synthesis of thioamides and thiolactams |
| Synthesis of thioesters and thiolactones |
| Selenoesters of all oxidation states |
| Synthesis of iminium salts, orthoesters and related compounds |
| Inorganic acid derivatives |
| Protecting Groups |
| Alcohols, amines and thiols, including multiple protecting groups |
| Functional Group Interconversion |
| Carbonyl group derivatization |
| Use of carbonyl derivatives for heterocyclic synthesis |
| Functional group transformations via carbonyl derivatives |
| Degradation reactions |
| Functional group transformation via allyl rearrangement |
| 2,3-sigmatropic rearrangements |
| Polonovski- and Pummerer-type reactions and the Nef reaction |
| Elimination Reactions |
| Eliminations to form alkenes, allenes and alkynes and related reactions |
| Reductive elimination, vicinal deoxygenation and vicinal desilylation |
| The Cope elimination, sulfoxide elimination and related thermal reactions |
| Fragmentation reactions |
| Selected contents: Oxidation of Unactivated C-H Bonds |
| Oxidation by chemical methods |
| Oxidation by nitrene insertion |
| Oxidation by microbial methods |
| Oxidation of Activated C-H Bonds |
| Oxidation adjacent to C=C bonds |
| Oxidation adjacent to sulfur |
| Oxidation adjacent to nitrogen |
| Oxidation adjacent to oxygen of ethers |
| Oxidation adjacent to oxygen of alcohols by other methods |
| Synthesis of quinones |
| Oxidation of C=C Bonds |
| Addition reactions with formation of carbon-oxygen bonds: (i) General methods of epoxidation |
| Addition reactions with formation of carbon-oxygen bonds: (iv) The Wacker oxidation and related reactions |
| Addition reactions with formation of carbon-nitrogen bonds |
| Cleavage reactions |
| Oxidation of C-X Bonds |
| Oxidation of carbon-boron bonds |
| Oxidation of carbon-metal bonds |
| Oxidation of carbon-halogen bonds |
| Oxidation of C-C Bonds |
| The Baeyer-Villiger reaction |
| The Beckmann and related reactions |
| Glycol cleavage reactions |
| Oxidation of Heteroatoms |
| Oxidation of nitrogen and phosphorus |
| Oxidation of sulfur, selenium and tellurium |
| Special Topics |
| Oxidation by electrochemical methods |
| Oxidative rearrangement reactions |
| Electron transfer oxidation |
| Selected contents: Reduction of C=X Bonds |
| Reduction of C=O to CHOH by metal hydrides |
| Reduction of C=N to CHNH by metal hydrides |
| Reduction of C=X to CHXH by hydride delivery from carbon |
| Reduction of C=X to CHXH by dissolving metals and related methods |
| Reduction of C=X to CHXH by catalytic hydrogenation |
| Reduction of carboxylic acids to alcohols, ethers and amines |
| Reduction of carboxylic acids to aldehydes by metal hydrides |
| Reduction of carboxylic acids to aldehydes by other methods |
| Reduction of C=X to CH 2 by dissolving metals and related methods |
| Reduction of X=Y Bonds |
| Reduction of nitro and nitroso compounds |
| Reduction of N=N, N-N, N-O and O-O bonds |
| Reduction of S=O and SO 2 to S, of P=O to P, and of S-X to SH |
| Reduction of C=C and Cequiv;C Bonds |
| Heterogeneous catalytic hydrogenation of C=C and Cequiv;C |
| Homogeneous catalytic hydrogenation of C=C and Cequiv;C |
| Reduction of C=C and Cequiv;C by noncatalytic chemical methods |
| Partial and complete reduction of pyridines and their benzo analogs |
| Hydrozirconation of C=C and Cequiv;C, and hydrometallation by other metals |
| Hydroboration of C=C and Cequiv;C |
| Hydroalumination of C=C and Cequiv;C |
| Hydrosilylation of C=C and Cequiv;C |
| Reductions of C-X to C-H |
| Reduction of saturated alkyl halides to alkanes |
| Reduction of saturated alcohols and amines to alkenes |
| Reduction of epoxides |
| Reduction of ketones to alkenes |
| Hydrogenolysis of allyl and benzyl halides and related compounds |
| Reduction of agr;-substituted carbonyl compounds-CX-CO- to carbonyl compounds -CH-CO- |
| Nonstabilized Carbanion Equivalents. |
| Carbanions of alkali and alkaline earth cations |
| synthesis and structural characterization / (i)： |
| selectivity of carbonyl addition reactions / (ii)： |
| Organoaluminum reagents |
| Organocopper reagents |
| Organo-titanium and organo-zirconium reagents |
| Organochromium reagents |
| Organo-zinc, -cadmium and -mercury reagents |
| Organocerium reagents |
| Samarium and ytterbium reagents |
| Lewis acid carbonyl complexation |
| Lewis acid promoted addition reactions of organometallic compounds |
| Nucleophilic addition to imines and imine derivatives |
| Nucleophilic addition to carboxylic acid derivatives |
| Heteroatom-Stabilized Carbanion Equivalents |
| Nitrogen stabilization |
| Boron stabilization |
| Sulfur stabilization |
| The Benzoin and related reactions |
| Silicon stabilization |
| Selenium stabilization |
| Transformation of the Carbonyl Group into Nonhydroxylic Groups |
| Alkene synthesis |
| Epoxidation and related processes |
| Skeletal reorganizations: chain extension and ring expansion |
| Alkylation of Carbon |
| Alkylations of enols and enolates |
| Alkylations of nitrogen-stabilized carbanions |
| Alkylations of sulphur-and selenium-stabilized carbanions |
| Alkylations of other heteroatom-stabilized carbanions |
| Alkylations of nonstabilized carbanions |
| Alkylations of vinyl carbanions |
| Alkylations of alkynyl carbanions |
| Friedel-Crafts alkylations |
| Polyene cyclizations |
| Transannular electrophilic cyclizations |
| Coupling Reactions |
| Coupling reactions between sp 3 carbon centers |
| Coupling reactions between sp 3 and sp 2 carbon centers |
| Coupling reactions between sp 2 carbon centers |
| Coupling reactions between sp 2 and sp carbon centers |
| Coupling reactions between sp carbon centers |
| Pinacol coupling reactions |
| Acyloin coupling reactions |
| Kolbe reactions |
| Oxidative coupling of phenols and phenol ethers |
| Rearrangement Reactions |
| Wagner-Meerwein rearrangements |
| The Pinacol rearrangement |
| Acid-catalyzed rearrangements of epoxides |
| The semipinacol and other rearrangements |
| Dienone-phenol rearrangements and related reactions |
| Benzil-benzilic acid rearrangements |
| The Favorskii rearrangement |
| The Ramberg-Bauml;cklund rearrangement |
| The Wolff rearrangement |
| The Stevens and related rearrangements |
| The Wittig rearrangement |
| Other Carbon-Carbon Bond Forming Reactions |
| Carbonylation and decarbonylation reactions |
| Carbon-carbon bond formation by C-H insertion |
図書
Modern catalytic methods for organic synthesis with diazo compounds : from cyclopropanes to ylides